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1. 发明申请

US20090166911A1 Process for Producing Molded Article by T-Die Molding 审中-公开
标题翻译： T型模具成型制造工艺
公开(公告)号：US20090166911A1
公开(公告)日：2009-07-02
申请号：US12225527
申请日：2007-03-23
申请人： Hirotaka Uosaki , Kuniaki Kawabe , Motoyasu Yasui , Hideki Kuroki , Terufumi Suzuki , Hideo Nakamura , Yasushi Amada
发明人： Hirotaka Uosaki , Kuniaki Kawabe , Motoyasu Yasui , Hideki Kuroki , Terufumi Suzuki , Hideo Nakamura , Yasushi Amada
IPC分类号： B29C39/42 , B29C39/00
CPC分类号： C08L23/04 , B29C48/08 , B29C48/30 , B29C48/305 , B29C48/914 , C08J5/18 , C08J2323/02 , C08J2323/10 , C08L23/02 , C08L23/06 , C08L2205/02 , C08L91/06 , C08L2666/06
摘要： [Object] Disclosed is to provide a process for producing a molded article of polyethylene excellent in mechanical properties while the productivity at the time of T-die molding is improved, and a process for producing a secondary molded article by vacuum molding of the molded article with high formability. [Means to Solve the Problems] A process for producing a molded article by T-die molding of a mixture comprising a polyolefinic resin and a polyethylene wax, the polyethylene wax having a density of 880 to 980 (kg/m3) as measured by a density gradient tube method in accordance with JIS K7112 and a number average molecular weight (Mn) of 500 to 4,000 in terms of polyethylene as determined by gel permeation chromatography (GPC) and satisfying the relationship shown by the following expression (I): B≦0.0075×K (I) (In the expression (I), B is a content ratio (% by weight) of components having a molecular weight of 20,000 or more in terms of polyethylene in the polyethylene wax as determined by gel permeation chromatography and K is a melt viscosity (mPa·s) of the polyethylene wax at 140° C.).
摘要翻译：本发明提供一种制造机械特性优异的聚乙烯模塑制品的方法，同时提高T型模塑成型时的生产率，以及通过真空成型模制品制备二次模制品的方法具有高成形性。解决问题的手段通过使用包含聚烯烃树脂和聚乙烯蜡的混合物的T模成型来制造模制品的方法，通过以下方式测量密度为880至980（kg / m 3）的聚乙烯蜡按照JIS K7112的密度梯度管法和通过凝胶渗透色谱法（GPC）测定的聚乙烯换算的数均分子量（Mn）为500〜4000，满足下述式（I）所示的关系： in-line-formula description =“In-line Formulas”end =“lead”？> B <= 0.0075xK（I）<？in-line-formula description =“In-line Formulas”end =“tail”？> （式（I）中，B是通过凝胶渗透色谱法测定的聚乙烯蜡中的分子量为20,000以上的分子量为20,000以上的成分的含有比例（重量％），K为熔融粘度（mPa .s）的聚乙烯蜡在140℃）。

