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    • 1. 发明授权
    • Production of beta form pigmentary copper phthalocyanine
    • 生产β型色素铜酞菁
    • US5449774A
    • 1995-09-12
    • US678482
    • 1991-04-01
    • Ian A. LambieMichael D. McFarlaneRobert Langley
    • Ian A. LambieMichael D. McFarlaneRobert Langley
    • C09B47/06C09B67/00C09B67/18C09B67/20C09B67/50C09B47/04
    • C09B67/002C09B67/0032
    • The present invention provides a process for producing beta-form pigmentary copper phthalocyanine comprising a) producing crude copper phthalocyanine by charging phthalic anhydride or phthalimide, urea, a copper compound and a catalyst, at a substantially continuous and uniform rate, into a reaction chamber containing dry, granular, pre-formed copper phthalocyanine, and removing the reaction product from the reaction chamber; and b) convening the crude copper phthalocyanine produced in step a) into pigmentary form, by milling it either in the dry state or in an aqueous medium; mixing the milled material with an aqueous emulsion comprising i) a liquid C.sub.6 -C.sub.20 amine which is insoluble in water or alkali but is soluble in acid and ii) a surfactant capable of emulsifying the liquid amine; rendering the resulting mixture acidic to thereby dissolve the amine; and finally separating the desired pigmentary copper phthalocyanine from the treatment mixture.
    • 本发明提供了一种生产β-型颜料铜酞菁的方法,其包括:a)通过将邻苯二甲酸酐或邻苯二甲酰亚胺,尿素,铜化合物和催化剂以基本上连续和均匀的速率加入到含有 干燥,粒状,预形成的铜酞菁,并从反应室中除去反应产物; 和b)将步骤a)中制备的粗铜酞菁通过在干燥状态下或在水性介质中研磨而成为颜料形式; 将研磨的材料与水乳液混合,其包括i)不溶于水或碱但可溶于酸的液体C6-C20胺,和ii)能够乳化液体胺的表面活性剂; 使得到的混合物呈酸性,从而溶解胺; 最后从处理混合物中分离所需的颜料铜酞菁。