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1. 发明申请

US20120107519A1 RADIATION CURING OF COATINGS 审中-公开
标题翻译：涂料的辐射固化
公开(公告)号：US20120107519A1
公开(公告)日：2012-05-03
申请号：US13259676
申请日：2010-03-29
申请人： Huig Klinkenberg , Marcella Gagliardo , Keimpe Jan Van Den Berg , Berend Mulder , Douglas Thomas Mallin Kirk
发明人： Huig Klinkenberg , Marcella Gagliardo , Keimpe Jan Van Den Berg , Berend Mulder , Douglas Thomas Mallin Kirk
IPC分类号： C09D175/04 , B05D3/06 , B05D3/02 , B05D7/24
CPC分类号： C09D175/16 , C08G18/3215 , C08G18/4854 , C08G18/7621
摘要： The invention relates to a process of coating a substrate with a non-aqueous coating composition comprising a) a polyol, b) a polyisocyanate crosslinker, c) a metal based catalyst for the addition reaction of hydroxyl groups and isocyanate groups, d) a thiol-functional compound at least partly deactivating the metal based catalyst, and e) a photolatent base which can be activated by actinic radiation, wherein the photolatent base prior to activation has a pKa value below 8, and wherein at least 60 mol-% of all isocyanate-reactive groups are hydroxyl groups, comprising the steps of: i) applying the coating composition to a substrate and ii) curing the coating composition.
摘要翻译：本发明涉及一种用非水性涂料组合物涂覆基材的方法，该组合物包含a）多元醇，b）多异氰酸酯交联剂，c）用于羟基和异氰酸酯基团的加成反应的金属基催化剂，d）硫醇官能化合物至少部分地使所述金属基催化剂失活，以及e）可以通过光化辐射活化的光引发剂碱，其中在活化之前所述光致变色碱基具有低于8的pKa值，并且其中至少60mol％的全部异氰酸酯反应性基团是羟基，包括以下步骤：i）将涂料组合物施加到基材上，和ii）固化涂料组合物。

2. 发明授权

US06548565B1 Non-aqueous coating composition based on an oxidatively drying alkyd resin and a photo-initiator 失效
标题翻译：基于氧化干燥的醇酸树脂和光引发剂的非水性涂料组合物
公开(公告)号：US06548565B1
公开(公告)日：2003-04-15
申请号：US09659871
申请日：2000-09-13
申请人： Keimpe Jan Van Den Berg , Huig Klinkenberg , Arie Noomen
发明人： Keimpe Jan Van Den Berg , Huig Klinkenberg , Arie Noomen
IPC分类号： C08F246
CPC分类号： C08G63/48 , C09D167/08 , C08L2666/28
摘要： A non-aqueous coating composition based on an oxidatively drying alkyd resin and a photo-initiator. An acid or latent acid and one or more compounds of the group of vinyl ethers, acetals, and alkoxysilanes which are reactive in the presence of an acid are incorporated into the coating composition. The vinyl ethers, acetals, and alkoxysilanes preferably are covalently bounded to the alkyd resin. The ratio of the number of oxidatively drying groups present in the alkyd resin to the number of groups reactive in the presence of an acid preferably is in the range of 1/10 to 15/1. The acid preferably is the phosphoric acid dibutyl ester.
摘要翻译：基于氧化干燥的醇酸树脂和光引发剂的非水性涂料组合物。在酸存在下反应的酸或潜酸和一种或多种乙烯基醚，缩醛和烷氧基硅烷的化合物被并入涂料组合物中。乙烯基醚，缩醛和烷氧基硅烷优选与醇酸树脂共价结合。存在于醇酸树脂中的氧化干燥基团的数量与在酸存在下反应的基团数目的比例优选为1/10至15/1。酸优选为磷酸二丁酯。

