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1. 发明授权

US07108727B2 Reactive dyes and the use thereof for dyeing substrates containing nucleophilic groups 有权
标题翻译：活性染料及其用于染色含有亲核基团的底物的用途
公开(公告)号：US07108727B2
公开(公告)日：2006-09-19
申请号：US10469600
申请日：2002-03-05
申请人： Helmut Reichelt , Günther Seybold , Manfred Patsch , Gunter-Rudolf Schröder , Stevan David Jones , James Charles Dunbar , Colin John Clarke
发明人： Helmut Reichelt , Günther Seybold , Manfred Patsch , Gunter-Rudolf Schröder , Stevan David Jones , James Charles Dunbar , Colin John Clarke
IPC分类号： D06P1/38 , A61K7/13
CPC分类号： C09B62/503 , A61K8/418 , A61Q5/10
摘要： The present invention relates to novel reactive dyes of formula I, (I), in which the variable independently denote X hydrogen, NO2, or NR3R4, Y NR5R6, OR7, SR8, or SO2R9 or a group suitable as a leaving group under the conditions of nucleophilic, aromatic substitution, R1 to R9 independently hydrogen, C1–C8 alkyl, C2–C8 alkyl, in which non-adjacent CH2 groups can be replaced by oxygen atoms, imino groups, or C1–C4 alkylimino groups, and/or CH2 groups may be replaced by carbonyl groups, C2–C8 alkenyl, or a group containing an active site or the precursor of an active site, with the proviso that at least one group R1 to R9 is present which contains an active site or the precursor of an active site. The present invention also relates to the use of the reactivedyes of formula I for dyeing substrates containing nucleophilic groups, and to compositions containing at least one reactive dye of formula I.
摘要翻译：本发明涉及式I，（I）的新型活性染料，其中该变量独立地表示X氢，NO 2或NR 3 R 4 或者，其中，R 1，R 2，R 3，R 5，R 6，或者在亲核，芳香取代的条件下，适合作为离去基团的基团R 1至R 9，独立地为氢，C 1 -C 8烷基，C 2 -C 8烷基，其中不相邻 CH 2 2基团可以被氧原子，亚氨基或C 1 -C 4烷基亚氨基取代，和/或CH 2 - 2个基团可以被羰基，C 2 -C 8链烯基或含有活性位点或活性位点的前体的基团取代，与存在条件是存在至少一个R 1至R 9基团，其含有活性位点或活性位点的前体。本发明还涉及式I的反应物用于染色含有亲核基团的底物的用途，以及含有至少一种式I的活性染料的组合物的用途。

2. 发明授权

US06989036B2 Reactive dyes and use thereof for dyeing substrates containing nucleophilic groups 有权
标题翻译：活性染料及其用于染色含有亲核基团的底物的用途
公开(公告)号：US06989036B2
公开(公告)日：2006-01-24
申请号：US10473211
申请日：2002-04-24
申请人： Gunter-Rudolf Schröder , Helmut Reichelt , Günther Seybold , Manfred Patsch , Stevan David Jones , James Charles Dunbar , Colin John Clarke
发明人： Gunter-Rudolf Schröder , Helmut Reichelt , Günther Seybold , Manfred Patsch , Stevan David Jones , James Charles Dunbar , Colin John Clarke
IPC分类号： C09B62/44 , A61K7/13
CPC分类号： C09B62/014 , A61K8/418 , A61Q5/10 , C09B62/503
摘要： The present invention relates to novel reactive dyes of the formula (I) where R1 to R4 are independently hydrogen, C1–C8-alkyl, C2–C8-alkyl, wherein nonadjacent CH2 groups may be replaced by oxygen atoms or imino or C1–C4-alkylimino groups and/or CH2 groups by carbonyl groups, C2–C8-alkenyl, aryl, arylalkylene or a moiety containing a reactive group or the precursor of a reactive group, with the proviso that at least one of R1 to R4 is a moiety which contains a reactive group or the precursor of a reactive group. The present invention further relates to the use of the reactive dyes of the formula (I) for dyeing substrates containing nucleophilic groups and to preparations containing at least one reactive dye of the formula (I).
摘要翻译：本发明涉及式（I）的新型活性染料，其中R 1至R 4独立地是氢，C 1 -C 3烷基，亚烷基，C 2 -C 8 - 烷基，其中不相邻的CH 2基团可被氧原子取代或亚氨基或C 1 -C 4 - 亚烷基亚氨基和/或CH 2基团，通过羰基，C 2

