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    • 5. 发明申请
    • JOINT PRODUCT BETWEEN STEEL PRODUCT AND ALUMINUM MATERIAL, SPOT WELDING METHOD FOR THE JOINT PRODUCT, AND ELECTRODE CHIP FOR USE IN THE JOINT PRODUCT
    • 钢产品和铝材料之间的接合产品,接头产品的点焊焊接方法和用于接合产品的电极芯片
    • US20090011269A1
    • 2009-01-08
    • US12280599
    • 2007-02-21
    • Wataru UrushiharaMikako TakedaKatsushi MatsumotoJun Katoh
    • Wataru UrushiharaMikako TakedaKatsushi MatsumotoJun Katoh
    • B32B15/01B32B15/18B23K11/30B23K11/11B32B15/20
    • B23K11/115B23K11/20B23K11/3009B23K2101/006B23K2101/18B23K2101/20B23K2103/20C09J5/10Y10T428/12347
    • To provide a joint product of a steel product and an aluminum material, and a spot welding method for the joint product, ensuring that spot welding with high bonding strength can be performed. In one embodiment, a steel product 1 having a sheet thickness t1 of 0.3 to 3.0 mm and an aluminum material 2 having a sheet thickness t2 of 0.5 to 4.0 mm are joined together by spot welding to form a joint product of a steel product and an aluminum produce. In this joint product, the nugget area in the joint part is from 20×t20.5 to 100×t20.5 mm2, the area of a portion where the thickness of the interface reaction layer is from 0.5 to 3 μm is 10×t20.5 mm2 or more, and the difference between the interface reaction layer thickness at the joint part center and the interface reaction layer thickness at a point distant from the joint part center by a distance of one-fourth of the joint diameter Dc is 5 μm or less. According to this construction, there can be provided a dissimilar material joint product with excellent bonding strength, which can be formed by an existing spot welding apparatus at a low cost without newly using other materials such as clad material or without newly adding a separate step, and a spot welding method for the dissimilar material joint product.
    • 为了提供钢材和铝材的联合产品,以及用于接合产品的点焊方法,确保可以执行高粘合强度的点焊。 在一个实施例中,通过点焊将片材厚度t1为0.3〜3.0mm的钢制品1和板厚t2为0.5〜4.0mm的铝材2接合在一起,形成钢材和 铝制品。 在该接合部中,接合部的熔核面积为20×20.5〜100×20.5mm 2,界面反应层的厚度为0.5〜3μm的部分的面积为10×20.5mm 2以上, 并且在接合部中心的界面反应层厚度与远离接合部中心的点的界面反应层厚度之间的差为接合直径Dc的四分之一的距离为5μm以下。 根据这种结构,可以提供一种具有优异接合强度的不同材料接合产品,其可以通过现有的点焊装置以低成本形成,而不需要重新使用诸如包覆材料的其它材料,或者不新增单独的步骤, 以及用于异种材料接合产品的点焊方法。
    • 6. 发明授权
    • Steel sheet for dissimilar materials weldbonding to aluminum material and dissimilar materials bonded body
    • 用于不同材料的钢板焊接到铝材料和异种材料粘结体
    • US07521129B2
    • 2009-04-21
    • US11436703
    • 2006-05-19
    • Mikako TakedaWataru UrushiharaKatsushi MatsumotoJun Katoh
    • Mikako TakedaWataru UrushiharaKatsushi MatsumotoJun Katoh
    • B32B15/04
    • C22C21/06B23K35/0261B23K35/286B32B15/012C21D9/46C22C21/02C22C21/08C22C38/02C22C38/04C22C38/12C22C38/22C22C38/26C22C38/28C22C38/34Y10T428/12472Y10T428/12757
    • Disclosed is a steel sheet for dissimilar materials weldbonding to an aluminum material, the steel sheet containing, in mass, C: 0.02 to 0.3%, Si: 0.2 to 5.0%, Mn: 0.2 to 2.0%, and Al: 0.002 to 0.1%, further one or more of Ti: 0.005 to 0.10%, Nb: 0.005 to 0.10%, Cr: 0.05 to 1.0%, and Mo: 0.01 to 1.0%, and the balance consisting of Fe and unavoidable impurities. In the steel sheet, (i) the proportion of the oxide containing Mn and Si by 1 at. % or more in total in the external oxide layer which is newly formed after an original oxide layer having already existed on the surface of the steel sheet is once removed and now exists on the surface of the base steel material of the steel sheet is 50 to 80% in terms of the average proportion of the total length of the oxide to 1 μm length of the interface between the base steel material and the external oxide layer nearly in the horizontal direction, (ii) the proportion of the internal oxide, including oxide at the grain boundary, which exists in the steel region up to the depth of 10 μm from the surface of said base steel material of said steel sheet and contains Mn and Si by 1 at. % or more in total is 3% or more to less than 10% in terms of the average area percentage of said internal oxide in the visual field of 10 μm2 of said steel region, (iii) the proportion of the internal oxide, including oxide at the grain boundary, which exists in the steel region exceeding 10 μm in depth from the surface of said base steel material of said steel sheet and contains Mn and Si by 1 at. % or more in total is 0.1% or less in terms of the average area percentage of said internal oxide in the visual field of 10 μm2 of said steel region.