3. 发明申请

US20130230648A1 KIT OF PARTS FOR CURABLE COATING COMPOSITION 审中-公开
标题翻译：可固化涂料组合部件套件
公开(公告)号：US20130230648A1
公开(公告)日：2013-09-05
申请号：US13825734
申请日：2011-09-27
申请人： Keimpe Jan Van Den Berg , Marcella Gagliardo , Robert Pieter Lagendijk
发明人： Keimpe Jan Van Den Berg , Marcella Gagliardo , Robert Pieter Lagendijk
IPC分类号： C09D167/04
CPC分类号： C09D167/04 , B05D3/067 , C08G18/24 , C08G18/3876 , C08G18/4063 , C08G18/792 , C08J3/24 , C08J3/28 , C08J2375/04 , C09D175/04
摘要： The invention relates to a kit of parts for preparation of a crosslinkable coating composition comprising a) a binder module comprising a film-forming binder comprising crosslinkable functional groups A, b) a crosslinker module comprising a crosslinker comprising at least two functional groups B capable of reacting with the crosslinkable functional groups A of the binder, c) a thermal activator module comprising one or more components which exhibit an accelerating effect on the reaction between functional groups A and B of the mixture of the binder module and the crosslinker module, d) an ultraviolet activator module comprising one or more components which after irradiation with ultraviolet light exhibit a greater accelerating effect on the reaction between functional groups A and B of the mixture of the binder module and the crosslinker module than before irradiation with ultraviolet light.
摘要翻译：本发明涉及一种用于制备可交联涂料组合物的试剂盒，其包含a）包含含有可交联官能团A的成膜粘合剂的粘合剂组合物，b）包含交联剂的交联剂模块，所述交联剂模块包含至少两个能够与粘合剂的可交联官能团A反应，c）包含一种或多种组分的热活化剂模块，其对粘合剂模块和交联剂模块的混合物的官能团A和B之间的反应具有加速作用，d）包含紫外线照射后的紫外线活化剂组合物，与紫外线照射之前相比，对粘合剂组合物和交联剂组合物的混合物的官能团A和B的反应的加速效果更大。

4. 发明授权

US07015298B2 Coating composition comprising a compound comprising a spiro-ortho silicate group 失效
标题翻译：包含包含螺 - 原硅酸盐基团的化合物的涂料组合物
公开(公告)号：US07015298B2
公开(公告)日：2006-03-21
申请号：US10671511
申请日：2003-09-29
申请人： Keimpe Jan Van Den Berg , Klaus Hobel , Josephus Christiaan Van Oorschot , Jan Cornelis Van Beelen , Huig Klinkenberg
发明人： Keimpe Jan Van Den Berg , Klaus Hobel , Josephus Christiaan Van Oorschot , Jan Cornelis Van Beelen , Huig Klinkenberg
IPC分类号： C08G77/00
CPC分类号： C09D175/04 , C08G18/3893 , C08G18/792
摘要： The invention pertains to a coating composition comprising a compound comprising at least one spiro-ortho silicate group and a hydroxyl-reactive cross-linker, to a process for curing the composition, and to the use of the composition. The coating composition of the current invention can be formulated to a coating composition having a low content of volatile organic solvents, is curable at a temperature as low as 5° C., and the cured coating composition of the current invention is essentially free of unreacted low-molecular weight blocking agents. Further, the pot life: drying time ratio of coating compositions according to the invention is particularly favorable.
摘要翻译：本发明涉及包含至少一种螺 - 原硅酸盐基团和羟基 - 反应性交联剂的化合物，用于固化该组合物的方法以及该组合物的用途的涂料组合物。本发明的涂料组合物可以配制成具有低含量挥发性有机溶剂的涂料组合物，可在低至5℃的温度下固化，本发明的固化涂料组合物基本上不含未反应低分子量封闭剂。此外，本发明的涂料组合物的适用期：干燥时间比是特别有利的。

