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1. 发明授权

US07074843B2 Microencapsulated pigment, production process therefor, aqueous dispersion and ink jet recording ink 失效
公开(公告)号：US07074843B2
公开(公告)日：2006-07-11
申请号：US10228162
申请日：2002-08-26
申请人： Hiroto Nakamura , Toshiyuki Miyabayashi , Masahiro Yatake , Hidehiko Komatsu
发明人： Hiroto Nakamura , Toshiyuki Miyabayashi , Masahiro Yatake , Hidehiko Komatsu
IPC分类号： C08K9/10 , C08K5/23
CPC分类号： C09C1/56 , B01J13/04 , B01J13/14 , C01P2004/54 , C09B67/0013 , C09B67/0097 , C09B68/4253 , C09B68/44 , C09B68/4475 , C09C3/10 , C09D11/322 , C09D11/326 , C09D17/001 , Y10T428/29 , Y10T428/2982 , Y10T428/2991 , Y10T428/2993 , Y10T428/2998
摘要： Provided are ink jet ink excellent in dispersion stability and ejection stability and capable of forming images with fastness, abrasion resistance, color developability, and high density with little feathering; a microencapsulated pigment (MCP) providing the ink and a process of making the same; and an aqueous dispersion of the MCP. The MCP comprises pigment particles having a hydrophilic group on their surface (hydrophilized pigment particles) and coated with a polymer by emulsion polymerization. The process comprises emulsion polymerization in the presence of the hydrophilized pigment particles. The ink essentially contains the MCP and water.

2. 发明授权

US06802893B1 Ink for ink-jet recording and process for producing the same, ink set for ink-jet recording, and ink cartridge 有权
标题翻译：用于喷墨记录的墨水及其制造方法，用于喷墨记录的墨水组和墨盒
公开(公告)号：US06802893B1
公开(公告)日：2004-10-12
申请号：US09762722
申请日：2001-04-11
申请人： Hidehiko Komatsu , Hiroto Nakamura , Masahiro Yatake , Hiroko Hayashi , Makoto Matsuzaki , Fumitsugu Ito , Hitoshi Ohta
发明人： Hidehiko Komatsu , Hiroto Nakamura , Masahiro Yatake , Hiroko Hayashi , Makoto Matsuzaki , Fumitsugu Ito , Hitoshi Ohta
IPC分类号： C09D1102
CPC分类号： C09D11/322 , C09D11/324 , C09D11/40
摘要： An ink for ink jet recording including at least a particulate pigment having a sulfur-containing dispersibility providing group chemically bonded to the pigment surface with a treatment containing sulfur, a penetrating agent and a liquid component including water. In one embodiment, the liquid component includes polyvalent metal ions and has a sulfur content that is 2,000 ppm or less as calculated in terms of SO42−. In other embodiments, the ink has (a) a sulfonic acid anion group or a sulfinic acid anion group and an alkaline metal or monovalent counter ion; (b) a penetrating agent having the formula R—EOn2—POm2—X; and (c) a sulfur-containing dispersibility providing group in an amount of 10×106 equivalent or more per gram of particulate pigment.
摘要翻译：一种用于喷墨记录的油墨，其至少包括具有含硫分散性提供基团的颗粒颜料，所述分散性提供基团与颜料表面化学键合，所述处理含有硫，渗透剂和包含水的液体组分。在一个实施方案中，液体组分包括多价金属离子，并且根据SO 4 2-的计算，其硫含量为2,000ppm以下。在其它实施方案中，油墨具有（a）磺酸阴离子基团或亚磺酸阴离子基团和碱金属或一价抗衡离子; （b）具有式R-EOn2-POm2-X的渗透剂; 和（c）含量分散性提供基团，其量为每克颗粒颜料10×10 6当量或更多。

