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    • 1. 发明授权
    • Fungicidal mixtures
    • 杀菌混合物
    • US06521628B1
    • 2003-02-18
    • US09492440
    • 2000-01-27
    • Henry Van Tuyl CotterGunter ReichertEwald SieverdingPetrus Martinus Franciscus Emanuel Jegerings
    • Henry Van Tuyl CotterGunter ReichertEwald SieverdingPetrus Martinus Franciscus Emanuel Jegerings
    • A01N3744
    • A01N35/04A01N2300/00
    • The invention relates to a novel fungicidal composition comprising a fungicidally acceptable carrier and/or surface active agent together with, and synergistically effective amounts of (a) at least one benzophenone of formula I wherein R1, R2, R3, R4, R5, R6, R7, m and n have the meaning given; at least one fungicidal active ingredient selected from the following groups (A), (B), (C), (D) and (E): (A) an ergosterol biosynthesis inhibitor; (B) a strobilurine derivative, (C) a melanin biosynthesis inhibitor; (D) a compound selected from the group consisting of acibenzolar, benomyl, captan, carboxin, chlorothalonil, copper, cyprodinil, dinocap, dithianon, dimethomorph, dodine, ethirimol, famoxadone, fenpiclonil, fluazinam, mancozeb, metalaxyl, pyrifenox, sulfur, vinclozolin and (E) an azolopyrimidine of formula II in which R8, R9, R10, R11, A, L and p have the meaning given; and to a method of controlling the growth of phytopathogenic fungi at a locus which comprises applying synergistically effective amounts of (a) at least one benzophenones of formula I and (b) at least one fungicidal active ingredient selected from the groups (A), (B), (C), (D) and (E) to the locus.
    • 本发明涉及一种新颖的杀真菌组合物,其包含杀真菌剂可接受的载体和/或表面活性剂以及协同有效量的(a)至少一种式I的二苯甲酮,其中R 1,R 2,R 3,R 4,R 5,R 6,R 7 ,m和n具有给定的含义; 至少一种选自以下组(A),(B),(C),(D)和(E):( A)麦角甾醇生物合成抑制剂的杀真菌活性成分;(B)嗜球果ur碱衍生物,(C) 黑色素生物合成抑制剂;(D)选自由以下物质组成的组的化合物:苯偶姻,苯菌灵,克拉曼,羧酸,百菌清,铜,嘧菌胺,二硝基,二噻吩,烯酰吗啉,十二烷,乙烯咪唑, ,硫,连环素和(E)式IIin的偶氮嘧啶,其中R8,R9,R10,R11,A,L和p具有给定的含义;以及一种控制植物病原真菌在一个位点生长的方法,其包括协同应用 有效量的(a)至少一种式I的二苯甲酮和(b)至少一种选自(A),(B),(C),(D)和(E)的杀真菌活性成分。
    • 3. 发明授权
    • Fungicidal mixtures
    • 杀菌混合物
    • US06699874B2
    • 2004-03-02
    • US10314594
    • 2002-12-10
    • Henry Van Tuyl CotterLeslie MayGunter ReichertEwald Sieverding
    • Henry Van Tuyl CotterLeslie MayGunter ReichertEwald Sieverding
    • A01N4354
    • A01N43/90A01N2300/00
    • Fungicidal compositions comprising an acceptable carrier and/or surface active agent and synergistically effective amounts of (a) at least one azolopyrimidine of formula I  in which R1, R2, L1, L2 and L3 have the meaning given in claim 1; and (b) at least one fungicidal active ingredient selected from benomyl, carboxin, captan, chlorothalonil, copper oxychloride, cyprodinil, dimethomorph, dithianon, dodine, famoxadone, fenhexamid, fenpiclonil, fenpropimorph, fluazinam, mancozeb, metalaxyl, pyrimethanil, quinoxifen, sulfur, triforine, vinclozolin, a fungicidal triazole derivative, and a synthetic strobilurine derivative. The invention also provides a method of controlling the growth of phytopathogenic fungi at a locus by applying synergistically effective amounts of at least one azolopyrimidine of formula I and at least one fungicidal active ingredient (b) to the locus.
