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1. 发明授权

US06492298B1 Ordinary-temperature purifying catalyst 失效
标题翻译：普通温度净化催化剂
公开(公告)号：US06492298B1
公开(公告)日：2002-12-10
申请号：US09538375
申请日：2000-03-29
申请人： Hideo Sobukawa , Toshitaka Tanabe , Kenichirou Suzuki , Megumi Sasaki , Hiroaki Hayashi , Akira Morikawa , Masahiro Sugiura
发明人： Hideo Sobukawa , Toshitaka Tanabe , Kenichirou Suzuki , Megumi Sasaki , Hiroaki Hayashi , Akira Morikawa , Masahiro Sugiura
IPC分类号： B01J2300
CPC分类号： B01D53/8668 , B01D53/8628 , B01D53/864 , B01J23/63 , B01J35/0013 , B01J35/006 , B01J37/18
摘要： An ordinary-temperature purifying catalyst includes an oxide having an oxygen defect introduced by a reduction treatment, and a noble metal loaded on the oxide. For example, the oxide can be at least one oxide selected from the group consisting of cerium oxides and zirconium oxides, at least a part of which has an oxygen defect. The catalyst can purify an environmental loading material, such as carbon monoxide, a nitrogen oxide, ethylene, formaldehyde, trimethylamine, methyl mercaptan and acetaldehyde, in air at an ordinary temperature. A method for how to use the catalyst is also disclosed.
摘要翻译：常温净化催化剂包括通过还原处理引入氧缺陷的氧化物和负载在氧化物上的贵金属。例如，氧化物可以是选自氧化铈和氧化锆中的至少一种氧化物，其至少一部分具有氧缺陷。催化剂可以在常温下在空气中净化环境负荷物质，如一氧化碳，氮氧化物，乙烯，甲醛，三甲胺，甲基硫醇和乙醛。还公开了如何使用催化剂的方法。

2. 发明授权

US07247597B2 Composite oxide, process for producing the same, and exhaust gas reducing co-catalyst 有权
标题翻译：复合氧化物，其制造方法和废气还原助催化剂
公开(公告)号：US07247597B2
公开(公告)日：2007-07-24
申请号：US10225186
申请日：2002-08-22
申请人： Akira Morikawa , Yasutaka Nagai , Toshitaka Tanabe , Tadashi Suzuki , Akihiko Suda , Hideo Sobukawa
发明人： Akira Morikawa , Yasutaka Nagai , Toshitaka Tanabe , Tadashi Suzuki , Akihiko Suda , Hideo Sobukawa
IPC分类号： B01J23/00 , C01G49/00 , C04B35/48
CPC分类号： B01J35/002 , B01D2255/1021 , B01D2255/2065 , B01D2255/20715 , B01D2255/407 , B01D2255/908 , B01J21/066 , B01J23/10 , B01J23/63 , B01J35/023 , B01J35/1014 , B01J37/03 , F01N2570/16
摘要： A composite oxide includes CeO2, ZrO2 and a metallic oxide being free from reacting with CeO2 and ZrO2 at 700° C. or more, preferably at 900° C. or more and further preferably at 1,000° C. or more. The composite oxide has a regulatory oriented phase, such as a pyrochlore phase, etc., in which at least a part of Ce cations and Zr cations are oriented regularly. The composite oxide makes a catalytic support. The CeO2—ZrO2 composite oxide and the reaction-free metallic oxide make barriers each other which suppress the granular growth when the composite oxide is subjected to high-temperature heat in a reducing heat treatment to form the regulatory oriented phase. The regulatory oriented phase improves the oxygen storage-and-release capability of the catalytic support. Thus, it is possible to simultaneously attain a large a specific surface area and a high oxygen storage-and-release capability.
摘要翻译：复合氧化物包括CeO 2 SiO 2，ZrO 2 2和不与CeO 2和ZrO 2的反应的金属氧化物 > 700℃以上，优选为900℃以上，进一步优选为1000℃以上。复合氧化物具有调节取向相，如烧绿石相等，其中至少一部分Ce阳离子和Zr阳离子定期取向。复合氧化物起催化作用。当复合氧化物经受高温加热时，CeO 2 -ZrO 2复合氧化物和无反应的金属氧化物形成彼此的屏障，其抑制颗粒生长一种还原热处理，形成规范导向相。调节取向相提高了催化支持物的储氧和释放能力。因此，可以同时获得大的比表面积和高的储氧 - 释放能力。

