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    • 7. 发明授权
    • Long-term antistatic composition
    • 长期抗静电组成
    • US6072001A
    • 2000-06-06
    • US13897
    • 1998-01-27
    • Hsin-Herng WangBin-Yuan Lin
    • Hsin-Herng WangBin-Yuan Lin
    • C08L51/06C08L77/00C08G63/48C08G63/91C08L51/08C08L75/00
    • C08L51/06C08L77/00
    • The present invention uses high molecular weight polyethene glycol copolymer with high antistatic property, and other solubilizer agent to proceed blending and enhancing the co-solublization property of the polyamide. The long-term antistatic plastic particles obtained by blending the modified antistatic composition and the polyamide material are made into different articles according to various composites. The molded articles are divided into three types: (1) an antistatic polyamide article with surface resistance of about 10.sup.10 -10.sup.11 (.OMEGA./sq.), and the dissipation time of electrostatic charge is less than 1.5 sec; (2) an antistatic polyamide fiber with surface resistance of about 6.times.l0.sup.10 -1.2.times.10.sup.12 (.OMEGA./sq.), and the dissipation time of electrostatic charge is less than 60 sec; (3) a polishing resistant antistatic polyamide with surface resistance of about 10.sup.10 -10.sup.11 (.OMEGA./sq.), and the dissipation time of electrostatic charge is less than 1.5 sec.
    • 本发明使用具有高抗静电性的高分子量聚乙二醇共聚物和其它增溶剂进行共混并提高聚酰胺的共溶性。 通过将改性抗静电组合物和聚酰胺材料混合得到的长期抗静电塑料颗粒根据各种复合材料制成不同的制品。 模制品分为三种类型:(1)表面电阻约为1010-1011(OMEGA / sq。)的抗静电聚酰胺制品,静电荷耗散时间小于1.5秒; (2)抗电聚酰胺纤维,表面电阻约为6×10-1-1×10×12(欧米加/平方),静电消耗时间小于60秒; (3)表面电阻约为1010-1011(OMEGA / sq。)的抗抛光抗静电聚酰胺,静电耗散时间小于1.5秒。
    • 8. 发明授权
    • Catalytic compositions for the preparation of poly(butylene
terephthalate)
    • 用于制备聚对苯二甲酸丁二醇酯的催化组合物
    • US5516879A
    • 1996-05-14
    • US413025
    • 1995-03-28
    • Wu-Bin YuoWen-Jeng LinHsin-Herng WangJian-Hong Chen
    • Wu-Bin YuoWen-Jeng LinHsin-Herng WangJian-Hong Chen
    • C08G63/82C08G63/02
    • C08G63/82
    • A catalyst composition for use in the preparation of poly(butylene terephthalate) from dimethyl terephthalate, comprising: (a) a titanium compound primary catalyst, from about 0.01 PHR to about 1 PHR; and (b) an alkali metal phosphate or alkali metal phosphite co-catalyst, from about 0.001 PHR to about 1 PHR; wherein PHR represents parts of the primary catalyst or the co-catalyst per one hundred parts, by weight, of dimethyl terephthalate. Preferred titanium compounds include tetrabutyl titanate or tetra(isopropyl) titanate; the alkali metal phosphate can be a phosphate salt containing one, two, or three metal groups; and the alkali metal phosphite can be a phosphite salt containing one or two metal groups. With this catalyst composition, the transesterification rate was increased by 10 percent or more. Furthermore, the reaction product poly(butylene terephthalate) shows an increased intrinsic viscosity over those without the co-catalyst, indicating a greater degree of polymerization.
    • 一种用于从对苯二甲酸二甲酯制备聚(对苯二甲酸丁二醇酯)的催化剂组合物,包括:(a)钛化合物一次催化剂,约0.01PHR至约1PHR; 和(b)约0.001PHR至约1PHR的碱金属磷酸盐或碱金属亚磷酸盐助催化剂; 其中PHR代表每100重量份对苯二甲酸二甲酯的主要催化剂或助催化剂的部分。 优选的钛化合物包括钛酸四丁酯或钛酸四(异丙基)酯; 碱金属磷酸盐可以是含有一个,两个或三个金属基团的磷酸盐; 碱金属亚磷酸盐可以是含有一个或两个金属基团的亚磷酸盐。 使用该催化剂组合物,酯交换率提高10%以上。 此外,反应产物聚(对苯二甲酸丁二醇酯)显示出比不含助催化剂的反应产物增加的特性粘度,表明聚合度更高。