    • 公开了一种用于与铝材料焊接的不同材料的钢板,该钢板以质量计含有C:0.02〜0.3%,Si:0.2〜5.0%,Mn:0.2〜2.0%,Al:0.002〜0.1% ,进一步Ti:0.005〜0.10%,Nb:0.005〜0.10%,Cr:0.05〜1.0%,Mo:0.01〜1.0%,余量由Fe和不可避免的杂质组成。 在钢板中,(i)含有Mn和Si的氧化物的比例为1at。 在钢板表面已经存在的原始氧化物层被一次除去之后新形成的外部氧化物层中,总共存在%以上,现在存在于钢板的基体钢材的表面上,为50〜 以基本钢材和外部氧化物层之间的界面几乎在水平方向上的氧化物总长度与1mm长度的平均比例为80%,(ii)内部氧化物(包括氧化物)的比例 在与所述钢板的所述基体钢材的表面直径相距10μm的钢区域存在的晶界,其含有Mn和Si为1at。 所述钢区域的10mum2的视野内的所述内部氧化物的平均面积百分比为3%以上〜小于10%,(iii)包含氧化物的内部氧化物的比例 在与所述钢板的所述基材的表面相比,钢区域的厚度超过10μm的晶界,并且含有Mn和Si为1at。 所述钢区域的10mum2的视野内的所述内部氧化物的平均面积百分比,总计为0.1%以下。
    • 8. 发明申请
    • Steel sheet for dissimilar materials weldbonding to aluminum material and dissimilar materials bonded body
    • 用于不同材料的钢板焊接到铝材料和异种材料粘结体
    • US20060275623A1
    • 2006-12-07
    • US11436703
    • 2006-05-19
    • Mikako TakedaWataru UrushiharaKatsushi MatsumotoJun Katoh
    • Mikako TakedaWataru UrushiharaKatsushi MatsumotoJun Katoh
    • C22C38/00B32B15/10
    • C22C21/06B23K35/0261B23K35/286B32B15/012C21D9/46C22C21/02C22C21/08C22C38/02C22C38/04C22C38/12C22C38/22C22C38/26C22C38/28C22C38/34Y10T428/12472Y10T428/12757
    • Disclosed is a steel sheet for dissimilar materials weldbonding to an aluminum material, the steel sheet containing, in mass, C: 0.02 to 0.3%, Si: 0.2 to 5.0%, Mn: 0.2 to 2.0%, and Al: 0.002 to 0.1%, further one or more of Ti: 0.005 to 0.10%, Nb: 0.005 to 0.10%, Cr: 0.05 to 1.0%, and Mo: 0.01 to 1.0%, and the balance consisting of Fe and unavoidable impurities. In the steel sheet, (i) the proportion of the oxide containing Mn and Si by 1 at. % or more in total in the external oxide layer which is newly formed after an original oxide layer having already existed on the surface of the steel sheet is once removed and now exists on the surface of the base steel material of the steel sheet is 50 to 80% in terms of the average proportion of the total length of the oxide to 1 μm length of the interface between the base steel material and the external oxide layer nearly in the horizontal direction, (ii) the proportion of the internal oxide, including oxide at the grain boundary, which exists in the steel region up to the depth of 10 μm from the surface of said base steel material of said steel sheet and contains Mn and Si by 1 at. % or more in total is 3% or more to less than 10% in terms of the average area percentage of said internal oxide in the visual field of 10 μm2 of said steel region, (iii) the proportion of the internal oxide, including oxide at the grain boundary, which exists in the steel region exceeding 10 μm in depth from the surface of said base steel material of said steel sheet and contains Mn and Si by 1 at. % or more in total is 0.1% or less in terms of the average area percentage of said internal oxide in the visual field of 10 μm2 of said steel region.
