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1. 发明授权

US06194650B1 Coated object and process for producing the same 有权
标题翻译：涂层物体及其制造方法
公开(公告)号：US06194650B1
公开(公告)日：2001-02-27
申请号：US09297051
申请日：1999-04-27
申请人： Hiroaki Wakayama , Yoshiaki Fukushima , Narihito Tatsuda , Yoshitsugu Kojima , Osami Kamigaito , Yasutomo Goto , Shinji Inagaki , Kenichirou Suzuki , Megumi Sasaki , Hiroaki Hayashi , Kazuo Higuchi , Norihiko Setoyama
发明人： Hiroaki Wakayama , Yoshiaki Fukushima , Narihito Tatsuda , Yoshitsugu Kojima , Osami Kamigaito , Yasutomo Goto , Shinji Inagaki , Kenichirou Suzuki , Megumi Sasaki , Hiroaki Hayashi , Kazuo Higuchi , Norihiko Setoyama
IPC分类号： H01L3100
CPC分类号： H01G4/005 , B01J20/3204 , B01J20/321 , B01J20/3212 , B01J20/3236 , B01J21/06 , B01J21/063 , B01J21/08 , B01J21/18 , B01J23/38 , B01J23/42 , B01J37/0215 , B01J37/0219 , B01J37/033 , H01G4/10 , H01G4/12
摘要： A coated material comprising a substrate which has micropores and a reaction product coated thereon along the surface configuration of the substrate and an inner wall of the micropores thereof. The coated material is preferably produced by performing a supercritical coating step wherein a reaction precursor is dissolved in a supercritical fluid to form a precursor fluid and then the precursor fluid is brought into contact with a substrate in the presence with a reaction initiator to allow a reaction between the reaction precursor and the reaction initiator, thereby coating a reaction product onto the substrate.
摘要翻译：一种涂覆材料，其包括具有微孔的基底和沿着基底的表面形状涂覆在其上的反应产物及其微孔的内壁。涂覆的材料优选通过进行超临界涂覆步骤来制备，其中将反应前体溶解在超临界流体中以形成前体流体，然后在反应引发剂存在下将前体流体与底物接触以允许反应在反应前体和反应引发剂之间，从而将反应产物涂覆到基材上。

2. 发明授权

US4889885A Composite material containing a layered silicate 失效
标题翻译：含有层状硅酸盐的复合材料
公开(公告)号：US4889885A
公开(公告)日：1989-12-26
申请号：US164217
申请日：1988-03-04
申请人： Arimitsu Usuki , Tadashi Mizutani , Yoshiaki Fukushima , Megumi Fujimoto , Kenzo Fukumori , Yoshitsugu Kojima , Norio Sato , Toshio Kurauchi , Osami Kamigaito
发明人： Arimitsu Usuki , Tadashi Mizutani , Yoshiaki Fukushima , Megumi Fujimoto , Kenzo Fukumori , Yoshitsugu Kojima , Norio Sato , Toshio Kurauchi , Osami Kamigaito
IPC分类号： C01B33/44 , C04B14/10 , C04B14/20 , C04B24/42 , C04B26/02 , C08F2/44 , C08K3/34 , C08K9/04 , C10M113/16 , C10M169/00
CPC分类号： C08K3/34 , C01B33/44 , C04B14/10 , C04B14/206 , C04B24/425 , C04B26/02 , C08F2/44 , C08K9/04 , C10M113/16 , C10M169/00 , C08K2201/014 , C10M2201/103 , C10M2201/14 , C10M2201/145 , C10M2205/003 , C10M2209/00 , C10M2209/02 , C10M2209/10 , C10M2209/101 , C10M2215/02
摘要： A composite material comprising a resin other than polyamide resin and a layered silicate dispersed therein, said layered silicate having a layer thickness of 7 to 12 .ANG. and an interlayer distance of 30 .ANG. or above. Owing to the layered silicate uniformly dispersed in the resin matrix, the composite material is superior in mechanical characteristics and heat resistance. It also has good water resistance and chemical resistance.
摘要翻译：一种复合材料，其包含除了聚酰胺树脂之外的树脂和分散在其中的层状硅酸盐，所述层状硅酸盐的层厚度为7至12安培，层间距离为30安培或更高。由于层状硅酸盐均匀分散在树脂基体中，复合材料的机械性能和耐热性都优异。它还具有良好的耐水性和耐化学性。

