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1. 发明申请

US20140039231A1 HYDROGEN RECYCLE AND HYDROGEN CLORIDE RECOVERY IN AN ALKYLATION PROCESS 有权
标题翻译：在氢化过程中氢回收和氢气回收
公开(公告)号：US20140039231A1
公开(公告)日：2014-02-06
申请号：US13563385
申请日：2012-07-31
申请人： Hye Kyung Cho Timken , Robert Fletcher Cleverdon , Bong-Kyu Chang , Donald Henry Mohr , Christine Marie Phillips
发明人： Hye Kyung Cho Timken , Robert Fletcher Cleverdon , Bong-Kyu Chang , Donald Henry Mohr , Christine Marie Phillips
IPC分类号： B01D3/00 , C07C2/58 , C07C5/02
CPC分类号： B01D3/009 , B01J31/0277 , C07C2/58 , C07C5/02 , C10G29/205
摘要： We provide an alkylation process, comprising: separating and recycling a hydrogen gas and a hydrogen chloride from an offgas of a hydrogenation reactor; wherein the hydrogen gas is recycled to the hydrogenation reactor; and wherein the hydrogen chloride is recycled to an alkylation reactor. We also provide an alkylation process unit for performing this process.
摘要翻译：我们提供烷基化方法，包括：从氢化反应器的废气中分离和再循环氢气和氯化氢; 其中氢气被再循环到氢化反应器中; 并且其中氯化氢被再循环到烷基化反应器中。我们还提供了一个用于执行此过程的烷基化处理单元。

2. 发明授权

US09233316B2 Hydrogen recycle and hydrogen chloride recovery in an alkylation process 有权
标题翻译：在烷基化过程中氢循环和氯化氢回收
公开(公告)号：US09233316B2
公开(公告)日：2016-01-12
申请号：US13563385
申请日：2012-07-31
申请人： Hye Kyung Cho Timken , Robert Fletcher Cleverdon , Bong-Kyu Chang , Donald Henry Mohr , Christine Marie Phillips
发明人： Hye Kyung Cho Timken , Robert Fletcher Cleverdon , Bong-Kyu Chang , Donald Henry Mohr , Christine Marie Phillips
IPC分类号： C07C2/58 , C07C5/02 , C07C2/60 , B01D3/00 , B01J31/02 , C10G29/20
CPC分类号： B01D3/009 , B01J31/0277 , C07C2/58 , C07C5/02 , C10G29/205
摘要： We provide an alkylation process, comprising: separating and recycling a hydrogen gas and a hydrogen chloride from an offgas of a hydrogenation reactor; wherein the hydrogen gas is recycled to the hydrogenation reactor; and wherein the hydrogen chloride is recycled to an alkylation reactor. We also provide an alkylation process unit for performing this process.
摘要翻译：我们提供烷基化方法，包括：从氢化反应器的废气中分离和再循环氢气和氯化氢; 其中氢气被再循环到氢化反应器中; 并且其中氯化氢被再循环到烷基化反应器中。我们还提供了一个用于执行此过程的烷基化处理单元。

3. 发明申请

US20160289574A1 ETHYLENE OLIGOMERIZATION PROCESS FOR MAKING HYDROCARBON LIQUIDS 有权
标题翻译：用于制造烃类液体的乙烯低聚工艺
公开(公告)号：US20160289574A1
公开(公告)日：2016-10-06
申请号：US14674918
申请日：2015-03-31
申请人： Hye-Kyung Cho Timken , Bong-Kyu Chang , Curtis Bay Campbell , Andrew Michael Thomas , Mark Anthony Fernandez , Madeleine Sessions
发明人： Hye-Kyung Cho Timken , Bong-Kyu Chang , Curtis Bay Campbell , Andrew Michael Thomas , Mark Anthony Fernandez , Madeleine Sessions
IPC分类号： C10G50/00 , C10M101/02 , C10L1/08 , C10G57/02 , C10L1/04
CPC分类号： C10G50/00 , B01J31/0284 , B01J31/0298 , C07C2/22 , C07C2527/11 , C07C2527/125 , C10G57/02 , C10G2300/1022 , C10G2300/1092 , C10G2400/04 , C10G2400/08 , C10G2400/10 , C10L1/04 , C10L1/08 , C10L2200/043 , C10L2200/0446 , C10L2270/026 , C10L2270/04 , C10L2290/543 , C10M101/02 , Y02P20/52 , C07C11/02
摘要： Provided herein are processes for ethylene oligomerization in the presence of an ionic liquid catalyst and a co-catalyst to produce a hydrocarbon product comprising C10-C55 oligomers.
摘要翻译：本文提供了在离子液体催化剂和助催化剂存在下乙烯低聚的方法，以产生包含C10-C55低聚物的烃产物。