3. 发明授权

US06989149B2 Delivery of reactive agents via self emulsification for use in shelf-stable products 失效
公开(公告)号：US06989149B2
公开(公告)日：2006-01-24
申请号：US09764561
申请日：2001-01-17
申请人： Robert Wayne Glenn, Jr. , James Charles Dunbar , Tharwat Tadros
发明人： Robert Wayne Glenn, Jr. , James Charles Dunbar , Tharwat Tadros
IPC分类号： A61K6/00 , A61K7/06
CPC分类号： A61K8/585 , A61K8/31 , A61K8/34 , A61K8/46 , A61K8/86 , A61K8/898 , A61K8/899 , A61Q5/12
摘要： Disclosed are treatment compositions comprising a liquid emulsifiable concentrate which comprises a chemically unstable reactive agent wherein the reactive agent is comprised of one or more reactive groups of the electrophilic, nucleophilic or protected thiol type, a water immiscible solvent, one or more surfactants, which is usable upon dilution within a separate aqueous composition to form a micro- or macro-emulsion in-situ immediately prior or simultaneous to application to the substrate and wherein the reactive agent is chemically shelf stable. Also disclosed are methods for treating amino acid based substrates, and methods for bleaching, coloring and conditioning hair with these treatment compositions.

4. 发明授权

US6080707A Crystalline hydroxy waxes as oil in water stabilizers for skin cleansing liquid composition 有权
标题翻译：结晶羟基蜡作为油中水稳定剂，用于皮肤清洁液体组成
公开(公告)号：US6080707A
公开(公告)日：2000-06-27
申请号：US221423
申请日：1998-12-28
申请人： Robert Wayne Glenn, Jr. , James Charles Dunbar , Mark Leslie Kacher , Fernando Ray Tollens , Raymond Edward Bolich, Jr. , Robert Raymond Schmidt , David John Weisgerber , Wayne Ellis Eccard , Mannie Lee Clapp , Christopher Dean Putman , Kevin Lee Hartzler , Anna Reavis Husk , Mary Elizabeth Carethers
发明人： Robert Wayne Glenn, Jr. , James Charles Dunbar , Mark Leslie Kacher , Fernando Ray Tollens , Raymond Edward Bolich, Jr. , Robert Raymond Schmidt , David John Weisgerber , Wayne Ellis Eccard , Mannie Lee Clapp , Christopher Dean Putman , Kevin Lee Hartzler , Anna Reavis Husk , Mary Elizabeth Carethers
IPC分类号： A61K8/31 , A61K8/37 , A61K8/60 , A61K8/81 , A61Q19/10 , C11D3/20 , A61K7/50
CPC分类号： A61K8/31 , A61K8/375 , A61K8/60 , A61K8/8111 , A61Q19/10
摘要： Disclosed is a stress stable lathering skin cleansing liquid composition comprising by weight parts of the liquid composition:(a) from about 0.5 parts to 10 parts of a crystalline, hydroxyl-containing stabilizer;(b) from about 1 part to about 80 parts of lipid skin moisturizing agent;(c) from about 1 part to about 30 parts of surfactant having a combined CMC equilibrium surface tension value of from 15 to 50;(d) water.Such stress stable lathering skin cleansing liquid compositions have a Lipid Deposition Value (LDV) of from about 5 to about 100. Such compositions are also stable for at least two weeks at 100.degree. F.
摘要翻译：公开了一种应力稳定起泡皮肤清洁液体组合物，其包含液体组合物的重量份：（a）约0.5份至10份结晶的含羟基的稳定剂; （b）约1份至约80份脂质皮肤保湿剂; （c）约1份至约30份具有组合CMC平衡表面张力值为15至50的表面活性剂; （d）水。这种应力稳定起泡的皮肤清洁液体组合物具有约5至约100的脂质沉积值（LDV）。该组合物在100°F下也稳定至少两周。

