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    • 2. 发明授权
    • Carbon material and a process for its manufacture
    • 碳材料及其制造工艺
    • US08394530B2
    • 2013-03-12
    • US12458914
    • 2009-07-28
    • Tooru FujiwaraHiroshi Yamamoto
    • Tooru FujiwaraHiroshi Yamamoto
    • H01M4/02H01M4/58
    • H01M10/4235C01B32/05C01P2004/61C01P2006/12H01M4/02H01M4/362H01M4/587H01M10/0525H01M2004/021
    • A carbon material suitable as a negative electrode material for a lithium ion battery which can suppress decomposition of a nonaqueous electrolytic solution, which has excellent compressibility capable of highly dense packing, and which can form an electrode of high capacity without worsening charge and discharge efficiency or cycling performance. Graphite powder A having an average particle diameter of 10-30 μm and a specific surface area S1 of at most 12.5 m2/g and pitch powder B having a softening point of 80-180° C. and an average particle diameter of 15-150 μm are mixed in proportions such that the mass ratio A/B is 98/2-95.5/4.5, and the resulting mixed powder is subjected to heat treatment in a stationary condition in an inert atmosphere at 900-1100° C. to carbonize the pitch and thereby manufacture a carbon material having carbon adhered to the surface of the above-described graphite powder. Carbon preferentially adheres to the edge planes of the graphite particles. The carbon material has a specific surface area S2 of 1.0-5.0 m2/g, and it satisfies 0.4≦S2/S1≦0.8.
    • 适合作为锂离子电池用负极材料的碳材料,能够抑制能够高密度填充的压缩性优异的非水电解液的分解,能够形成高容量的电极而不会使充放电效率恶化, 自行车表演。 石墨粉末A的平均粒径为10〜30μm,比表面积S1为12.5m2 / g以下,沥青粉末B的软化点为80〜180℃,平均粒径为15〜150 以使质量比A / B为98 / 2-95.5 / 4.5的比例混合,并将所得混合粉末在惰性气氛中在900-1100℃下在静止条件下进行热处理以使 从而制造具有粘附到上述石墨粉末的表面上的碳的碳材料。 碳优先粘附在石墨颗粒的边缘平面上。 碳材料的比表面积S2为1.0-5.0m2 / g,满足0.4≦̸ S2 / S1≦̸ 0.8。
    • 3. 发明申请
    • Carbon material and a process for its manufacture
    • 碳材料及其制造工艺
    • US20100035149A1
    • 2010-02-11
    • US12458914
    • 2009-07-28
    • Tooru FujiwaraHiroshi Yamamoto
    • Tooru FujiwaraHiroshi Yamamoto
    • H01M4/133C01B31/04H01M4/88
    • H01M10/4235C01B32/05C01P2004/61C01P2006/12H01M4/02H01M4/362H01M4/587H01M10/0525H01M2004/021
    • A carbon material suitable as a negative electrode material for a lithium ion battery which can suppress decomposition of a nonaqueous electrolytic solution, which has excellent compressibility capable of highly dense packing, and which can form an electrode of high capacity without worsening charge and discharge efficiency or cycling performance. Graphite powder A having an average particle diameter of 10-30 μm and a specific surface area S1 of at most 12.5 m2/g and pitch powder B having a softening point of 80-180° C. and an average particle diameter of 15-150 μm are mixed in proportions such that the mass ratio A/B is 98/2-95.5/4.5, and the resulting mixed powder is subjected to heat treatment in a stationary condition in an inert atmosphere at 900-1100° C. to carbonize the pitch and thereby manufacture a carbon material having carbon adhered to the surface of the above-described graphite powder. Carbon preferentially adheres to the edge planes of the graphite particles. The carbon material has a specific surface area S2 of 1.0-5.0 m2/g, and it satisfies 0.4≦S2/S1≦0.8.