4. 发明授权

US10683460B2 Ethylene oligomerization process for making hydrocarbon liquids 有权
公开(公告)号：US10683460B2
公开(公告)日：2020-06-16
申请号：US15910957
申请日：2018-03-02
申请人： Hye-Kyung Cho Timken , Bong-Kyu Chang , Curtis Bay Campbell , Andrew Michael Thomas , Mark Anthony Fernandez , Madeleine Sessions
发明人： Hye-Kyung Cho Timken , Bong-Kyu Chang , Curtis Bay Campbell , Andrew Michael Thomas , Mark Anthony Fernandez , Madeleine Sessions
IPC分类号： C10G50/00 , C10L1/04 , C10L1/08 , C10M101/02 , C07C2/22 , C10G57/02 , B01J31/02
摘要： Provided herein are processes for ethylene oligomerization in the presence of an ionic liquid catalyst and a co-catalyst to produce a hydrocarbon product comprising C10-C55 oligomers.

5. 发明申请

US20180251691A1 ETHYLENE OLIGOMERIZATION PROCESS FOR MAKING HYDROCARBON LIQUIDS 审中-公开
公开(公告)号：US20180251691A1
公开(公告)日：2018-09-06
申请号：US15910957
申请日：2018-03-02
申请人： Hye-Kyung Cho Timken , Bong-Kyu Chang , Curtis Bay Campbell , Andrew Michael Thomas , Mark Anthony Fernandez , Madeleine Sessions
发明人： Hye-Kyung Cho Timken , Bong-Kyu Chang , Curtis Bay Campbell , Andrew Michael Thomas , Mark Anthony Fernandez , Madeleine Sessions
IPC分类号： C10G50/00 , C07C2/22 , B01J31/02 , C10G57/02 , C10M101/02 , C10L1/08 , C10L1/04 , C07C11/02
CPC分类号： C10G50/00 , B01J31/0284 , B01J31/0298 , B01J2231/20 , C07C2/22 , C07C2527/11 , C07C2527/125 , C10G57/02 , C10G2300/1022 , C10G2300/1092 , C10G2400/04 , C10G2400/08 , C10G2400/10 , C10L1/04 , C10L1/08 , C10L2200/043 , C10L2200/0446 , C10L2270/026 , C10L2270/04 , C10L2290/543 , C10M101/02 , Y02P20/52 , C07C11/02
摘要： Provided herein are processes for ethylene oligomerization in the presence of an ionic liquid catalyst and a co-catalyst to produce a hydrocarbon product comprising C10-C55 oligomers.

6. 发明授权

US09938473B2 Ethylene oligomerization process for making hydrocarbon liquids 有权
公开(公告)号：US09938473B2
公开(公告)日：2018-04-10
申请号：US14674918
申请日：2015-03-31
申请人： Hye-Kyung Cho Timken , Bong-Kyu Chang , Curtis Bay Campbell , Andrew Michael Thomas , Mark Anthony Fernandez , Madeleine Sessions
发明人： Hye-Kyung Cho Timken , Bong-Kyu Chang , Curtis Bay Campbell , Andrew Michael Thomas , Mark Anthony Fernandez , Madeleine Sessions
IPC分类号： C10G50/00 , C07C2/22 , C10G57/02 , C10L1/08 , C10L1/04 , C10M101/02 , B01J31/02
CPC分类号： C10G50/00 , B01J31/0284 , B01J31/0298 , C07C2/22 , C07C2527/11 , C07C2527/125 , C10G57/02 , C10G2300/1022 , C10G2300/1092 , C10G2400/04 , C10G2400/08 , C10G2400/10 , C10L1/04 , C10L1/08 , C10L2200/043 , C10L2200/0446 , C10L2270/026 , C10L2270/04 , C10L2290/543 , C10M101/02 , Y02P20/52 , C07C11/02
摘要： Provided herein are processes for ethylene oligomerization in the presence of an ionic liquid catalyst and a co-catalyst to produce a hydrocarbon product comprising C10-C55 oligomers.

