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    • 2. 发明授权
    • Curable resin, process for making and electronic part protective coating
    • 可固化树脂,制造工艺和电子部件保护涂层
    • US5346979A
    • 1994-09-13
    • US3398
    • 1993-01-12
    • Hiroshige OkinoshimaHideto Kato
    • Hiroshige OkinoshimaHideto Kato
    • C07F7/10C08G73/10C08G77/48C08G77/54H01B3/46C08G77/26
    • C08G73/106C08G73/101C08G73/1039
    • A novel curable polyimide resin of structural formula (1) or (2) is provided wherein R.sup.1 and R.sup.2 are independently substituted or unsubstituted monovalent C.sub.1-10 hydrocarbon groups, R.sup.3 is a divalent C.sub.1-10 organic group, X is a tetravalent organic group containing an aromatic or aliphatic ring, Y is a divalent organic group, Z is a divalent organic group containing an aromatic ring, W is a trivalent organic group containing an aromatic ring, m is an integer of 1 to 3, and n is an integer of at least 1. It can be prepared by reacting a polyimide with a silicon compound. The curable resin forms with a solvent a solution having a low viscosity and shelf stability and cures at relatively low temperatures below 300.degree. C. into coatings having heat resistance, mechanical strength, electrical properties, solvent resistance and substrate adherence. ##STR1##
    • 提供了结构式(1)或(2)的新型可固化聚酰亚胺树脂,其中R1和R2独立地是取代或未取代的一价C1-10烃基,R3是二价C1-10有机基团,X是含四价有机基团 芳香族或脂肪族环,Y为二价有机基团,Z为含有芳香环的二价有机基团,W为含有芳环的三价有机基团,m为1〜3的整数,n为 可以通过使聚酰亚胺与硅化合物反应来制备。 固化树脂与溶剂形成具有低粘度和储存稳定性的溶液,并且在低于300℃的相对低的温度下固化成具有耐热性,机械强度,电性能,耐溶剂性和基材粘附性的涂层。
    • 9. 发明授权
    • Photo-curable organopolysiloxane composition and a method for producing
a (meth) acryloyloxyl group-containing organopolysiloxane used therein
    • 光固化型有机聚硅氧烷组合物及其中使用的(甲基)丙烯酰氧基的有机聚硅氧烷的制造方法
    • US5738976A
    • 1998-04-14
    • US617240
    • 1996-03-18
    • Hiroshige OkinoshimaTsutomu KashiwagiShinsuke Yamaguchi
    • Hiroshige OkinoshimaTsutomu KashiwagiShinsuke Yamaguchi
    • C08G77/20G03F7/075
    • G03F7/0757C08G77/20
    • The composition comprises a (meth)acryloyloxyl group-containing organopolysiloxane having an average molecular weight of 3,000 to 100,000, in terms of polystyrene, and a photosensitizer. Such an organopolysiloxane having an average molecular weight of 3,000 or more is produced by subjecting (meth)acryloyloxypropyltrimethoxysilane and phenyltrimethoxysilane to cohydrolysis and subsequent condensation polymerization to produce a cohydrolysis-condensation polymerization product and then reacting and silylating the same product with a silylating agent such as hexamethyldisilazane. The composition containing such a high molecular weight (meth)acryloyloxyl-group-containing organopolysiloxane is excellent in sensitivity, resolution and storage stability and has little tackiness in uncured state after being coated, as well as being excellent in heat resistance after being cured. Thus, the composition is useful for photosensitive heat-resistant materials for use in semiconductor lithography and photosensitive heat-resistant materials for use in semiconductor passivation.
    • 该组合物包含平均分子量为3,000至100,000(以聚苯乙烯换算)和光敏剂的(甲基)丙烯酰氧基的有机聚硅氧烷。 通过使(甲基)丙烯酰氧基丙基三甲氧基硅烷和苯基三甲氧基硅烷进行共水解和随后的缩聚以产生共水解 - 缩聚产物,然后使相同的产物与甲硅烷基化试剂反应和甲硅烷化,从而制备平均分子量为3,000以上的有机聚硅氧烷, 六甲基二硅氮烷。 含有这种高分子量(甲基)丙烯酰氧基的有机聚硅氧烷的组合物的灵敏度,分辨率和储存稳定性优异,并且在涂布后的未固化状态下具有很小的粘合性,并且在固化后的耐热性优异。 因此,该组合物可用于半导体光刻用的感光耐热材料和用于半导体钝化的感光耐热材料。
    • 10. 发明授权
    • Optical fibers and core - forming compositions
    • 光纤和芯成型组合物
    • US5314979A
    • 1994-05-24
    • US803552
    • 1991-12-09
    • Hiroshige OkinoshimaShohei KozakaiTomiya Abe
    • Hiroshige OkinoshimaShohei KozakaiTomiya Abe
    • C08L83/04G02B1/04C08G77/04
    • G02B1/046C08L83/04C08G77/12C08G77/16C08G77/20
    • A composition comprising (A) an organopolysiloxane having a unit of the formula: R.sup.1 SiO.sub.3/2 wherein R.sup.1 is methyl, phenyl or vinyl in its molecule and having at least 0.05 alkenyl groups each directly attached to a silicon atom per silicon atom, (B) an organohydrogenpolysiloxane having at least 2 hydrogen atoms each directly attached to a silicon atom per molecule, (C) a platinum catalyst, and (D) an organosilane or organopolysiloxane of the formula: R.sup.2.sub.a (R.sup.3 O).sub.b SiO.sub.(4-a-b)/2 wherein R.sup.2 and R.sup.3 are hydrogen, methyl, phenyl or vinyl maintains good light transmission in cured form when exposed to humidity and is thus suitable for forming cores of optical fibers. Similar benefits are obtained with a composition comprising components (A) and (B), (C') a platinum catalyst and/or a radical polymerization initiator, and (E) a carboxylate.
    • (A)具有下式的有机聚硅氧烷:R1SiO3 / 2其中R1是甲基,分子内是苯基或乙烯基并且每个硅原子直接连接到硅原子上的至少0.05个烯基;(B) 具有至少2个氢原子的有机氢聚硅氧烷,每个分子直接连接到硅原子,(C)铂催化剂和(D)下式的有机硅烷或有机聚硅氧烷:(R 2 O)(R 3 O)b SiO(4-ab) R2和R3是氢,甲基,苯基或乙烯基在暴露于湿度时,以固化形式保持良好的透光性,因此适合于形成光纤芯。 使用包含组分(A)和(B),(C')铂催化剂和/或自由基聚合引发剂的组合物和(E)羧酸酯获得类似的益处。