2. 发明申请

US20090137729A1 Process for Producing Oriented Film 审中-公开
标题翻译：制作定向胶片的方法
公开(公告)号：US20090137729A1
公开(公告)日：2009-05-28
申请号：US12225581
申请日：2007-03-26
申请人： Hirotaka Uosaki , Kuniaki Kawabe , Motoyasu Yasui , Terufumi Suzuki , Hideo Nakamura , Yasushi Amada
发明人： Hirotaka Uosaki , Kuniaki Kawabe , Motoyasu Yasui , Terufumi Suzuki , Hideo Nakamura , Yasushi Amada
IPC分类号： C08K5/01
CPC分类号： B29C55/005 , B29C55/06 , B29K2023/06 , B29K2023/12 , B29K2091/00 , B29K2105/0038 , C08J5/18 , C08J2323/08 , C08L23/06 , C08L23/0815 , C08L23/10 , C08L2314/06 , C08L2666/06
摘要： [Object]Disclosed is to provide a process for producing a film by using a raw material comprising a polyethylene having a density of 900 to 980 kg/m3 or a polypropylene, whereby improving the productivity at the time of producing the film by a stretch molding. Further the film is obtained without impairing the optical characteristics and mechanical characteristics, which are intrinsic characteristics of polyethylene or polypropylene. [Solving Means]A process for producing a film by a stretch molding of a mixture comprising a polyethylene and a polyethylene wax, the polyethylene having a density of 900 to 980 kg/m3 and an MI of 0.01 to 100 g/10-minutes as measured at 190° C. and a testing load of 21.18 N in accordance with JIS K7210 or a polypropylene, and the polyethylene wax having a density of 890 to 980 kg/m3 and a number-average molecular weight (Mn) of 500 to 4,000 as measured by the gel permeation chromatography (GPC) and satisfying the relationship shown by the following equation (I). B≦0.0075×K (I) (In the above formula (I), B represents the weight ratio (% by weight) of a component having a molecular weight of 20,000 or more in terms of polyethylene as measured by the gel permeation chromatography in the polyethylene wax, and K represents the melt viscosity (mPa·s) of the polyethylene wax at 140° C.)
摘要翻译：公开了通过使用密度为900〜980kg / m 3的聚乙烯或聚丙烯的原料制造膜的方法，由此通过拉伸成型提高膜的制造时的生产率。此外，在不损害作为聚乙烯或聚丙烯的固有特性的光学特性和机械特性的情况下获得膜。本发明提供一种通过拉伸成型包含聚乙烯和聚乙烯蜡的混合物制造膜的方法，聚乙烯的密度为900至980kg / m 3，MI为0.01至100g / 10分钟，为根据JIS K7210或聚丙烯在190℃下测定的试验负荷为21.18N，密度为890〜980kg / m 3，数均分子量（Mn）为500〜4000的聚乙烯蜡通过凝胶渗透色谱法（GPC）测定，满足下述式（I）所示的关系。 <？in-line-formula description =“In-line Formulas”end =“lead”？> B <= 0.0075xK（I）<？in-line-formula description =“In-line Formulas”end =“tail” （上式（I）中，B表示通过聚乙烯蜡中的凝胶渗透色谱法测定的分子量为20,000以上的聚乙烯成分的重量比（重量％），K表示表示聚乙烯蜡在140℃下的熔融粘度（mPa.s）

3. 发明申请

US20090127751A1 Process for Producing Molded Product by Inflation Molding 审中-公开
标题翻译：通过膨胀成型生产成型产品的方法
公开(公告)号：US20090127751A1
公开(公告)日：2009-05-21
申请号：US12224835
申请日：2007-02-27
申请人： Hirotaka Uosaki , Kuniaki Kawabe , Motoyasu Yasui , Hideki Kuroki , Hideo Nakamura , Yasushi Amada
发明人： Hirotaka Uosaki , Kuniaki Kawabe , Motoyasu Yasui , Hideki Kuroki , Hideo Nakamura , Yasushi Amada
IPC分类号： B29D22/00
CPC分类号： C08L23/04 , B29C48/0018 , B29C48/0019 , B29C48/10 , B29C48/21 , B29C48/912 , B29K2023/06 , B29K2105/256 , B29K2491/00 , C08K5/01 , C08L23/06 , C08L2205/02 , C08L2666/06
摘要： A process for producing a molded product by inflation molding, which is improved in productivity in molding and can give a molded product not impaired in properties inherent in polyethylene, wherein a molded product is produced by inflation molding using a mixture comprising polyethylene having a density of 900 to 980 (kg/m3) and a polyethylene wax having a density of 890 to 980 (kg/m3) and a number-average molecular weight (Mn), as measured by gel permeation chromatography (GPC), of 500 to 4,000 in terms of polyethylene and satisfying a relationship represented by the following formula (I): B≦0.0075×K (I) wherein B is a content (% by weight) of a component having a molecular weight, as measured by gel permeation chromatography, of not less than 20,000 in terms of polyethylene, in the polyethylene wax, and K is a melt viscosity (mPa·s) of the polyethylene wax at 140° C.
摘要翻译：一种通过吹塑成型制造模制产品的方法，其提高了模塑生产率，并且可以得到不损害聚乙烯固有性能的模塑制品，其中通过使用包含密度为 900〜980（kg / m 3），通过凝胶渗透色谱法（GPC）测定的密度为890〜980（kg / m 3），数均分子量（Mn）的聚乙烯蜡为500〜4000 聚乙烯的术语并满足由下式（I）表示的关系：<？in-line-formula description =“In-line Formulas”end =“lead”？> B <= 0.0075xK（I）<？ line-formula description =“In-line Formulas”end =“tail”？>其中B是通过凝胶渗透色谱法测定的具有分子量的组分的含量（重量％），不小于20,000 的聚乙烯蜡，聚乙烯蜡中的K是熔体粘度（mPa.s） 140℃