5. 发明授权

US6100349A Thermosetting powder coating composition 失效
标题翻译：热固性粉末涂料组合物
公开(公告)号：US6100349A
公开(公告)日：2000-08-08
申请号：US108397
申请日：1998-07-01
申请人： Martinus Adrianus Anthonius Maria Koenraadt , Arie Noomen , Keimpe Jan Van Den Berg , Huig Klinkenberg , Klaus Hobel
发明人： Martinus Adrianus Anthonius Maria Koenraadt , Arie Noomen , Keimpe Jan Van Den Berg , Huig Klinkenberg , Klaus Hobel
IPC分类号： C08K5/1565 , C08K5/3492 , C09D167/00 , C09D201/00 , C08G59/40
CPC分类号： C09D167/00 , C08K5/1565 , C08K5/34926 , C09D201/00 , Y10S525/934
摘要： Proposed is a thermosetting powder coating composition comprising a mixture of particles reactive towards one another and a catalyst, with a portion of the reactive particles comprising a polymer reacting with epoxy to form ester forming or ether forming groups, while another portion comprises an at least bifunctional cross-linking agent which contains 2-oxo-1,3-dioxolan-4-yl groups, hereinafter referred to as cyclocarbonate groups, and, optionally, epoxy groups, with both the polymer reacting with epoxy to form ester forming and/or ether forming groups and the cross-linking agent being obtained by means of a non-vinylic addition and/or polymerization process. The catalyst used as ring opener for the cyclocarbonate groups is present in a quantity of 0.01 to 10, preferably 0.1 to 5, parts by weight per 100 parts by weight of the mixture of particles reactive towards one another. The quantity of epoxy oxygen present in the cross-linking agent after CO.sub.2 unblocking preferably is at least 0.4 wt. %. The reactive polymer preferably is a polymer containing groups reactive towards epoxy such as carboxyl, anhydride and/or hydroxyl groups, with preference being given to polyesters and/or polyurethanes.
摘要翻译：提出了一种热固性粉末涂料组合物，其包含彼此反应的颗粒的混合物和催化剂，其中一部分反应性颗粒包含与环氧树脂反应以形成酯形成或醚形成基团的聚合物，而另一部分包含至少双官能包含2-氧代-1,3-二氧戊环-4-基的交联剂，以下称为环碳酸酯基，和任选的环氧基，聚合物与环氧基反应形成酯形成和/或醚通过非乙烯基加成和/或聚合方法得到交联剂。用作环碳酸酯基的开环剂的催化剂的存在量为每100重量份彼此反应的颗粒混合物的0.01至10重量份，优选为0.1至5重量份。二氧化碳解封后交联剂中存在的环氧氧化物的量优选为0.4重量％以上。％。反应性聚合物优选是含有对环氧化合物如羧基，酸酐和/或羟基具有反应性的基团的聚合物，优选给予聚酯和/或聚氨酯。

6. 发明授权

US6015864A Thermosetting powder coating composition 失效
标题翻译：热固性粉末涂料组合物
公开(公告)号：US6015864A
公开(公告)日：2000-01-18
申请号：US83074
申请日：1998-05-21
申请人： Martinus Adrianus Anthonius Maria Koenraadt , Arie Noomen , Keimpe Jan Van Den Berg , Josephus Christiaan Van Oorschot , Huig Klinkenberg
发明人： Martinus Adrianus Anthonius Maria Koenraadt , Arie Noomen , Keimpe Jan Van Den Berg , Josephus Christiaan Van Oorschot , Huig Klinkenberg
IPC分类号： C09D5/03 , C09D167/00 , C08C19/30
CPC分类号： C09D5/03 , C09D167/00
摘要： Proposed is a thermosetting powder coating composition comprising a mixture of particles reactive towards one another, optionally in combination with a catalyst, with a portion of the reactive particles comprising a polymer reactive towards oxetane groups while another portion comprises an oxetane groups-containing cross-linking agent having an oxetane functionality of more than 1. The quantity of oxetane oxygen in the cross-linking agent preferably is at least 0.4 wt. %. The reactive polymer preferably is a polymer having groups reactive towards oxetane, such as carboxyl, epoxy, oxetane, anhydride, and hydroxyl, with preference being given to a polyester or a hydroxypolyacrylate.
摘要翻译：提出了一种热固性粉末涂料组合物，其包含彼此反应的颗粒的混合物，任选地与催化剂组合，一部分反应性颗粒包含对氧杂环丁烷基团具有反应性的聚合物，而另一部分包含含氧杂环丁烷基团的交联氧杂环丁烷官能度大于1.交联剂中氧杂环丁烷氧的量优选为至少0.4wt。％。反应性聚合物优选是具有与氧杂环丁烷反应的基团的聚合物，例如羧基，环氧基，氧杂环丁烷，酸酐和羟基，优选给予聚酯或羟基聚丙烯酸酯。