3. 发明授权

US06648953B2 Ink composition for ink jet recording, process for the preparation thereof, and ink jet recording process using said ink composition 有权
标题翻译：用于喷墨记录的油墨组合物，其制备方法和使用所述油墨组合物的喷墨记录方法
公开(公告)号：US06648953B2
公开(公告)日：2003-11-18
申请号：US09842180
申请日：2001-04-26
申请人： Hideo Yamazaki , Michinari Tsukahara , Hiroto Nakamura , Hidehiko Komatsu
发明人： Hideo Yamazaki , Michinari Tsukahara , Hiroto Nakamura , Hidehiko Komatsu
IPC分类号： C09D1102
CPC分类号： C09D11/32 , C09D11/324
摘要： The present invention provides an ink composition for an ink jet recording process, which exhibits excellent print quality with good water fastness and light fastness and without flying in deflected directions from the ink head or nozzle fill-in even after a prolonged ink jet printing. The ink comprises (1) a carbon black, (2) an organic pigment, (3) a dispersant incorporated in an aqueous medium and (4) a saccharide.
摘要翻译：本发明提供了一种用于喷墨记录方法的油墨组合物，其即使在长时间的喷墨打印之后也显示出优异的印刷质量，具有良好的耐水牢度和耐光性，并且不会从墨头或喷嘴填充物偏转方向飞散。油墨包括（1）炭黑，（2）有机颜料，（3）掺入水性介质中的分散剂和（4）糖。

4. 发明授权

US6083315A Agglomerated pigment, process for producing the same, aqueous pigment dispersion, and water-based ink composition 失效
标题翻译：聚集颜料，其制造方法，水性颜料分散体和水性油墨组合物
公开(公告)号：US6083315A
公开(公告)日：2000-07-04
申请号：US996194
申请日：1997-12-22
申请人： Hiroto Nakamura , Hidehiko Komatsu , Michinari Tsukahara , Hideo Yamazaki , Minoru Waki , Naoki Okamoto , Kazumi Adachi
发明人： Hiroto Nakamura , Hidehiko Komatsu , Michinari Tsukahara , Hideo Yamazaki , Minoru Waki , Naoki Okamoto , Kazumi Adachi
IPC分类号： C09B67/46 , C09B63/00 , C09B67/08 , C09B67/22 , C09D11/00 , C09D11/322 , C09D11/326 , C09D11/38 , C09B67/50
CPC分类号： C09D11/32 , C09B63/005 , C09B67/0004 , C09B67/0034 , C09D11/17
摘要： An agglomerated pigment comprises (1) an organic pigment compound, (2) either a sulfonated organic pigment compound obtained by incorporating at least one sulfonic group into the organic pigment compound or a sulfonated organic pigment derivative obtained by incorporating at least one sulfonic group into a derivative of the organic pigment compound, (3) univalent inorganic counter ions bonded to sulfonic groups of component (2), and (4) bivalent or higher inorganic counter ions which are bonded to sulfonic groups of component (2) and wherein each such group has an at least univalent positive charge, the surface of the agglomerated organic pigment as a whole being positively charged. An aqueous pigment dispersion and a water-based ink composition both having excellent storage stability, an agglomerated pigment for use as a raw material for the dispersion, and a process for producing the pigment are provided.
摘要翻译：凝聚颜料包括（1）有机颜料化合物，（2）通过在有机颜料化合物中引入至少一个磺酸基而获得的磺化有机颜料化合物或通过将至少一个磺酸基并入到有机颜料化合物的衍生物，（3）与组分（2）的磺酸基键合的一价无机抗衡离子，和（4）与组分（2）的磺酸基键合的二价或更高级无机抗衡离子，并且其中每个这样的基团具有至少一价的正电荷，聚集的有机颜料的整个表面带正电荷。提供了具有优异的储存稳定性的水性颜料分散体和水性油墨组合物，用作分散体的原料的凝聚颜料，以及颜料的制造方法。

