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    • 4. 发明申请
    • PROCESS FOR PRODUCTION OF HYDROCARBONS WITH CATALYST CONDITIONING
    • 用催化剂条件生产碳氢化合物的方法
    • US20130158139A1
    • 2013-06-20
    • US13712232
    • 2012-12-12
    • IFP ENERGIES NOUVELLES
    • Marie-Claire MARIONFabrice DIEHLFrancois HUGUES
    • C10G2/00
    • C10G2/332B01J21/12B01J23/75B01J23/83B01J23/8892B01J23/8896B01J23/8913B01J37/0201B01J37/18
    • A method for continuous production of hydrocarbons from synthesis gas in the presence of a cobalt-based catalyst which comprises a step of providing synthesis gas from a source (1) of synthesis gas in a Fischer-Tropsch synthesis reactor (4). The method also includes the following steps: a) conditioning of the catalyst in reduced state in a conditioning reactor (2) by contact with a flow of reducing gas from a synthesis gas source supplying the synthesis reactor, the reducing conditioning gas comprising carbon monoxide (CO) or a mixture comprising hydrogen (H2) and carbon monoxide (CO), the H2/CO molar ratio of which is between 0.1 and 0.9, at a temperature between 200 and 500° C., and a total pressure between 0.1 and 5 MPa and under a gas flow between 1 and 20 NI/h/g of catalyst to be treated, b) supply of reduced catalyst conditioned in step a) to the synthesis reactor (4).
    • 一种在钴基催化剂存在下从合成气中连续生产烃的方法,该方法包括在费 - 托合成反应器(4)中从合成气源(1)提供合成气的步骤。 该方法还包括以下步骤:a)通过与供应合成反应器的合成气源的还原气体流接触,调节反应器(2)中处于还原状态的催化剂,还原调节气体包括一氧化碳( CO)或H 2 / CO摩尔比为0.1-0.9之间的氢(H 2)和一氧化碳(CO)的混合物,温度为200-500℃,总压力为0.1-5 MPa,并且在待处理催化剂的1至20Ni / h / g之间的气流下,b)将在步骤a)中调节的还原催化剂供应到合成反应器(4)。