3. 发明授权

US06933259B2 Composite oxide powder, a method for producing the same and a catalyst using the same 有权
标题翻译：复合氧化物粉末，其制造方法和使用其的催化剂
公开(公告)号：US06933259B2
公开(公告)日：2005-08-23
申请号：US09987262
申请日：2001-11-14
申请人： Miho Hatanaka , Akira Morikawa , Akihiko Suda , Hideo Sobukawa , Kiyoshi Yamazaki
发明人： Miho Hatanaka , Akira Morikawa , Akihiko Suda , Hideo Sobukawa , Kiyoshi Yamazaki
IPC分类号： B01D53/86 , B01D53/94 , B01J23/00 , B01J23/10 , B01J23/63 , B01J32/00 , B01J35/10 , B01J37/03 , C01B13/14 , C01B13/36 , C01B25/00 , C01B33/00 , C01F17/00 , C01G23/00 , B01J21/02 , B01J21/06 , B01J23/03
CPC分类号： C01B13/14 , B01D53/945 , B01J23/002 , B01J23/10 , B01J23/63 , B01J35/10 , B01J37/031 , B01J2523/00 , B82Y30/00 , C01P2002/60 , C01P2004/64 , C01P2006/13 , C01P2006/14 , C01P2006/16 , Y02A50/2324 , Y02T10/22 , Y10T428/2982 , Y10T428/2993 , B01J2523/3712 , B01J2523/48 , B01J2523/31 , B01J2523/25 , B01J2523/36
摘要： This composite oxide powder can secure a large pore volume even after calcination at high temperature and, when a catalyst is formed by loading a noble metal on this composite oxide powder, noble metal grain growth can be suppressed. The composite oxide powder comprises particles of an oxide of a metal M1 and an oxide of a metal M2 which does not dissolve in the oxide of the metal M1, the oxide of the metal M1 and the oxide of the metal M2 being dispersed at the nanometer level. Since different oxides serve as a barrier to each other, sintering is suppressed. Therefore, in the case of composite oxide powder comprising Ce as a metal M1 and Al as a metal M2, grain growth is small even after exposed to high temperature and pores of 3.5-100 nm secure a volume of 0.07 cc/g or more after calcination at 600° C. for 5 hours and a volume of 0.04 cc/g or more after calcination at 800° C. for 5 hours.
摘要翻译：该复合氧化物粉末即使在高温下煅烧后也能确保较大的孔体积，并且当通过在该复合氧化物粉末上负载贵金属形成催化剂时，可以抑制贵金属晶粒生长。复合氧化物粉末包含不溶于金属M 1 O 3的氧化物的金属M 1氧化物和金属M 2 O 3的氧化物的颗粒，金属M 1的氧化物和金属M 2的氧化物分散在纳米级。由于不同的氧化物彼此作为隔离物，因此抑制烧结。因此，在作为金属M 1 C的Ce和作为金属M 2 N的Al的复合氧化物粉末的情况下，即使在暴露于高温和细孔之后，晶粒生长也很小 3.5-100nm，在800℃煅烧5小时后，在600℃煅烧5小时后，体积为0.07cc / g以上，体积为0.04cc / g以上。

4. 发明授权

US06335305B1 Catalyst for purifying exhaust gas 有权
标题翻译：废气净化催化剂
公开(公告)号：US06335305B1
公开(公告)日：2002-01-01
申请号：US09547347
申请日：2000-04-11
申请人： Tadashi Suzuki , Akira Morikawa , Hideo Sobukawa
发明人： Tadashi Suzuki , Akira Morikawa , Hideo Sobukawa
IPC分类号： B01J2300
CPC分类号： B01D53/945 , B01J23/63 , B01J37/03 , Y02T10/22
摘要： A catalyst for purifying an exhaust gas includes a support and a noble metal loaded on the support. The support includes a mixture containing a porous oxide and a composite oxide. The composite oxide is expressed by the following formula: (Al2O3)a(CeO2)b(ZrO2)1−b in which the values “a” and “b” are molar ratios and the value “a” falls in a range of from 0.4 to 2.5 and the value “b” falls in a range of from 0.2 to 0.7. The support includes a particle having a particle diameter of 5 &mgr;m or more in an amount of 30% by volume or more. With the thus arranged support, even when the catalyst is subjected to such a severe durability test that it is heated at 1,000° C. for 10 to 20 hours, it exhibits a high purifying activity, and its coating layer is inhibited from cracking or coming off.
摘要翻译：用于净化废气的催化剂包括负载在载体上的载体和贵金属。载体包括含有多孔氧化物和复合氧化物的混合物。复合氧化物由下式表示：其中值“a”和“b”是摩尔比，值“a”在0.4至2.5的范围内，并且值“b”落在从0.2到0.7。该载体包含30体积％以上的粒径为5μm以上的粒子。通过这样排列的支撑体，即使催化剂进行如此严格的耐久试验，即在1000℃下加热10〜20小时，显示出高的净化活性，并且其涂层被抑制开裂或开始关闭

