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1. 发明授权

US08748659B2 Method for producing alpha,beta-unsaturated carboxylic acid-N,N-disubstituted amide and method for producing 3-alkoxycarboxylic acid-N,N-disubstituted amide 失效
标题翻译：制备α，β-不饱和羧酸-N，N-二取代酰胺的方法及其制备3-烷氧基羧酸-N，N-二取代酰胺的方法
公开(公告)号：US08748659B2
公开(公告)日：2014-06-10
申请号：US13266899
申请日：2010-04-28
申请人： Hironori Tashiro , Yasushi Shiraki , Makoto Kashima
发明人： Hironori Tashiro , Yasushi Shiraki , Makoto Kashima
IPC分类号： C07C231/02
CPC分类号： C07C231/02 , C07C227/06 , C07C227/08 , C07C231/12 , C07C231/22 , C07C229/12 , C07C233/05 , C07C233/09
摘要： The invention is directed to a technique for effectively producing an amide compound suitable for use as a solvent or a detergent on a large scale and at low cost.
摘要翻译：本发明涉及一种有效地生产适合用作大规模和低成本的溶剂或洗涤剂的酰胺化合物的技术。

2. 发明申请

US20120088931A1 METHOD FOR PRODUCING ALPHA,BETA-UNSATURATED CARBOXYLIC ACID-N,N-DISUBSTITUTED AMIDE AND METHOD FOR PRODUCING 3-ALKOXYCARBOXYLIC ACID-N,N-DISUBSTITUTED AMIDE 失效
标题翻译：用于制备ALPHA，不饱和羧酸，N，N-取代的酰胺的方法和用于生产3-烷氧羰基氧基-N，N-取代的酰胺的方法
公开(公告)号：US20120088931A1
公开(公告)日：2012-04-12
申请号：US13266899
申请日：2010-04-28
申请人： Hironori Tashiro , Yasushi Shiraki , Makoto Kashima
发明人： Hironori Tashiro , Yasushi Shiraki , Makoto Kashima
IPC分类号： C07C231/02 , C07C227/18
CPC分类号： C07C231/02 , C07C227/06 , C07C227/08 , C07C231/12 , C07C231/22 , C07C229/12 , C07C233/05 , C07C233/09
摘要： The invention is directed to a technique for effectively producing an amide compound suitable for use as a solvent or a detergent on a large scale and at low cost.
摘要翻译：本发明涉及一种有效地生产适合用作大规模和低成本的溶剂或洗涤剂的酰胺化合物的技术。

3. 发明申请

US20100076223A1 METHOD FOR PRODUCING A BETA-ALKOXYPROPIONAMIDE 失效
标题翻译：生产β-羟基丙酸酰胺的方法
公开(公告)号：US20100076223A1
公开(公告)日：2010-03-25
申请号：US12526530
申请日：2008-01-30
申请人： Yasushi Shiraki , Shigeru Matsuo , Toyozo Fujioka
发明人： Yasushi Shiraki , Shigeru Matsuo , Toyozo Fujioka
IPC分类号： C07C231/00
CPC分类号： C07C231/02 , C07C235/06
摘要： A method for producing a β-alkoxypropionamide shown by the following formula (I) including the step of reacting a β-alkoxypropionic acid ester with an amine in the presence of a basic catalyst or in the presence of a basic catalyst and a polyol: wherein R1 is an alkyl group having 1 to 8 carbon atoms, and R2 and R3 are independently hydrogen, a methyl group, an ethyl group, a methoxy group, an ethoxy group, a methoxymethyl group or a glycidyl group.
摘要翻译：一种由下式（I）表示的α-烷氧基丙酰胺的制备方法，包括在碱性催化剂存在下或在碱性催化剂和多元醇存在下使α-烷氧基丙酸酯与胺反应的步骤：其中R1是具有1-8个碳原子的烷基，R2和R3独立地是氢，甲基，乙基，甲氧基，乙氧基，甲氧基甲基或缩水甘油基。

