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    • 4. 发明授权
    • Chromogenic process for the production of color images using a color
photographic recording material, which contains embedded color
developer compounds that can be activated by heat treatment
    • 用于使用彩色照相记录材料生产彩色图像的显色方法,其包含可通过热处理活化的嵌入式显色剂化合物
    • US6013420A
    • 2000-01-11
    • US92168
    • 1998-06-05
    • Kaspar WingenderGunther Schenk
    • Kaspar WingenderGunther Schenk
    • G03C7/392G03C7/413G03C5/00
    • G03C7/413G03C1/42G03C7/39236G03C7/4136G03C8/402
    • A chromogenic process for the production of color images using, a color photographic recording material with at least one light-sensitive silver halide emulsion layer to which are assigned a thermosolvent, a color coupler and a color developer compound, and optionally further non light-sensitive layers, by exposure and development in an aqueous alkaline treatment bath (activator bath), characterised by the following features (a) and (b):(a) the color developer compound is assigned to the silver halide emulsion layer in the form of an inactive precursor compound corresponding to formula I (capped color developer compound): ##STR1## wherein: R.sup.1 and R.sup.2 (the same or different) mean alkyl with up to 6 carbon atoms;R.sup.3, R.sup.4, R.sup.5 and R.sup.6 (independently of one another) mean H, halogen, --OH, alkyl, alkoxy, acylamino or sulphonamido;M.sup.+ means an alkali metal ion, NH.sub.4.sup.+, a cation derived from a nitrogen-containing organic base, or a compound with a quaternary ammonium group,(b) the recording material undergoes a heat treatment prior to development in order to convert the capped color developer compound to an active form capable of color coupling.
    • 用于使用具有至少一个感光卤化银乳剂层的彩色照相记录材料生产彩色图像的显色方法,其中分配有热溶胶,彩色成色剂和显色剂化合物,以及任选地进一步的非光敏性 通过在含水碱性处理浴(活化剂浴)中曝光和显影,其特征在于以下特征(a)和(b):(a)显色剂化合物被赋予卤化银乳剂层,形式为 对应于式I的无活性前体化合物(加帽显色剂化合物):其中:R1和R2(相同或不同)表示具有至多6个碳原子的烷基; R 3,R 4,R 5和R 6(彼此独立地)表示H,卤素,-OH,烷基,烷氧基,酰氨基或磺酰胺基; M +表示碱金属离子NH 4+,衍生自含氮有机碱的阳离子或具有季铵基团的化合物,(b)记录材料在显影前进行热处理,以便将封盖的彩色显影剂 复合成能够进行彩色偶联的活性形式。
    • 6. 发明授权
    • Photographic recording material
    • 摄影记录材料
    • US4865940A
    • 1989-09-12
    • US309040
    • 1989-02-09
    • Karl-Wilhelm SchranzGunther Schenk
    • Karl-Wilhelm SchranzGunther Schenk
    • G03C1/04G03C1/30G03C7/388
    • G03C7/388
    • A color photographic recording material contains a dispersion of hardened particles of a complex coacervate (packet emulsion) in at least one layer of binder, which particles are hardened with a hardener corresponding to the following formula I ##STR1## wherein R.sup.1 and R.sup.2 are identical or different and each denotes an alkyl group with 1 to 8 carbon atoms or an aryl or aralkyl group optionally substituted with an alkyl group having 1 or 2 carbon atoms or with a halogen atom or R.sup.1 and R.sup.2 together denote the atoms required for completing a heterocyclic ring, e.g. a piperidine or morpholine ring, optionally substituted with an alkyl group having 1 or 2 carbon atoms or with a halogen atom,R.sup.3 denotes a hydrogen atom or an alkyl group having 1 or 2 carbon atoms andn represents 0 or 2.
