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    • 4. 发明授权
    • Preparation of lakes having improved performance characteristics
    • 制备具有改进性能特征的湖泊
    • US4664715A
    • 1987-05-12
    • US780317
    • 1985-09-26
    • Joachim Jesse
    • Joachim Jesse
    • C09B63/00C09B67/10C09B67/14C09B67/18C09B69/06C04B14/00
    • C09B69/06C09B67/0014C09B67/0017C09B67/002
    • Improved lakes based on basic dyes and heteropolyacids (PM, PTM, SM, PSTM and STM) are prepared by a process in which the lakes are heated to 50.degree.-100.degree. C. at pH 2-5 in the presence of (1) primary, secondary or tertiary aliphatic amines, (2) alkylamino-C.sub.2 -C.sub.8 -alkanoic acids, (3) diaryl- or triarylamines, (4) acidic or neutral phosphates based on fatty alcohols, their ethylene oxide or propylene oxide/ethylene oxide adducts, polypropylene glycol, polyethylene glycol, or propylene oxide/ethylene oxide block copolymers, (5) sulfuric acid half esters of fatty alcohols, of their ethylene oxide adducts or alkylphenol/ethylene oxide adducts, (6) C.sub.8 -C.sub.20 -alkanoic acids and alkenoic acids, alkylbenzenesulfonic acids, alkylnaphthalenesulfonic acids or dialkylsulfimides, (7) alkylphenol/ethylene oxide adducts, alkanol/ethylene oxide adducts or alkylamine/ethylene oxide adducts, (8) propylene glycols or propylene oxide/ethylene oxide block copolymers of alkanediols or -polyols or (9) naphthols or alkylphenols. The pigments obtained possess improved tinctorial properties and performance characteristics and are readily dispersible in printing inks. The prints exhibit high gloss and high transparency.
    • 通过一种方法制备基于碱性染料和杂多酸(PM,PTM,SM,PSTM和STM)的改进的湖泊,其中在(1)的存在下,将湖被加热至50℃-100℃, 伯,仲或叔脂族胺,(2)烷基氨基-C 2 -C 8 - 链烷酸,(3)二芳基或三芳基胺,(4)基于脂肪醇的酸性或中性磷酸酯,它们的环氧乙烷或环氧丙烷/环氧乙烷加成物 ,聚丙二醇,聚乙二醇或环氧丙烷/环氧乙烷嵌段共聚物,(5)脂肪醇的硫酸半酯,它们的环氧乙烷加成物或烷基酚/环氧乙烷加成物,(6)C8-C20-链烷酸和链烯 酸,烷基苯磺酸,烷基萘磺酸或二烷基亚硫酰亚胺,(7)烷基酚/环氧乙烷加合物,链烷醇/环氧乙烷加合物或烷基胺/环氧乙烷加合物,(8)链烷二醇或多元醇的丙二醇或环氧丙烷/环氧乙烷嵌段共聚物或 (9)萘酚 或烷基酚。 获得的颜料具有改善的着色性能和性能特征,并且易于分散在印刷油墨中。 印刷品具有高光泽度和高透明度。
    • 10. 发明授权
    • Process for the preparation of easily dispersible, high color strength,
powdered alkali blue pigments
    • 制备易分散,高颜色强度的粉状碱性蓝色颜料的方法
    • US4456485A
    • 1984-06-26
    • US466759
    • 1983-02-15
    • Doreswamy R. IyengarJoachim Jesse
    • Doreswamy R. IyengarJoachim Jesse
    • C09B67/08C09B67/18C09B67/20C09B48/00
    • C09B67/002
    • Easily dispersible alkali blue pigments with high color strength are obtained if the pigment is precipitated in the presence of (1) primary, secondary or tertiary aliphatic amines, (2) N-alkylamino alkanic acid, (3) a diaryl or triarylamine, (4) an acid or neutral aliphatic ester of phosphoric acid, (5) a half ester of sulfuric acid based on fatty alcohol, fatty alcohol-EO adducts or alkyl phenol-EO adducts, (6) an alkane or alkene sulfonic acid on a dialkylsulfimide, (7) EO adducts based on alkylphenols, alkanols or alkylamines, (8) polypropylene glycol or PO/EO block copolymers based on alkane diols or alkane polyols or in the presence of mixtures of these compounds or is mixed with at least one of the substances listed under (1) to (8) after the precipitation with acid in the acid suspension and is isolated.Alkali blue pigments are obtained which are easily dispersible in offset printing ink varnishes and which result in excellent color strength of the printed matter.
    • 在(1)伯,仲或叔脂族胺,(2)N-烷基氨基链烷酸,(3)二芳基或三芳基胺(4)的存在下,颜料沉淀,得到具有高着色强度的易分散碱性蓝色颜料 )磷酸的酸或中性脂肪酸酯,(5)基于脂肪醇的硫酸的半酯,脂肪醇-E0加合物或烷基酚-EA加成物,(6)二烷基亚硫酰亚胺上的烷烃或烯烃磺酸, (7)基于烷基酚,链烷醇或烷基胺的EO加合物,(8)基于烷烃二醇或烷烃多元醇的聚丙二醇或PO / EO嵌段共聚物,或在这些化合物的混合物存在下或与至少一种物质 在酸性悬浮液中用酸沉淀后分离(1)至(8)所述的化合物。 得到碱性蓝色颜料,其易于分散在胶版印刷油墨清漆中,并且导致印刷品的优异的着色强度。