4. 发明授权

US08258227B2 Laminating resin composition and multilayer structure 有权
标题翻译：层压树脂组合物和多层结构
公开(公告)号：US08258227B2
公开(公告)日：2012-09-04
申请号：US12745245
申请日：2008-11-25
申请人： Kuniaki Kawabe , Hirotaka Uosaki , Motoyasu Yasui , Hideo Nakamura , Yasushi Amada , Akihito Ohga
发明人： Kuniaki Kawabe , Hirotaka Uosaki , Motoyasu Yasui , Hideo Nakamura , Yasushi Amada , Akihito Ohga
IPC分类号： C08K5/01 , C08F210/00
CPC分类号： C08L23/02 , B32B5/022 , B32B5/024 , B32B7/12 , B32B15/08 , B32B15/20 , B32B21/08 , B32B27/08 , B32B27/10 , B32B27/12 , B32B27/18 , B32B27/20 , B32B27/22 , B32B27/302 , B32B27/304 , B32B27/306 , B32B27/308 , B32B27/32 , B32B27/34 , B32B27/36 , B32B27/365 , B32B2255/10 , B32B2255/20 , B32B2255/205 , B32B2255/26 , B32B2270/00 , B32B2307/306 , B32B2307/412 , B32B2307/50 , B32B2307/514 , B32B2307/5825 , B32B2307/702 , B32B2307/714 , B32B2307/72 , C08K5/098 , C08K5/10 , C08L23/06 , C08L23/0815 , C08L23/12 , C08L23/142 , C08L91/06 , C08L2205/02 , C08L2207/066 , C08L2666/06
摘要： Laminating resin compositions of the invention enable excellent productivity in the lamination processes, and are free from deterioration in optical characteristics such as transparency or surface properties inherent to resins such as polypropylenes. Multilayer structures obtained by laminating the composition on a substrate have tear strength which is as high as that of multilayer structures obtained by simply laminating a polyolefin resin such as polypropylene on a substrate. The laminating resin composition includes a polyolefin resin and a polyethylene wax having a density in the range of 890 to 955 kg/m3 as measured by a density gradient tube method in accordance with JIS K 7112 and a number average molecular weight (Mn) in terms of polyethylene in the range of 500 to 2900 as measured by gel permeation chromatography (GPC).
摘要翻译：本发明的层压树脂组合物能够实现层压方法的优异的生产率，并且不会导致诸如聚丙烯等树脂固有的透明性或表面性能等光学特性的劣化。通过将组合物层叠在基材上而获得的多层结构体具有与在基材上简单层压聚丙烯等聚烯烃树脂而得到的多层结构一样高的撕裂强度。层压树脂组合物包括通过根据JIS K 7112的密度梯度管法和数均分子量（Mn）测量的密度在890至955kg / m 3范围内的聚烯烃树脂和聚乙烯蜡的聚乙烯，其通过凝胶渗透色谱（GPC）测量的范围为500至2900。

