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1. 发明授权

US06218460B1 Fibers flash-spun from fully halogenated polymers 有权
标题翻译：从完全卤化的聚合物闪光的纤维
公开(公告)号：US06218460B1
公开(公告)日：2001-04-17
申请号：US09346411
申请日：1999-07-01
申请人： Hyunkook Shin , William H. Tuminello
发明人： Hyunkook Shin , William H. Tuminello
IPC分类号： D01D511
CPC分类号： D01F6/18 , D01D5/11 , D01F6/32
摘要： A flash-spun material comprised of at least 90% by weight of polymers selected from the groups A, B, and C; wherein group A comprises polymers with a melting point above 280° C. that are comprised of halocarbon polymers in which at least 20% of the total number of halogen atoms in each halocarbon polymer are fluorine atoms; wherein group B comprises polymers with a melting point above 280° C. that are comprised of oxyhalocarbon polymers in which at least 20% of the total number of halogen atoms in each oxyhalocarbon polymer are fluorine atoms; and wherein group C comprises fully halogenated, highly fluorinated ion exchange polymers. A process for producing such flash-spun material and a solvent for producing such flash-spun material are also provided.
摘要翻译：由至少90重量％选自A，B和C组的聚合物组成的闪纺材料; 其中组A包括熔点高于280℃的聚合物，其由卤代烃聚合物组成，其中每个卤代烃聚合物中卤素原子总数的至少20％是氟原子; 其中组B包含熔点高于280℃的聚合物，其由卤代烃聚合物组成，其中每个卤代烃聚合物中卤素原子总数的至少20％是氟原子; 并且其中基团C包括完全卤化的高度氟化的离子交换聚合物。还提供了这种闪纺材料的制造方法和用于制造这种闪纺材料的溶剂。

2. 发明授权

US5459191A Solvents for tetrafluoroethylene polymers 失效
标题翻译：四氟乙烯聚合物溶剂
公开(公告)号：US5459191A
公开(公告)日：1995-10-17
申请号：US220477
申请日：1994-03-31
申请人： William H. Tuminello , Robert J. Cavanaugh
发明人： William H. Tuminello , Robert J. Cavanaugh
IPC分类号： C08J3/09 , C08J5/18 , D01F6/12 , C08J5/02
CPC分类号： C08J3/093 , C08J5/18 , D01F6/12 , C08J2327/18
摘要： Perfluorinated cycloalkane solvents for dissolving high melting polymers containing tetrafluoroethylene, are disclosed. These solvents dissolve such polymers more rapidly, and/or are more stable, than previously known solvents. Also disclosed is a process for dissolution of the polymers and their resulting solutions. The solutions are useful for making polymer films, coatings and for encapsulating objects.
摘要翻译：公开了用于溶解含有四氟乙烯的高熔点聚合物的全氟化环烷烃溶剂。这些溶剂比以前已知的溶剂更快地溶解这种聚合物，和/或更稳定。还公开了一种溶解聚合物及其所得溶液的方法。该溶液可用于制备聚合物膜，涂层和封装物体。

3. 发明授权

US5356663A Process for making and repairing ion exchange membranes and films 失效
标题翻译：制造和修复离子交换膜和膜的方法
公开(公告)号：US5356663A
公开(公告)日：1994-10-18
申请号：US89022
申请日：1993-07-14
申请人： Stephen A. Perusich , William H. Tuminello , Shoibal Banerjee
发明人： Stephen A. Perusich , William H. Tuminello , Shoibal Banerjee
IPC分类号： C08J5/22 , C08J3/09 , C09D127/12 , H01M8/02 , B32B35/00
CPC分类号： C08J3/091 , C08J2327/12
摘要： Ion exchange membranes or films are made from a solution of perfluorinated cycloalkanes, perfluorinated aromatic compounds and perfluorotrialkyl amines having a critical temperature greater than 150.degree. C. and certain carboxylic fluorinated polymers having an equivalent weight greater than 900. A process for repairing ion exchange membranes and films by spray coating the surface of the membrane or film with the solution is also claimed. The ion exchange membranes and films are useful in chloroalkali cells or fuel cells.
摘要翻译：离子交换膜或膜由全氟化环烷烃，全氟化芳族化合物和临界温度大于150℃的全氟三烷基胺溶液和某些当量重量大于900的羧基氟化聚合物的溶液制成。一种修复离子交换膜的方法并且还要求保护通过用溶液喷涂膜或膜的表面的膜。离子交换膜和膜可用于氯碱细胞或燃料电池。

