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1. 发明申请

US20090196760A1 Nickel-Base Superalloy Excellent in the Oxidation Resistance 有权
标题翻译：镍基合金耐氧化性优良
公开(公告)号：US20090196760A1
公开(公告)日：2009-08-06
申请号：US11992308
申请日：2006-09-27
申请人： Hiroshi Harada , Kyoko Kawagishi , Toshiharu Kobayashi , Yutaka Koizumi , Atsushi Sato
发明人： Hiroshi Harada , Kyoko Kawagishi , Toshiharu Kobayashi , Yutaka Koizumi , Atsushi Sato
IPC分类号： F01D5/28 , C22C19/05 , F01D9/02
CPC分类号： C22C1/0433 , B22F2998/00 , C22C19/057 , B22F5/04 , B22F5/009
摘要： A nickel-base superalloy having excellent oxidation resistance is provided. It is useful as high-temperature members such as turbine blades and turbine vanes for jet engines or gas turbines. The nickel-base superalloy has a composition containing Co: 0.1 to 15% by weight, Cr: 0.1 to 10% by weight, Mo: 0.1 to 4.5% by weight, W: 0.1 to 15% by weight, Al: 2 to 8% by weight, Ta+Nb+Ti: 0 to 16% by weight, Hf: 0 to 5% by weight, Re: 0.1 to 16% by weight, Ru: 0.1 to 16% by weight, Si: 0.2 to 5% by weight and a balance made of Ni and unavoidable impurities.
摘要翻译：提供了具有优异抗氧化性的镍基超耐热合金。作为喷气发动机或燃气轮机的涡轮叶片和涡轮叶片的高温部件是有用的。镍基超级合金具有Co：0.1〜15重量％，Cr：0.1〜10重量％，Mo：0.1〜4.5重量％，W：0.1〜15重量％，Al：2〜8 重量％Ta + Nb + Ti：0〜16％（重量），Hf：0〜5％（重量）Re：0.1〜16％（重量）Ru：0.1〜16％（重量）Si：0.2〜和由Ni和不可避免的杂质构成的平衡物。

2. 发明授权

US08926897B2 Nickel-base superalloy excellent in the oxidation resistance 有权
标题翻译：镍基超耐热合金性能优良
公开(公告)号：US08926897B2
公开(公告)日：2015-01-06
申请号：US11992308
申请日：2006-09-27
申请人： Hiroshi Harada , Kyoko Kawagishi , Toshiharu Kobayashi , Yutaka Koizumi , Atsushi Sato
发明人： Hiroshi Harada , Kyoko Kawagishi , Toshiharu Kobayashi , Yutaka Koizumi , Atsushi Sato
IPC分类号： C22C19/05 , C22C1/04
CPC分类号： C22C1/0433 , B22F2998/00 , C22C19/057 , B22F5/04 , B22F5/009
摘要： A nickel-base superalloy having excellent oxidation resistance is provided. It is useful as high-temperature members such as turbine blades and turbine vanes for jet engines or gas turbines. The nickel-base superalloy has a composition containing Co: 0.1 to 15% by weight, Cr: 0.1 to 10% by weight, Mo: 0.1 to 4.5% by weight, W: 0.1 to 15% by weight, Al: 2 to 8% by weight, Ta+Nb+Ti: 0 to 16% by weight, Hf: 0 to 5% by weight, Re: 0.1 to 16% by weight, Ru: 0.1 to 16% by weight, Si: 0.2 to 5% by weight and a balance made of Ni and unavoidable impurities.
摘要翻译：提供了具有优异抗氧化性的镍基超耐热合金。作为喷气发动机或燃气轮机的涡轮叶片和涡轮叶片的高温部件是有用的。镍基超级合金具有Co：0.1〜15重量％，Cr：0.1〜10重量％，Mo：0.1〜4.5重量％，W：0.1〜15重量％，Al：2〜8 重量％，Ta + Nb + Ti：0〜16％（重量），Hf：0〜5％（重量）Re：0.1〜16％（重量）Ru：0.1〜16％（重量）Si：0.2〜和由Ni和不可避免的杂质构成的平衡物。

