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1. 发明授权

US07345130B2 Silane functional prepolymer and isocyanate functional prepolymer blend based adhesive composition 有权
标题翻译：硅烷官能预聚物和异氰酸酯官能预聚物共混物基粘合剂组合物
公开(公告)号：US07345130B2
公开(公告)日：2008-03-18
申请号：US11585010
申请日：2006-10-23
申请人： Huide D. Zhu , Syed Z. Mahdi , Matthew B. Feldpausch
发明人： Huide D. Zhu , Syed Z. Mahdi , Matthew B. Feldpausch
IPC分类号： C08G77/08
CPC分类号： C09J183/14 , Y10T428/31663
摘要： The invention is an adhesive composition comprising a) one or more silane functional prepolymers comprising a polyether or a polyolefin backbone and silane moieties capable of silanol condensation; b) one or more isocyanate functional prepolymers comprising a polyether backbone and isocyanate moieties; c) one or more organotin compounds or titanate or zirconate compounds having one or more ligands comprising a hydrocarbyl phosphate ester or a hydrocarbyl sulfonate ester, or a mixture thereof; d) a tertiary amine or an anhydrous strong organic acid which is miscible with the polymer and enhances the bonding of the adhesive to a coated unprimed substrate. In one embodiment, the invention is a method of bonding two or more substrates together using the adhesive compositions of this invention. The process comprises applying an adhesive as described herein to one or more of the substrates; contacting the one or more substrates with the adhesive disposed between the substrates; and allowing the adhesive to cure.
摘要翻译：本发明是一种粘合剂组合物，其包含a）一种或多种包含聚醚或聚烯烃骨架的硅烷官能预聚物和能够硅烷醇缩合的硅烷部分; b）一种或多种包含聚醚主链和异氰酸酯部分的异氰酸酯官能预聚物; c）一种或多种有机锡化合物或具有一个或多个配体的钛酸酯或锆酸酯化合物，所述配体包含烃基磷酸酯或烃基磺酸酯，或其混合物; d）可与聚合物混溶的叔胺或无水强有机酸，并增强粘合剂与涂覆的未染色基质的粘结。在一个实施方案中，本发明是使用本发明的粘合剂组合物将两个或更多个基材粘合在一起的方法。该方法包括将如本文所述的粘合剂施加到一个或多个基底上; 使一个或多个基底与布置在基底之间的粘合剂接触; 并使粘合剂固化。

2. 发明授权

US09102854B2 Polyurethane sealant compositions having high filler levels 有权
标题翻译：具有高填料含量的聚氨酯密封剂组合物
公开(公告)号：US09102854B2
公开(公告)日：2015-08-11
申请号：US12249030
申请日：2008-10-10
申请人： Huide D. Zhu , Jeffrey W. Saracsan , Frank V. Billotto , Michael Frishcosy
发明人： Huide D. Zhu , Jeffrey W. Saracsan , Frank V. Billotto , Michael Frishcosy
IPC分类号： B32B17/10 , B32B17/06 , C08L75/04 , C09J175/04 , C08G18/12
CPC分类号： C09J175/04 , C08G18/12 , C08G18/42
摘要： In one aspect, this invention is a composition comprising a urethane prepolymer having isocyanate moieties; a catalytic amount of a compound which catalyzes the reaction of isocyanate moieties with water or an active hydrogen containing compound; and untreated calcium carbonate as filler. The composition of the invention can be used to bond a window into a structure especially for the automobile windshield installation with good adhesion strength and durability.
摘要翻译：一方面，本发明是包含具有异氰酸酯部分的氨基甲酸酯预聚物的组合物; 催化量的催化异氰酸酯部分与水或含活性氢化合物的反应的化合物; 和未处理的碳酸钙作为填料。本发明的组合物可用于将窗口结合到特别是用于汽车挡风玻璃安装的结构中，具有良好的粘合强度和耐久性。