3. 发明授权

US4739007A Composite material and process for manufacturing same 失效
标题翻译：复合材料及其制造方法相同
公开(公告)号：US4739007A
公开(公告)日：1988-04-19
申请号：US909472
申请日：1986-09-19
申请人： Akane Okada , Yoshiaki Fukushima , Masaya Kawasumi , Shinji Inagaki , Arimitsu Usuki , Shigetoshi Sugiyama , Toshio Kurauchi , Osami Kamigaito
发明人： Akane Okada , Yoshiaki Fukushima , Masaya Kawasumi , Shinji Inagaki , Arimitsu Usuki , Shigetoshi Sugiyama , Toshio Kurauchi , Osami Kamigaito
IPC分类号： C08K3/34 , C08L77/02
CPC分类号： B82Y30/00 , C08J5/005 , C08K3/346 , C08L77/02 , C08J2377/00
摘要： Composite material with high mechanical strength and excellent high-temperature characteristics comprising a polymer matrix containing polyamide and layers of a silicate uniformly dispersed in the order of molecules in the polymer matrix, each of said silicate layers being 7 to 12 .ANG. thick and the interlayer distance being at least 20 .ANG.; and a process for manufacturing such composite material.
摘要翻译：具有高机械强度和优异的高温特性的复合材料包括含有聚酰胺的聚合物基体和分层的均匀分散的硅酸盐层，每个硅酸盐层的厚度为7至12，层间距离至少有20个ANGSTROM; 以及这种复合材料的制造方法。

4. 再颁专利

USRE37385E1 Composite material and process for manufacturing same 有权
标题翻译：复合材料及其制造方法相同
公开(公告)号：USRE37385E1
公开(公告)日：2001-09-18
申请号：US09396871
申请日：1999-09-15
申请人： Akane Okada , Yoshiaki Fukushima , Masaya Kawasumi , Shinji Inagaki , Arimitsu Usuki , Shigetoshi Sugiyama , Toshio Kurauchi , Osami Kamigaito
发明人： Akane Okada , Yoshiaki Fukushima , Masaya Kawasumi , Shinji Inagaki , Arimitsu Usuki , Shigetoshi Sugiyama , Toshio Kurauchi , Osami Kamigaito
IPC分类号： C08K302
CPC分类号： B82Y30/00 , C08J5/005 , C08J2377/00 , C08K3/346 , C08L77/02 , C08L77/00
摘要： Composite material with high mechanical strength and excellent high-temperature characteristics comprising a polymer matrix containing polyamide and layers of a silicate uniformly dispersed in the order of molecules in the polymer matrix, each of said silicate layers being 7 to 12 Å thick and the interlayer distance being at least 20 Å; and a process for manufacturing such composite material.
摘要翻译：具有高机械强度和优异的高温特性的复合材料包括含有聚酰胺的聚合物基体和以聚合物基质中的分子顺序均匀分散的硅酸盐层，每个所述硅酸盐层的厚度为7至12埃，层间距离至少20Å; 以及这种复合材料的制造方法。

5. 发明授权

US4810734A Process for producing composite material 失效
标题翻译：复合材料生产工艺
公开(公告)号：US4810734A
公开(公告)日：1989-03-07
申请号：US168392
申请日：1988-03-15
申请人： Masaya Kawasumi , Masao Kohzaki , Yoshitsugu Kojima , Akane Okada , Osami Kamigaito
发明人： Masaya Kawasumi , Masao Kohzaki , Yoshitsugu Kojima , Akane Okada , Osami Kamigaito
IPC分类号： C08F2/44 , C08G69/00 , C08G69/02 , C08G69/04 , C08G69/14 , C08G85/00 , C08K3/34 , C08K9/04 , C08L77/00 , C08L101/00
CPC分类号： C08G85/00 , C08F2/44
摘要： Provided herein is a process for producing a composite material composed of a polymer and the layered silicate constituting the clay mineral being connected to the polymer through ionic bonding. The process comprises contacting a layered clay mineral with a swelling agent in the presence of a dispersion medium, thereby forming a complex, mixing said complex containing said dispersion medium with a monomer, and polymerizing said monomer contained in said mixture. The process permits the economical and efficient production of a composite material in which the layered silicate is uniformly dispersed.
摘要翻译：本文提供了一种由聚合物和构成粘土矿物的层状硅酸盐通过离子键连接到聚合物的复合材料的方法。该方法包括在分散介质存在下使层状粘土矿物与溶胀剂接触，从而形成络合物，将含有所述分散介质的所述络合物与单体混合，并使包含在所述混合物中的所述单体聚合。该方法允许经济有效地生产层状硅酸盐均匀分散的复合材料。

