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    • 3. 发明授权
    • Liquid crystal display
    • 液晶显示器
    • US5389288A
    • 1995-02-14
    • US109269
    • 1993-08-20
    • Katsuhiko RindoTadashi NishimoriKazuo KubotaAkira Yoshimatsu
    • Katsuhiko RindoTadashi NishimoriKazuo KubotaAkira Yoshimatsu
    • G02F1/1339C09K19/00
    • G02F1/13392C09K19/0208C09K2019/523Y10T428/1073Y10T428/1077
    • A liquid crystal display which can provide a homogeneous display by preventing an abnormal orientation of a liquid crystal around the spacers or between the spacers during energization, and which comprises spacer particles each having, at least on the surface thereof, a nonionic hydrophilic unit represented by the following formula (1): ##STR1## wherein R represents a C.sub.1 -C.sub.18 alkyl group, a C.sub.2 -C.sub.18 alkenyl group, a C.sub.6 -C.sub.18 aryl group, a C.sub.7 -C.sub.18 alkylaryl group, a C.sub.1 -C.sub.18 acyl group, a C.sub.2 -C.sub.18 alkylcarbamoyl group, a C.sub.2 -C.sub.18 acylcarbamoyl group or a C.sub.7 -C.sub.18 arylcarbamoyl group; R.sub.1 represents a linear or branched alkylene group having 2 to 4 carbon atoms wherein a hydroxyl group may be substituted for a hydrogen atom on the alkylene group; and m is a positive number of 1 to 100 on the average, with the proviso that the plural R.sub.1 's may be the same or different from each other.
    • 一种液晶显示器,其能够通过在通电期间防止间隔物周围或间隔物之间​​的液晶的异常取向而提供均匀的显示,并且包括间隔物颗粒,其至少在其表面上具有由 下式(1):其中R表示C1-C18烷基,C2-C18烯基,C6-C18芳基,C7-C18烷基芳基,C1-C18酰基 C2-C18烷基氨基甲酰基,C2-C18酰基氨基甲酰基或C7-C18芳基氨基甲酰基; R1表示碳原子数为2〜4的直链或支链亚烷基,其中羟基可以被取代在亚烷基上的氢原子; 并且m是平均为1至100的正数,条件是多个R 1可以彼此相同或不同。
    • 5. 发明授权
    • Process for production of organopolysiloxane compound
    • 有机聚硅氧烷化合物的制备方法
    • US08716411B2
    • 2014-05-06
    • US13516081
    • 2010-12-14
    • Takashi KodateKatsuhiko RindoOsamu Takiguchi
    • Takashi KodateKatsuhiko RindoOsamu Takiguchi
    • C08F283/12C08G77/388
    • C08G77/455C08G77/26C08G81/00C08L83/08C08L79/085
    • A method of producing an organopolysiloxane compound in which a poly(N-acylalkyleneimine) segment comprising repeating units represented by formula (1): wherein R1 is a hydrogen atom, an alkyl group having 1 to 22 carbon atoms, an aralkyl group, or an aryl group, and n is 2 or 3, is bonded to a terminal end and/or a side chain of an organopolysiloxane segment, the method comprising: a step (a) of subjecting a cyclic imino ether compound represented by formula (I): wherein R1 is a hydrogen atom, an alkyl group having 1 to 22 carbon atoms, an aralkyl group, or an aryl group, and n is 2 or 3, to ring opening polymerization in a solvent, thereby preparing a terminal reactive poly(N-acylalkyleneimine) solution; a step (b) of mixing a modified organopolysiloxane having an amino group at a terminal end and/or a side chain of its molecular chain and a solvent, thereby preparing a modified organopolysiloxane solution; a step (c) of mixing the terminal reactive poly(N-acylalkyleneimine) solution obtained in step (a) and the modified organopolysiloxane solution obtained in step (b), thereby allowing 65 to 95 mol % of total amino groups in the modified organopolysiloxane to react with the terminal reactive poly(N-acylalkyleneimine); and a step (d) of removing the solvent at 100 to 200° C. after completing step (c).
    • 一种生产有机聚硅氧烷化合物的方法,其中包含由式(1)表示的重复单元的聚(N-酰基亚烷基亚胺)链段:其中R1是氢原子,具有1至22个碳原子的烷基,芳烷基或 芳基,n为2或3,与有机聚硅氧烷链段的末端和/或侧链结合,该方法包括:(I)将式(I)表示的环状亚氨基醚化合物 其中R1是氢原子,具有1至22个碳原子的烷基,芳烷基或芳基,n是2或3,在溶剂中开环聚合,由此制备末端反应性聚(N- 酰基亚烷基亚胺)溶液; 将在分子链末端和/或侧链上具有氨基的改性有机聚硅氧烷与溶剂混合的步骤(b),从而制备改性的有机聚硅氧烷溶液; 将步骤(a)中得到的末端反应性聚(N-酰基亚烷基亚胺)溶液与步骤(b)中得到的改性有机聚硅氧烷溶液混合,从而使改性有机聚硅氧烷中的总氨基的65〜95摩尔% 与末端反应性聚(N-酰基亚烷基亚胺)反应; 以及在完成步骤(c)之后在100至200℃下除去溶剂的步骤(d)。
    • 6. 发明申请
    • PROCESS FOR PRODUCTION OF ORGANOPOLYSILOXANE COMPOUND
    • 生产有机硅氧烷化合物的方法
    • US20120302705A1
    • 2012-11-29
    • US13516081
    • 2010-12-14
    • Takashi KodateKatsuhiko RindoOsamu Takiguchi
    • Takashi KodateKatsuhiko RindoOsamu Takiguchi
    • C08G77/388
    • C08G77/455C08G77/26C08G81/00C08L83/08C08L79/085
    • A method of producing an organopolysiloxane compound in which a poly(N-acylalkyleneimine) segment comprising repeating units represented by formula (1): wherein R1 is a hydrogen atom, an alkyl group having 1 to 22 carbon atoms, an aralkyl group, or an aryl group, and n is 2 or 3, is bonded to a terminal end and/or a side chain of an organopolysiloxane segment, the method comprising: a step (a) of subjecting a cyclic imino ether compound represented by formula (I): wherein R1 is a hydrogen atom, an alkyl group having 1 to 22 carbon atoms, an aralkyl group, or an aryl group, and n is 2 or 3, to ring opening polymerization in a solvent, thereby preparing a terminal reactive poly(N-acylalkyleneimine) solution; a step (b) of mixing a modified organopolysiloxane having an amino group at a terminal end and/or a side chain of its molecular chain and a solvent, thereby preparing a modified organopolysiloxane solution; a step (c) of mixing the terminal reactive poly(N-acylalkyleneimine) solution obtained in step (a) and the modified organopolysiloxane solution obtained in step (b), thereby allowing 65 to 95 mol % of total amino groups in the modified organopolysiloxane to react with the terminal reactive poly(N-acylalkyleneimine); and a step (d) of removing the solvent at 100 to 200° C. after completing step (c).