4. 发明申请

US20100317750A1 Process and Catalyst for Production of Mixed Alcohols from Synthesis Gas 有权
标题翻译：从合成气体生产混合醇的工艺和催化剂
公开(公告)号：US20100317750A1
公开(公告)日：2010-12-16
申请号：US12298733
申请日：2007-04-27
申请人： Andrew J. Lucero , Vijay K. Sethi , William H. Tuminello
发明人： Andrew J. Lucero , Vijay K. Sethi , William H. Tuminello
IPC分类号： C07C27/06
CPC分类号： B01J23/883 , B01J23/755 , B01J27/22 , B01J35/0006 , B01J37/084 , B01J37/18 , B22F9/22 , B22F2999/00 , C01B32/20 , C07C29/156 , C22C29/067 , Y02P20/52 , B22F2201/013 , B22F2201/30 , B22F2202/00 , B22F2203/11 , C07C31/04 , C07C31/08
摘要： At least one embodiment of the inventive technology focuses on a new composition that comprises hexagonally close packed molybdenum carbide crystals, in addition to metallic nickel crystals and/or sodium, and having use as a catalyst in a Fischer-Tropsch process to produce alcohol. At least one embodiment of a related aspect of the inventive technology is a Fischer-Tropsch reaction to produce alcohols from carbon monoxide and hydrogen using the aforementioned composition to catalyze reactions producing higher alcohols.
摘要翻译：本发明技术的至少一个实施方案集中在除了金属镍晶体和/或钠之外还包括六边形紧密堆积的碳化钼晶体的新组合物，并且在费 - 托法中用作催化剂以产生醇。本发明技术的相关方面的至少一个实施方案是使用上述组合物从一氧化碳和氢气产生醇催化产生高级醇的反应的费 - 托反应。

5. 发明授权

US5364929A Dissolution of tetrafluoroethylene polymers at superautogenous pressure 失效
标题翻译：四氟乙烯聚合物在超级压力下溶解
公开(公告)号：US5364929A
公开(公告)日：1994-11-15
申请号：US3762
申请日：1993-01-13
申请人： Gregory T. Dee , William H. Tuminello
发明人： Gregory T. Dee , William H. Tuminello
IPC分类号： C08J3/09 , C08L27/12 , C08L27/18 , C08K5/20 , C08F6/00
CPC分类号： C08J3/093 , C08J2327/18
摘要： Disclosed herein is a process for dissolving high melting polymers containing tetrafluoroethylene units at pressures greater than autogenous pressure, using selected halogenated solvents that are often not solvents at autogenous pressure. Also disclosed are the solutions resulting from this process. The solutions are useful for preparing fibers and paper-like webs from these polymers.
摘要翻译：本文公开了一种使用在自生压力下通常不是溶剂的选择的卤化溶剂来溶解含有四氟乙烯单元的压力高于自生压力的高熔点聚合物的方法。还公开了由该方法产生的解决方案。该溶液可用于从这些聚合物制备纤维和纸状网。