3. 发明授权

US08524840B2 Polyurethane sealant compositions having primerless to paint and glass properties 有权
标题翻译：具有无底漆和玻璃性能的聚氨酯密封剂组合物
公开(公告)号：US08524840B2
公开(公告)日：2013-09-03
申请号：US11442839
申请日：2006-05-30
申请人： Huide D. Zhu , Daniel P. Heberer
发明人： Huide D. Zhu , Daniel P. Heberer
IPC分类号： C08G18/48
CPC分类号： C08G18/4812 , B32B2605/08 , C08G18/12 , C08G2190/00 , C09J175/04 , C08G18/289 , C08G18/307 , C08G18/48 , C08G18/792
摘要： In one aspect, this invention is a composition comprising a urethane prepolymer having isocyanate moieties; a catalytic amount of a compound which catalyzes the reaction of isocyanate moieties with water or an active hydrogen containing compound; alpha hydrocarbyl silane compound; and a catalytic amount of a compound which catalyzes silanol condensation. The composition of the invention can be used to bond a window into a structure without the need to prime the window or the window flange of the structure.
摘要翻译：一方面，本发明是包含具有异氰酸酯部分的氨基甲酸酯预聚物的组合物; 催化量的催化异氰酸酯部分与水或含活性氢化合物的反应的化合物; α烃基硅烷化合物; 和催化量的催化硅烷醇缩合的化合物。本发明的组合物可用于将窗户结合到结构中，而不需要施加结构的窗口或窗口凸缘。

4. 发明授权

US06184269B2 Moldable intumescent materials containing novel silicone elastomers 失效
标题翻译：含有新型有机硅弹性体的可成型膨胀材料
公开(公告)号：US06184269B2
公开(公告)日：2001-02-06
申请号：US09345370
申请日：1999-07-01
申请人： Ismat Ali Abu-Isa , Huide D. Zhu
发明人： Ismat Ali Abu-Isa , Huide D. Zhu
IPC分类号： C08K502
CPC分类号： C09K21/14 , C08K3/01 , C08K5/0066 , C08K2003/222 , C08K2003/2227 , C08K2003/323 , C08L23/04
摘要： Moldable intumescent thermoplastic elastomer materials are disclosed based on suitable proportions of polyethylene, chlorinated polyethylene and a silicone elastomer with silphenylene siloxane monomer moieties and stabilizers, all with foamers, char formers and fillers. Examples of suitable silphenylene-siloxane monomer moieties are 1,4-phenylene-hexamethyltrisiloxanyl and 1,4-phenylene-1,1,3,5,5-pentamethyl-3-vinyltrisiloxanyl where the respective methyl groups may be replaced with suitable phenyl groups or other lower alkyl groups and their fluorinated analogs.
摘要翻译：基于合适比例的聚乙烯，氯化聚乙烯和硅氧烷弹性体以及具有硅酮硅氧烷单体部分和稳定剂的所有泡沫塑料弹性体材料，所有这些材料都具有起泡剂，炭黑和填料。合适的硅亚苯基 - 硅氧烷单体部分的实例是1,4-亚苯基 - 六甲基三硅氧烷基和1,4-亚苯基-1,1,3,5,5-五甲基-3-乙烯基三羟基硅烷基，其中各个甲基可以被适当的苯基或其它低级烷基及其氟化类似物。

5. 发明授权

US07789990B2 Silane functional adhesive composition and method of bonding a window to a substrate without a primer 有权
标题翻译：硅烷功能性粘合剂组合物和将窗口粘合到没有底漆的基材上的方法
公开(公告)号：US07789990B2
公开(公告)日：2010-09-07
申请号：US11825085
申请日：2007-07-03
申请人： Huide D. Zhu , Daniel P. Heberer
发明人： Huide D. Zhu , Daniel P. Heberer
IPC分类号： B60J1/00 , E06B3/00 , E06B5/00 , E06B7/00 , C04B37/00 , B41J2/16 , B32B7/12 , C09J4/00 , C09J101/00 , C09J201/00 , C09J7/02 , C08L83/00 , C08L83/04
CPC分类号： C09J5/00 , C09J201/10 , C09J2400/143 , C09J2483/00
摘要： The invention is an adhesive composition comprising one or more polymers having a flexible backbone and silane moieties capable of silanol condensation; one or more hydrophobic silanes having one or more hydrocarbyloxy groups and one or more hydrocarbyl groups; one or more catalysts for the reaction of silane moieties with active hydrogen containing compounds. Preferably, the adhesive composition further comprises one or more heat stabilizers and/or light stabilizers. In another embodiment, the invention is a method of bonding a window to a coated substrate, such as a window in a vehicle, which comprises applying to the window or the coated substrate an adhesive as described; contacting the window with the coated substrate wherein the adhesive is located between the window and the substrate; and allowing the adhesive to cure.
摘要翻译：本发明是一种粘合剂组合物，其包含一种或多种具有柔性主链和能够硅烷醇缩合的硅烷部分的聚合物; 一个或多个具有一个或多个烃氧基和一个或多个烃基的疏水性硅烷; 用于使硅烷部分与含活性氢化合物反应的一种或多种催化剂。优选地，粘合剂组合物还包含一种或多种热稳定剂和/或光稳定剂。在另一个实施方案中，本发明是将窗口结合到涂覆的基底，例如车辆中的窗口的方法，其包括向所述窗口或所述涂覆的基底施加如上所述的粘合剂; 使所述窗与所述涂覆的基底接触，其中所述粘合剂位于所述窗和所述基底之间; 并使粘合剂固化。