    • 一种生产有机聚硅氧烷化合物的方法,其中包含由式(1)表示的重复单元的聚(N-酰基亚烷基亚胺)链段:其中R1是氢原子,具有1至22个碳原子的烷基,芳烷基或 芳基,n为2或3,与有机聚硅氧烷链段的末端和/或侧链结合,该方法包括:(I)将式(I)表示的环状亚氨基醚化合物 其中R1是氢原子,具有1至22个碳原子的烷基,芳烷基或芳基,n是2或3,在溶剂中开环聚合,由此制备末端反应性聚(N- 酰基亚烷基亚胺)溶液; 将在分子链末端和/或侧链上具有氨基的改性有机聚硅氧烷与溶剂混合的步骤(b),从而制备改性的有机聚硅氧烷溶液; 将步骤(a)中得到的末端反应性聚(N-酰基亚烷基亚胺)溶液与步骤(b)中得到的改性有机聚硅氧烷溶液混合,从而使改性有机聚硅氧烷中的总氨基的65〜95摩尔% 与末端反应性聚(N-酰基亚烷基亚胺)反应; 以及在完成步骤(c)之后在100至200℃下除去溶剂的步骤(d)。
    • 7. 发明申请
    • PROCESS FOR PRODUCTION OF ORGANOPOLYSILOXANE COMPOUND
    • 生产有机硅氧烷化合物的方法
    • US20120296052A1
    • 2012-11-22
    • US13515966
    • 2010-12-14
    • Takashi KodateKatsuhiko RindoOsamu Takiguchi
    • Takashi KodateKatsuhiko RindoOsamu Takiguchi
    • C08G77/388
    • C08G77/455C08G77/26C08G81/00C08L83/08C08L79/085
    • A method of producing an organopolysiloxane compound in which a poly(N-acylalkyleneimine) segment comprising repeating units represented by formula (1): is bonded to a terminal end and/or a side chain of an organopolysiloxane segment, the method comprising: a step (a) of subjecting a cyclic imino ether compound represented by formula (I): to ring opening polymerization in a solution thereof which is obtained by mixing the cyclic imino ether compound and a solvent, thereby preparing a solution of a terminal reactive poly(N-acylalkyleneimine); a step (b) of dehydrating a solution which is obtained by mixing a modified organopolysiloxane having an amino group at a terminal end and/or a side chain of its molecular chain and a solvent, such that a water concentration of a mixed solution to be obtained by mixing the solution of the terminal reactive poly(N-acylalkyleneimine) obtained in step (a) and the resultant solution of the modified organopolysiloxane is regulated to be 150 mg/kg or less; and a step (c) of mixing the solution of the modified organopolysiloxane obtained in step (b) and the solution of the terminal reactive poly(N-acylalkyleneimine) obtained in step (a) and allowing the modified organopolysiloxane and the terminal reactive poly(N-acylalkyleneimine) to react, in the above formulae, R1 is a hydrogen atom, an alkyl group having 1 to 22 carbon atoms, an aralkyl group, or an aryl group, and n is 2 or 3.
    • 一种制备有机聚硅氧烷化合物的方法,其中包含由式(1)表示的重复单元的聚(N-酰基亚烷基亚胺)链段结合到有机聚硅氧烷链段的末端和/或侧链上,该方法包括:步骤 (a)使由式(I)表示的环状亚胺醚化合物在通过混合环状亚胺醚化合物和溶剂而获得的溶液中开环聚合,从而制备末端反应性聚(N - 酰基亚烷基亚胺); 将通过在其分子链的末端和/或侧链上具有氨基的改性有机聚硅氧烷和溶剂混合而获得的溶液脱水的步骤(b),使得混合溶液的水浓度为 将步骤(a)中得到的末端反应性聚(N-酰基亚烷基亚胺)和所得改性有机聚硅氧烷溶液的混合溶液调节为150mg / kg以下, 和步骤(c),将步骤(b)中得到的改性有机聚硅氧烷溶液与步骤(a)中得到的末端反应性聚(N-酰基亚烷基亚胺)溶液混合,并将改性有机聚硅氧烷和末端反应性聚( N-酰基亚烷基亚胺)反应,在上式中,R 1为氢原子,碳原子数1〜22的烷基,芳烷基或芳基,n为2或3。