5. 发明申请

US20070080483A1 Process for producing injection molded product 审中-公开
标题翻译：注塑产品生产工艺
公开(公告)号：US20070080483A1
公开(公告)日：2007-04-12
申请号：US11543901
申请日：2006-10-06
申请人： Hirotaka Uosaki , Kuniaki Kawabe , Motoyasu Yasui
发明人： Hirotaka Uosaki , Kuniaki Kawabe , Motoyasu Yasui
IPC分类号： B29C45/00 , C08L91/08 , C08J3/22 , C08K5/01
CPC分类号： B29C45/0001 , B29K2105/0094 , C08K5/01 , C08L23/02 , C08L23/06 , C08L23/10 , C08L23/16 , C08L91/06 , C08L91/08 , C08L2205/03 , C08L2666/04 , C08L2666/06 , C08L2666/02
摘要： The present invention provides an injection molding process of a thermoplastic resin which is capable of thin molding or precision molding by improving injection moldability, particularly releasability or fluidity, without deteriorating the characteristics of the injection molded article of the thermoplastic resin. The process for producing an injection molded product comprises injection molding a mixture containing a thermoplastic resin and a polyolefin wax, wherein the mixture has L/L0≧1.05, the L being a flow length in the case where the mixture contains the polyolefin wax and the Lo being a flow length in the case where the mixture contains no polyolefin wax, the L and L0 being measured under the conditions of a mold temperature of 40° C. and a resin temperature, Tr, as determined by the following equation: Tr=¾×Tm+100(wherein Tm represents a melting temperature (° C.) of the thermoplastic resin), using a spiral flow mold having a thickness of 1 mm and a width of 10 mm.
摘要翻译：本发明提供一种热塑性树脂的注射成型方法，其能够通过提高注射成型性，特别是脱模性或流动性而能够进行薄型化或精密成型，而不会降低热塑性树脂的注塑制品的特性。制造注射成型制品的方法包括注射模塑含有热塑性树脂和聚烯烃蜡的混合物，其中混合物的L / L <0.01 / L = 1.05，L是在该情况下的流动长度其中混合物包含聚烯烃蜡，并且在混合物不含聚烯烃蜡的情况下Lo为流动长度，在模具温度为40℃的条件下测量L和L 0 和树脂温度Tr，由以下等式确定：<？in-line-formula description =“In-line Formulas”end =“lead”？> Tr =¾xTm+ 100 <？in-line-formula description （“In-line Formulas”end =“tail”？>（其中Tm表示热塑性树脂的熔融温度（℃）），使用厚度为1mm，宽度为10mm的螺旋流动模具。

6. 发明申请

US20080064805A1 Process for producing injection molded product 审中-公开
标题翻译：注塑产品生产工艺
公开(公告)号：US20080064805A1
公开(公告)日：2008-03-13
申请号：US11806416
申请日：2007-05-31
申请人： Hirotaka Uosaki , Kuniaki Kawabe , Motoyasu Yasui
发明人： Hirotaka Uosaki , Kuniaki Kawabe , Motoyasu Yasui
IPC分类号： B29C45/00
CPC分类号： C08L23/02 , B29C45/0001 , B29K2105/0094 , C08K5/01 , C08L23/06 , C08L23/10 , C08L23/16 , C08L91/06 , C08L91/08 , C08L2205/03 , C08L2666/04 , C08L2666/06 , C08L2666/02
摘要： The present invention provides a process for producing an injection molded product comprising injection molding a mixture containing a thermoplastic resin (A) and a polyolefin wax (B), wherein the mixture has L/L0≧1.05, the L being a flow length in the case where the mixture contains the polyolefin wax and the L0 being a flow length in the case where the mixture contains no polyolefin wax, the L and L0 being measured under the conditions of a mold temperature of 40° C. and a resin temperature, Tr, as determined by the following expression: Tr=3/4×Tm+100 (wherein Tm represents a melting temperature (° C.) of the thermoplastic resin), using a spiral flow mold having a thickness of 1 mm and a width of 10 mm. According to the invention, by adding the polyolefin wax, a flow length of a thermoplastic resin can be lengthened, and releasability can be improved, and thus the thermoplastic resin can be thin molded or precision molded by injection molded without deteriorating the characteristics of the molded product to be obtained.
摘要翻译：本发明提供一种注射成型制品的制造方法，其特征在于，包括注射成型含有热塑性树脂（A）和聚烯烃蜡（B）的混合物的混合物，其中所述混合物的L / L <0.01 在混合物不含聚烯烃蜡的情况下，L是流动长度，在混合物含有聚烯烃蜡和L 0 O 3是流动长度的情况下，L和L < 0℃在模具温度为40℃的条件下测定，树脂温度Tr通过以下表达式确定：<？in-line-formula description =“In-line formula”end = “lead”→Tr = 3 / 4xTm + 100 <？in-line-formula description =“In-line Formulas”end =“tail”？>（其中Tm表示热塑性树脂的熔融温度（℃）），使用厚度为1mm，宽度为10mm的螺旋流动模具。根据本发明，通过添加聚烯烃蜡，可以延长热塑性树脂的流动长度，并且可以提高脱模性，因此热塑性树脂可以通过注射成型而被模制成型或精密模制而不会劣化成型的特性产品要获得。