4. 发明授权

US08338645B2 Method for producing a β-alkoxypropionamide 失效
标题翻译：生产α-氧基丙酰胺的方法
公开(公告)号：US08338645B2
公开(公告)日：2012-12-25
申请号：US12526530
申请日：2008-01-30
申请人： Yasushi Shiraki , Shigeru Matsuo , Toyozo Fujioka
发明人： Yasushi Shiraki , Shigeru Matsuo , Toyozo Fujioka
IPC分类号： C07C231/02
CPC分类号： C07C231/02 , C07C235/06
摘要： A method for producing a β-alkoxypropionamide shown by the following formula (I) including the step of reacting a β-alkoxypropionic acid ester with an amine in the presence of a basic catalyst or in the presence of a basic catalyst and a polyol: wherein R1 is an alkyl group having 1 to 8 carbon atoms, and R2 and R3 are independently hydrogen, a methyl group, an ethyl group, a methoxy group, an ethoxy group, a methoxymethyl group or a glycidyl group.
摘要翻译：一种由下式（I）表示的α-烷氧基丙酰胺的制备方法，包括在碱性催化剂存在下或在碱性催化剂和多元醇存在下使α-烷氧基丙酸酯与胺反应的步骤：其中R1是具有1-8个碳原子的烷基，R2和R3独立地是氢，甲基，乙基，甲氧基，乙氧基，甲氧基甲基或缩水甘油基。

5. 发明申请

US20110251430A1 METHOD FOR PRODUCING BETA-ALKOXYPROPIONAMIDE 失效
标题翻译：生产β-羟基丙酰胺的方法
公开(公告)号：US20110251430A1
公开(公告)日：2011-10-13
申请号：US13133683
申请日：2009-12-09
申请人： Yasushi Shiraki , Toyozo Fujioka , Koichi Kodoi
发明人： Yasushi Shiraki , Toyozo Fujioka , Koichi Kodoi
IPC分类号： C07C231/02
CPC分类号： C07C231/02 , C07C235/06
摘要： A method for producing a β-alkoxypropionamide including: subjecting a β-alkoxypropionic acid ester represented by the following formula (I) and a polyol having two or more OH groups to a transesterification reaction in the presence of a basic catalyst, thereby to synthesize a transesterified polyol of a β-alkoxypropionic acid ester; and subjecting the transesterified polyol and an amine represented by the following formula (II) to an amidation reaction, thereby to synthesize a β-alkoxypropionamide represented by the following formula (III):
摘要翻译：其包括：在碱性催化剂的存在下使由下式（I）表示的α-烷氧基丙酸酯和具有两个或多个OH基团的多元醇进行酯交换反应，由此得到合成α-烷氧基丙酸酯的酯交换多元醇; 并将酯交换的多元醇和下述式（II）所示的胺进行酰胺化反应，合成由下式（III）表示的α-烷氧基丙酰胺：