3. 发明申请

US20110262299A1 Ni-BASED SINGLE CRYSTAL SUPERALLOY AND COMPONENT USING THE SAME AS SUBSTRATE 审中-公开
标题翻译：镍基单晶超级合金及其相同的元件作为基板
公开(公告)号：US20110262299A1
公开(公告)日：2011-10-27
申请号：US13000111
申请日：2009-06-26
申请人： Hiroshi Harada , Yutaka Koizumi , Toshiharu Kobayashi , Tadaharu Yokokawa , Masao Sakamoto , Kyoko Kawagishi , Tomonori Kitashima , An-chou Yeh
发明人： Hiroshi Harada , Yutaka Koizumi , Toshiharu Kobayashi , Tadaharu Yokokawa , Masao Sakamoto , Kyoko Kawagishi , Tomonori Kitashima , An-chou Yeh
IPC分类号： C22C19/05
CPC分类号： C22C19/057
摘要： Provided is an Ni-based single crystal superalloy wherein the ingredients have a composition containing, as ratio by mass, from 5.0% by mass to 7.0% by mass of Al, from 4.0% by mass to 8.0% by mass of Ta, from 0% by mass to 2.0% by mass of Mo, from 3.0% by mass to 8.0% by mass of W, from 3.0% by mass to 8.0% by mass of Re, from 0% by mass to 0.50% by mass of Hf, from 3.0% by mass to 6.0% by mass of Cr, from 0% by mass to 9.9% by mass of Co, from 1.0% by mass to 14.0% by mass of Ru, and from 0.1% by mass to 4.0% by mass of Nb, with the balance of Ni and inevitable impurities. The alloy prevents TCP phase precipitation at high temperatures, therefore having improved strength at high temperatures and having oxidation resistance at high temperatures.Specifically, the invention is to provide a high-performance Ni-based single crystal superalloy having well balanced high-temperature strength and high-temperature oxidation resistance in practical use. The invention is also to provide the Ni-based single crystal superalloy having sufficient characteristics in point of “heat treatment window” that should not be overlooked in practical use.
摘要翻译：本发明提供一种Ni基单晶超耐热合金，其中成分具有以质量比计含有5.0质量％至7.0质量％的Al，4.0质量％至8.0质量％的Ta，0 以质量计2.0质量％，3.0质量％〜8.0质量％的W，3.0质量％〜8.0质量％的Re，0质量％〜0.50质量％的Hf，从3.0质量％至6.0质量％的Cr，0质量％至9.9质量％的Co，1.0质量％至14.0质量％的Ru和0.1质量％至4.0质量％的Nb，余量为Ni和不可避免的杂质。该合金防止高温下的TCP相沉淀，因此在高温下具有改善的强度并且在高温下具有抗氧化性。具体地说，本发明提供一种在实际应用中具有良好平衡的高温强度和高温抗氧化性的高性能Ni基单晶超合金。本发明还提供在实际应用中不应忽视的“热处理窗”的具有足够特性的Ni基单晶超合金。