6. 发明授权

US5237049A Purification and adhesion of fluoropolymers 失效
标题翻译：含氟聚合物的净化和粘附
公开(公告)号：US5237049A
公开(公告)日：1993-08-17
申请号：US936446
申请日：1992-08-28
申请人： Robert J. Cavanaugh , William H. Tuminello
发明人： Robert J. Cavanaugh , William H. Tuminello
IPC分类号： C08F14/18 , B05D5/08 , C08F6/00 , C08F6/04 , C08F6/06 , C08J3/09 , C08J5/12 , C09J201/04
CPC分类号： C08J5/122 , B05D5/083 , C08F6/04 , C08J3/093 , C08J5/125 , C09J201/04 , C08J2327/12
摘要： A process for purifying fluoropolymers by contacting them at temperatures above 140.degree. C. with a liquid perfluorinated cycloalkane. The resulting polymers are particularly useful where polymers with reduced impurities are desirable, such as in medical devices and in parts for the semiconductor manufacturing industry. The liquid perfluorinated cycloalkanes improve the adhesion of fluoropolymer to themselves and other materials.
摘要翻译：通过在140℃以上的温度下与液态全氟化环烷烃接触来纯化含氟聚合物的方法。所得到的聚合物特别适用于需要减少杂质的聚合物，例如在医疗装置和用于半导体制造业的部件中。液体全氟化环烷烃改善了含氟聚合物对自身和其他材料的粘附性。

7. 发明授权

US08048933B2 Process and catalyst for production of mixed alcohols from synthesis gas 有权
标题翻译：从合成气生产混合醇的工艺和催化剂
公开(公告)号：US08048933B2
公开(公告)日：2011-11-01
申请号：US12298733
申请日：2007-04-27
申请人： Andrew J. Lucero , Vijay K. Sethi , William H. Tuminello
发明人： Andrew J. Lucero , Vijay K. Sethi , William H. Tuminello
IPC分类号： C07C27/00
CPC分类号： B01J23/883 , B01J23/755 , B01J27/22 , B01J35/0006 , B01J37/084 , B01J37/18 , B22F9/22 , B22F2999/00 , C01B32/20 , C07C29/156 , C22C29/067 , Y02P20/52 , B22F2201/013 , B22F2201/30 , B22F2202/00 , B22F2203/11 , C07C31/04 , C07C31/08
摘要： At least one embodiment of the inventive technology focuses on a new composition that comprises hexagonally close packed molybdenum carbide crystals, in addition to metallic nickel crystals and/or sodium, and having use as a catalyst in a Fischer-Tropsch process to produce alcohol. At least one embodiment of a related aspect of the inventive technology is a Fischer-Tropsch reaction to produce alcohols from carbon monoxide and hydrogen using the aforementioned composition to catalyze reactions producing higher alcohols.
摘要翻译：本发明技术的至少一个实施方案集中在除了金属镍晶体和/或钠之外还包括六边形紧密堆积的碳化钼晶体的新组合物，并且在费 - 托法中用作催化剂以产生醇。本发明技术的相关方面的至少一个实施方案是使用上述组合物从一氧化碳和氢气产生醇催化产生高级醇的反应的费 - 托反应。

8. 发明授权

US5328946A Solvents for tetrafluoroethylene polymers 失效
标题翻译：四氟乙烯聚合物溶剂
公开(公告)号：US5328946A
公开(公告)日：1994-07-12
申请号：US936449
申请日：1992-08-28
申请人： William H. Tuminello , Robert J. Cavanaugh
发明人： William H. Tuminello , Robert J. Cavanaugh
IPC分类号： C08J3/09 , C08J3/11 , C08J5/18 , C08L27/12 , C08L27/18 , D01F6/12 , C08J5/02
CPC分类号： C08J3/093 , C08J5/18 , D01F6/12 , C08J2327/18
摘要： Perfluorinated cycloalkane solvents for dissolving high melting polymers containing tetrafluoroethylene, are disclosed. These solvents dissolve such polymers more rapidly, and/or are more stable, than previously known solvents. Also disclosed is a process for dissolution of the polymers and their resulting solutions. The solutions are useful for making polymer films, coatings and for encapsulating objects.
摘要翻译：公开了用于溶解含有四氟乙烯的高熔点聚合物的全氟化环烷烃溶剂。这些溶剂比以前已知的溶剂更快地溶解这种聚合物，和/或更稳定。还公开了一种溶解聚合物及其所得溶液的方法。该溶液可用于制备聚合物膜，涂层和封装物体。