5. 发明授权

US06830612B1 Ink for ink jet recording 失效
标题翻译：墨水用于喷墨记录
公开(公告)号：US06830612B1
公开(公告)日：2004-12-14
申请号：US09660012
申请日：2000-09-12
申请人： Masahiro Yatake , Hiroto Nakamura , Hidehiko Komatsu
发明人： Masahiro Yatake , Hiroto Nakamura , Hidehiko Komatsu
IPC分类号： C09D1100
CPC分类号： C09D11/30 , C08G65/3344 , C08G2650/58 , C08L71/02
摘要： An ink is provided which can realize good images on various recording media, especially plain papers. The ink comprises at least a water-soluble colorant, a water-soluble organic solvent, water, and a mixture of two or more compounds represented by formula (I): R—[(EO)n-(PO)m]k-T wherein EO represents an ethyleneoxy group; PO represents a propyleneoxy group; T represents an OH group or SO3M wherein M represents a hydrogen atom, an alkali metal, an inorganic base, or an organic amine; m and n are each an integer; k is a natural number of not less than 1; and R represents an alkyl or cyclic group.
摘要翻译：提供了能够在各种记录介质，特别是普通纸上实现良好图像的油墨。油墨至少包含水溶性着色剂，水溶性有机溶剂，水和两种或更多种由式（ I）：其中EO表示亚乙基氧基; PO表示丙烯氧基; T表示OH基或SO3M，其中M表示氢原子，碱金属，无机碱或有机胺; m和n各自为整数; k是不小于1的自然数; R表示烷基或环状基团。

6. 发明授权

US06524383B2 Method for manufacturing pigment dispersion, pigment dispersion obtained by this method, and ink jet recording ink using same 有权
标题翻译：用于制造颜料分散体的方法，通过该方法获得的颜料分散体和使用该方法的喷墨记录油墨
公开(公告)号：US06524383B2
公开(公告)日：2003-02-25
申请号：US10083701
申请日：2001-10-19
申请人： Hidehiko Komatsu , Hiroto Nakamura , Hitoshi Ohta , Masahiro Yatake , Kazuhiko Hara
发明人： Hidehiko Komatsu , Hiroto Nakamura , Hitoshi Ohta , Masahiro Yatake , Kazuhiko Hara
IPC分类号： C09D1700
CPC分类号： C09D11/322 , C09B67/0008 , C09B67/0084 , C09B68/26 , C09B68/4253 , C09B68/441 , C09B68/446 , C09D17/001
摘要： Disclosed is a pigment dispersion that can be used for an ink jet printing-use pigment ink that affords stable printing characteristics and has excellent storage stability in an ink jet printer having a head driven at a high frequency and having finer nozzles in order to enhance image quality and raise the speed. Disclosed is also a method for manufacturing this pigment dispersion. This manufacturing method includes a step of surface-treating a self-dispersing type of pigment, in which at least hydrophilic, dispersibility-imparting group is introduced to the pigment surface directly and/or via a polyvalent group, and a step of dispersing the self-dispersing pigment obtained in said surface-treating step in an aqueous medium, wherein the dispersion step is a step in which at least the self-dispersing pigment, a wetting agent, and water are dispersed in the form of a liquid mixture.
摘要翻译：公开了一种可用于喷墨印刷用颜料墨水的颜料分散体，其具有稳定的印刷特性，并且在喷墨打印机中具有优异的储存稳定性，该喷墨打印机具有以高频率驱动的头部并且具有更细的喷嘴以增强图像质量提高速度。还公开了这种颜料分散体的制造方法。该制造方法包括对自分散型颜料进行表面处理的步骤，其中至少亲水性，分散性赋予基团直接和/或经由多价基团引入颜料表面，以及分散自身的步骤在所述表面处理步骤中获得的分散颜料在水性介质中，其中所述分散步骤是至少所述自分散颜料，润湿剂和水以液体混合物的形式分散的步骤。