7. 发明授权

US07045579B2 Coating composition comprising an acetal-functional binder 失效
标题翻译：包含缩醛官能粘合剂的涂料组合物
公开(公告)号：US07045579B2
公开(公告)日：2006-05-16
申请号：US10383600
申请日：2003-03-07
申请人： Keimpe Jan Van Den Berg , Klaus Hobel , Josephus Christiaan Van Oorschot , Marcel Johannes Antonius Mensink , Kenny Abdoel Nassier Raghosing , Edith Hulsbos
发明人： Keimpe Jan Van Den Berg , Klaus Hobel , Josephus Christiaan Van Oorschot , Marcel Johannes Antonius Mensink , Kenny Abdoel Nassier Raghosing , Edith Hulsbos
IPC分类号： C09D129/14 , C09D201/06 , C09D175/04 , C08K5/37
CPC分类号： C09D175/04 , C07C237/08 , C07C271/16 , C08G18/0866 , C08G18/12 , C08G18/283 , C08G18/3819 , C08G18/4036 , C08G18/423 , C08G18/8108 , C08G18/834 , C08K5/37 , C08K5/372 , C08L31/02 , C08L75/04 , C09D129/14 , C09D175/10 , Y10T428/28 , C08G18/3876 , C08G18/3271 , C08L57/04 , C08L2666/20 , C08L2666/04 , C08L75/10
摘要： The invention relates to a coating composition comprising an acetal-functional binder and a thiol-functional cross-linker, wherein the acetal-functional binder is represented by the following formula wherein P is a binder backbone, K is a divalent and/or trivalent organic moiety having 1 to 30 carbon atoms and having one or two links to the binder backbone, A is selected from oxygen, sulphur, and NRVII, wherein RVII is hydrogen or an alkyl group with 1 to 4 carbon atoms, m is an integer from 1 to 50, n is an integer from 1 to 10, and R and R′ may be the same or different and represent alkyl groups with 1 to 4 carbon atoms. In a further aspect, the invention relates to acetal-functional binders, acetal-functional monomers, a process for the preparation of said monomers, coating compositions comprising said acetal-functional binders, and to a process for the preparation of a coating composition comprising an acetal-functional polyurethane dispersion and a thiol-functional cross-linker.
摘要翻译：本发明涉及包含缩醛官能粘合剂和硫醇官能交联剂的涂料组合物，其中缩醛官能粘合剂由下式表示：其中P是粘合剂主链，K是二价和/或三价有机物具有1至30个碳原子并且具有一个或两个连接到粘合剂主链的部分，A选自氧，硫和NR VII，其中R VII是氢或具有1至4个碳原子的烷基，m为1至50的整数，n为1至10的整数，R和R'可以相同或不同，表示具有1至4个碳原子的烷基。在另一方面，本发明涉及缩醛官能的粘合剂，缩醛官能单体，制备所述单体的方法，包含所述缩醛官能粘合剂的涂料组合物，以及制备涂料组合物的方法，所述涂料组合物包含缩醛官能聚氨酯分散体和硫醇功能交联剂。

8. 发明授权

US6077929A Internally blocked polyamine crosslinkers and coating compositions containing the same 失效
标题翻译：内部封闭的聚胺交联剂和含有它们的涂料组合物
公开(公告)号：US6077929A
公开(公告)日：2000-06-20
申请号：US56445
申请日：1998-04-07
申请人： Johannes Adrianus Pardoen , Wincenty Lambertus Stanislaw Pilaszek , Jan Wilhelm Ernst Moos , Keimpe Jan Van Den Berg
发明人： Johannes Adrianus Pardoen , Wincenty Lambertus Stanislaw Pilaszek , Jan Wilhelm Ernst Moos , Keimpe Jan Van Den Berg
IPC分类号： C09D4/00 , C08L33/00 , C08F8/32 , C08F20/00 , C08F59/40
CPC分类号： C09D4/00
摘要： The present invention pertains to coating compositions including a particular class of internally blocked polyamines as replacement for traditional blocked and unblocked polyamine crosslinkers. The use of these internally blocked polyamines results in better appearance characteristics and a lower VOC than are generally available with the traditional blocked varieties.
摘要翻译：本发明涉及涂料组合物，其包括特定类型的内部封端的多胺作为传统的封闭和未封端的聚胺交联剂的替代物。这些内部封闭的多胺的使用导致比传统封闭品种通常可获得的更好的外观特征和更低的VOC。