9. 发明授权

US5273694A Process for making ion exchange membranes and films 失效
标题翻译：制造离子交换膜和膜的方法
公开(公告)号：US5273694A
公开(公告)日：1993-12-28
申请号：US935350
申请日：1992-08-28
申请人： Stephen A. Perusich , William H. Tuminello , Shoibal Banerjee
发明人： Stephen A. Perusich , William H. Tuminello , Shoibal Banerjee
IPC分类号： C08J5/22 , C08J3/09 , C09D127/12 , H01M8/02 , B29C67/20
CPC分类号： C08J3/091 , C08J2327/12
摘要： Ion exchange membranes or films are made from a solution of perfluorinated cycloalkanes, perfluorinated aromatic compounds and perfluorotrialkyl amines having a critical temperature greater than 150.degree. C. and certain carboxylic fluorinated polymers having an equivalent weight greater than 900. A process for repairing ion exchange membranes and films by spray coating the surface of the membrane or film with the solution is also disclosed. The ion exchange membranes and films are useful in chloralkali cells or fuel cells.
摘要翻译：离子交换膜或膜由全氟化环烷烃，全氟化芳族化合物和临界温度大于150℃的全氟三烷基胺溶液和某些当量重量大于900的羧基氟化聚合物的溶液制成。一种修复离子交换膜的方法并且还公开了通过用溶液喷涂膜或膜的表面的膜。离子交换膜和膜可用于氯碱槽或燃料电池。

10. 发明授权

US5397829A Low-melting tetrafluoroethylene copolymer and its uses 失效
标题翻译：低熔点四氟乙烯共聚物及其用途
公开(公告)号：US5397829A
公开(公告)日：1995-03-14
申请号：US156621
申请日：1993-11-23
申请人： Richard A. Morgan , William H. Tuminello , Mark E. Wagman
发明人： Richard A. Morgan , William H. Tuminello , Mark E. Wagman
IPC分类号： C08J3/11 , B29C47/00 , B29C65/48 , B29K23/00 , B32B27/30 , C08F214/26 , C08J5/12 , C08L23/00 , C08L23/02 , C08L27/00 , C08L27/12 , C08L27/18 , C09D127/12 , C09D127/18 , C09J127/12 , C09J127/18 , C08K5/02 , C08K5/03
CPC分类号： C09D127/18 , C08F214/26 , C08L23/02 , C08L23/16 , C08L27/18 , C08L27/20
摘要： Copolymers of tetrafluoroethylene (TFE) and hexafluoropropylene (HFP) having high HFP content and end-of-melting temperature, T.sub.m (end), as low as 200.degree. C. are disclosed. Exceptional performance as a processing aid in polyolefins results from having T.sub.m (end) of the TFE/HFP copolymer close to the processing temperature of the polyolefin. These TFE/HFP copolymers are soluble in fluorinated cyclic solvents. Copolymer/solvent systems copolymer at significant concentrations in selected solvents are fluid and stable at room temperature.
摘要翻译：公开了具有高HFP含量和末端熔融温度Tm（末端）低至200℃的四氟乙烯（TFE）和六氟丙烯（HFP）的共聚物。由于TFE / HFP共聚物的Tm（末端）接近聚烯烃的加工温度，所以作为聚烯烃的加工助剂具有卓越的性能。这些TFE / HFP共聚物可溶于氟化环状溶剂。在选择的溶剂中显着浓度的共聚物/溶剂体系共聚物在室温下是流动性和稳定性的。

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