5. 发明授权

US5883059A Three in one ultra mild lathering antibacterial liquid personal cleansing composition 失效
标题翻译：三合一超轻柔起泡抗菌液体个人清洁组合物
公开(公告)号：US5883059A
公开(公告)日：1999-03-16
申请号：US720692
申请日：1996-10-02
申请人： Christopher Allen Furman , Michel Joseph Giret , James Charles Dunbar , Jon Joseph Damiano
发明人： Christopher Allen Furman , Michel Joseph Giret , James Charles Dunbar , Jon Joseph Damiano
IPC分类号： C11D1/16 , C11D1/88 , C11D3/48
CPC分类号： A61Q17/005 , A61K8/347 , A61K8/37 , A61K8/42 , A61K8/44 , A61K8/463 , A61K8/4946 , A61Q19/10 , A61K2800/596
摘要： A mild antibacterial liquid personal cleanser compositions. (More specifically, a mild, lathering compositions, especially those that are useful for application to the body, face and hands.) comprising:(a) from about 0.1 parts to about 20 parts, preferably 1 part to 15 parts, especially 3 to 12 parts by weight of anionic surfactant,(b) from about 0.1 parts to about 20 parts, preferably 1 part to 15 parts, especially 3 to 12 parts by weight of amphoteric surfactant,(c) from about 0.5 parts to about 25 parts, preferably 0.5 parts to 15 parts, especially 3 parts to about 10 parts by weight of an oily skin moisturizer, preferably an adduct prepared from vegetable oils containing non-conjugated polyunsaturated fatty acid esters which are conjugated and elaidinized and then modified via Diels-Alder addition with a member of the group consisting of acrylic acid, fumaric acid and maleic anhydride,(d) from about 0.1 parts to about 2.0 parts antibacterial agent, and(e) water,wherein the anionic surfactant and amphoteric surfactant together comprise from about 0.5 parts to about 30 parts, preferably 5 parts to 25 parts, especially 10 parts to 20 parts by weight of the composition, and where the weight ratio of anionic surfactant:amphoteric surfactant is in the range from about 1:5 to about 20:1, preferably 1:2 to about 5:1, especially 1:1 to about 2:1.
摘要翻译：温和的抗菌液体个人清洁剂组合物。（更具体地说，温和的起泡组合物，特别是可用于施用于身体，面部和手部的组合物）包括：（a）约0.1份至约20份，优选1份至15份，特别是3至 12重量份阴离子表面活性剂，（b）约0.1重量份至约20份，优选1份至15份，特别是3至12份重量的两性表面活性剂，（c）约0.5份至约25份，优选0.5份至15份，特别是3份至约10份重量的油性皮肤保湿剂，优选由含有非共轭多不饱和脂肪酸酯的植物油制备的加合物，所述非共轭多不饱和脂肪酸酯通过Diels-Alder添加具有由丙烯酸，富马酸和马来酸酐组成的组的组分，（d）约0.1份至约2.0份的抗菌剂和（e）水，其中阴离子表面活性剂和两性表面活性剂一起包括约0.5份至约30份，优选5份至25份，特别是10份至20份重量的组合物，其中阴离子表面活性剂：两性表面活性剂的重量比为约1:5至约 20：1，优选1：2至约5：1，特别是1：1至约2：1。

6. 发明申请

US20110195098A1 Porous, Dissolvable Solid Substrate and Surface Resident Coating Comprising Water Sensitive Actives 有权
标题翻译：多孔，可溶性固体基质和包含水敏感性活性剂的表面活性涂料
公开(公告)号：US20110195098A1
公开(公告)日：2011-08-11
申请号：US12962888
申请日：2010-12-08
申请人： Robert Wayne GLENN, JR. , Kathleen Mary Kaufman , James Charles Dunbar , John Michael Gardlik , Bryan Patrick Murphy
发明人： Robert Wayne GLENN, JR. , Kathleen Mary Kaufman , James Charles Dunbar , John Michael Gardlik , Bryan Patrick Murphy
IPC分类号： A61K8/02 , A61K8/81 , A61Q5/08 , A61Q5/02 , B05D7/00 , B05D7/24 , B05D3/00
CPC分类号： A61K8/02 , A61K8/0216 , A61K8/345 , A61K8/463 , A61K8/8129 , A61Q5/02 , A61Q5/08 , A61Q19/10
摘要： The present invention relates to personal care compositions, especially those personal care compositions in the form of a personal care article that is a porous dissolvable solid substrate. The porous dissolvable solid substrate has a surface resident coating comprising a water sensitive active that can deliver a consumer benefit.
摘要翻译：本发明涉及个人护理组合物，特别是作为多孔可溶性固体基质的个人护理制品形式的那些个人护理组合物。多孔可溶解固体基质具有包含能够提供消费者益处的水敏性活性物质的表面驻留涂层。

