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1. 发明授权

US06506495B1 Complex skin, slush molding thermoplastic elastomer composition for use in the skin, and an article including the skin 失效
标题翻译：复合皮肤，用于皮肤的搪塑热塑性弹性体组合物和包含皮肤的制品
公开(公告)号：US06506495B1
公开(公告)日：2003-01-14
申请号：US09290796
申请日：1999-04-13
申请人： Hirohide Enami , Kenrou Ono , Kenji Kubomoto , Takahide Okazawa
发明人： Hirohide Enami , Kenrou Ono , Kenji Kubomoto , Takahide Okazawa
IPC分类号： B32B2700
CPC分类号： C08L23/04 , B29C41/18 , B32B5/18 , C08L9/06 , C08L23/10 , Y10T428/2495 , Y10T428/31536 , Y10T428/31587 , Y10T428/31913 , C08L2666/04
摘要： A multilayer skin comprising an outer layer prepared by slush molding powder of a thermoplastic elastomer composition having a polypropylene resin, a hydrogenated styrene-butadiene random copolymer rubber, a process oil, an elastomer with high oil absorption capability, and a release agent. An inner layer is bonded to the outer layer, is prepared by slush molding, and is a blend of an elastomer with high oil absorption capability, an olefinic polymer with active hydrogen, and a catalyst which promotes isocyanate reaction. There is also a multilayer skin with a different composition as well as an article made with a multilayer skin having the compositions. There is further a thermoplastic elastomer composition for a layer of a multilayer skin.
摘要翻译：一种多层皮，其包含通过将具有聚丙烯树脂，氢化苯乙烯 - 丁二烯无规共聚物橡胶，加工油，具有高吸油能力的弹性体和脱模剂的热塑性弹性体组合物的粉末粉碎成型而制备的外层。内层结合到外层，通过搪塑成型制备，并且是具有高吸油能力的弹性体，具有活性氢的烯烃聚合物和促进异氰酸酯反应的催化剂的共混物。还有一种具有不同组成的多层皮肤以及由具有该组合物的多层皮制成的制品。还有一种用于多层皮肤层的热塑性弹性体组合物。

2. 发明授权

US06780495B2 Complex skin, slush molding thermoplastic elastomer composition for use in the skin, and an article including the skin 失效
标题翻译：复合皮肤，用于皮肤的搪塑热塑性弹性体组合物和包含皮肤的制品
公开(公告)号：US06780495B2
公开(公告)日：2004-08-24
申请号：US10341115
申请日：2003-01-13
申请人： Hirohide Enami , Kenrou Ono , Kenji Kubomoto , Takahide Okazawa
发明人： Hirohide Enami , Kenrou Ono , Kenji Kubomoto , Takahide Okazawa
IPC分类号： B32B2708
CPC分类号： C08L23/04 , B29C41/18 , B32B5/18 , C08L9/06 , C08L23/10 , Y10T428/2495 , Y10T428/31536 , Y10T428/31587 , Y10T428/31913 , C08L2666/04
摘要： A multilayer skin comprising an outer layer prepared by slush molding powder of a thermoplastic elastomer composition having a polypropylene resin, a hydrogenated styrene-butadiene random copolymer rubber, a process oil, an elastomer with high oil absorption capability, and a release agent. An inner layer is bonded to the outer layer, is prepared by slush molding, and is a blend of an elastomer with high oil absorption capability, an olefinic polymer with active hydrogen, and a catalyst which promotes isocyanate reaction. There is also a multilayer skin with a different composition as well as an article made with a multilayer skin having the compositions. There is further a thermoplastic elastomer composition for a layer of a multilayer skin.
摘要翻译：一种多层皮，其包含通过将具有聚丙烯树脂，氢化苯乙烯 - 丁二烯无规共聚物橡胶，加工油，具有高吸油能力的弹性体和脱模剂的热塑性弹性体组合物的粉末粉碎成型而制备的外层。内层结合到外层，通过搪塑成型制备，并且是具有高吸油能力的弹性体，具有活性氢的烯烃聚合物和促进异氰酸酯反应的催化剂的共混物。还有一种具有不同组成的多层皮肤以及由具有该组合物的多层皮制成的制品。还有一种用于多层皮肤层的热塑性弹性体组合物。

3. 发明授权

US06812285B2 Thermoplastic elastomer composition for a powder for slush molding and skin formed therefrom 失效
标题翻译：用于搪塑的粉末的热塑性弹性体组合物和由其形成的皮肤
公开(公告)号：US06812285B2
公开(公告)日：2004-11-02
申请号：US10055169
申请日：2001-10-26
申请人： Hirohide Enami , Kenrou Ono , Kenji Kubomoto , Yoshihiro Toda
发明人： Hirohide Enami , Kenrou Ono , Kenji Kubomoto , Yoshihiro Toda
IPC分类号： C08L900
CPC分类号： C08L23/16 , C08L23/10 , C08L25/10 , C08L53/02 , C08L53/025 , C08L2666/04 , C08L2666/24 , C08L2666/06
摘要： A thermoplastic elastomer composition for a powder material used for slush molding. The thermoplastic elastomer composition consists of a polypropylene resin and 20 to 500 parts by mass of a hydrogenated block copolymer per 100 parts by mass of the polypropylene resin. The hydrogenated block copolymer has a) at least one polymer block A with a primary component that is a vinyl aromatic hydrocarbon monomer unit and b) at least one polymer block B with a primary component that is a hydrogenated butadiene monomer unit. The polymer block B has a hydrogenation degree of at least 90%. The vinyl aromatic hydrocarbon in the hydrogenated block copolymer is present in an amount more than 5 mass % and less than 25 mass %. The polymer block B before hydrogenation contains 62 mol % or more 1, 2 bonds on average. The melt flow rate (MFR) of the thermoplastic elastomer composition is at least 10 g/10 min at 230° C. under a load of 2.16 kgf in accordance with Japanese Industrial Standards (JIS) K7210.
摘要翻译：用于搪塑的粉末材料的热塑性弹性体组合物。热塑性弹性体组合物由聚丙烯树脂和每100质量份聚丙烯树脂20〜500质量份氢化嵌段共聚物构成。氢化嵌段共聚物具有a）至少一种聚合物嵌段A，其主要组分为乙烯基芳族烃单体单元，和b）至少一种聚合物嵌段B，其主要组分为氢化丁二烯单体单元。聚合物嵌段B的氢化度至少为90％。氢化嵌段共聚物中的乙烯基芳族烃以超过5质量％且小于25质量％的量存在。氢化前的聚合物嵌段B平均含有62mol％以上的1,2键。根据日本工业标准（JIS）K7210，热塑性弹性体组合物的熔体流动速率（MFR）在230℃，2.16kgf负荷下为至少10g / 10分钟。

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