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1. 发明授权

US08043707B2 Highly heat-resistant low-emissivity multilayer system for transparent substrates 失效
标题翻译：用于透明基板的高耐热低发射多层系统
公开(公告)号：US08043707B2
公开(公告)日：2011-10-25
申请号：US12295090
申请日：2007-03-28
申请人： Heinz Schicht , Uwe Schmidt , Pierre-Alain Gillet
发明人： Heinz Schicht , Uwe Schmidt , Pierre-Alain Gillet
IPC分类号： B32B17/06
CPC分类号： C03C17/36 , C03C17/3626 , C03C17/3652 , C03C17/366 , C03C2217/73 , C03C2218/154 , C23C14/06 , C23C14/086 , Y10T428/265 , Y10T428/31601
摘要： A low-emissivity multilayer system highly resistant to heat treatment for transparent substrates, in particular for window panes comprises, starting from the substrate, at least a lower antireflection coating consisting of several partial layers and including a layer essentially consisting of ZnO which is adjacent with a silver-based functional layer, an essentially metallic blocking layer located on top of the silver-based layer, an upper antireflection coating consisting of several partial layers and a cover coating optionally consisting of several partial layers. The upper antireflection coating has: a partial layer of ZnO or a mixed oxide ZnMeOx that contains ZnO or a succession of layers of mixed oxides of the ZnO:Al/ZnMeOx type; a partial layer of Si3N4 or SixOyNz; and between these two partial layers, a separating layer with a thickness of 0.5 to 5 nm, consisting of a metal oxide or a mixed oxide with a cubic crystal lattice, which prevents direct contact between these two partial layers. Coated window panes that are highly resistant to technical handling operations comprising an inserted separating layer that makes it possible to further improve the mechanical and chemical properties of the multilayer system.
摘要翻译：对于透明基板，特别是用于窗玻璃的耐热处理的低发射率多层系统包括从基板开始的至少一个由几个部分层组成的下部抗反射涂层，并且包括基本上由ZnO组成的层银基功能层，位于银基层顶部的基本上金属的阻挡层，由几个部分层组成的上部抗反射涂层和可选地由几个部分层组成的覆盖涂层。上部抗反射涂层具有：ZnO的一部分层或含有ZnO的混合氧化物ZnMeO x或ZnO：Al / ZnMeOx类型的一系列混合氧化物层; Si3N4或SixOyNz的部分层; 并且在这两个部分层之间，由金属氧化物或具有立方晶格的混合氧化物组成的厚度为0.5至5nm的分离层，其防止这两个部分层之间的直接接触。涂覆的窗玻璃对技术处理操作具有高度的抵抗性，包括插入的分离层，其使得可以进一步提高多层体系的机械和化学性质。

2. 发明申请

US20100178492A1 HIGHLY HEAT-RESISTANT LOW-EMISSIVITY MULTILAYER SYSTEM FOR TRANSPARENT SUBSTRATES 失效
标题翻译：用于透明基板的高耐热低电平多层系统
公开(公告)号：US20100178492A1
公开(公告)日：2010-07-15
申请号：US12295090
申请日：2007-03-28
申请人： Heinz Schicht , Uwe Schmidt , Pierre-Alain Gillet
发明人： Heinz Schicht , Uwe Schmidt , Pierre-Alain Gillet
IPC分类号： B32B5/00
CPC分类号： C03C17/36 , C03C17/3626 , C03C17/3652 , C03C17/366 , C03C2217/73 , C03C2218/154 , C23C14/06 , C23C14/086 , Y10T428/265 , Y10T428/31601
摘要： A low-emissivity multilayer system highly resistant to heat treatment for transparent substrates, in particular for window panes comprises, starting from the substrate, at least a lower antireflection coating consisting of several partial layers and including a layer essentially consisting of ZnO which is adjacent with a silver-based functional layer, an essentially metallic blocking layer located on top of the silver-based layer, an upper antireflection coating consisting of several partial layers and a cover coating optionally consisting of several partial layers. The upper antireflection coating has: a partial layer of ZnO or a mixed oxide ZnMeOx that contains ZnO or a succession of layers of mixed oxides of the ZnO:Al/ZnMeOx type; a partial layer of Si3N4 or SixOyNz; and between these two partial layers, a separating layer with a thickness of 0.5 to 5 nm, consisting of a metal oxide or a mixed oxide with a cubic crystal lattice, which prevents direct contact between these two partial layers. According to the invention, the inserted separating layer makes it possible to further improve the mechanical and chemical properties of the multilayer system and to obtain coated window panes that are highly resistant to technical handling operations.
摘要翻译：对于透明基板，特别是用于窗玻璃的耐热处理的低发射率多层系统包括从基板开始的至少一个由几个部分层组成的下部抗反射涂层，并且包括基本上由ZnO组成的层银基功能层，位于银基层顶部的基本上金属的阻挡层，由几个部分层组成的上部抗反射涂层和可选地由几个部分层组成的覆盖涂层。上部抗反射涂层具有：ZnO的一部分层或含有ZnO或ZnO：Al / ZnMeOx类型的一系列混合氧化物层的混合氧化物ZnMeO x; Si3N4或SixOyNz的部分层; 并且在这两个部分层之间，由金属氧化物或具有立方晶格的混合氧化物组成的厚度为0.5至5nm的分离层，其防止这两个部分层之间的直接接触。根据本发明，插入的分离层使得可以进一步提高多层体系的机械和化学性质，并获得对技术处理操作具有高度抵抗力的涂层窗玻璃。