7. 发明授权

US06398821B1 Hair coloring compositions 失效
标题翻译：头发着色组合物
公开(公告)号：US06398821B1
公开(公告)日：2002-06-04
申请号：US09331683
申请日：1999-06-23
申请人： Louis Carlos Dias , James Charles Dunbar , Dominic Pratt
发明人： Louis Carlos Dias , James Charles Dunbar , Dominic Pratt
IPC分类号： A61K713
CPC分类号： A61K8/22 , A61K8/411 , A61K8/415 , A61K8/4926 , A61Q5/10
摘要： A hair coloring composition comprising: (a) an inorganic peroxygen oxidizing agent; and (b) an oxidative hair coloring agent; wherein the pH of each of components (a) and (b) is in the range of from about pH 1 to about pH 4.5 and wherein the pH of the composition is in the range of from about pH 1 to about pH 4.5. The products can provide excellent hair coloring and in-use efficacy benefits including excellent initial color and good wash fastness in combination with reduced hair damage at low pH.
摘要翻译：一种染发组合物，其包含：（a）无机过氧氧化剂; 和（b）氧化性着色剂; 其中组分（a）和（b）中的每一种的pH在约pH 1至约pH 4.5的范围内，并且其中组合物的pH在约pH 1至约pH 4.5的范围内。该产品可以提供优异的头发着色和使用功效，包括优异的初始颜色和良好的洗涤牢度，同时在低pH下减少毛发损伤。

8. 发明授权

US06309426B1 Hair coloring compositions 失效
标题翻译：头发着色组合物
公开(公告)号：US06309426B1
公开(公告)日：2001-10-30
申请号：US09331682
申请日：1999-06-23
申请人： Louis Carlos Dias , James Charles Dunbar , Dominic Pratt
发明人： Louis Carlos Dias , James Charles Dunbar , Dominic Pratt
IPC分类号： A61K713
CPC分类号： A61K8/22 , A61K8/347 , A61K8/411 , A61K8/415 , A61Q5/10
摘要： A hair coloring composition present in a single package suitable for direct application to the hair wherein the hair coloring mixture comprises: a) an oxidising agent; and b) an oxidative hair coloring agent; and wherein the combined mixture of a) and b) has a pH in the range of from about 1 to about 5 and wherein the resultant color delivered to the hair (Delta E), after at least about 1 month of storage at room temperature, is up to about 75%, preferably up to about 85%, more preferably up to about 90% and most preferably up to about 95% of the total color delivered to the hair (Delta E) from a mixture of a) and b) on application. The products are storage stable, re-usable and can provide both excellent hair coloring and in-use efficacy benefits as well as improved color development potential after storage at room temperature.
摘要翻译：存在于适合直接施用于毛发的单一包装中的染发组合物，其中染发混合物包含：a）氧化剂; 和b）氧化性着色剂; 并且其中a）和b）的组合的混合物具有在约1至约5范围内的pH，并且其中在室温下保存至少约1个月后，将所得颜色递送至毛发（ΔE）是从a）和b）的混合物递送至头发的总颜色（ΔE）的至多约75％，优选至多约85％，更优选至多约90％，最优选至多约95％在应用程序。该产品储存稳定，可重复使用，并可在室温下储存后提供优异的发色和使用效果，以及改善显色潜力。