4. 发明申请

US20120014832A1 Ni-BASED SINGLE CRYSTAL SUPERALLOY 有权
标题翻译：镍基单晶超级合金
公开(公告)号：US20120014832A1
公开(公告)日：2012-01-19
申请号：US13144748
申请日：2010-01-15
申请人： Hiroshi Harada , Tadaharu Yokokawa , Yutaka Koizumi , Toshiharu Kobayashi , Masao Sakamoto , Kyoko Kawagishi , Ikuo Okada , Hidataka Oguma , Tøiji Torigoe , Masaki Taneike , Eisaku Ito , Junichiro Masada , Keizo Tsukagoshi , Hidemichi Koyabu
发明人： Hiroshi Harada , Tadaharu Yokokawa , Yutaka Koizumi , Toshiharu Kobayashi , Masao Sakamoto , Kyoko Kawagishi , Ikuo Okada , Hidataka Oguma , Tøiji Torigoe , Masaki Taneike , Eisaku Ito , Junichiro Masada , Keizo Tsukagoshi , Hidemichi Koyabu
IPC分类号： C22C19/05
CPC分类号： F01D5/28 , C22C19/057 , C22F1/00 , C22F1/02 , C22F1/10 , C30B11/00 , C30B29/52 , F05D2300/607 , Y02T50/671
摘要： The Ni-based single crystal alloy disclosed here is a single crystal and has a chemical composition containing, as % by mass, Co: 8 to 12%, Cr: 5 to 7.5%, Mo: 0.2 to 1.2%, W: 5 to 7%, Al: 5 to 6.5%, Ta: 8 to 12%. Hf: 0.01 to 0.2%, Re: 2 to 4%, Si: 0.005 to 0.1%, with the balance of Ni and inevitable impurities.
摘要翻译：这里公开的Ni系单晶合金为单晶，其化学组成为：Co：8〜12％，Cr：5〜7.5％，Mo：0.2〜1.2％，W：5〜 7％，Al：5〜6.5％，Ta：8〜12％。 Hf：0.01〜0.2％，Re：2〜4％，Si：0.005〜0.1％，余量由Ni和不可避免的杂质构成。

5. 发明授权

US08771440B2 Ni-based single crystal superalloy 有权
标题翻译：镍基单晶超合金
公开(公告)号：US08771440B2
公开(公告)日：2014-07-08
申请号：US12441017
申请日：2007-09-12
申请人： Akihiro Sato , Hiroshi Harada , Kyoko Kawagishi , Toshiharu Kobayashi , Tadaharu Yokokawa , Yutaka Koizumi , Yasuhiro Aoki , Mikiya Arai , Kazuyoshi Chikugo , Shoju Masaki
发明人： Akihiro Sato , Hiroshi Harada , Kyoko Kawagishi , Toshiharu Kobayashi , Tadaharu Yokokawa , Yutaka Koizumi , Yasuhiro Aoki , Mikiya Arai , Kazuyoshi Chikugo , Shoju Masaki
IPC分类号： C22C19/05
CPC分类号： C22C19/057 , C22C19/00 , C22C19/007 , C22C19/03 , C22F1/10
摘要： A Ni-based single crystal superalloy according to the invention has, for example, a composition including: 5.0 to 7.0 wt % of Al, 4.0 to 10.0 wt % of Ta, 1.1 to 4.5 wt % of Mo, 4.0 to 10.0 wt % of W, 3.1 to 8.0 wt % of Re, 0.0 to 2.0 wt % of Hf, 2.5 to 8.5 wt % of Cr, 0.0 to 9.9 wt % of Co, 0.0 to 4.0 wt % of Nb, and 1.0 to 14.0 wt % of Ru in terms of weight ratio; and the remainder including Ni and incidental impurities. In addition, the contents of Cr, Hf and Al are preferably set so as to satisfy the equation OP≧108. According to the Ni-based single crystal superalloy of the invention, high creep strength can be maintained and the oxidation resistance can be improved.
摘要翻译：本发明的Ni系单晶超耐热合金例如具有以下组成：5.0〜7.0重量％的Al，4.0〜10.0重量％的Ta，1.1〜4.5重量％的Mo，4.0〜10.0重量％ W为3.1〜8.0重量％，Hf为0.0〜2.0重量％，Cr为2.5〜8.5重量％，Co为0.0〜9.9重量％，Nb为0.0〜4.0重量％，Ru为1.0〜14.0重量％在重量比方面; 其余包括Ni和杂质。此外，优选将Cr，Hf，Al的含量设定为满足OP≥1010的式。根据本发明的Ni系单晶超耐热合金，能够维持高的蠕变强度，能够提高耐氧化性。