6. 发明申请

US20090114336A1 POLYURETHANE SEALANT COMPOSITIONS HAVING HIGH FILLER LEVELS 有权
标题翻译：具有高填充水平的聚氨酯密封组合物
公开(公告)号：US20090114336A1
公开(公告)日：2009-05-07
申请号：US12249030
申请日：2008-10-10
申请人： Huide D. Zhu , Jeffrey W. Saracsan , Frank V. Billotto , Michael A. Frishcosy
发明人： Huide D. Zhu , Jeffrey W. Saracsan , Frank V. Billotto , Michael A. Frishcosy
IPC分类号： B32B17/10 , C08L75/04 , B32B17/06
CPC分类号： C09J175/04 , C08G18/12 , C08G18/42
摘要： In one aspect, this invention is a composition comprising a urethane prepolymer having isocyanate moieties; a catalytic amount of a compound which catalyzes the reaction of isocyanate moieties with water or an active hydrogen containing compound; and untreated calcium carbonate as filler. The composition of the invention can be used to bond a window into a structure especially for the automobile windshield installation with good adhesion strength and durability.
摘要翻译：一方面，本发明是包含具有异氰酸酯部分的氨基甲酸酯预聚物的组合物; 催化量的催化异氰酸酯部分与水或含活性氢化合物的反应的化合物; 和未处理的碳酸钙作为填料。本发明的组合物可用于将窗口结合到特别是用于汽车挡风玻璃安装的结构中，具有良好的粘合强度和耐久性。

7. 发明申请

US20080017296A1 Silane functional adhesive composition and method of bonding a window to a substrate without a primer 有权
标题翻译：硅烷功能性粘合剂组合物和将窗口粘合到没有底漆的基材上的方法
公开(公告)号：US20080017296A1
公开(公告)日：2008-01-24
申请号：US11825085
申请日：2007-07-03
申请人： Huide D. Zhu , Daniel P. Heberer
发明人： Huide D. Zhu , Daniel P. Heberer
IPC分类号： C09J183/05 , B60J1/02 , C09J5/00
CPC分类号： C09J5/00 , C09J201/10 , C09J2400/143 , C09J2483/00
摘要： The invention is an adhesive composition comprising one or more polymers having a flexible backbone and silane moieties capable of silanol condensation; one or more hydrophobic silanes having one or more hydrocarbyloxy groups and one or more hydrocarbyl groups; one or more catalysts for the reaction of silane moieties with active hydrogen containing compounds. Preferably, the adhesive composition further comprises one or more heat stabilizers and/or light stabilizers. In another embodiment, the invention is a method of bonding a window to a coated substrate, such as a window in a vehicle, which comprises applying to the window or the coated substrate an adhesive as described; contacting the window with the coated substrate wherein the adhesive is located between the window and the substrate; and allowing the adhesive to cure.
摘要翻译：本发明是一种粘合剂组合物，其包含一种或多种具有柔性主链和能够硅烷醇缩合的硅烷部分的聚合物; 一个或多个具有一个或多个烃氧基和一个或多个烃基的疏水性硅烷; 用于使硅烷部分与含活性氢化合物反应的一种或多种催化剂。优选地，粘合剂组合物还包含一种或多种热稳定剂和/或光稳定剂。在另一个实施方案中，本发明是将窗口结合到涂覆的基底，例如车辆中的窗口的方法，其包括向所述窗口或所述涂覆的基底施加如上所述的粘合剂; 使所述窗与所述涂覆的基底接触，其中所述粘合剂位于所述窗和所述基底之间; 并使粘合剂固化。

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