3. 发明授权

US5240646A Electrochromic materials 失效
标题翻译：电化学材料
公开(公告)号：US5240646A
公开(公告)日：1993-08-31
申请号：US712680
申请日：1991-06-10
申请人： Pierre-Alain Gillet , Jean-Louis Fourquet , Odile Bohnke
发明人： Pierre-Alain Gillet , Jean-Louis Fourquet , Odile Bohnke
IPC分类号： C09K9/00 , G02F1/15
CPC分类号： C09K9/00 , G02F1/1523
摘要： The invention relates to novel electrochromic materials useful as electrochromic electrodes in eletrochromic cells and to their preparation process. These materials are constituted by at least one transition metal oxyhydroxide chosen from among H.sub.2 Ti.sub.3 O.sub.7 and HNbWO.sub.6, H.sub.2 O or by a thin film obtained by vacuum evaporation of at least one of these oxyhydroxides.
摘要翻译：本发明涉及用作电致变色电池中的电致变色电极的新型电致变色材料及其制备方法。这些材料由选自H 2 Ti 3 O 7和HNbWO 6，H 2 O中的至少一种过渡金属氢氧化物或通过真空蒸发这些羟基氧化物中的至少一种而获得的薄膜构成。

4. 发明申请

US20090197077A1 SUBSTRATE COMPRISING A STACK HAVING THERMAL PROPERTIES 有权
标题翻译：包括具有热性能的堆叠的基板
公开(公告)号：US20090197077A1
公开(公告)日：2009-08-06
申请号：US12281480
申请日：2007-03-06
申请人： Pascal Reutler , Eric Petitjean , Eric Mattmann , Pierre-Alain Gillet
发明人： Pascal Reutler , Eric Petitjean , Eric Mattmann , Pierre-Alain Gillet
IPC分类号： B32B17/06 , C23C14/35 , C23C14/34
CPC分类号： B32B17/10174 , B32B17/10229 , C03C17/36 , C03C17/3618 , C03C17/3626 , C03C17/3644 , C03C17/3652 , C03C17/366 , Y10T428/265
摘要： The invention relates to a substrate (10), especially a transparent glass substrate, provided with a thin-film multilayer comprising a functional layer (40) having reflection properties in the infrared and/or in solar radiation, especially a metallic functional layer based on silver or on a metal alloy containing silver, and two coatings (20, 60), said coatings being composed of a plurality of dielectric layers (24, 26; 64), so that the functional layer (40) is placed between the two coatings (20, 60), the functional layer (40) being deposited on a wetting layer (30) itself deposited directly onto a subjacent coating (20), characterized in that the subjacent coating (20) comprises at least one dielectric layer (24) based on nitride, especially on silicon nitride and/or aluminum nitride, and at least one noncrystalline smoothing layer (26) made from a mixed oxide, said smoothing layer (26) being in contact with said superjacent wetting layer (30).
摘要翻译：本发明涉及一种设置有薄膜多层的基片（10），特别是透明玻璃基片，该薄膜多层包括在红外和/或太阳辐射中具有反射特性的功能层（40），特别是基于银或含有银的金属合金和两个涂层（20,60），所述涂层由多个电介质层（24,26; 64）组成，使得功能层（40）位于两个涂层（20,60），所述功能层（40）沉积在其本身直接沉积在下层涂层（20）上的润湿层（30）上，其特征在于，所述下层涂层（20）包括至少一个介电层（24）基于氮化物，特别是氮化硅和/或氮化铝，以及由混合氧化物制成的至少一个非结晶平滑层（26），所述平滑层（26）与所述上层润湿层（30）接触。

