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    • 1. 发明授权
    • Process for producing photocurable material, photocurable material and article
    • 制备光固化材料,光固化材料和制品的方法
    • US08207242B2
    • 2012-06-26
    • US13152740
    • 2011-06-03
    • Hideo NomotoYasuhide KawaguchiHideshi Sasakura
    • Hideo NomotoYasuhide KawaguchiHideshi Sasakura
    • C08J3/28B32B5/16B05D3/00C08G79/00C08F20/06
    • C08F2/44C08F292/00Y10S977/773Y10S977/778Y10T428/2995Y10T428/31678Y10T428/31855C08F220/26
    • To provide a photocurable material which can form a cured product having a high transparency and a high refractive index, a process for producing the material easily, and an article having a high transparency and a high refractive index.The photocurable material is obtained by a production process comprising (i) a step of reacting a polymerizable component (A) comprised of at least one type of a compound (a) having a (meth)acryloyloxy group, and a compound (B) having a mercapto group and a carboxy group to obtain a surface modifier (C) which has the carboxy group derived from the compound (B) at a terminal, (ii) a step of modifying the surface of inorganic fine particles (D) with the surface modifier (C) to obtain surface-modified inorganic fine particles (E), and (iii) a step of obtaining a photocurable material which contains the surface-modified inorganic fine particles (E), a polymerizable component (F) comprised of at least one type of a compound (f) having a (meth)acryloyloxy group, and a photopolymerization initiator (G).
    • 为了提供可以形成具有高透明度和高折射率的固化产物的光固化材料,容易制造材料的方法和具有高透明度和高折射率的制品。 光固化性材料通过以下制造方法得到:(i)使由至少一种具有(甲基)丙烯酰氧基的化合物(a)组成的聚合性组分(A)和具有(甲基)丙烯酰氧基的化合物(B))和 巯基和羧基,得到在末端具有来自化合物(B)的羧基的表面改性剂(C),(ii)使表面改性无机微粒(D)的表面的工序, 改性剂(C)以获得表面改性的无机细颗粒(E),和(iii)获得含有表面改性无机细颗粒(E)的光固化材料,至少包含可聚合组分(F)的步骤 一种具有(甲基)丙烯酰氧基的化合物(f)和光聚合引发剂(G)。
    • 2. 发明申请
    • PROCESS FOR PRODUCING PHOTOCURABLE MATERIAL, PHOTOCURABLE MATERIAL AND ARTICLE
    • 生产光电材料,光电材料和制品的工艺
    • US20110237703A1
    • 2011-09-29
    • US13152740
    • 2011-06-03
    • Hideo NOMOTOYasuhide KawaguchiHideshi Sasakura
    • Hideo NOMOTOYasuhide KawaguchiHideshi Sasakura
    • C08J3/28C08F267/06
    • C08F2/44C08F292/00Y10S977/773Y10S977/778Y10T428/2995Y10T428/31678Y10T428/31855C08F220/26
    • To provide a photocurable material which can form a cured product having a high transparency and a high refractive index, a process for producing the material easily, and an article having a high transparency and a high refractive index.The photocurable material is obtained by a production process comprising (i) a step of reacting a polymerizable component (A) comprised of at least one type of a compound (a) having a (meth)acryloyloxy group, and a compound (B) having a mercapto group and a carboxy group to obtain a surface modifier (C) which has the carboxy group derived from the compound (B) at a terminal, (ii) a step of modifying the surface of inorganic fine particles (D) with the surface modifier (C) to obtain surface-modified inorganic fine particles (E), and (iii) a step of obtaining a photocurable material which contains the surface-modified inorganic fine particles (E), a polymerizable component (F) comprised of at least one type of a compound (f) having a (meth)acryloyloxy group, and a photopolymerization initiator (G).
    • 为了提供可以形成具有高透明度和高折射率的固化产物的光固化材料,容易制造材料的方法和具有高透明度和高折射率的制品。 光固化性材料通过以下制造方法得到:(i)使由至少一种具有(甲基)丙烯酰氧基的化合物(a)组成的聚合性组分(A)和具有(甲基)丙烯酰氧基的化合物(B))和 巯基和羧基,得到在末端具有来自化合物(B)的羧基的表面改性剂(C),(ii)使表面改性无机微粒(D)的表面的工序, 改性剂(C)以获得表面改性的无机细颗粒(E),和(iii)获得含有表面改性无机细颗粒(E)的光固化材料,至少包含可聚合组分(F)的步骤 一种具有(甲基)丙烯酰氧基的化合物(f)和光聚合引发剂(G)。