7. 发明授权

US06379443B1 Ink jet recording method and ink composition for use in said method 失效
标题翻译：用于所述方法的喷墨记录方法和油墨组合物
公开(公告)号：US06379443B1
公开(公告)日：2002-04-30
申请号：US09521573
申请日：2000-03-09
申请人： Hidehiko Komatsu , Hiroto Nakamura
发明人： Hidehiko Komatsu , Hiroto Nakamura
IPC分类号： C09D1100
CPC分类号： C09D11/30
摘要： Disclosed is an ink jet recording method which can efficiently realize good images, particularly an ink jet recording method which can realize, on plain papers, high-quality prints free from feathering or color-to-color mixing at a relatively low heating temperature, and an ink composition for use in this method. An ink composition comprising at least a colorant, a water-soluble organic solvent, water, and at least one compound represented by formula (I) is printed on a recording medium heated at a temperature of or above the cloud point of the compound represented by formula (I): R—[O—(EO)m—(PO)n]—H wherein EO represents an ethyleneoxy group; PO represents a propyleneoxy group; m and n are each an integer; k is a natural number of 1 or more; and R represents CkH2k−1 wherein k is a natural number of 4 to 18, EO and PO being arranged, regardless of order in the parentheses, randomly or as blocks joined together.
摘要翻译：公开了一种能够有效地实现良好图像的喷墨记录方法，特别是能够在普通纸上实现在相对低的加热温度下无羽化或颜色到颜色混合的高质量打印的喷墨记录方法，以及一种用于该方法的油墨组合物。至少包含着色剂，水溶性有机溶剂，水和至少一种由式（I）表示的化合物的油墨组合物印刷在加热至或在由式（I）表示的化合物的浊点之上：其中EO表示乙烯氧基; PO表示丙烯氧基; m和n分别为整数; k是1以上的自然数; 并且R表示CkH2k-1，其中k是4至18的自然数，EO和PO被排列，不论括号中的顺序如何，随机地或作为连接在一起的嵌段。

8. 发明申请

US20060155008A1 Microencapsulated pigment, production process therefor, aqueous dispersion, and ink jet recording ink 有权
公开(公告)号：US20060155008A1
公开(公告)日：2006-07-13
申请号：US11373680
申请日：2006-03-10
申请人： Hiroto Nakamura , Toshiyuki Miyabayashi , Masahiro Yatake , Hidehiko Komatsu
发明人： Hiroto Nakamura , Toshiyuki Miyabayashi , Masahiro Yatake , Hidehiko Komatsu
IPC分类号： C08K9/00
CPC分类号： C09C1/56 , B01J13/04 , B01J13/14 , C01P2004/54 , C09B67/0013 , C09B67/0097 , C09B68/4253 , C09B68/44 , C09B68/4475 , C09C3/10 , C09D11/322 , C09D11/326 , C09D17/001 , Y10T428/29 , Y10T428/2982 , Y10T428/2991 , Y10T428/2993 , Y10T428/2998
摘要： Provided are ink jet ink excellent in dispersion stability and ejection stability and capable of forming images with fastness, abrasion resistance, color developability, and high density with little feathering; a microencapsulated pigment (MCP) providing the ink and a process of making the same; and an aqueous dispersion of the MCP. The MCP comprises pigment particles having a hydrophilic group on their surface (hydrophilized pigment particles) and coated with a polymer by emulsion polymerization. The process comprises emulsion polymerization in the presence of the hydrophilized pigment particles. The ink essentially contains the MCP and water.