5. 发明授权

US10384163B2 Exhaust gas purifying catalyst 有权
公开(公告)号：US10384163B2
公开(公告)日：2019-08-20
申请号：US15534794
申请日：2015-12-11
申请人： Isao Chinzei , Hiromasa Suzuki , Takeru Yoshida , Masahide Miura , Yuki Aoki , Mitsuyoshi Okada , Toshitaka Tanabe , Akihiko Suda , Yoshinori Saito , Hirotaka Ori , Kosuke Iizuka , Akira Morikawa
发明人： Isao Chinzei , Hiromasa Suzuki , Takeru Yoshida , Masahide Miura , Yuki Aoki , Mitsuyoshi Okada , Toshitaka Tanabe , Akihiko Suda , Yoshinori Saito , Hirotaka Ori , Kosuke Iizuka , Akira Morikawa
IPC分类号： B01D53/94 , B01J37/02 , B01J37/03 , B01J35/00 , B01J23/00 , B01J23/10 , B01J23/63 , C01G25/02 , C01F17/00 , F01N3/10 , B01J35/10 , B01J37/00 , B01J35/02 , B01J37/08 , B01J27/053
摘要： The object of the present invention is to provide an exhaust gas purifying catalyst that can achieve high purification performance while suppressing H2S emissions. The object is solved by an exhaust gas purifying catalyst in which the lower layer of the catalyst coating layer comprises a ceria-zirconia composite oxide having a pyrochlore-type ordered array structure, in which the ceria-zirconia composite oxide contains at least one additional element selected from the group consisting of praseodymium, lanthanum, and yttrium at 0.5 to 5.0 mol % in relation to the total cation amount, and the molar ratio of (cerium+additional element):(zirconium) is within the range from 43:57 to 48:52.

6. 发明授权

US08242046B2 Inorganic oxide, exhaust gas purifying catalyst carrier, and exhaust gas purifying catalyst 有权
标题翻译：无机氧化物，废气净化催化剂载体和废气净化催化剂
公开(公告)号：US08242046B2
公开(公告)日：2012-08-14
申请号：US10572040
申请日：2005-07-22
申请人： Akira Morikawa , Toshitaka Tanabe , Kae Yamamura , Naoki Takahashi , Hiromasa Suzuki , Akemi Sato , Mamoru Ishikiriyama , Takaaki Kanazawa , Oji Kuno
发明人： Akira Morikawa , Toshitaka Tanabe , Kae Yamamura , Naoki Takahashi , Hiromasa Suzuki , Akemi Sato , Mamoru Ishikiriyama , Takaaki Kanazawa , Oji Kuno
IPC分类号： B01J23/10
CPC分类号： B01J23/002 , B01D53/945 , B01D2255/1025 , B01D2255/204 , B01D2255/206 , B01D2255/2092 , B01J23/02 , B01J23/10 , B01J35/023 , B01J37/03 , B01J2523/00 , B82Y30/00 , C01F7/002 , C01G25/006 , C01P2002/52 , C01P2004/50 , C01P2004/64 , Y02T10/22 , Y10T428/2982 , Y10T428/2991 , B01J2523/31 , B01J2523/3706 , B01J2523/3725 , B01J2523/48
摘要： A particulate inorganic oxide containing aluminum oxide, a metal oxide forming no composite oxide with aluminum oxide, and an additional element including at least one of a rare-earth element and an alkali earth element, the inorganic oxide containing a secondary particle formed by aggregating primary particles; wherein at least a part of the secondary particle includes a plurality of first primary particles, each having a particle size of 100 nm or less, containing aluminum oxide and the additional element, and a plurality of second primary particles, each having a particle size of 100 nm or less, containing the metal oxide and the additional element; wherein at least a part of the first and second primary particles has a surface concentrated region where the additional element has a locally increased content in a surface layer part thereof.
摘要翻译：包含氧化铝的颗粒状无机氧化物，不与氧化铝形成复合氧化物的金属氧化物，以及包含稀土元素和碱土金属元素中的至少一种的附加元素，所述无机氧化物含有通过将初级粒子; 其中所述二次粒子的至少一部分包括多个第一一次粒子，每个具有100nm以下的粒径为100nm以下的第一一次粒子，其含有氧化铝和所述附加元素，以及多个第二一次粒子， 100nm以下，含有金属氧化物和附加元素; 其中所述第一和第二一次粒子的至少一部分具有表面浓缩区域，其中所述附加元素在其表层部分中具有局部增加的含量。