9. 发明授权

US06277797B1 Dispersed amorphous silica as oil in water stabilizer for skin cleansing liquid composition 失效
标题翻译：分散的无定形二氧化硅作为油稳定剂，用于皮肤清洁液体组合物
公开(公告)号：US06277797B1
公开(公告)日：2001-08-21
申请号：US08756834
申请日：1996-11-26
申请人： Robert Wayne Glenn, Jr. , Mark Leslie Kacher , James Charles Dunbar
发明人： Robert Wayne Glenn, Jr. , Mark Leslie Kacher , James Charles Dunbar
IPC分类号： C11D1700
CPC分类号： A61K8/92 , A61K8/26 , A61Q19/10
摘要： The present invention relates to a stress stable lathering skin cleansing liquid composition comprising by weight parts of the liquid composition: (a) from about 0.5 parts to 10 parts dispersed amorphous silica of synthetic origin, i.e., fumed or precipitated; (b) from about 5 parts to about 30 parts of lipid skin moisturizing agent having a Vaughan Solubility Parameter (VSP) of between 5 and 10; wherein said lipid has a shear index, n, value at 35° C. in the range 0.1 to 0.5 and a consistency, k, value at 35° C. in the range 10 to 3,000 poise; (c) from about 5 part to about 30 parts of surfactant; (d) water; wherein said surfactant has a combined CMC equilibrium surface tension value of from 15 to 50; and wherein said stress stable lathering skin cleansing liquid composition has a Lipid Deposition Value (LDV) of from about 5 to about 1000; also wherein said lathering cleansing liquid preferably has a shear index, n, value at 35° C. in the range 0.20-0.005 and a consistency, k, value at 35° C. preferably in the range 300-550 poise; and wherein said composition is stable for at least two weeks at 100° F. (38° C.).
摘要翻译：本发明涉及一种应力稳定起泡皮肤清洁液体组合物，其包含液体组合物的重量份：（a）约0.5份至10份合成来源的分散无定形二氧化硅，即热解或沉淀;（b）约 5份至约30份具有5至10之间的Vaughan溶解度参数（VSP）的脂质皮肤保湿剂; 其中所述脂质在35℃下的剪切指数n值为0.1至0.5，在35℃下的稠度k值为10至3,000泊;（c）约5份至约30份表面活性剂;（d）水;其中所述表面活性剂具有组合的CMC平衡表面张力值为15至50; 并且其中所述应力稳定起泡皮肤清洁液体组合物具有约5至约1000的脂质沉积值（LDV）; 其中所述起泡清洁液体优选在35℃下的剪切指数n值为0.20-0.005，在35℃下的稠度k值优选在300-550泊的范围内; 并且其中所述组合物在100°F（38℃）下稳定至少两周。

10. 发明授权

US6080708A Crystalline hydroxy waxes as oil in water stabilizers for skin cleansing liquid composition 失效
标题翻译：结晶羟基蜡作为油中水稳定剂，用于皮肤清洁液体组成
公开(公告)号：US6080708A
公开(公告)日：2000-06-27
申请号：US247493
申请日：1999-02-10
申请人： Robert Wayne Glenn, Jr. , James Charles Dunbar , Mark Leslie Kacher , Fernando Ray Tollens , Raymond Edward Bolich, Jr. , Robert Raymond Schmidt , David John Weisgerber , Wayne Ellis Eccard , Mannie Lee Clapp , Christopher Dean Putman , Kevin Lee Hartzler , Anna Reavis Husk , Mary Elizabeth Carethers
发明人： Robert Wayne Glenn, Jr. , James Charles Dunbar , Mark Leslie Kacher , Fernando Ray Tollens , Raymond Edward Bolich, Jr. , Robert Raymond Schmidt , David John Weisgerber , Wayne Ellis Eccard , Mannie Lee Clapp , Christopher Dean Putman , Kevin Lee Hartzler , Anna Reavis Husk , Mary Elizabeth Carethers
IPC分类号： A61K8/31 , A61K8/37 , A61K8/60 , A61K8/81 , A61Q19/10 , C11D3/20 , A61K7/50
CPC分类号： A61K8/31 , A61K8/375 , A61K8/60 , A61K8/8111 , A61Q19/10
摘要： The present invention relates to a stress stable lathering skin cleansing liquid composition comprising by weight parts of the liquid composition:(a) from about 0.5 parts to 10 parts of a stabilizer; for example trihydroxystearin;(b) from about 1 part to about 80 parts of lipid skin moisturizing agent;(c) from about 1 part to about 30 parts of surfactant having a combined CMC equilibrium surface tension value of from 15 to 50;(d) water;wherein said stress stable lathering skin cleansing liquid composition has a Lipid Deposition Value (LDV) of from about 5 to about 100 and wherein said composition is stable for at least two weeks at 100 F.
摘要翻译：本发明涉及一种应力稳定起泡皮肤清洁液体组合物，其包含液体组合物的重量份：（a）约0.5份至10份稳定剂; 例如三羟基硬脂酸; （b）约1份至约80份脂质皮肤保湿剂; （c）约1份至约30份具有组合CMC平衡表面张力值为15至50的表面活性剂; （d）水; 其中所述应力稳定起泡皮肤清洁液体组合物具有约5至约100的脂质沉积值（LDV），并且其中所述组合物在100°F下稳定至少两周。

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