    • 公开了一种用于与铝材料焊接的不同材料的钢板,该钢板以质量计含有C:0.02〜0.3%,Si:0.2〜5.0%,Mn:0.2〜2.0%,Al:0.002〜0.1% ,进一步Ti:0.005〜0.10%,Nb:0.005〜0.10%,Cr:0.05〜1.0%,Mo:0.01〜1.0%,余量由Fe和不可避免的杂质组成。 在钢板中,(i)含有Mn和Si的氧化物的比例为1at。 在钢板表面已经存在的原始氧化物层被一次除去之后新形成的外部氧化物层中,总共存在%以上,现在存在于钢板的基体钢材的表面上,为50〜 以基本钢材和外部氧化物层之间的界面几乎在水平方向上的氧化物总长度与1mm长度的平均比例为80%,(ii)内部氧化物(包括氧化物)的比例 在与所述钢板的所述基体钢材的表面直径相距10μm的钢区域存在的晶界,其含有Mn和Si为1at。 (iii)所述钢区域的10mm 2的视野内的所述内部氧化物的平均面积百分比为3%以上至小于10%,(iii) 内部氧化物,包括在所述钢板的所述基体钢材表面上存在于钢区域内的深度超过10μm的晶界处的氧化物,并且含有Mn和Si为1at。 所述钢区域的10mum 2视野内的所述内部氧化物的平均面积百分比,总计为0.1%以下。
    • 9. 发明申请
    • FLUX-CORED WIRE FOR DIFFERENT-MATERIAL BONDING AND METHOD OF BONDING DIFFERENT MATERIALS
    • 用于不同材料结合的通用线和粘合不同材料的方法
    • US20090017328A1
    • 2009-01-15
    • US12279470
    • 2007-02-06
    • Jun KatohMikako TakedaSeiji SasabeKatsushi MatsumotoHidekazu IdoTsuyoshi Matsumoto
    • Jun KatohMikako TakedaSeiji SasabeKatsushi MatsumotoHidekazu IdoTsuyoshi Matsumoto
    • B32B15/01B23K35/34B23K9/00
    • B23K35/0266B23K9/173B23K9/232B23K35/362B23K35/406B23K2101/18B23K2103/20Y10T428/12757
    • There are provided a flux cored wire for joining dissimilar materials with each other, capable of enhancing a bonding strength upon joining an aluminum-base material with a steel-base material, and excellent in bonding efficiency, a method for joining the dissimilar materials with each other, and a bonded joint obtained by the method. In particular, there is provided a method for joining dissimilar materials with each other, in the case of melt weld-bonding of high-strength dissimilar materials with each other, that is, the high-strength steel member with the high-strength 6000 series aluminum alloy member and in the case of the steel member being a galvanized steel member. In one mode, use is made of a flux cored wire wherein the interior of an aluminum alloy envelope is filled up with a flux, the flux has fluoride composition containing a given amount of AlF3 without containing chloride, and the aluminum alloy of the envelope contains Si in a range of 1 to 13 mass %. If such a flux cored wire is use, it is possible to obtain a high bonding strength in the case of melt weld-bonding of high-strength dissimilar materials with each other, that is, the high-strength steel member with the high-strength 6000 series aluminum alloy member.
    • 提供了用于将不同材料彼此接合的药芯焊丝,能够在将铝基材料与钢基材料接合时提高接合强度,并且接合效率优异,将不同材料与各种材料接合的方法 另外,通过该方法得到的接合接头。 特别是提供了一种将异种材料彼此接合的方法,在高强度异种材料彼此熔融熔接的情况下,即具有高强度6000系列的高强度钢构件 铝合金构件,在钢构件为镀锌钢构件的情况下。 在一种模式中,使用药芯焊丝,其中铝合金外壳的内部填充有焊剂,焊剂具有含有给定量的不含氯化物的AlF 3的氟化物组合物,并且信封的铝合金包含 Si在1〜13质量%的范围内。 如果使用这样的药芯焊丝,则在高强度异种材料的熔融熔接的情况下,即具有高强度的高强度钢构件的情况下,可以获得高的接合强度 6000系列铝合金构件。