7. 发明申请

US20090149321A1 INORGANIC OXIDE AND CATALYST FOR PURIFICATION OF EXHAUST GAS OBTAINED BY USING THE SAME 审中-公开
标题翻译：无机氧化物和催化剂，用于净化使用相同的排气
公开(公告)号：US20090149321A1
公开(公告)日：2009-06-11
申请号：US12300676
申请日：2007-06-08
申请人： Akira Morikawa , Toshitaka Tanabe , Naoki Takahashi , Kae Yamamura , Takeru Yoshida , Akemi Sato
发明人： Akira Morikawa , Toshitaka Tanabe , Naoki Takahashi , Kae Yamamura , Takeru Yoshida , Akemi Sato
IPC分类号： B01J21/00
CPC分类号： C01B13/363 , B01D53/945 , B01D2255/202 , B01D2255/204 , B01D2255/206 , B01D2255/40 , B01D2255/407 , B01J23/002 , B01J23/58 , B01J23/63 , B01J35/023 , B01J37/0201 , B01J37/031 , B01J2523/00 , B82Y30/00 , C01G23/047 , C01G25/02 , C01P2002/50 , C01P2002/52 , C01P2004/04 , C01P2004/64 , C01P2006/32 , Y02T10/22 , B01J2523/31 , B01J2523/3725 , B01J2523/48 , B01J2523/3706
摘要： A particulate inorganic oxide contains an aluminum oxide, a metal oxide forming no composite oxide with an aluminum oxide, and at least one additional element selected from the group consisting of rare earth elements and alkaline earth elements. In the inorganic oxide, a percentage content of the aluminum oxide to a total amount of aluminum in the aluminum oxide, a metal element in the metal oxide, and the additional element is in a range from 48 at % to 92 at % in terms of element content. At least 80% of primary particles in the inorganic oxide have a particle diameter of 100 nm or smaller. At least a part of the primary particles have a surface concentrated region where a percentage content of the additional element is locally increased in a surface layer part thereof. The content of the additional element in the surface concentrated region to a whole amount of the inorganic oxide is in a range from 0.06% by mass to 0.98% by mass in terms of oxide amount.
摘要翻译：颗粒状无机氧化物含有氧化铝，不与氧化铝形成复合氧化物的金属氧化物和至少一种选自稀土元素和碱土金属元素的附加元素。在无机氧化物中，氧化铝中的铝的总量的比例，氧化铝中的铝的总量，金属氧化物中的金属元素和附加元素的含量在48at％至92at％的范围内，以元素内容。无机氧化物中的至少80％的一次粒子的粒径为100nm以下。至少一部分初级颗粒具有表面浓缩区域，其中附加元素的百分含量在其表面层部分局部增加。表面浓缩区域中的附加元素与无机氧化物的总量的含量相对于氧化物量为0.06质量％〜0.98质量％。

8. 发明申请

US20070104950A1 Inorganic oxide, exhaust gas purifying catalyst carrier, and exhaust gas purifying catalyst 有权
标题翻译：无机氧化物，废气净化催化剂载体和废气净化催化剂
公开(公告)号：US20070104950A1
公开(公告)日：2007-05-10
申请号：US10572040
申请日：2005-07-22
申请人： Akira Morikawa , Toshitaka Tanabe , Kae Yamamura , Naoki Takahashi , Hiromasa Suzuki , Akemi Sato , Mamoru Ishikiriyama , Takaaki Kanazawa , Oji Kuno
发明人： Akira Morikawa , Toshitaka Tanabe , Kae Yamamura , Naoki Takahashi , Hiromasa Suzuki , Akemi Sato , Mamoru Ishikiriyama , Takaaki Kanazawa , Oji Kuno
IPC分类号： B32B15/02
CPC分类号： B01J23/002 , B01D53/945 , B01D2255/1025 , B01D2255/204 , B01D2255/206 , B01D2255/2092 , B01J23/02 , B01J23/10 , B01J35/023 , B01J37/03 , B01J2523/00 , B82Y30/00 , C01F7/002 , C01G25/006 , C01P2002/52 , C01P2004/50 , C01P2004/64 , Y02T10/22 , Y10T428/2982 , Y10T428/2991 , B01J2523/31 , B01J2523/3706 , B01J2523/3725 , B01J2523/48
摘要： A particulate inorganic oxide containing aluminum oxide, a metal oxide forming no composite oxide with aluminum oxide, and an additional element including at least one of a rare-earth element and an alkali earth element, the inorganic oxide containing a secondary particle formed by aggregating primary particles; wherein at least a part of the secondary particle includes a plurality of first primary particles, each having a particle size of 100 nm or less, containing aluminum oxide and the additional element, and a plurality of second primary particles, each having a particle size of 100 nm or less, containing the metal oxide and the additional element; wherein at least a part of the first and second primary particles has a surface concentrated region where the additional element has a locally increased content in a surface layer part thereof.
摘要翻译：包含氧化铝的颗粒状无机氧化物，不与氧化铝形成复合氧化物的金属氧化物，以及包含稀土元素和碱土金属元素中的至少一种的附加元素，所述无机氧化物含有通过将初级粒子; 其中所述二次粒子的至少一部分包括多个第一一次粒子，每个具有100nm以下的粒径为100nm以下的第一一次粒子，其含有氧化铝和所述附加元素，以及多个第二一次粒子， 100nm以下，含有金属氧化物和附加元素; 其中所述第一和第二一次粒子的至少一部分具有表面浓缩区域，其中所述附加元素在其表层部分中具有局部增加的含量。