    • 彩色照相记录材料包含在至少一层粘合剂中的复合凝聚层(包乳液)的硬化颗粒的分散体,该颗粒用对应于下列式I的硬化剂硬化:其中R1和R2相同 或不同,并且各自表示具有1至8个碳原子的烷基或任选被具有1或2个碳原子的烷基或与卤素原子取代的芳基或芳烷基或R 1和R 2一起表示完成杂环所需的原子 环,例如 任选被具有1或2个碳原子的烷基或卤素原子取代的哌啶或吗啉环,R 3表示氢原子或具有1或2个碳原子的烷基,n表示0或2。
    • 8. 发明授权
    • Color photographic recording material containing a non-diffusible dye
releaser from which a complexible azo dye is released during development
    • 包含非扩散性染料释放剂的彩色照相记录材料,在显影过程中从其中释放可络合的偶氮染料
    • US4461827A
    • 1984-07-24
    • US455319
    • 1983-01-03
    • Peter BergthallerGunther SchenkGerhard Wolfrum
    • Peter BergthallerGunther SchenkGerhard Wolfrum
    • C09B29/01C09B29/36C09B45/14G03C8/10G03C5/54G03C1/40G03C7/00
    • C09B29/36C09B29/0007C09B45/14G03C8/10
    • Metal complexes, particularly copper and nickel complexes, of azo dyes corresponding to formula suitable for use as magenta-colored image dyes for the production of colored images by the dye diffusion transfer process. The dyes are linked (in non-metallized form) to a carrier radical provided with a ballast group as so-called color-providing compounds which are associated with a photosensitive silver halide emulsion layer. During development, the metallizable dyes are released imagewise and, after diffusion into an image-receiving layer, are converted into the corresponding metal complexes. ##STR1## In formula II, R.sup.1, R.sup.2, R.sup.3 and R.sup.4 represent H, F, Cl, Br, --CN, --NO.sub.2, --CF.sub.3, --OCH.sub.3, --SCF.sub.3, alkyl, alkoxy, alkylthio, acylamino, alkyl sulphonyl, aryl sulphonyl, --CO--X or --SO.sub.2 Y; or two adjacent radicals from the group of radicals R.sup.1 to R.sup.4 together represent a fused benzene ring;R.sup.5 represents H, alkyl, alkoxy, aryl, alkoxy carbonyl, carbamoyl or cyano,R.sup.6 and R.sup.7 represent H, halogen, alkyl, --CF.sub.3 or --SO.sub.2 --Y,G represents --OH or a hydrolyzable precursor thereof,X represents --OH, alkoxy or an amino group;Y represents H, --OH, an amino group or a group of the formula --NH--SO.sub.2 --R.sup.8 whereR.sup.8 represents alkyl, aryl or an amino group; andm=0 or 1.
    • 金属络合物,特别是铜和镍络合物,对应于适合用作品红色图像染料的式的偶氮染料,用于通过染料扩散转移方法生产彩色图像。 将染料以非金属化形式连接到具有镇流器基团的载体基团上,所述载体基团与感光卤化银乳剂层相关联的所谓的提供色彩的化合物。 在显影过程中,金属化染料被成像释放,并且在扩散到图像接收层中后,转化成相应的金属络合物。 式II中,R 1,R 2,R 3和R 4表示H,F,Cl,Br,-CN,-NO 2,-CF 3,-OCH 3,-SCF 3,烷基,烷氧基,烷硫基,酰氨基,烷基磺酰基, 芳基磺酰基,-CO-X或-SO 2 Y; 或者R 1〜R 4基团的两个相邻基团一起表示稠合苯环; R5代表H,烷基,烷氧基,芳基,烷氧基羰基,氨基甲酰基或氰基,R6和R7表示H,卤素,烷基,-CF3或-SO2-Y,G表示-OH或其可水解的前体,X表示-OH, 烷氧基或氨基; Y表示H,-OH,氨基或式-NH-SO 2 -R 8的基团,其中R 8表示烷基,芳基或氨基; m = 0或1。
    • 9. 发明授权
    • Color photographic recording material
    • 彩色摄影材料
    • US4418143A
    • 1983-11-29
    • US351103
    • 1982-02-22
    • Peter BergthallerGunther SchenkGerhard WolfrumHans-Volker RunzheimerHolger Heidenreich
    • Peter BergthallerGunther SchenkGerhard WolfrumHans-Volker RunzheimerHolger Heidenreich
    • C09B29/01C09B29/36G03C8/10G03C7/00G03C1/10G03C1/40
    • C09B29/36G03C8/10
    • Azo dyes of formula II are released on development from dye releasers which are associated with a light-sensitive silver halide emulsion layer. The azo dyes are chelatable and form with metal ions blue or cyan dye-metal-complex image dyes. ##STR1## In the formula A.sup.1 and A.sup.2 represent electronegative substituents whose meta-sigma values .sigma..sub.m (according to D. H. McDaniel and H. C. Brown in J. Org. Chem. 23, 420 et seq (1958) conform to at least one of the following three relationships:1. .sigma..sub.m (A.sup.1), .sigma..sub.m (A.sup.2) +0.332. .sigma..sub.m (A.sup.1) +.sigma..sub.m (A.sup.2) +0.75;3. .sigma..sub.m (A.sup.1) +0.33 and A.sup.2 represents--SO.sub.2.sup.XX represents H, --OH, --NH.sub.2, --NH--Y or a cyclic amino group, andY represents alkyl, aryl, alkylsulfonyl, arylsulfonyl or acylQ represents a group for completing a 2-amino-3-hydroxypyridine ring, a 4,5-diphenylimidazole ring or a 4-hydroxyisoquinoline ring which is attached through the 1-position; andG represents a group capable of chelate formation.