7. 发明申请

US20070100056A1 Process for producing thermoplastic resin composition 审中-公开
标题翻译：热塑性树脂组合物的制造方法
公开(公告)号：US20070100056A1
公开(公告)日：2007-05-03
申请号：US11589854
申请日：2006-10-31
申请人： Hirotaka Uosaki , Kuniaki Kawabe , Motoyasu Yasui
发明人： Hirotaka Uosaki , Kuniaki Kawabe , Motoyasu Yasui
IPC分类号： C08L91/08
CPC分类号： C08J3/005 , C08J2323/10 , C08K5/01 , C08L23/06 , C08L23/10 , C08L91/08 , C08L101/00 , C08L2314/06 , C08L2666/06
摘要： The present invention provides a process for producing a thermoplastic resin composition having good dispersibility of a polyolefin wax for a thermoplastic resin under a stable production condition, a process for producing a molded product using the thermoplastic resin composition, and a molded product obtained from the thermoplastic resin composition. According to the present invention, a mixture of a wax masterbatch (A) containing a polyolefin wax and a thermoplastic resin, and a thermoplastic resin (B) is melt-kneaded to prepare the thermoplastic resin composition and the molded product.
摘要翻译：本发明提供一种在稳定的生产条件下制备热塑性树脂聚烯烃蜡具有良好分散性的热塑性树脂组合物的方法，使用该热塑性树脂组合物制备模塑产品的方法和由热塑性树脂树脂组合物。根据本发明，将含有聚烯烃蜡的蜡母料（A）和热塑性树脂（B）与热塑性树脂（B）的混合物进行熔融捏合以制备热塑性树脂组合物和模塑产品。

8. 发明授权

US07605208B2 Process for producing thermoplastic resin composition 有权
标题翻译：热塑性树脂组合物的制造方法
公开(公告)号：US07605208B2
公开(公告)日：2009-10-20
申请号：US11589853
申请日：2006-10-31
申请人： Hirotaka Uosaki , Kuniaki Kawabe , Motoyasu Yasui
发明人： Hirotaka Uosaki , Kuniaki Kawabe , Motoyasu Yasui
IPC分类号： C08J3/22
CPC分类号： C08J3/005 , C08J2323/02 , C08L23/06 , C08L23/10 , C08L91/08 , C08L101/00 , C08L2314/06 , C08L2666/06
摘要： The present invention provides a process for producing a thermoplastic resin composition comprising a polyolefin wax having good dispersibility for a thermoplastic resin, a molded product, which is excellent in physical properties such as blocking property and mechanical properties, from the thermoplastic resin composition and a process for producing the molded product.Specifically, a process for producing a thermoplastic resin composition comprises melt-kneading a mixture of a polyolefin wax (A) which has a passing ratio through a mesh having a sieve opening of 5.66 mmφ of 95% by weight or more, and a non-passing ratio through a mesh having a sieve opening of 2.00 mmφ of 95% by weight or more, and is in the particle form, and a thermoplastic resin (B), a molded product, which is excellent in physical properties such as blocking property and mechanical properties, obtained from the thermoplastic resin composition and a process for producing the molded product are provided.
摘要翻译：本发明提供一种热塑性树脂组合物的制造方法，该热塑性树脂组合物包含热塑性树脂具有良好分散性的聚烯烃蜡，热塑性树脂组合物的物理性能如机械性能优异的成型体，以及工序用于生产模制产品。具体而言，制造热塑性树脂组合物的方法包括将具有95重量％以上的筛孔5.66mmφ的筛网的通过率的聚烯烃蜡（A）的混合物熔融捏合，通孔比为2.00mmφ的筛孔为95重量％以上的筛网，为粒状，热塑性树脂（B），成型品，其物理性质如粘合性优异，提供从热塑性树脂组合物获得的机械性能和制造模塑产品的方法。

