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1. 发明申请

US20160083406A1 EXTRACTION SOLVENT CONTROL FOR REDUCING STABLE EMULSIONS 有权
标题翻译：用于降低稳定乳液的萃取溶剂控制
公开(公告)号：US20160083406A1
公开(公告)日：2016-03-24
申请号：US14962095
申请日：2015-12-08
申请人： INVISTA NORTH AMERICA S.A R.L.
发明人： William J. TENN, III , Sudhir N.V.K. AKI , Thomas E. VOS , Tseng H. CHAO
IPC分类号： C07F9/48 , B01D11/04 , B01J31/18 , B01J38/56 , B01J31/40
CPC分类号： C07F9/4841 , B01D11/0426 , B01D11/0434 , B01D11/0488 , B01D11/0492 , B01D2011/002 , B01J31/1865 , B01J31/4053 , B01J38/56 , B01J2231/343 , B01J2531/847 , Y02P20/582 , Y02P20/584
摘要： Disclosed herein are methods for recovering diphosphonite-containing compounds from mixtures comprising organic mononitriles and organic dinitriles, using liquid-liquid extraction. Also disclosed are treatments to enhance extractability of the diphosphonite-containing compounds.
摘要翻译：本文公开了使用液 - 液萃取从含有有机单腈和有机二腈的混合物中回收含二亚磷酸盐的化合物的方法。还公开了用于提高含有二亚磷酸盐的化合物的提取性的处理。

2. 发明申请

US20150299106A1 PENTENENITRILE ISOMERIZATION 有权
标题翻译： PENTENENITRILE异构化
公开(公告)号：US20150299106A1
公开(公告)日：2015-10-22
申请号：US14649644
申请日：2013-12-05
申请人： INVISTA NORTH AMERICA S.A. R.L.
发明人： Sudhir N.V.K. AKI , William J. TENN, III , Thomas E. VOS
IPC分类号： C07C253/30 , B01J21/08 , B01J27/053 , B01J23/30 , B01J23/44 , B01J23/06 , B01J23/26 , B01J23/20 , B01J29/18 , B01J23/10 , B01J21/10
CPC分类号： C07C253/30 , B01J21/08 , B01J21/10 , B01J23/06 , B01J23/10 , B01J23/20 , B01J23/26 , B01J23/30 , B01J23/44 , B01J27/053 , B01J29/18 , C07C255/07
摘要： Disclosed is a process for isomerizing cis-2-pentenenitrile to 3-pentenenitrile in the presence of a non-aluminium metal oxide catalyst, wherein: (a) the metal in the catalyst has an oxidation state in the range from +1 to +4; (b) the metal has a cation radius in the range from 0.35 to 1.0 Å; (c) the metal of the catalyst has a polarising power, C/r, is in the range from 2 to >8, wherein C is the charge of the metal and r is the ionic radius in Å; (d) the bond network of the catalyst has a % ionicity of >20; (e) the metal oxide has an acidity strength in the range from strong to very weak; and (f) the metal oxide has a basicity (nucleophilicity) strength of weak to strong.
摘要翻译：公开了一种在非铝金属氧化物催化剂存在下将顺式-2-戊烯腈异构化为3-戊烯腈的方法，其中：（a）催化剂中的金属的氧化态为+1至+4 ; （b）金属的阳离子半径在0.35至1.0的范围内; （c）催化剂的金属具有极化功率，C / r在2至> 8的范围内，其中C是金属的电荷，r是的离子半径; （d）催化剂的键合网络具有> 20的％离子性; （e）金属氧化物的酸度强度在强到非常弱的范围内; 和（f）金属氧化物具有弱至强的碱性（亲核性）强度。

3. 发明申请

US20150368189A1 PENTENENITRILE ISOMERIZATION 有权
标题翻译： PENTENENITRILE异构化
公开(公告)号：US20150368189A1
公开(公告)日：2015-12-24
申请号：US14649634
申请日：2013-12-05
申请人： INVISTA NORTH AMERICA S.A R.L.
发明人： Sudhir N.V.K. AKI , William J. TENN, III , Thomas E. VOS
IPC分类号： C07C253/30
CPC分类号： C07C253/30 , C07C255/07
摘要： Pentenenitrile oligomers formed in a process for isomerizing cis-2-pentenenitrile to 3-pentenenitrile are minimized in the presence of an aluminium oxide catalyst. The process comprises providing an aluminium oxide catalyst having an alkali metal and/or alkaline earth metal and/or iron content, measured in the form of alkali metal oxide and/or alkaline earth metal oxide and/or iron oxide, respectively of less than 5000 ppm by weight.
摘要翻译：在氧化铝催化剂存在下使在顺式-2-戊烯腈异构化为3-戊烯腈的方法中形成的戊烯腈低聚物最小化。该方法包括提供具有碱金属和/或碱土金属和/或铁含量的氧化铝催化剂，其以碱金属氧化物和/或碱土金属氧化物和/或氧化铁的形式分别测量为小于5000 重量ppm。

4. 发明申请

US20150314280A1 COMPOSITION FOR IMPROVED NICKEL-LIGAND SOLUBILITY 有权
标题翻译：用于改善镍基配体溶解性的组合物
公开(公告)号：US20150314280A1
公开(公告)日：2015-11-05
申请号：US14649648
申请日：2013-12-06
申请人： INVISTA NORTH AMERICA S.A R.L.
发明人： Thomas E. VOS
IPC分类号： B01J31/18 , B01J37/00 , C07C253/10
CPC分类号： B01J31/185 , B01J37/00 , B01J2231/322 , B01J2531/847 , B01J2531/90 , C07C253/10 , C07C255/07 , C07C255/04
摘要： In the hydrocyanation reaction of butadiene proceeding through pentenenitriles to adiponitrile, catalysis by complexes of zerovalent nickel with bidentate phosphorus-based ligands of the NiL2A type wherein L2 is a bidentate ligand and A is an unsaturated compound, can be rate-limited by the solubility of the catalytic complex. The present invention concerns solvent compositions for the nickel-ligand complex comprising mixtures of unsaturated nitriles that provide for increased metal solubility, particularly in the absence of a Lewis acid promoter, resulting in higher hydrocyanation reaction rates in an industrial-scale process for production of important nylon manufacturing intermediates. The mixed nitrile solvent compositions can include mixtures of pentenenitriles and/or methylbutenenitriles. The mixtures of mixed unsaturated nitriles can be, at least in part, from recycle streams from the hydrocyanation reaction for which the nickel-bidentate ligand complexes are used as catalysts.
摘要翻译：在通过戊烯腈进行己二腈的丁二烯的氢氰化反应中，通过与零价镍的络合物与NiL2A型的二齿磷系配体的催化作用，其中L2是双齿配体，A是不饱和化合物，可以通过溶解度进行速率限制催化复合物。本发明涉及用于镍 - 配体络合物的溶剂组合物，其包含不饱和腈的混合物，其提供增加的金属溶解度，特别是在不存在路易斯酸促进剂的情况下，导致在工业规模过程中较高的氢氰化反应速率用于生产重要的尼龙制造中间体。混合的腈溶剂组合物可以包括戊烯腈和/或甲基丁烯腈的混合物。混合的不饱和腈的混合物可以至少部分地来自使用镍二齿配位体配合物作为催化剂的氢化氰化反应的再循环流。

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