7. 发明申请

US20140066678A1 ALKYLATION PROCESS WITH RECYLE OF HYDROGEN AND RECOVERY OF HYDROGEN CHLORIDE 有权
标题翻译：氢气回收和氯化氢回收的烷基化方法
公开(公告)号：US20140066678A1
公开(公告)日：2014-03-06
申请号：US13563355
申请日：2012-07-31
申请人： Hye Kyung Cho Timken , Bong-Kyu Chang
发明人： Hye Kyung Cho Timken , Bong-Kyu Chang
IPC分类号： B01J10/00 , C07C2/66 , C07C2/58
CPC分类号： B01D3/009 , B01J38/10 , C07C2/54 , C07C2/58 , C07C2527/125 , Y02P20/582 , Y02P20/584 , C07C9/16
摘要： We provide processes, and process units for practicing the processes, comprising a. regenerating a used catalyst comprising an ionic liquid catalyst and a chloride, from an alkylation reactor, in a hydrogenation reactor to produce a regenerated catalyst effluent; b. separating at least a portion of the regenerated catalyst effluent into a gas fraction comprising a hydrogen gas and into a light hydrocarbon fraction comprising a hydrogen chloride; c. recycling at least a part of the gas fraction comprising the hydrogen gas to the hydrogenation reactor; and d. recovering at least an amount of the light hydrocarbon fraction comprising the hydrogen chloride and recycling the at least the amount of the light hydrocarbon fraction to the alkylation reactor. The alkylation process units comprise a hydrogenation reactor, a fractionation unit, and connections for transmitting the gas fraction to the hydrogenation reactor and for transmitting the light hydrocarbon fraction to the alkylation reactor.
摘要翻译：我们为实施流程提供流程和流程单元，包括a。在氢化反应器中将来自烷基化反应器的包含离子液体催化剂和氯化物的二氧化碳再生，生成再生催化剂流出物; b。将至少一部分再生的催化剂流出物分离成包含氢气的气体馏分并进入包含氯化氢的轻质烃馏分中; C。将至少一部分包含氢气的气体馏分再循环到氢化反应器中; 和d。回收至少一定量的包含氯化氢的轻烃馏分，并将至少一定量的轻烃馏分再循环到烷基化反应器中。烷基化方法单元包括氢化反应器，分馏单元和用于将气体馏分传送到氢化反应器并将轻质烃馏分传输到烷基化反应器的连接。

8. 发明授权

US09302200B2 Alkylation process unit with recyle of hydrogen and recovery of hydrogen chloride 有权
标题翻译：烷基化工艺单元，氢气回收和氯化氢回收
公开(公告)号：US09302200B2
公开(公告)日：2016-04-05
申请号：US13901935
申请日：2013-05-24
申请人： Hye Kyung Cho Timken , Bong-Kyu Chang
发明人： Hye Kyung Cho Timken , Bong-Kyu Chang
IPC分类号： B01J8/00 , C07C2/54 , B01J38/10 , B01D3/00 , C07C2/58
CPC分类号： B01D3/009 , B01J38/10 , C07C2/54 , C07C2/58 , C07C2527/125 , Y02P20/582 , Y02P20/584 , C07C9/16
摘要： We provide alkylation process units, one comprising: a) a hydrogenation reactor that produces a regenerated catalyst effluent; b) a fractionation unit that separates the effluent into gas and light hydrocarbon; c) a connection between the fractionation unit for transmitting the gas to the hydrogenation reactor; and d) a connection between the fractionation unit and an alkylation reactor to transmit the light hydrocarbon to the alkylation reactor. The other comprising: a) a separator, connected between the hydrogenation reactor and a fractionation unit; that separates the effluent into gas and liquid; and wherein the fractionation unit separates a hydrocarbon stream from the liquid into a light hydrocarbon comprising a hydrogen chloride and an extracted conjunct polymer naphtha; b) a connection between the separator and the hydrogenation reactor for transmitting the gas to the hydrogenation reactor; and c) a connection between the fractionation unit and an alkylation reactor to transmit the light hydrocarbon.
摘要翻译：我们提供烷基化处理单元，一个包括：a）产生再生催化剂流出物的氢化反应器; b）将流出物分离成气体和轻烃的分馏单元; c）用于将气体传送到氢化反应器的分馏单元之间的连接; 和d）分馏单元和烷基化反应器之间的连接，以将轻烃传输到烷基化反应器。另一个包括：a）连接在氢化反应器和分馏单元之间的分离器; 将流出物分离成气体和液体; 并且其中所述分馏单元将烃流从液体分离成包含氯化氢和提取的结合聚合物石脑油的轻质烃; b）分离器和氢化反应器之间的连接，用于将气体传送到氢化反应器; 和c）分馏单元和烷基化反应器之间的连接以透过轻质烃。