9. 发明授权

US06987135B2 Photoactivatable water borne coating composition 失效
公开(公告)号：US06987135B2
公开(公告)日：2006-01-17
申请号：US10045272
申请日：2001-10-25
申请人： Keimpe Jan Van Den Berg , Arie Noomen , Frederik Rous , Ignace Damiaan Christiaan Rood , Heert Andringa , Klaas Jan Hendrik Kruithof , Ann Kerstin Birgitta Lindell Kjellqvist
发明人： Keimpe Jan Van Den Berg , Arie Noomen , Frederik Rous , Ignace Damiaan Christiaan Rood , Heert Andringa , Klaas Jan Hendrik Kruithof , Ann Kerstin Birgitta Lindell Kjellqvist
IPC分类号： C08L75/16 , C08G18/48 , C08G18/67 , C08J3/03 , C08J3/28
CPC分类号： C09D175/16 , C08G18/283 , C08G18/672 , C08G18/0823
摘要： Photoactivatable water born coating composition comprising a) a (meth)acryloyl-functional polyurethane dispersion, with the (meth)acryloyl-functional polyurethane comprising 5 to 18 wt. % of alkylene oxide groups while the (meth)acryloyl functionality is in the range of 2 to 40, and b) a UV-initiator. Preferably, the (meth)acryloyl-functional polyurethane comprises 8 to 18 wt. % of alkylene oxide groups. More preferably, the coating composition comprises a reactive diluent.The (meth)acryloyl-functional polyurethane is obtainable by reaction of: a) at least one organic polyisocyanate, b) optionally, at least one organic compound containing at least two isocyanate-reactive groups and having a number average molecular weight in the range of 400 to 6,000, c) at least one isocyanate-reactive and/or isocyanate-functional compound bearing non-ionic dispersing groups, d) at least one isocyanate-reactive (meth)acryloyl-functional compound, e) optionally, at least one active hydrogen-containing chain extender, and f) optionally, at least one active hydrogen-containing compound bearing ionic groups. The water born coating composition is especially suitable for application as a clear coat.

10. 发明授权

US06765056B2 Aqueous cross-linkable binder composition and its use in the production of lacquer coatings 失效
标题翻译：水性交联粘合剂组合物及其在漆涂料生产中的应用
公开(公告)号：US06765056B2
公开(公告)日：2004-07-20
申请号：US09928616
申请日：2001-08-13
申请人： Klaus Hobel , Josephus Christiaan Van Oorschot , Keimpe Jan Van Den Berg
发明人： Klaus Hobel , Josephus Christiaan Van Oorschot , Keimpe Jan Van Den Berg
IPC分类号： C08L7510
CPC分类号： C08G18/83 , C08G18/0823 , C08G18/2815 , C08G18/6625 , C08G18/725 , C08G18/84 , C09D175/04
摘要： The aqueous-based cross-linkable binder composition comprising (A) an aqueous dispersion of an aldehyde-functional polyurethane having a number average molecular weight of more than 1,000 and an average aldehyde functionality of ≧2, which polyurethane comprises ionic and/or non-ionic dispersing groups, and (B) a low-molecular weight aldehyde-reactive cross-linker selected from the group of low-molecular weight polyamines and low-molecular weight compounds comprising at least one group of one of the formulae E1—CHR1—E2 and H—C—(E1E2E3), wherein —E1, —E2 and —E3 are independently chosen from electron-withdrawing groups such as —P(═O)—O—, —CO—, —CN, —SO2—, —NO2 and wherein R1 has the meaning of hydrogen or a hydrocarbon radical having 1 to 10 carbon atoms. Preference is given to a coating composition wherein the ionic dispersing group is an anionic dispersing group selected from the group of carboxylate, sulphonate and/or phosph(on)ate salt groups, and/or wherein for the nonionic dispersing group use is made of a C1-C4 alkoxy poly C2-C3 alkylene-oxide group in an amount between 2.5 and 20 wt. %, based on the polyurethane.
摘要翻译：所述水性可交联粘合剂组合物包含（A）数均分子量大于1,000且平均醛官能度> = 2的醛官能聚氨酯的水分散体，该聚氨酯包含离子和/或非 - - 离子分散基团，和（B）低分子量醛 - 反应性交联剂，其选自低分子量多胺和低分子量化合物，其包含至少一个式E 1之一 -CHR 1 -E 2和HC-（E 1 E 2 E 3），其中-E 1，-E 2和-E 3独立地选自吸电子基团如-P（= O）-O-，-CO-，-CN，-SO 2 - ， - NO 2，其中R 1具有氢或具有1-10个碳原子的烃基优选一种涂料组合物，其中离子分散基团是选自羧酸盐，磺酸盐和/或磷酸（酯）盐基团的阴离子分散基团，和/或其中非离子分散组使用的量为2.5至20重量％的C 1 -C 4烷氧基聚C 2 -C 3亚烷基氧基。％，基于聚氨酯。

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