9. 发明授权

US06409330B1 Sublimation transfer ink jet recording method and ink composition for use therein 有权
标题翻译：升华转印喷墨记录方法和用于其中的油墨组合物
公开(公告)号：US06409330B1
公开(公告)日：2002-06-25
申请号：US09508225
申请日：2000-03-08
申请人： Hiroto Nakamura , Hidehiko Komatsu , Akio Owatari
发明人： Hiroto Nakamura , Hidehiko Komatsu , Akio Owatari
IPC分类号： B41J201
CPC分类号： B41J2/0057 , B41J2/01 , B41M5/0256 , B41M5/0356 , C09D11/328
摘要： Disclosed are an ink composition which can satisfy, on a high level, various property requirements for ink compositions for use in ink jet recording (e.g., excellent ejection stability and realization of images free from feathering or color-to-color bleeding) and can realize good images by sublimation transfer. A sublimation transfer ink jet recording method using the ink composition is also disclosed. The ink composition comprises a heat transferable dye, a glycol ether, an acetylene glycol surfactant, and water. This ink composition is printed by ink jet recording onto an intermediate transfer medium to form a latent image on the intermediate transfer medium, and the intermediate transfer medium is then put on the surface of a receptor object, followed by heating of the intermediate transfer medium at a sufficient temperature and for a sufficient time to sublimate the heat transferable dye and to deposit the sublimated dye onto the surface of the receptor object. This recording method can realize good transferred images suffering from minimized bleeding.
摘要翻译：公开了一种可以高水平地满足用于喷墨记录的油墨组合物的各种性能要求的油墨组合物（例如，优异的喷射稳定性和实现无羽化或颜色到颜色渗色的图像），并且可以实现良好的图像通过升华转移。还公开了使用该油墨组合物的升华转印喷墨记录方法。油墨组合物包含可传热染料，二醇醚，乙炔二醇表面活性剂和水。该油墨组合物通过喷墨记录印刷到中间转印介质上以在中间转印介质上形成潜像，然后将中间转印介质放在受体物体的表面上，然后加热中间转印介质足够的温度和足够的时间使可热转移的染料升华并将升华的染料沉积在受体物体的表面上。该记录方法可以实现患有最小化出血的良好转移图像。

10. 发明授权

US07683108B2 Microencapsulated pigment, production process therefor, aqueous dispersion, and ink jet recording ink 有权
标题翻译：微胶囊化颜料，其制备方法，水分散体和喷墨记录油墨
公开(公告)号：US07683108B2
公开(公告)日：2010-03-23
申请号：US11373680
申请日：2006-03-10
申请人： Hiroto Nakamura , Toshiyuki Miyabayashi , Masahiro Yatake , Hidehiko Komatsu
发明人： Hiroto Nakamura , Toshiyuki Miyabayashi , Masahiro Yatake , Hidehiko Komatsu
IPC分类号： A61K9/16 , B32B5/16 , B32B9/00 , B32B15/02 , B32B17/02 , B32B19/00 , B32B21/02 , B32B23/02 , B32B27/02 , C08F283/00 , C08G67/02 , C08J3/02 , C08K3/20 , C08K9/00 , C09D5/00 , C09D11/00
CPC分类号： C09C1/56 , B01J13/04 , B01J13/14 , C01P2004/54 , C09B67/0013 , C09B67/0097 , C09B68/4253 , C09B68/44 , C09B68/4475 , C09C3/10 , C09D11/322 , C09D11/326 , C09D17/001 , Y10T428/29 , Y10T428/2982 , Y10T428/2991 , Y10T428/2993 , Y10T428/2998
摘要： Provided are ink jet ink excellent in dispersion stability and ejection stability and capable of forming images with fastness, abrasion resistance, color developability, and high density with little feathering; a microencapsulated pigment (MCP) providing the ink and a process of making the same; and an aqueous dispersion of the MCP. The MCP comprises pigment particles having a hydrophilic group on their surface (hydrophilized pigment particles) and coated with a polymer by emulsion polymerization. The process comprises emulsion polymerization in the presence of the hydrophilized pigment particles. The ink essentially contains the MCP and water.
摘要翻译：提供了分散稳定性和喷射稳定性优异的喷墨油墨，能够形成具有坚牢度，耐磨性，显色性，高密度，少羽毛的图像; 提供油墨的微胶囊化颜料（MCP）及其制备方法; 和MCP的水分散体。 MCP包含在其表面上具有亲水基团的颜料颗粒（亲水化颜料颗粒），并通过乳液聚合涂覆聚合物。该方法包括在亲水化颜料颗粒存在下的乳液聚合。油墨基本上含有MCP和水。

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