6. 发明授权

US4894411A Composite material and process for producing the same 失效
标题翻译：复合材料及其制造方法
公开(公告)号：US4894411A
公开(公告)日：1990-01-16
申请号：US168133
申请日：1988-03-14
申请人： Akane Okada , Masaya Kawasumi , Masao Kohzaki , Megumi Fujimoto , Yoshitsugu Kojima , Toshio Kurauchi , Osami Kamigaito
发明人： Akane Okada , Masaya Kawasumi , Masao Kohzaki , Megumi Fujimoto , Yoshitsugu Kojima , Toshio Kurauchi , Osami Kamigaito
IPC分类号： C08J3/20 , C08K3/34
CPC分类号： C08J3/20 , C08K3/34 , C08J2377/00
摘要： Provided herein is a composite material which comprises a polyamide-containing resin, a layered silicate dispersed therein, and a substance such as polyamine which controls the crystalline structure or molecular structure of the resin. The composite material has improved mechanical strength and toughness and high clarity or transparency.
摘要翻译：本文提供了一种复合材料，其包含含聚酰胺的树脂，分散在其中的层状硅酸盐以及控制树脂的结晶结构或分子结构的物质如多胺。复合材料具有改善的机械强度和韧性以及高清晰度或透明度。

7. 发明授权

US4486235A Clay mineral sheet 失效
标题翻译：粘土矿物片
公开(公告)号：US4486235A
公开(公告)日：1984-12-04
申请号：US506222
申请日：1983-06-21
申请人： Osami Kamigaito , Haruo Doi , Yoshiaki Fukushima
发明人： Osami Kamigaito , Haruo Doi , Yoshiaki Fukushima
IPC分类号： C04B30/00 , C09K3/00 , B05D1/18 , B32B5/16
CPC分类号： C04B30/00 , Y10T428/2982 , Y10T428/2993 , Y10T428/2995 , Y10T428/31663
摘要： The vermiculite sheet is immersed in a silane compound in liquid state so that the silane compound is permeated into the sheet to react with the water absorbed on the whole surface of each thin leave of vermiculite and to form silanol. Thin leaves of vermiculite are strongly bonded with one another through such silanol to form a strong composite sheet.
摘要翻译：将蛭石片浸入液态的硅烷化合物中，使得硅烷化合物渗透到片中以与每个薄蛭石的整个表面吸收的水反应并形成硅烷醇。蛭石的薄叶通过这种硅烷醇彼此牢固地结合以形成强的复合片材。

8. 发明授权

US4987106A Process for producing clay mineral of chain structure 失效
标题翻译：链结构粘土矿物生产工艺
公开(公告)号：US4987106A
公开(公告)日：1991-01-22
申请号：US457835
申请日：1989-12-27
申请人： Tadashi Mizutani , Yoshiaki Fukushima , Haruo Doi , Osami Kamigaito
发明人： Tadashi Mizutani , Yoshiaki Fukushima , Haruo Doi , Osami Kamigaito
IPC分类号： C01B33/26 , B28C1/00 , C01B25/45 , C01B33/20 , C01B33/22 , C01B33/36 , C01B33/40 , C01B33/44
CPC分类号： B28C1/006 , C01B33/36 , C01B33/405 , C01B33/44
摘要： A process for producing a clay mineral of chain structure such as sepiolite and attapulgite. The process comprises suspending a metal silicate gel in an aqueous solution which has a pH value of 3-11 at room temperature and contains a clay mineral of chain structure suspending therein, and then heating the resulting suspension at a temperature below 350.degree. C. According to this process, it is possible to produce a clay mineral of chain structure in a simple, stable manner.
摘要翻译：一种生产链状结构的粘土矿物的方法，如海泡石和绿坡缕石。该方法包括在室温下将金属硅酸盐凝胶悬浮在pH值为3-11的水溶液中，并含有悬浮在其中的链状结构的粘土矿物，然后在低于350℃的温度下加热得到的悬浮液。根据在该过程中，可以以简单，稳定的方式生产链结构的粘土矿物。

