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    • 3. 发明授权
    • Opaque quartz glass and process for production thereof
    • 不透明石英玻璃及其生产方法
    • US5972488A
    • 1999-10-26
    • US887967
    • 1997-07-03
    • Hiroya NagataKoji TsukumaMasayuki Kudo
    • Hiroya NagataKoji TsukumaMasayuki Kudo
    • C03B19/09C03C3/06C03C11/00B32B17/00
    • C03C11/007C03B19/09C03C3/06C03C2201/80C03C2203/10Y10T428/249953Y10T428/249969Y10T428/2975
    • Opaque quartz glass is provided which contains gas bubbles uniformly dispersed therein and is excellent in high-temperature viscosity and heat-insulating property. The opaque quartz glass has a defined apparent density, contains bubbles having a defined average bubble diameter in a defined amount, has a defined total bubble sectional area, generally exhibits a defined linear transmittance at a thickness of 1 mm or larger to projected light of a defined wavelength and contains nitrogen in a defined concentration. The opaque quartz glass is produced by a process comprising packing into a mold a powdery source material of powdery silica having a defined average particle diameter and powdery silicon nitride dispersed therein in a defined amount, heating the powdery source material to one of two first defined temperature ranges (both under vacuum) and further heating the source material up to a second temperature higher than the melting point and not higher than 1900.degree. C. in a vacuum or an inert gas atmosphere for vitrification and bubble formation.
    • 提供了不透明石英玻璃,其包含均匀分散在其中的气泡,并且具有优异的高温粘度和绝热性能。 不透明石英玻璃具有限定的表观密度,包含具有确定的具有确定的平均气泡直径的气泡,具有确定的总气泡截面面积,通常在1mm以上的厚度下呈现出规定的线性透射率, 并含有规定浓度的氮。 不透明石英玻璃是通过一种方法生产的,该方法包括将具有确定的平均粒径的粉末二氧化硅的粉状源材料和分散在其中的粉末状氮化硅以规定的量包装在模具中,将粉末源材料加热至两个第一限定温度 范围(均为真空),并在真空或惰性气体气氛中将源材料进一步加热至高于熔点且不高于1900℃的第二温度,用于玻璃化和气泡形成。
    • 4. 发明授权
    • Opaque silica glass article having transparent portion and process for producing same
    • 具有透明部分的不透明二氧化硅玻璃制品及其制造方法
    • US06312775B1
    • 2001-11-06
    • US09173685
    • 1998-10-16
    • Hiroya NagataMasayuki KudoKoji Tsukuma
    • Hiroya NagataMasayuki KudoKoji Tsukuma
    • B32B1700
    • C03B19/09C03C3/06C03C11/007C03C2201/24C03C2201/80C03C2203/10Y10S65/08Y10T428/1317Y10T428/249969
    • An opaque silica glass article comprising a transparent portion and an opaque portion, wherein the opaque portion has an apparent density of 1.70-2.15 g/cm3 and contains 5×104−5×106 bubbles per cm3, said bubbles having an averaged diameter of 10-100 &mgr;m; and the transparent portion has an apparent density of 2.19-2.21 g/cm3 and the amount of bubbles having a diameter of at least 100 &mgr;m in the transparent portion is not more than 1×103 per cm3. The opaque silica glass article is made by a process wherein a mold is charged with a raw material for forming the opaque portion, which is a mixture comprising a silica powder with a small amount of a silicon nitride powder, and a raw material for forming the transparent portion so that the two raw materials are located in the positions corresponding to the opaque and the transparent portions, respectively, of the silica glass article to be produced; and the raw materials are heated in vacuo to be thereby vitrified.
    • 一种不透明的石英玻璃制品,其包括透明部分和不透明部分,其中所述不透明部分的表观密度为1.70-2.15g / cm 3,并且每立方厘米含有5×10 4至5×10 6个气泡,所述气泡具有10-100μm的平均直径; 并且透明部分的表观密度为2.19-2.21g / cm 3,透明部分中直径至少为100μm的气泡量不超过1×103 / cm3。 不透明的石英玻璃制品通过以下方法制造,其中模具装有用于形成不透明部分的原料,该不透明部分是包含少量氮化硅粉末的二氧化硅粉末的混合物,以及用于形成 透明部分,使得两个原料分别位于与待制造的石英玻璃制品的不透明部分和透明部分相对应的位置; 并将原料真空加热,从而玻璃化。