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    • 2. 发明授权
    • Composite ceramic
    • 复合陶瓷
    • US5616527A
    • 1997-04-01
    • US593282
    • 1996-01-30
    • Hideki KitaWenjea J. Tseng
    • Hideki KitaWenjea J. Tseng
    • C04B35/597C04B35/65C04B35/80C04B38/00C04B35/596
    • C04B35/597C04B35/65C04B35/803C04B38/00
    • A composite ceramic is produced by forming a mixed powder of Si and a compound oxide as the starting material into a formed material, nitriding and firing the formed material to form a sinter, and subjecting the sinter to oxidation treatment. The composite ceramic, which is:lightweight and reduced in heat conductivity, has a specific gravity of at most 2.6, and comprises a phase composed of all of elements Si, O and N, and at least one element selected from the element group consisting of A1, Zr, Li, P and Mg, in which phase a subphase composed of Si, Al, 0 and N and a subphase composed of Si, O and N are formed. Another composite ceramic has pores and a disperse phase in a matrix phase composed of Si.sub.3 N.sub.4 crystal grains, an oxide and an oxynitride, and further comprises coarse Si.sub.3 N.sub.4 grains dispersed in the matrix phase with O-containing boundary reaction product layers formed in the boundaries between the matrix phase and the coarse Si.sub.3 N.sub.4 grains. Thus, this composite ceramic, though reduced in heat conductivity, has a high toughness and a high strength due to dispersion of the coarse Si.sub.3 N.sub.4 grains in the matrix phase.
    • 通过将Si和复合氧化物的混合粉末作为原料形成成形材料,氮化和烧制所形成的材料以形成烧结体,并对烧结体进行氧化处理来制造复合陶瓷。 复合陶瓷:重量轻且导热性降低,其比重至多为2.6,并且包括由所有元素Si,O和N组成的相,以及选自元素组中的至少一种元素 Al,Zr,Li,P和Mg,其中形成由Si,Al,O和N组成的亚相和由Si,O和N组成的亚相的相。 另一种复合陶瓷在由Si 3 N 4晶粒,氧化物和氮氧化物组成的基体相中具有孔和分散相,并且还包含分散在基质相中的粗​​大的Si 3 N 4晶粒,其中所述的含有O的边界反应产物层形成在 基体相和粗Si3N4晶粒。 因此,该复合陶瓷虽然导热率降低,但是由于基体相中的粗大的Si 3 N 4晶粒的分散,所以具有高的韧性和高的强度。