9. 发明授权

US09302199B2 Alkylation process with recycle of hydrogen and recovery of hydrogen chloride 有权
标题翻译：烷基化过程与氢气再循环和氯化氢回收
公开(公告)号：US09302199B2
公开(公告)日：2016-04-05
申请号：US13563355
申请日：2012-07-31
申请人： Hye Kyung Cho Timken , Bong-Kyu Chang
发明人： Hye Kyung Cho Timken , Bong-Kyu Chang
IPC分类号： C07C2/58 , C07C5/02 , C07C2/60 , B01D3/00
CPC分类号： B01D3/009 , B01J38/10 , C07C2/54 , C07C2/58 , C07C2527/125 , Y02P20/582 , Y02P20/584 , C07C9/16
摘要： We provide processes, and process units for practicing the processes, comprising a. regenerating a used catalyst comprising an ionic liquid catalyst and a chloride, from an alkylation reactor, in a hydrogenation reactor to produce a regenerated catalyst effluent; b. separating at least a portion of the regenerated catalyst effluent into a gas fraction comprising a hydrogen gas and into a light hydrocarbon fraction comprising a hydrogen chloride; c. recycling at least a part of the gas fraction comprising the hydrogen gas to the hydrogenation reactor; and d. recovering at least an amount of the light hydrocarbon fraction comprising the hydrogen chloride and recycling the at least the amount of the light hydrocarbon fraction to the alkylation reactor. The alkylation process units comprise a hydrogenation reactor, a fractionation unit, and connections for transmitting the gas fraction to the hydrogenation reactor and for transmitting the light hydrocarbon fraction to the alkylation reactor.
摘要翻译：我们为实施流程提供流程和流程单元，包括a。在氢化反应器中将来自烷基化反应器的包含离子液体催化剂和氯化物的二氧化碳再生，生成再生催化剂流出物; b。将至少一部分再生的催化剂流出物分离成包含氢气的气体馏分并进入包含氯化氢的轻质烃馏分中; C。将至少一部分包含氢气的气体馏分再循环到氢化反应器中; 和d。回收至少一定量的包含氯化氢的轻烃馏分，并将至少一定量的轻烃馏分再循环到烷基化反应器中。烷基化方法单元包括氢化反应器，分馏单元和用于将气体馏分传送到氢化反应器并将轻质烃馏分传输到烷基化反应器的连接。

10. 发明申请

US20140037512A1 ALKYLATION PROCESS UNIT WITH RECYLE OF HYDROGEN AND RECOVERY OF HYDROGEN CHLORIDE 有权
标题翻译：氢氧化还原氯化氢回收工艺装置
公开(公告)号：US20140037512A1
公开(公告)日：2014-02-06
申请号：US13901935
申请日：2013-05-24
申请人： Hye Kyung Cho Timken , Bong-Kyu Chang
发明人： Hye Kyung Cho Timken , Bong-Kyu Chang
IPC分类号： B01D3/00
CPC分类号： B01D3/009 , B01J38/10 , C07C2/54 , C07C2/58 , C07C2527/125 , Y02P20/582 , Y02P20/584 , C07C9/16
摘要： We provide alkylation process units, one comprising: a) a hydrogenation reactor that produces a regenerated catalyst effluent; b) a fractionation unit that separates the effluent into gas and light hydrocarbon; c) a connection between the fractionation unit for transmitting the gas to the hydrogenation reactor; and d) a connection between the fractionation unit and an alkylation reactor to transmit the light hydrocarbon to the alkylation reactor. The other comprising: a) a separator, connected between the hydrogenation reactor and a fractionation unit; that separates the effluent into gas and liquid; and wherein the fractionation unit separates a hydrocarbon stream from the liquid into a light hydrocarbon comprising a hydrogen chloride and an extracted conjunct polymer naphtha; b) a connection between the separator and the hydrogenation reactor for transmitting the gas to the hydrogenation reactor; and c) a connection between the fractionation unit and an alkylation reactor to transmit the light hydrocarbon.
摘要翻译：我们提供烷基化处理单元，一个包括：a）产生再生催化剂流出物的氢化反应器; b）将流出物分离成气体和轻烃的分馏单元; c）用于将气体传送到氢化反应器的分馏单元之间的连接; 和d）分馏单元和烷基化反应器之间的连接，以将轻烃传输到烷基化反应器。另一个包括：a）连接在氢化反应器和分馏单元之间的分离器; 将流出物分离成气体和液体; 并且其中所述分馏单元将烃流从液体分离成包含氯化氢和提取的结合聚合物石脑油的轻质烃; b）分离器和氢化反应器之间的连接，用于将气体传送到氢化反应器; 和c）分馏单元和烷基化反应器之间的连接以透过轻质烃。

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