6. 发明授权

US06555633B1 Catalysts for &agr;-olefin production and processes for producing &agr;-olefin 失效
标题翻译：用于α-烯烃生产的催化剂和用于生产α-烯烃的方法
公开(公告)号：US06555633B1
公开(公告)日：2003-04-29
申请号：US09623974
申请日：2000-09-11
申请人： Shinji Tanaka , Yasushi Shiraki , Takao Tamura , Masahiko Kuramoto , Haruhito Sato , Masami Watanabe
发明人： Shinji Tanaka , Yasushi Shiraki , Takao Tamura , Masahiko Kuramoto , Haruhito Sato , Masami Watanabe
IPC分类号： C08F442
CPC分类号： C08F4/025 , B01J21/06 , B01J21/066 , B01J21/16 , B01J23/745 , B01J31/1616 , B01J31/1805 , B01J31/181 , B01J31/1815 , B01J31/22 , B01J31/2295 , B01J31/26 , B01J2231/20 , B01J2531/0244 , B01J2531/48 , B01J2531/842 , C07C2/32 , C07C2521/16 , C07C2531/08 , C07C2531/22 , Y02P20/52 , Y10S526/943
摘要： A catalyst which is able to express a high oligomerizing activity of ethylene and a method for the production of &agr;-olefin where ethylene is oligomerized using said catalyst are provided. The present invention relates to a catalyst for the production of &agr;-olefin obtained by contacting (a) clay, clay mineral or ion-exchange layer compound with (b-1) a transition metal complex of Groups 4 to 6 of the Periodic Table and also relates to a method for the production of &agr;-olefin by oligomerization of ethylene using said catalyst. The present invention further relates to a catalyst for the production of &agr;-olefin obtained by contacting (a) clay, clay mineral or ion-exchange layer compound with (b-2) a transition metal complex of Groups 8 to 10 of the Periodic Table and also relates to a method of the production of &agr;-olefin by oligomerization of ethylene using said catalyst.
摘要翻译：提供能够表达乙烯的高低聚活性的催化剂和使用所述催化剂使乙烯低聚的α-烯烃的制备方法。本发明涉及通过使（a）粘土，粘土矿物或离子交换层化合物与（b-1）周期表第4〜6族的过渡金属络合物接触而制备的α-烯烃的催化剂，还涉及通过使用所述催化剂使乙烯低聚制备α-烯烃的方法。本发明还涉及通过使（a）粘土，粘土矿物或离子交换层化合物与（b-2）周期表第8〜10族的过渡金属络合物接触而制备α-烯烃的催化剂并且还涉及通过使用所述催化剂使乙烯低聚制备α-烯烃的方法。

7. 发明授权

US06222085B1 Catalyst for dehydrogenation of alkylaromatic hydrocarbon, process for producing the catalyst, and process for producing vinylaromatic hydrocarbon by using the catalyst 失效
标题翻译：用于烷基芳族烃脱氢的催化剂，用于制备催化剂的方法，以及通过使用该催化剂生产乙烯基芳族烃的方法
公开(公告)号：US06222085B1
公开(公告)日：2001-04-24
申请号：US09381644
申请日：1999-11-04
申请人： Yasushi Shiraki , Kichinari Kawamura , Fumitaka Honjo
发明人： Yasushi Shiraki , Kichinari Kawamura , Fumitaka Honjo
IPC分类号： C07C264
CPC分类号： C07C5/3332 , B01J23/78 , B01J35/1009 , B01J35/1061 , B01J35/1066 , B01J35/108 , C07C2523/04 , C07C2523/745 , C07C2523/78 , C07C15/46 , C07C15/40
摘要： A solid catalyst containing a potassium component and an iron oxide component, which is such that the ratio of the pore volume of pores therein having a diameter of from 20 to 100 nm to that of pores therein having a diameter of up to 100 nm falls between 0.7/1 and 0.9/1 and which is stable to oxygen-containing vapor, is favorably used as a dehydrogenation catalyst in producing vinyl-aromatic hydrocarbons from alkyl-aromatic hydrocarbons. The catalyst has high initial activity and good initial selectivity and its life is long. In addition, it is easy to handle. The catalyst may be produced by reducing a potassium component-containing iron oxide composition with hydrogen at a temperature falling between 350 and 600° C., and then oxidizing it with an oxygen molecules-containing vapor at a temperature falling between 250 and 500° C.
摘要翻译：含有钾成分和氧化铁成分的固体催化剂使得其直径为20〜100nm的孔的细孔容积与直径为100nm以下的孔的孔体积之比在第 0.7 / 1和0.9 / 1，对于含氧蒸汽是稳定的，有利地用作从烷基 - 芳族烃生产乙烯基芳族烃的脱氢催化剂。催化剂具有高的初始活性和良好的初始选择性，寿命长。另外，它很容易处理。催化剂可以通过在350〜600℃的温度下用氢还原含有钾成分的氧化铁组合物，然后在含有氧分子的蒸气中在250〜500℃的温度下进行氧化，。

