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    • 4. 发明授权
    • Resin aqueous dispersion composition
    • 树脂水分散体组合物
    • US07105597B2
    • 2006-09-12
    • US10485152
    • 2002-07-16
    • Yoshihiro SodaNobuyuki TomihashiHiromichi MomoseKoichiro Ogita
    • Yoshihiro SodaNobuyuki TomihashiHiromichi MomoseKoichiro Ogita
    • C08L1/00
    • C08K5/06C08L27/18C08L33/08C08L71/02C08L2205/03C08L2666/02
    • The present invention provides a resin aqueous dispersion composition comprising water and at least one kind of resin particle, wherein when a primary average particle of each resin particle is taken as a sphere of the same volume, a nonionic surfactant is present in the composition in an amount which occupies 75 to 95% of a theoretical void among resin particles of 26% when each resin particle is arranged in a close packed structure. The nonionic surfactant is a solvent which is substantially nonvolatile in a temperature range of up to 100° C. and evaporates or thermally decomposes at a temperature lower than the thermal decomposition temperature of the resin particles. The resin aqueous dispersion composition can be coated thickly and can prevent development of mud crack.
    • 本发明提供一种树脂水分散体组合物,其含有水和至少一种树脂颗粒,其中当将每种树脂颗粒的一次平均颗粒作为相同体积的球体时,非离子表面活性剂存在于组合物中 当每个树脂颗粒以紧密堆积的结构布置时,占26%的树脂颗粒中的理论空隙的75至95%的量。 非离子表面活性剂是在至多100℃的温度范围内基本上不挥发的溶剂,并且在低于树脂颗粒的热分解温度的温度下蒸发或热分解。 树脂水性分散体组合物可以粗糙地涂布并且可以防止泥浆裂纹的发展。
    • 5. 发明授权
    • Aqueous dispersion composition of fluororesin for coating
    • 用于涂料的氟树脂的水分散体组合物
    • US07067574B2
    • 2006-06-27
    • US10484965
    • 2002-07-16
    • Nobuyuki TomihashiYoshihiro SodaHiromichi MomoseKoichiro Ogita
    • Nobuyuki TomihashiYoshihiro SodaHiromichi MomoseKoichiro Ogita
    • C08L27/12C08L27/18C08L27/20
    • C09D127/12C08L33/00C08L33/06C09D127/18C08L2666/04
    • The present invention relates to an aqueous dispersion composition of fluororesin for coating comprising (A) fluororesin particles, (B) a nitrogen-free high boiling point polyol having a boiling point of at least 100° C. and containing at least 2 hydroxyl groups, (C) depolymerizable acrylic resin particles having a decomposition and vaporization temperature within a temperature range of up to the decomposition temperature of said fluororesin particles, (D) a nonionic surfactant, and (E) an aqueous medium, wherein the high boiling point polyol (B) and the depolymerizable acrylic resin particles (C) are respectively contained in an amount of 5 to 18 parts by mass and 5 to 25 parts by mass based on 100 parts by mass of fluororesin particles (A) and an oxidant and an amine-type solvent are not contained. This composition is an aqueous dispersion composition of fluororesin for coating, which has favorable storage stability, can be coated thickly, controls development of mud crack and can form a coating film in which cracking and coloring do not occur when baking. Also, the composition controls discharge of endocrine disrupter substances as much as possible.
    • 本发明涉及包含(A)氟树脂颗粒,(B)沸点至少为100℃并含有至少2个羟基的无氮高沸点多元醇的涂料用氟涂料用水分散体组合物, (C)分解蒸发温度在所述氟树脂颗粒的分解温度以下的可解聚丙烯酸树脂颗粒,(D)非离子表面活性剂和(E)水性介质,其中所述高沸点多元醇( B)和可解聚丙烯酸树脂颗粒(C)的含量相对于100质量份的氟树脂粒子(A)和氧化剂和胺类化合物,分别为5〜18质量份,5〜25质量份, 型溶剂不含。 该组合物是涂料用氟树脂的水性分散体组合物,其储存稳定性良好,可以较厚地进行涂布,控制泥浆裂纹的发展,并且可以形成在烘烤时不会发生裂纹和着色的涂膜。 此外,组合物尽可能地控制内分泌干扰物质的排出。