    • 适合作为锂离子电池用负极材料的碳材料,能够抑制能够高密度填充的压缩性优异的非水电解液的分解,能够形成高容量的电极而不会使充放电效率恶化, 自行车表演。 石墨粉末A的平均粒径为10〜30μm,比表面积S1为12.5m2 / g以下,沥青粉B的软化点为80〜180℃,平均粒径为15〜150 以比例A / B为98 / 2-95.5 / 4.5的比例进行混合,将得到的混合粉末在惰性气氛中在900-1100℃下在静止状态下进行热处理,使碳酸化 从而制造具有粘附到上述石墨粉末的表面上的碳的碳材料。 碳优先粘附在石墨颗粒的边缘平面上。 碳材料的比表面积S2为1.0〜5.0m2 / g,满足0.4≤S2/S1≤0.8。
    • 5. 发明授权
    • Carbon powder suitable as a negative electrode material for nonaqueous secondary batteries
    • 适用于非水二次电池的负极材料的碳粉
    • US08038977B2
    • 2011-10-18
    • US12068437
    • 2008-02-06
    • Hiroshi YamamotoTooru Fujiwara
    • Hiroshi YamamotoTooru Fujiwara
    • C01B31/04
    • H01M4/587C01B32/05C01B32/20
    • Carbon powder having low temperature calcined carbon derived from pitch adhered to a portion of the surface of natural graphite powder is obtained by solids mixing of natural graphite powder and pitch powder as a carbon precursor followed by heat treatment at 900-1500° C. to carbonize the pitch. The amount of pitch powder is such that the ratio V2/V1 of the pore volume V2 of pores having a diameter of 50-200 nm to the pore volume V1 of pores having a diameter of 2-50 nm in a pore size distribution curve obtained by analysis of the nitrogen desorption isotherm of the resulting carbon powder by the BJH method is at least 1. This carbon powder can be used as a negative electrode material for a nonaqueous secondary battery able to operate at low temperatures.
    • 通过将天然石墨粉末和作为碳前体的沥青粉末固体混合,然后在900-1500℃进行热处理以碳化,得到具有由附着在天然石墨粉末的表面部分上的沥青衍生的低温煅烧碳的碳粉末 球场。 间距粉末的量使得在获得的孔径分布曲线中,直径为50-200nm的孔的孔体积V2与直径为2-50nm的孔的孔体积V1的比V2 / V1 通过用BJH法分析得到的碳粉末的氮解吸等温线为至少1.该碳粉末可以用作能够在低温下操作的非水二次电池的负极材料。
    • 6. 发明授权
    • Mixed carbon material and negative electrode for a nonaqueous secondary battery
    • 用于非水二次电池的混合碳材料和负极
    • US08501047B2
    • 2013-08-06
    • US13006693
    • 2011-01-14
    • Hiroshi YamamotoTatsuo NagataTooru Fujiwara
    • Hiroshi YamamotoTatsuo NagataTooru Fujiwara
    • H01B1/02
    • H01M4/587C01B32/20H01M4/133H01M10/0525
    • A negative electrode material provided by the present invention capable of suppressing a decrease in charge acceptance and high temperature storage properties in an electrode with a high capacity and a high density is a mixed carbon material comprising carbon material A having cores of graphite powder with amorphous carbon and/or turbostratic carbon adhered to or coated on the surface of the cores and carbon material B which is graphite powder, the compressibility which is the density (g/cm3) of the material when 1.00 grams of the material are packed into a cylindrical mold with an inner diameter of 15 mm and compressed by applying a pressing force of 8.7 kN and reducing the pressing force to 0.15 kN is 1.60-1.78 g/cm3 for carbon material A and 1.75-1.85 g/cm3 for carbon material B, the compressibility of carbon material A is less than the compressibility of carbon material B, and the mixing ratio (carbon material A/carbon material B) is 1-9 as a mass ratio.