8. 发明授权

US07498467B2 Antioxidant and bisaminophenol derivative 失效
标题翻译：抗氧化剂和二氨基苯酚衍生物
公开(公告)号：US07498467B2
公开(公告)日：2009-03-03
申请号：US12039804
申请日：2008-02-29
申请人： Yasushi Shiraki
发明人： Yasushi Shiraki
IPC分类号： C07C215/54
CPC分类号： C08K5/18 , C07C215/76 , C08K5/005 , C09K15/24 , C09K15/28
摘要： The present invention provides antioxidants made of an aromatic hydroxyamine derivative having a structure represented by the general formula (I): wherein R1, R2 and R3 are each independently a hydrogen atom or an alkyl group having 1 to 20 carbon atoms; X is a hydrogen atom or an OH group; Y is a hydrogen atom or an NHR1 group; A is a direct bond, —O—, —NH—, —SO2—, —CH2— or —C(CH3)2—, and when an OH group and an NHR1 group are introduced to a unilateral benzene ring, these groups are respectively bonded to adjacent positions of the benzene ring; and n is 0 or 1 with the proviso that when n is 0, R1 is not a hydrogen atom, as well as bisaminophenol derivatives represented by the above general formula (I) wherein n is 1; R2 and R3 are each a hydrogen atom; X is an OH group; Y is an NHR1 group; A is —C(CH3)2—; and R1 is isopropyl, isobutyl or isohexyl. The aromatic hydroxyamine derivatives having a structure represented by the general formula (I), in particular, the bisaminophenol derivatives as novel substances, exhibit an excellent oxidation-inhibiting property, and are usable as antioxidants or polymerization inhibitors.
摘要翻译：本发明提供由具有由通式（I）表示的结构的芳族羟胺衍生物制成的抗氧化剂：其中R 1，R 2和R 3各自独立地为氢原子或具有1至20个碳原子的烷基; X是氢原子或OH基团; Y是氢原子或NHR1基团; A是直接键合-O - ， - NH - ， - SO 2 - ， - CH 2 - 或-C（CH 3）2 - ，当将OH基团和NHR 1基团引入单侧苯环时，分别结合到苯环的相邻位置; n为0或1，条件是当n为0时，R 1不是氢原子，以及由上述通式（I）表示的二氨基苯酚衍生物，其中n为1; R2和R3各自为氢原子; X是OH基; Y是NHR1基团; A是-C（CH 3）2 - ; 并且R 1是异丙基，异丁基或异己基。具有由通式（I）表示的结构的芳族羟胺衍生物，特别是作为新物质的二氨基苯酚衍生物，表现出优异的氧化抑制性，可用作抗氧化剂或聚合抑制剂。

9. 发明申请

US20060208227A1 Antioxidant and bisaminophenol derivative 审中-公开
标题翻译：抗氧化剂和二氨基苯酚衍生物
公开(公告)号：US20060208227A1
公开(公告)日：2006-09-21
申请号：US10551451
申请日：2004-03-31
申请人： Yasushi Shiraki
发明人： Yasushi Shiraki
IPC分类号： C09K15/16
CPC分类号： C08K5/18 , C07C215/76 , C08K5/005 , C09K15/24 , C09K15/28
摘要： The present invention provides antioxidants made of an aromatic hydroxyamine derivative having a structure represented by the general formula (I): wherein R1, R2 and R3 are each independently a hydrogen atom or an alkyl group having 1 to 20 carbon atoms; X is a hydrogen atom or an OH group; Y is a hydrogen atom or an NHR1 group; A is a direct bond, —O—, —NH—, —SO2—, —CH2— or —C(CH3)2—, and when an OH group and an NHR1 group are introduced to a unilateral benzene ring, these groups are respectively bonded to adjacent positions of the benzene ring; and n is 0 or 1 with the proviso that when n is 0, R1 is not a hydrogen atom, as well as bisaminophenol derivatives represented by the above general formula (I) wherein n is 1; R2 and R3 are each a hydrogen atom; X is an OH group; Y is an NHR1 group; A is —C(CH3)2—; and R1 is isopropyl, isobutyl or isohexyl. The aromatic hydroxyamine derivatives having a structure represented by the general formula (I), in particular, the bisaminophenol derivatives as novel substances, exhibit an excellent oxidation-inhibiting property, and are usable as antioxidants or polymerization inhibitors.
摘要翻译：本发明提供由具有由通式（I）表示的结构的芳族羟胺衍生物制成的抗氧化剂：其中R 1，R 2和R 3， / SUP>各自独立地为氢原子或具有1至20个碳原子的烷基; X是氢原子或OH基团; Y是氢原子或NHR 1 H 1基团; A是直接键，-O - ， - NH - ， - SO 2 - ， - CH 2 - 或-C（CH 3））2 <！ - SIPO - >，并且当将OH基团和NHR 1 H 2基团引入单侧苯环时，这些基团分别键合到苯环的相邻位置; n为0或1，条件是当n为0时，R 1不为氢原子，以及由上述通式（I）表示的二氨基苯酚衍生物，其中n为1; R 2和R 3各自为氢原子; X是OH基; Y是NHR 1个基团; A是-C（CH 3）2 - 。 R 1是异丙基，异丁基或异己基。具有由通式（I）表示的结构的芳族羟胺衍生物，特别是作为新物质的二氨基苯酚衍生物，表现出优异的氧化抑制性，可用作抗氧化剂或聚合抑制剂。

