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    • 2. 发明申请
    • Method for the production of organic carbonates
    • 生产有机碳酸酯的方法
    • US20070082985A1
    • 2007-04-12
    • US10571476
    • 2004-07-16
    • Henning BucholdJurgen EberhardtUlrich WagnerHans-Jorg Wolk
    • Henning BucholdJurgen EberhardtUlrich WagnerHans-Jorg Wolk
    • C08K5/49
    • C07C68/00C07C69/96
    • The invention relates to a method for the production of monomer organic carbonates, wherein urea, substituted urea, a salt or an ester of carbamide acid or one of the N-substituted derivatives thereof is reacted in a first step in a polyalkylene glycol, a polyester-polyol or a polyether-polyol of general formula (I), wherein R represents a linear or branched alkylene group having 2-12 carbon atoms and n is a number between (2) and (20), or in a completely or partially hydrolysed polyvinyl alcohol of general formula (II) wherein R′ represents an alkyl group, an aryl group or an acyl group having 1-12 carbon atoms, p and q are numbers between 1 and 20, or in mixtures of said compounds in the presence of a catalyst facilitating the separation of ammonia in order to form a mixture containing carbonates and carbamates, the ammonia becomes free or the amine is removed form the reaction mixture by means of a strip gas. In a second reaction step (transesterification), the mixture containing the carbonates and carbamates is reacted with a monomer alcohol or a phenol whereby monomer carbonates are formed and polymer polyalcohols of formulae (I) or (II) are reformed. HO—RnOH  (I)
    • 本发明涉及一种制备单体有机碳酸酯的方法,其中脲,取代的脲,脲或其中的一种或多种N-取代的衍生物的脲或其酯之一在第一步骤中在聚亚烷基二醇,聚酯 - 多元醇或通式(I)的聚醚多元醇,其中R表示具有2-12个碳原子的直链或支链亚烷基,n是(2)和(20)之间的数,或者在完全或部分水解的 通式(II)的聚乙烯醇,其中R'表示烷基,芳基或具有1-12个碳原子的酰基,p和q是1至20之间的数字,或所述化合物在存在下的 促进氨分离以形成含有碳酸酯和氨基甲酸酯的混合物的催化剂,氨变得游离,或者通过带状气体从反应混合物中除去胺。 在第二反应步骤(酯交换)中,将含有碳酸酯和氨基甲酸酯的混合物与单体醇或苯酚反应,由此形成单体碳酸酯,并且将式(I)或(II)的聚合物多元醇重整。 <?in-line-formula description =“In-line Formulas”end =“lead”?> H OR OH(I)<?in-line-formula description =“In-line Formulas”end =“tail”?>
    • 3. 发明申请
    • Method for the production of organic carbonates
    • 生产有机碳酸酯的方法
    • US20070203322A1
    • 2007-08-30
    • US10571479
    • 2004-07-16
    • Honning BucholdJurgen EberhardtUlrich WagnerHans-Jorg Wolk
    • Honning BucholdJurgen EberhardtUlrich WagnerHans-Jorg Wolk
    • C08G64/00
    • C07C68/06C07C68/00C07C69/96
    • The invention relates to a method for the production of monomer organic carbonates from a mixture of organic carbonates and carbamates which are obtained by reacting urea, substituted urea, a salt or ester of carbamide acid or one of the N-substituted derivatives thereof with a polyalkylene glycol, polyester-polyol or a polyether-polyol of general formula (I), wherein R represents a linear or branched alkylene group having 2-12 carbon atoms and n represents a number between 2 and 20, or with a completely or partially hydrolysed polyvinyl alcohol of general formula (II), wherein R′ represents an alkyl group, an aryl group or an acyl group having 1-12 carbon atoms, p and q represent a number between 120, or with mixtures of said compounds in the presence of a catalyst facilitating the separation of ammonia and the ammonia becomes free or the amine is removed from the reaction mixture by means of a strip gas, whereby said mixture is reacted m with an alcohol or a phenol whereby monomer carbonates are formed and polymer polyalcohols of formulae (I) or (II) are reformed.
    • 本发明涉及一种由有机碳酸酯和氨基甲酸酯的混合物制备单体有机碳酸酯的方法,其通过使脲,取代的脲,脲酰胺酸的盐或酯或其N-取代的衍生物之一与聚亚烷基 乙二醇,聚酯多元醇或通式(I)的聚醚多元醇,其中R表示具有2-12个碳原子的直链或支链亚烷基,n表示2至20的数,或具有完全或部分水解的聚乙烯 通式(II)的醇,其中R'表示烷基,芳基或具有1-12个碳原子的酰基,p和q表示120之间的数,或与所述化合物在存在下的 促进氨分离的催化剂变得游离,或者通过带状气体从反应混合物中除去胺,由此所述混合物与醇或酚反应,由此单体ca 形成波长形成物,将式(I)或(II)的聚合物多元醇重整。