    • 本发明提供的能够抑制具有高容量和高密度的电极中的电荷接受性和高温保存性降低的负极材料是包含碳材料A的混合碳材料,所述碳材料A具有具有无定形碳的石墨粉末的芯 和/或渗透碳附着在或涂覆在芯的表面上,并且作为石墨粉末的碳材料B,当将1.00克材料包装到圆柱形模具中时,该材料的密度(g / cm 3)的可压缩性 通过施加8.7kN的压力并将压力降低至0.15kN而压缩的碳素材料A为1.60-1.78g / cm 3,碳材料B为1.75-1.85g / cm 3,压缩率 碳材料A的比例小于碳材料B的压缩率,混合比(碳材料A /碳材料B)的质量比为1-9。
    • 9. 发明申请
    • Carbon powder suitable as a negative electrode material for nonaqueous secondary batteries
    • 适用于非水二次电池的负极材料的碳粉
    • US20090196816A1
    • 2009-08-06
    • US12068437
    • 2008-02-06
    • Hiroshi YamamotoTooru Fujiwara
    • Hiroshi YamamotoTooru Fujiwara
    • C01B31/00
    • H01M4/587C01B32/05C01B32/20
    • Carbon powder having low temperature calcined carbon derived from pitch adhered to a portion of the surface of natural graphite powder is obtained by solids mixing of natural graphite powder and pitch powder as a carbon precursor followed by heat treatment at 900-1500° C. to carbonize the pitch. The amount of pitch powder is such that the ratio V2/V1 of the pore volume V2 of pores having a diameter of 50-200 nm to the pore volume V1 of pores having a diameter of 2-50 nm in a pore size distribution curve obtained by analysis of the nitrogen desorption isotherm of the resulting carbon powder by the BJH method is at least 1. This carbon powder can be used as a negative electrode material for a nonaqueous secondary battery able to operate at low temperatures.
    • 通过将天然石墨粉末和作为碳前体的沥青粉末固体混合,然后在900-1500℃进行热处理以碳化,得到具有由附着在天然石墨粉末的表面部分上的沥青衍生的低温煅烧碳的碳粉末 球场。 间距粉末的量使得在获得的孔径分布曲线中,直径为50-200nm的孔的孔体积V2与直径为2-50nm的孔的孔体积V1的比V2 / V1 通过用BJH法分析得到的碳粉末的氮解吸等温线为至少1.该碳粉末可以用作能够在低温下操作的非水二次电池的负极材料。
    • 10. 发明授权
    • Toothed belt
    • 齿形带
    • US4302197A
    • 1981-11-24
    • US69434
    • 1979-08-24
    • Kazuo KimuraTooru FujiwaraNorio Harada
    • Kazuo KimuraTooru FujiwaraNorio Harada
    • F16G1/10F16G1/28
    • F16G1/28F16G1/10
    • A toothed belt having an endless rubber band formed with projecting tooth portions, the rubber band having tension members buried in parallel therein. A cloth cover is fastened to the toothed surface of the band. The cloth is formed of woven fibers, and one of the warp and woof fibers of the cloth has a high-adhesive characteristic, and has a greater exposed surface area on one side of the cloth, which side is fastened to the toothed surface. The other of the warp and woof is formed of a fiber having properties suited for the working environment, such as properties of abrasion resistance and low friction, these latter fibers having a greater exposed area on the other side of the cloth, which other side is positioned for engagement with a toothed pulley.
    • 具有形成有突出齿部的环形橡胶带的齿形带,所述橡胶带具有平行地埋设在其中的张力构件。 布罩固定在带子的齿形表面上。 布由编织纤维形成,布的经纱和纬纱之一具有高粘合特性,并且在布的一侧具有更大的暴露表面积,该侧被紧固到齿形表面。 经纱和纬纱中的另一个由具有适合于工作环境的性能的纤维形成,例如耐磨性和低摩擦性,这些纤维在布的另一侧具有较大的暴露面积,另一侧是 定位成与齿形滑轮接合。