6. 发明申请

US20100143182A1 Ni-BASED SINGLE CRYSTAL SUPERALLOY 有权
标题翻译：镍基单晶超级合金
公开(公告)号：US20100143182A1
公开(公告)日：2010-06-10
申请号：US12441017
申请日：2007-09-12
申请人： Akihiro Sato , Hiroshi Harada , Kyoko Kawagishi , Toshiharu Kobayashi , Tadaharu Yokokawa , Yutaka Koizumi , Yasuhiro Aoki , Mikiya Arai , Kazuyoshi Chikugo , Shoju Masaki
发明人： Akihiro Sato , Hiroshi Harada , Kyoko Kawagishi , Toshiharu Kobayashi , Tadaharu Yokokawa , Yutaka Koizumi , Yasuhiro Aoki , Mikiya Arai , Kazuyoshi Chikugo , Shoju Masaki
IPC分类号： C22C19/05
CPC分类号： C22C19/057 , C22C19/00 , C22C19/007 , C22C19/03 , C22F1/10
摘要： A Ni-based single crystal superalloy according to the invention has, for example, a composition including: 5.0 to 7.0 wt % of Al, 4.0 to 10.0 wt % of Ta, 1.1 to 4.5 wt % of Mo, 4.0 to 10.0 wt % of W, 3.1 to 8.0 wt % of Re, 0.0 to 2.0 wt % of Hf, 2.5 to 8.5 wt % of Cr, 0.0 to 9.9 wt % of Co, 0.0 to 4.0 wt % of Nb, and 1.0 to 14.0 wt % of Ru in terms of weight ratio; and the remainder including Ni and incidental impurities. In addition, the contents of Cr, Hf and Al are preferably set so as to satisfy the equation OP≧108. According to the Ni-based single crystal superalloy of the invention, high creep strength can be maintained and the oxidation resistance can be improved.
摘要翻译：本发明的Ni系单晶超耐热合金例如具有以下组成：5.0〜7.0重量％的Al，4.0〜10.0重量％的Ta，1.1〜4.5重量％的Mo，4.0〜10.0重量％ W为3.1〜8.0重量％，Hf为0.0〜2.0重量％，Cr为2.5〜8.5重量％，Co为0.0〜9.9重量％，Nb为0.0〜4.0重量％，Ru为1.0〜14.0重量％在重量比方面; 其余包括Ni和杂质。此外，优选将Cr，Hf，Al的含量设定为满足OP≥1010的式。根据本发明的Ni系单晶超耐热合金，能够维持高蠕变强度，能够提高耐氧化性。

7. 发明申请

US20110142714A1 Ni-BASED SINGLE CRYSTAL SUPERALLOY AND COMPONENT OBTAINED FROM THE SAME 审中-公开
标题翻译：镍基单晶超级合金及其成分
公开(公告)号：US20110142714A1
公开(公告)日：2011-06-16
申请号：US13000815
申请日：2009-06-26
申请人： Hiroshi Harada , Yutaka Koizumi , Toshiharu Kobayashi , Tadaharu Yokokawa , Masao Sakamoto , Kyoko Kawagishi , Tomonori Kitashima , An-chou Yeh
发明人： Hiroshi Harada , Yutaka Koizumi , Toshiharu Kobayashi , Tadaharu Yokokawa , Masao Sakamoto , Kyoko Kawagishi , Tomonori Kitashima , An-chou Yeh
IPC分类号： C22C19/05 , C22C30/00
CPC分类号： C22C19/057
摘要： Provided is an Ni-based single crystal superalloy wherein the ingredients have a composition containing, as ratio by mass, from 5.0% by mass to 7.0% by mass of Al, from 4.0% by mass to 8.0% by mass of Ta, from 0% by mass to 2.0% by mass of Mo, from 3.0% by mass to 8.0% by mass of W, from 3.0% by mass to 8.0% by mass of Re, from 0% by mass to 0.50% by mass of Hf, from 3.0% by mass to 7.0% by mass of Cr, from 0% by mass to 9.9% by mass of Co and from 1.0% by mass to 10.0% by mass of Ru, with the balance of Ni and inevitable impurities. The alloy prevents TCP phase precipitation at high temperatures, therefore having improved strength at high temperatures and having oxidation resistance at high temperatures.The above-mentioned first-generation alloy CMSX-2 and second-generation alloy CMSX-4 are, though comparable thereto in point of creep strength at low temperatures, inferior to third-generation alloys in point of creep strength at high temperatures, since a large quantity of eutectic γ′-phase remains therein even after high-temperature solution treatment.
摘要翻译：本发明提供一种Ni基单晶超耐热合金，其中成分具有以质量比计含有5.0质量％至7.0质量％的Al，4.0质量％至8.0质量％的Ta，0 以质量计2.0质量％，3.0质量％〜8.0质量％的W，3.0质量％〜8.0质量％的Re，0质量％〜0.50质量％的Hf，从3.0质量％至7.0质量％的Cr，0质量％至9.9质量％的Co和1.0质量％至10.0质量％的Ru，余量为Ni和不可避免的杂质。该合金防止高温下的TCP相沉淀，因此在高温下具有改善的强度并且在高温下具有抗氧化性。上述第一代合金CMSX-2和第二代合金CMSX-4尽管与低温下的蠕变强度相当，但在高温下的蠕变强度方面比第三代合金低，因为即使在高温溶液处理后，仍存在大量的共晶γ'相。

