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    • 1. 发明授权
    • Method for forming SBT ferroelectric thin film
    • 形成SBT铁电薄膜的方法
    • US6090455A
    • 2000-07-18
    • US128938
    • 1998-08-05
    • Ho Gi KimWon Jae LeeSoon Gil YoonJoon Hyung Ahn
    • Ho Gi KimWon Jae LeeSoon Gil YoonJoon Hyung Ahn
    • C23C16/40C23C16/50H05H1/20
    • C23C16/40
    • A method for forming SBT ferroelectric thin film. Sr(C.sub.5 F.sub.6 HO.sub.2).sub.2, Bi(C.sub.6 H.sub.5).sub.3 and Ta(C.sub.2 H.sub.5 O).sub.5 are used as the precursors of Sr, Bi and Ta and bubbled at a temperature of 110-130.degree. C., 140-160.degree. C., and 120-140.degree. C., respectively. The deposition of the precursors on a substrate is carried out at 500-550.degree. C. in plasma by using an RF power of 100-150 W. Having a residual polarity (Pr) of 15 .mu.C/cm.sup.2 or higher and a coercive electric field (Ec) of 50 kV/cm or less and, the SBT ferroelectric thin film does not show a fatigue phenomenon until 1.times.10.sup.11 cycles as measured under 6V bipolar square pulse in the structure comprising Pt upper and lower electrodes and thus, can be applied for non-volatile memory devices.
    • 一种形成SBT铁电薄膜的方法。 Sr(C5F6HO2)2,Bi(C6H5)3和Ta(C2H5O)5用作Sr,Bi和Ta的前体,在110-130℃,140-160℃,120 -140℃。 通过使用100-150W的RF功率,在等离子体中在500-550℃下在基板上沉积前体。残留极性(Pr)为15μC/ cm 2以上,矫顽电 (Ec)为50kV / cm以下,SBT铁电薄膜在由Pt上下电极构成的6V双极性方波脉冲下测定的1×10 11个循环之前不显示疲劳现象,因此可以应用于 非易失性存储器件。