    • 式II的偶氮染料在与感光卤化银乳剂层相关的染料释放剂的显影下释放。 偶氮染料是可螯合的,与金属离子形成蓝色或青色染料 - 金属络合物图像染料。 式中,A1和A2表示电子负值取代基,其σ-σ值σ(根据DHMandaniel和HCBrown在J.Org.Chem.23,320和seq(1958)中符合以下至少一个) 三个关系:1.西格玛(A1),西格玛(A2)+0.33 2.西格玛(A1)+西格玛(A2)+0.75;西格玛(A1)+0.33和A2代表-SO2X H,-OH,-NH 2,-NH-Y或环状氨基,Y表示烷基,芳基,烷基磺酰基,芳基磺酰基或酰基Q表示完成2-氨基-3-羟基吡啶环的基团, 二苯基咪唑环或通过1-位连接的4-羟基异喹啉环; G表示能够螯合形成的基团。
    • 10. 发明授权
    • Photographic recording material with metal complexable, heterocyclic azo
dye
    • 摄影记录材料与金属络合,杂环偶氮染料
    • US4396710A
    • 1983-08-02
    • US367761
    • 1982-04-12
    • Peter BergthallerGunther SchenkGerhard WolfrumHans-Volker Runzheimer
    • Peter BergthallerGunther SchenkGerhard WolfrumHans-Volker Runzheimer
    • G03C7/26C07D471/04C09B27/00C09B29/36C09B45/00G03C8/10G03C1/40G03C1/10G03C5/54
    • C09B27/00C09B29/3647C09B45/00G03C8/10
    • Cyan images may be prepared by the dye diffusion transfer process, using dye-releasers which on development release diffusible dyes capable of forming light-fast cyan metal-dye-complexes particularly with copper or nickel ions. As also the dye-releasers are capable of complexation, cyan images can be prepared not only from the released dyes but also from the dye-releasers ("retained image"). Released dyes and dye-releasers of the present invention contain a chromophor of the following formula: ##STR1## wherein R.sup.1, R.sup.2, R.sup.3 and R.sup.4, which may be the same or different, each represents --H, --F, --Cl, --Br, --CN, --NO.sub.2, --CF.sub.3, --OCF.sub.3, --SCF.sub.3, alkyl, alkoxy, alkylthio, acylamino, alkylsulfonyl, arylsulfonyl, --CO--X or --SO.sub.2 --Y or two adjacent groups R.sup.1 -R.sup.4 together constitute a condensed benzene ring which may contain further substituents;R.sup.5 represents hydrogen or a substituent having an electron donor character;R.sup.6 represents hydrogen, halogen or alkyl;G represents a group capable of chelate formation;X represents --OH, alkoxy, an amino group optionally substituted by alkyl or aryl, or a cyclic amino group;Y represents --H, --OH, an amino group optionally substituted by alkyl or aryl, a cyclic amino group or a group corresponding to the following general formula: --NH--So.sub.2 --R.sup.7 ;R.sup.7 represents alkyl, aryl, an amino group optionally disubstituted by alkyl or a cyclic amino group; andn represents 0 or 1.
    • 青色图像可以通过染料扩散转移法制备,使用染料释放剂,其在显影时释放能够形成特别是铜或镍离子的快速青色金属 - 染料 - 络合物的扩散染料。 染料释放剂也能够络合,不仅可以从释放的染料中制备青色图像,而且可以从染料释放剂(“保留图像”)制备青色图像。 本发明的释放的染料和染料释放剂含有下式的发色团:其中R1,R2,R3和R4可以相同或不同,表示-H,-F,-Cl, - Br,-CN,-NO 2,-CF 3,-OCF 3,-SCF 3,烷基,烷氧基,烷硫基,酰氨基,烷基磺酰基,芳基磺酰基,-CO-X或-SO 2 -Y或两个相邻基团R 1 -R 4一起构成稠合苯 可以含有其它取代基的环; R5表示氢或具有电子供体特性的取代基; R6表示氢,卤素或烷基; G表示能够螯合形成的基团; X表示-OH,烷氧基,任选被烷基或芳基取代的氨基或环状氨基; Y表示-H,-OH,任选被烷基或芳基取代的氨基,环状氨基或对应于以下通式的基团:-NH-SO 2 -R 7; R7表示烷基,芳基,任选被烷基或环氨基二取代的氨基; n表示0或1。