8. 发明授权

US08900512B2 Ni-based single crystal superalloy 有权
标题翻译：镍基单晶超合金
公开(公告)号：US08900512B2
公开(公告)日：2014-12-02
申请号：US13144748
申请日：2010-01-15
申请人： Hiroshi Harada , Tadaharu Yokokawa , Yutaka Koizumi , Toshiharu Kobayashi , Masao Sakamoto , Kyoko Kawagishi , Ikuo Okada , Hidataka Oguma , Taiji Torigoe , Masaki Taneike , Eisaku Ito , Junichiro Masada , Keizo Tsukagoshi , Hidemichi Koyabu
发明人： Hiroshi Harada , Tadaharu Yokokawa , Yutaka Koizumi , Toshiharu Kobayashi , Masao Sakamoto , Kyoko Kawagishi , Ikuo Okada , Hidataka Oguma , Taiji Torigoe , Masaki Taneike , Eisaku Ito , Junichiro Masada , Keizo Tsukagoshi , Hidemichi Koyabu
IPC分类号： C22C19/05 , F01D5/28 , C22F1/00 , C22F1/02 , C22F1/10 , C30B11/00 , C30B29/52
CPC分类号： F01D5/28 , C22C19/057 , C22F1/00 , C22F1/02 , C22F1/10 , C30B11/00 , C30B29/52 , F05D2300/607 , Y02T50/671
摘要： The Ni-based single crystal alloy disclosed here is a single crystal and has a chemical composition containing, as % by mass, Co: 8 to 12%, Cr: 5 to 7.5%, Mo: 0.2 to 1.2%, W: 5 to 7%, Al: 5 to 6.5%, Ta: 8 to 12%. Hf: 0.01 to 0.2%, Re: 2 to 4%, Si: 0.005 to 0.1%, with the balance of Ni and inevitable impurities.
摘要翻译：这里公开的Ni系单晶合金为单晶，其化学组成为：Co：8〜12％，Cr：5〜7.5％，Mo：0.2〜1.2％，W：5〜 7％，Al：5〜6.5％，Ta：8〜12％。 Hf：0.01〜0.2％，Re：2〜4％，Si：0.005〜0.1％，余量由Ni和不可避免的杂质构成。