9. 发明授权

US10556223B2 Exhaust gas purifying catalyst 有权
公开(公告)号：US10556223B2
公开(公告)日：2020-02-11
申请号：US15534841
申请日：2015-12-11
申请人： Hiromasa Suzuki , Takeru Yoshida , Masahide Miura , Yuki Aoki , Isao Chinzei , Yoshinori Saito , Daisuke Ochiai , Mitsuyoshi Okada , Toshitaka Tanabe , Akihiko Suda , Masanao Sato , Akiya Chiba , Akira Morikawa , Hirotaka Ori
发明人： Hiromasa Suzuki , Takeru Yoshida , Masahide Miura , Yuki Aoki , Isao Chinzei , Yoshinori Saito , Daisuke Ochiai , Mitsuyoshi Okada , Toshitaka Tanabe , Akihiko Suda , Masanao Sato , Akiya Chiba , Akira Morikawa , Hirotaka Ori
IPC分类号： F01N3/10 , B01D53/94 , B01J23/00 , B01J23/10 , B01J23/63 , B01J35/00 , B01J35/04 , B01J35/10 , B01J37/02 , B01J37/03 , B01J37/08 , C01F17/00 , C01G25/00 , C01G25/02 , B01J27/053
摘要： The object of the present invention is to provide an exhaust gas purifying catalyst that can achieve high purification performance while suppressing H2S emissions. The object is solved by an exhaust gas purifying catalyst in which the top layer of a catalyst coating layer comprises a ceria-zirconia composite oxide having a pyrochlore-type ordered array structure, in which the ceria-zirconia composite oxide contains at least one additional element selected from the group consisting of praseodymium, lanthanum, and yttrium at 0.5 to 5.0 mol % in relation to the total cation amount, and the molar ratio of (cerium+additional element):(zirconium) is within the range from 43:57 to 48:52.

10. 发明授权

US10143968B2 Exhaust gas purifying catalyst 有权
公开(公告)号：US10143968B2
公开(公告)日：2018-12-04
申请号：US15534805
申请日：2015-12-11
申请人： Hiromasa Suzuki , Takeru Yoshida , Masahide Miura , Isao Chinzei , Mitsuyoshi Okada , Toshitaka Tanabe , Akihiko Suda , Hirotaka Ori , Akiya Chiba , Kosuke Iizuka , Akira Morikawa
发明人： Hiromasa Suzuki , Takeru Yoshida , Masahide Miura , Isao Chinzei , Mitsuyoshi Okada , Toshitaka Tanabe , Akihiko Suda , Hirotaka Ori , Akiya Chiba , Kosuke Iizuka , Akira Morikawa
IPC分类号： B01J23/38 , B01J23/40 , B01J23/42 , B01J23/44 , B01J23/63 , B01J23/10 , B01J35/00 , B01D53/94 , B01J37/02 , B01J37/03 , C04B35/488
摘要： The object of the present invention is to provide a high-performance exhaust gas purifying catalyst that can achieve oxygen absorption/release capacity and NOx purification performance. The object is solved by an exhaust gas purifying catalyst, which comprises a ceria-zirconia composite oxide having a pyrochlore-type ordered array structure in the upstream part of the catalyst coating layer, in which the ceria-zirconia composite oxide contains at least one additional element selected from the group consisting of praseodymium, lanthanum, and yttrium at 0.5 to 5.0 mol % of the total cation amount, and has a molar ratio of (cerium+the additional element):(zirconium) of 43:57 to 48:52.

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