9. 发明申请

US20070100055A1 Process for producing thermoplastic resin composition 有权
标题翻译：热塑性树脂组合物的制造方法
公开(公告)号：US20070100055A1
公开(公告)日：2007-05-03
申请号：US11589853
申请日：2006-10-31
申请人： Hirotaka Uosaki , Kuniaki Kawabe , Motoyasu Yasui
发明人： Hirotaka Uosaki , Kuniaki Kawabe , Motoyasu Yasui
IPC分类号： C08L91/08
CPC分类号： C08J3/005 , C08J2323/02 , C08L23/06 , C08L23/10 , C08L91/08 , C08L101/00 , C08L2314/06 , C08L2666/06
摘要： The present invention provides a process for producing a thermoplastic resin composition comprising a polyolefin wax having good dispersibility for a thermoplastic resin, a molded product, which is excellent in physical properties such as blocking property and mechanical properties, from the thermoplastic resin composition and a process for producing the molded product. Specifically, a process for producing a thermoplastic resin composition comprises melt-kneading a mixture of a polyolefin wax (A) which has a passing ratio through a mesh having a sieve opening of 5.66 mmφ of 95% by weight or more, and a non-passing ratio through a mesh having a sieve opening of 2.00 mmφ of 95% by weight or more, and is in the particle form, and a thermoplastic resin (B), a molded product, which is excellent in physical properties such as blocking property and mechanical properties, obtained from the thermoplastic resin composition and a process for producing the molded product are provided.
摘要翻译：本发明提供一种热塑性树脂组合物的制造方法，该热塑性树脂组合物包含热塑性树脂具有良好分散性的聚烯烃蜡，热塑性树脂组合物的物理性能如机械性能优异的成型体，以及工序用于生产模制产品。具体而言，制造热塑性树脂组合物的方法包括将具有95重量％以上的筛孔5.66mmφ的筛网的通过率的聚烯烃蜡（A）的混合物熔融捏合，通孔比为2.00mmφ的筛孔为95重量％以上的筛网，为粒状，热塑性树脂（B），成型品，其物理性质如粘合性优异，提供从热塑性树脂组合物获得的机械性能和制造模塑产品的方法。

10. 发明申请

US20070225423A1 Process for producing blow molded product by blow molding 审中-公开
标题翻译：通过吹塑生产吹塑成型产品的方法
公开(公告)号：US20070225423A1
公开(公告)日：2007-09-27
申请号：US11730286
申请日：2007-03-30
申请人： Hirotaka Uosaki , Kuniaki Kawabe , Motoyasu Yasui
发明人： Hirotaka Uosaki , Kuniaki Kawabe , Motoyasu Yasui
IPC分类号： C08L91/08
CPC分类号： B29C49/0005 , B29C49/04 , B29C49/06 , B29K2023/12 , C08L23/04 , C08L2205/02 , C08L2666/02
摘要： Provided is a process for efficiently producing a molded product with an improved moldability in blow molding and no deterioration of the physical properties of the molded product. The process comprises melting a mixture of a thermoplastic resin and a polyolefin wax which has a number-average molecular weight (Mn) in terms of polyethylene, as measured by gel permeation chromatography (GPC), in the range of 200 to 5,000, and a crystallization temperature, as measured by a differential scanning calorimetry (DSC), in the range of 65 to 120° C.; and then subjecting the mixture to blow molding.
摘要翻译：提供了一种有效地生产具有改进的吹塑成形性的模制品的成型产品的方法，并且不会使成型品的物理性能下降。该方法包括将通过凝胶渗透色谱法（GPC）测得的数均分子量（Mn）以聚乙烯换算的热塑性树脂和聚烯烃蜡的混合物在200至5000范围内熔融，通过差示扫描量热法（DSC）测量的结晶温度在65至120℃的范围内。然后对混合物进行吹塑。

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