10. 发明授权

US06787499B2 Catalyst for the production of &agr;-olefin and &agr;-olefin production method 失效
标题翻译：用于生产α-烯烃和α-烯烃生产方法的催化剂
公开(公告)号：US06787499B2
公开(公告)日：2004-09-07
申请号：US10369595
申请日：2003-02-21
申请人： Shinji Tanaka , Yasushi Shiraki , Takao Tamura , Masahiko Kuramoto , Haruhito Sato , Masami Watanabe
发明人： Shinji Tanaka , Yasushi Shiraki , Takao Tamura , Masahiko Kuramoto , Haruhito Sato , Masami Watanabe
IPC分类号： B01J3100
CPC分类号： C08F4/025 , B01J21/06 , B01J21/066 , B01J21/16 , B01J23/745 , B01J31/1616 , B01J31/1805 , B01J31/181 , B01J31/1815 , B01J31/22 , B01J31/2295 , B01J31/26 , B01J2231/20 , B01J2531/0244 , B01J2531/48 , B01J2531/842 , C07C2/32 , C07C2521/16 , C07C2531/08 , C07C2531/22 , Y02P20/52 , Y10S526/943
摘要： A catalyst which is able to express a high oligomerizing activity of ethylene and a method for the production of &agr;-olefin where ethylene is oligomerized using said catalyst are provided. The present invention relates to a catalyst for the production of &agr;-olefin obtained by contacting (a) clay, clay mineral or ion-exchange layer compound with (b-1) a transition metal complex of Groups 4 to 6 of the Periodic Table and also relates to a method for the production of &agr;-olefin by oligomerization of ethylene using said catalyst. The present invention further relates to a catalyst for the production of &agr;-olefin obtained by contacting (a) clay, clay mineral or ion-exchange layer compound with (b-2) a transition metal complex of Groups 8 to 10 of the Periodic Table and also relates to a method of the production of &agr;-olefin by oligomerization of ethylene using said catalyst.
摘要翻译：提供了能够表现乙烯的高低聚活性的催化剂和使用所述催化剂使乙烯低聚的α-烯烃的制备方法。本发明涉及一种用于生产α-烯烃的催化剂，其通过接触（a）粘土，粘土矿物或离子交换层化合物与（b-1）周期表第4至6族的过渡金属络合物，以及通过乙烯低聚制备α-烯烃的方法所述催化剂。本发明还涉及通过使（a）粘土，粘土矿物或离子交换层化合物与（b-2）第8〜10族的过渡金属络合物接触而制备α-烯烃的催化剂。该周期表还涉及通过使用所述催化剂使乙烯低聚制备α-烯烃的方法。

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