9. 发明授权

US4497869A Formed product of vermiculite and method for producing the same 失效
标题翻译：蛭石成型品及其制造方法
公开(公告)号：US4497869A
公开(公告)日：1985-02-05
申请号：US476014
申请日：1983-03-15
申请人： Osami Kamigaito , Haruo Doi , Yoshiaki Fukushima
发明人： Osami Kamigaito , Haruo Doi , Yoshiaki Fukushima
IPC分类号： C04B30/00 , C04B14/20 , C04B26/02 , C04B30/02 , B32B3/26
CPC分类号： C04B30/02 , C04B14/206 , C04B26/02 , Y10T428/2911 , Y10T428/2982
摘要： A formed product of vermiculite comprising thin leaves of vermiculite containing cations of one or more elements selected from the group consisting of copper, aluminum, manganese, II group elements, IV group elements and VIII group elements, substituted for exchangeable cations retained in vermiculite. Such a formed vermiculite product has high strength as well as excellent heat resistance. The formed product of vermiculite can be obtained by a method comprising the steps of crushing vermiculite to obtain thin leaves thereof, subjecting the thin leaves to ion exchange to substitute exchangeable cations retained therein by cations of one or more elements selected from the group consisting of copper, aluminum, manganese, II group elements, IV group elements and VIII group elements, and forming the resulting thin leaves into a stack or laminate. The formed vermiculite product thus obtained can retain further properties, such as an ability to expand and water resistance. More particularly, when the formed product (subjected to such ion exchange) is contacted with hydrogen peroxide, the resulting expanded formed product of vermiculite is suitable as a fixing material, shock absorber and the like, further retaining excellent compressibility, on the other hand, the product is heated in an oxidative atmosphere to obtain a formed vermiculite product having excellent water resistance as well as high strength, which is useful for a heat-insulating material and a refractory-facing material for a building.
摘要翻译：包含蛭石的成形物，其包含选自铜，铝，锰，II族元素，IV族元素和VIII族元素中的一种或多种元素的阳离子的蛭石的叶，代替保留在蛭石中的可交换阳离子。这种形成的蛭石产品具有高强度以及优异的耐热性。蛭石的形成产物可以通过包括以下步骤的方法获得，该方法包括以下步骤：碾碎蛭石以获得其薄的叶片，使薄叶片进行离子交换，以使其中保留的可交换的阳离子中的一种或多种元素的阳离子选自铜，铝，锰，II族元素，IV族元素和VIII族元素，并将所得薄叶形成为叠层或层压体。由此获得的成形蛭石产品可以保持进一步的性能，例如膨胀能力和耐水性。更具体地，当形成的产品（经过这样的离子交换）与过氧化氢接触时，所得到的蛭石膨胀成型产品适合作为固定材料，减震器等，另外保持优异的压缩性，将产物在氧化气氛中加热以获得具有优异的耐水性和高强度的成形蛭石产品，其可用于建筑物的绝热材料和耐火材料材料。

10. 发明授权

US4472538A Composite material composed of clay mineral and organic high polymer and method for producing the same 失效
标题翻译：由粘土矿物和有机高分子组成的复合材料及其制造方法
公开(公告)号：US4472538A
公开(公告)日：1984-09-18
申请号：US318862
申请日：1981-11-06
申请人： Osami Kamigaito , Yoshiaki Fukushima , Haruo Doi
发明人： Osami Kamigaito , Yoshiaki Fukushima , Haruo Doi
IPC分类号： C08K3/00 , C08F2/00 , C08F2/44 , C08F4/00 , C08F4/42 , C08F4/58 , C08F4/72 , C08F36/06 , C08F292/00 , C08G83/00 , C08K3/34 , C08K3/36 , C08L7/00 , C08L21/00 , C09C1/42 , C08K3/10
CPC分类号： C09C1/42 , C08F2/44 , C08F36/06 , C08G83/001 , C01P2002/08 , C01P2002/72 , C01P2002/82 , C01P2002/88 , C01P2006/32 , C01P2006/90 , Y10S428/92 , Y10S428/921 , Y10T428/2995 , Y10T428/2998
摘要： A composite material is provided by contacting a clay mineral having laminated aluminum silicate layers with an organic monomer to allow the organic monomer to be adsorbed on or intercalated between the aluminum silicate layers, and contacting the clay mineral with a silane compound having 2 to 4 chlorine atoms to promote polymerization of the organic monomer, thereby forming a composite material composed of a clay mineral having organic high polymer adsorbed thereon or intercalated therebetween. The composite material thus obtained has a strong chemical bond between inorganic clay mineral and organic high polymer.
摘要翻译：通过使具有层叠铝硅酸盐层的粘土矿物与有机单体接触以使有机单体吸附在硅酸铝层之间或插入硅酸铝层之间并使粘土矿物与具有2-4个氯的硅烷化合物接触来提供复合材料原子以促进有机单体的聚合，从而形成由其上吸附有有机高聚物的粘土矿物或其间插入的复合材料。由此获得的复合材料在无机粘土矿物和有机高分子之间具有强烈的化学键。

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