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    • 1. 发明申请
    • INHERENTLY SAFE THERMO-RESPONSIVE GEL ELECTROLYTES FOR ELECTROCHEMICAL DEVICES
    • 电化学装置的安全热稳定凝胶电解液
    • US20160093923A1
    • 2016-03-31
    • US14868071
    • 2015-09-28
    • HongPeng WangChun-Yi Liang
    • HongPeng WangChun-Yi Liang
    • H01M10/42H01M10/0565
    • H01M10/4235H01M10/052H01M10/0565H01M2300/0085
    • Techniques for providing phase change electrolytes that can be used to improve safety of electrochemical devices, such as lithium batteries, are disclosed herein. At normal operation temperature, the phase change electrolyte is capable of switching “on” with high ionic conductivities in a liquid state. When an electrochemical device system (filled with the phase change electrolyte) encounters abnormal high temperature due to overcharge or shorting, the phase change electrolyte inside the device is capable of switching “off” with low ionic conductivities in a gel state and shut down ionic conductive flow to prevent disastrous electrochemical or chemical events, such as thermal runaway and explosion. When temperature of the electrochemical device returns to normal, the phase change material inside the electrochemical device can switch back to “on” with high ionic conductivities in a liquid state, thereby providing electrochemical devices with inherent safety, especially for rechargeable lithium batteries.
    • 本文公开了用于提供可用于改善诸如锂电池的电化学装置的安全性的相变电解质的技术。 在正常工作温度下,相变电解液能够在液态下以高离子电导率“开”。 当电化学装置系统(填充有相变电解质)由于过充电或短路而遇到异常高温时,装置内的相变电解质能够以低离子电导率在凝胶状态下切断,并关闭离子导电 流动以防止灾难性的电化学或化学事件,例如热失控和爆炸。 当电化学装置的温度恢复正常时,电化学装置内的相变材料可以以液体状态的高离子电导率回到“开”状态,从而为电化学装置提供固有的安全性,特别是对于可再充电的锂电池。