9. 发明授权

US08968643B2 Ni-based single crystal super alloy 有权
标题翻译：镍基单晶超合金
公开(公告)号：US08968643B2
公开(公告)日：2015-03-03
申请号：US12900896
申请日：2010-10-08
申请人： Toshiharu Kobayashi , Yutaka Koizumi , Tadaharu Yokokawa , Hiroshi Harada , Yasuhiro Aoki , Mikiya Arai , Shoju Masaki
发明人： Toshiharu Kobayashi , Yutaka Koizumi , Tadaharu Yokokawa , Hiroshi Harada , Yasuhiro Aoki , Mikiya Arai , Shoju Masaki
IPC分类号： C22C19/05 , C30B29/52
CPC分类号： C22C19/057 , C30B29/52
摘要： The object of the present invention is to provide an Ni-based single crystal super alloy capable of improving strength by preventing precipitation of a TCP phase at high temperatures. This object is achieved by an Ni-based single crystal super alloy having a composition comprising 5.0-7.0 wt % of Al, 4.0-10.0 wt % of Ta, 1.1-4.5 wt % of Mo, 4.0-10.0 wt % of W, 3.1-8.0 wt % of Re, 0-0.50 wt % of Hf, 2.0-5.0 wt % of Cr, 0-9.9 wt % of Co and 4.1-14.0 wt % of Ru in terms of its weight ratio, with the remainder consisting of Ni and unavoidable impurities. Furthermore, in this Ni-based single crystal super alloy, when lattice constant of matrix is taken to be a1 and lattice constant of precipitation phase is taken to be a2, a2≦0.999a1.
摘要翻译：本发明的目的是提供一种能够通过防止TCP相在高温下析出而提高强度的Ni系单晶超合金。该目的通过一种Ni基单晶超级合金来实现，该Ni基单晶超合金的组成包括5.0-7.0重量％的Al，4.0-10.0重量％的Ta，1.1-4.5重量％的Mo，4.0-10.0重量％的W，3.1 -8.0重量％的Re，0-0.50重量％的Hf，2.0-5.0重量％的Cr，0-9.9重量％的Co和4.1-14.0重量％的Ru，以其重量比计，其余由 Ni和不可避免的杂质。此外，在该Ni基单晶超合金中，当将晶格的晶格常数设为a1，析出相的晶格常数取为a2时，a2＆nlE; 0.999a1。

10. 发明授权

US08852500B2 Ni-base superalloy, method for producing the same, and turbine blade or turbine vane components 有权
标题翻译：镍基超级合金，其制造方法，涡轮叶片或涡轮叶片部件
公开(公告)号：US08852500B2
公开(公告)日：2014-10-07
申请号：US12225254
申请日：2007-03-16
申请人： Yutaka Koizumi , Hiroshi Harada , Tadaharu Yokokawa , Toshiharu Kobayashi
发明人： Yutaka Koizumi , Hiroshi Harada , Tadaharu Yokokawa , Toshiharu Kobayashi
IPC分类号： C22C19/05 , F01D5/14 , C22F1/10
CPC分类号： B22D21/025 , C22C19/05 , C22C19/057 , C22F1/10 , F01D5/288 , F05D2300/607
摘要： A Ni-base superalloy having a chemical composition comprising Cr: 3.0-5.0 wt %, Co: 5.0-10.0 wt %, Mo: 0.5-3.0 wt %, W: 8.0-10.0 wt %, Ta: 5.0-8.0 wt %, Nb: 3.0 wt % or less, Al: 4.5-6.0 wt %, Ti: 0.1-2.0 wt %, Re: more than 3.0-4.0 wt %, Ru: 0.2-4.0 wt %, Hf: 0.01-0.2 wt %, and the balance being Ni and unavoidable impurities, a method for producing the same, and turbine blade or turbine vane components are disclosed. The Ni-base superalloy has high creep strength and textural stability under high temperature environment, and is excellent in applicability to turbine blade or turbine vane components of large-sized gas turbines.
摘要翻译：具有Cr：3.0-5.0重量％，Co：5.0-10.0重量％，Mo：0.5-3.0重量％，W：8.0-10.0重量％，Ta：5.0-8.0重量％的化学组成的Ni基超合金， Nb：3.0重量％以下，Al：4.5〜6.0重量％，Ti：0.1〜2.0重量％，Re：3.0-4.0重量％以下，Ru：0.2〜4.0重量％，Hf：0.01-0.2重量％其余为Ni和不可避免的杂质，其制造方法，以及涡轮叶片或涡轮叶片部件。 Ni基超合金在高温环境下具有高蠕变强度和结构稳定性，适用于大型燃气轮机的涡轮叶片或涡轮叶片部件。

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