    • 包含可接受的载体和/或表面活性剂和协同有效量的(a)至少一种R 1,R 2,L 1,L 2和L 3的式Iin的偶氮嘧啶的杀真菌组合物 >具有权利要求1中给出的含义; 和(b)至少一种杀真菌活性成分,其选自苯菌灵,呋喃丹,克拉曼,百菌清,氯氧化铜,西酞替尼,烯酰吗啉,二噻吩,十二烷,恶唑酮,芬己酰,芬替尼,芬卡芬,氟啶胺,代森锰锌,甲霜灵,嘧霉胺,喹喔啉, ,triperine,长春菌素,杀真菌三唑衍生物和合成次溴酸衍生物。 本发明还提供了一种通过将协同有效量的至少一种式I的偶氮嘧啶和至少一种杀真菌活性成分(b)施用于该基因座来控制植物病原真菌在一个场所生长的方法。
    • 8. 发明授权
    • Process for improving the reactivity of phosphorus pentasulfide
    • 提高五硫化二磷的反应性的方法
    • US4173621A
    • 1979-11-06
    • US863081
    • 1977-12-22
    • Johannes KrauseGunter ReichertFranz MainzerHermann Niermann
    • Johannes KrauseGunter ReichertFranz MainzerHermann Niermann
    • C01B25/14
    • C01B25/14
    • The reactivity of phosphorus pentasulfide produced by reacting phosphorus and sulfur at a temperature higher than the melting point of phosphorus pentasulfide and allowing the resulting melt to cool and solidify on a cooling device is improved. To this end, liquid phosphorus pentasulfide is placed on, or introduced into, a cooling device; an upper liquid P.sub.2 S.sub.5 -layer portion A is separated immediately from a solidified lower P.sub.2 S.sub.5 -layer portion B which is in direct contact with the cooling surface area of the cooling device; the upper P.sub.2 S.sub.5 -layer portion A is recycled to a P.sub.2 S.sub.5 melt; the lower P.sub.2 S.sub.5 -layer portion B is removed from the cooling device and collected as final product; the reactivity of the collected P.sub.2 S.sub.5 -layer portion B is increased to the same extent as the quantitative ratio of the P.sub.2 S.sub.5 -layer portion A to the P.sub.2 S.sub.5 -layer portion B is increased.
    • 通过在高于五硫化二磷的熔点的温度下使磷和硫反应产生的五硫化二磷的反应性得到改善,并使所得的熔体在冷却装置上冷却和固化。 为此,将五硫化二磷液体放置在冷却装置上或引入冷却装置中; 立即从与冷却装置的冷却表面区域直接接触的凝固的下P2S5层部分B分离上液体P2S5层部分A; 上P2S5层部分A再循环到P2S5熔体中; 将较低的P2S5层部分B从冷却装置中取出并收集成最终产品; 收集的P2S5层部分B的反应性增加到与P2S5层部分A与P2S5层部分B的量比增加的程度相同的程度。
    • 10. 发明授权
    • Process for removing molten phosphorus pentsulfide from a reactor
    • 从反应器中除去二硫化磷的方法
    • US4473538A
    • 1984-09-25
    • US487998
    • 1983-04-29
    • Johannes KrauseFranz MainzerGunter ReichertHermann Niermann
    • Johannes KrauseFranz MainzerGunter ReichertHermann Niermann
    • C01B25/14
    • C01B25/14
    • The invention provides a process and an apparatus for removing molten phosphorus pentasulfide, via an overflow, from a reactor, wherein phosphorus is reacted with sulfur at temperatures higher than 300.degree. C.To this end, the reactor is supplied with phosphorus and sulfur from dosing vessels which are given the dimensions necessary (a) to receive the quantity of phosphorus and sulfur, respectively, which are required to produce phosphorus pentasulfide with a preselected quantitative ratio of P:S, (b) to provide a total filling volume corresponding to that of a P.sub.2 S.sub.5 -receiving tank. The quantity of the phosphorus and sulfur feed materials in the respective dosing vessels is in each case fully emptied into the reactor and a corresponding quantity of molten P.sub.2 S.sub.5 is simultaneously discharged directly from the reactor, via the overflow, into the respective P.sub.2 S.sub.5 -receiving tank, whose filling volume exactly corresponds, to that of the dosing vessels.
    • 本发明提供一种通过溢流从反应器中除去五硫化二磷的方法和装置,其中磷在高于300℃的温度下与硫反应。为此,向反应器中加入磷和硫 给定尺寸所需的尺寸(a)分别接收以预选的P:S定量比例生产五硫化二磷所需的磷和硫量,(b),以提供与该P 的P2S5接收罐。 在各个配量容器中的磷和硫进料的量在每种情况下都完全排空到反应器中,并且相应量的熔融P2S5同时从反应器经由溢流排放到相应的P2S5接收罐中, 其填充体积与计量容器的填充体积完全相符。