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    • 1. 发明申请
    • SILICONE-COMPATIBLE PHOTOINIATORS
    • 有机硅兼容光电器
    • US20150266907A1
    • 2015-09-24
    • US14729229
    • 2015-06-03
    • Henkel AG & Co. KGAAHenkel IP & Holding GMBH
    • Zhiming Pasing LiYong ZhangJinyou LiZhixiang LuZheng Lu
    • C07F7/18C07F7/02C08J3/28
    • C07F7/1804C07F5/02C07F7/025C07F7/0838C08G77/14C08G77/80C08J3/28C08J2343/04C08K5/5419
    • The present invention provides a compound represented by the following formula (I): wherein R1 and R2 each independently designates an alkyl group of 1 to 12 carbon atoms or a cycloalkyl group of 5 or 6 carbon atoms or R1 and R2 form together with the carbon atom to which they are attached a cycloaliphatic ring of 5 or 6 carbon atoms, Si* represents an organopolysiloxane residue bonded via a silicon atom of this residue to the oxygen shown in formula (I), or a silane group SiR4R5R6, wherein R4, R5 and R6 each independently designates an alkyl group of 1 to 12 carbon atoms, a cycloalkyl group of 5 or 6 carbon atoms or an aryl group of 6 to 10 carbon atoms, and R3 designates a hydrogen atom or a group represented by the following formula (II) wherein R7 and R8 each independently designates an alkyl group of 1 to 12 carbon atoms or a cycloalkyl group of 5 or 6 carbon atoms or R7 and R8 form together with the carbon atom to which they are attached a cycloaliphatic ring of 5 or 6 carbon atoms, and Si** represents an organopolysiloxane residue bonded via a silicon atom of this residue to the oxygen shown in formula (II), or a silane group SiR9R10R11, wherein R9, R10 and R11 each independently designates an alkyl group of 1 to 12 carbon atoms, a cycloalkyl group of 5 or 6 carbon atoms or an aryl group of 6 to 10 carbon atoms, a method to produce this compound and the use thereof as photoinitiator and/or photosensitizer.
    • 本发明提供由下式(I)表示的化合物:其中R 1和R 2各自独立地表示1至12个碳原子的烷基或5或6个碳原子的环烷基或R 1和R 2与碳形成 原子,它们连接有5或6个碳原子的脂环族环,Si *表示通过该残基的硅原子键合到式(I)所示的氧的有机聚硅氧烷残基或硅烷基SiR 4 R 5 R 6,其中R 4,R 5 R 6各自独立地表示碳原子数1〜12的烷基,碳原子数为5〜6的环烷基或碳原子数为6〜10的芳基,R 3表示氢原子或下述式 II)其中R 7和R 8各自独立地表示1至12个碳原子的烷基或5或6个碳原子的环烷基,或者R 7和R 8与它们所连接的碳原子一起形成5或6个脂环族环 碳阿托 ms,Si **表示通过该残基的硅原子与式(II)所示的氧键合的有机聚硅氧烷残基或硅烷基SiR 9 R 10 R 11,其中R 9,R 10和R 11各自独立地表示1〜12的烷基 碳原子数为5〜6的环烷基或碳原子数为6〜10的芳基,作为光引发剂和/或光敏剂的使用方法。