5. 发明授权

US09919497B2 Substrate comprising a stack having thermal properties 有权
公开(公告)号：US09919497B2
公开(公告)日：2018-03-20
申请号：US12281480
申请日：2007-03-06
申请人： Pascal Reutler , Eric Petitjean , Eric Mattmann , Pierre-Alain Gillet
发明人： Pascal Reutler , Eric Petitjean , Eric Mattmann , Pierre-Alain Gillet
IPC分类号： B32B17/00 , C03C17/36 , B32B17/10
CPC分类号： B32B17/10174 , B32B17/10229 , C03C17/36 , C03C17/3618 , C03C17/3626 , C03C17/3644 , C03C17/3652 , C03C17/366 , Y10T428/265
摘要： The invention relates to a substrate (10), especially a transparent glass substrate, provided with a thin-film multilayer comprising a functional layer (40) having reflection properties in the infrared and/or in solar radiation, especially a metallic functional layer based on silver or on a metal alloy containing silver, and two coatings (20, 60), said coatings being composed of a plurality of dielectric layers (24, 26; 64), so that the functional layer (40) is placed between the two coatings (20, 60), the functional layer (40) being deposited on a wetting layer (30) itself deposited directly onto a subjacent coating (20), characterized in that the subjacent coating (20) comprises at least one dielectric layer (24) based on nitride, especially on silicon nitride and/or aluminum nitride, and at least one noncrystalline smoothing layer (26) made from a mixed oxide, said smoothing layer (26) being in contact with said superjacent wetting layer (30).

6. 发明申请

US20120164443A1 MATERIAL AND GLAZING COMPRISING SAID MATERIAL 有权
标题翻译：材料和玻璃包装材料
公开(公告)号：US20120164443A1
公开(公告)日：2012-06-28
申请号：US13394249
申请日：2010-09-07
申请人： Anne Durandeau , Andriy Kharchenko , Bruno Mauvernay , Emilie Thollas , Etienne Sandre-Chardonnal , Pierre-Alain Gillet , Ulrich Billert
发明人： Anne Durandeau , Andriy Kharchenko , Bruno Mauvernay , Emilie Thollas , Etienne Sandre-Chardonnal , Pierre-Alain Gillet , Ulrich Billert
IPC分类号： B32B3/00 , C03C17/34 , C23C16/44 , C23C16/56 , B32B17/06 , C23C14/35
CPC分类号： C03C17/3435 , C03C17/36 , C03C17/3618 , C03C17/3626 , C03C17/3649 , C03C17/3652 , C03C17/366 , C03C17/3681 , C03C2217/71 , Y10T428/265
摘要： The subject of the invention is a material comprising a glass substrate coated on at least one of its faces with a thin-film multilayer comprising, starting from said substrate, at least one lower dielectric layer, at least one functional layer made of a metal or metal nitride, at least one upper dielectric layer and at least one layer of titanium oxide at least partially crystallized in the anatase form, said metal or metal nitride being based on Nb, NbN, W, WN, Ta, TaN or any of their alloys or solid solutions.
摘要翻译：本发明的主题是包括在其至少一个表面上涂覆有玻璃基板的材料，其中薄膜多层包括从所述基底开始的至少一个下介电层，至少一个由金属制成的功能层或金属氮化物，至少一个上介电层和至少一层氧化钛，其以锐钛矿形式至少部分结晶，所述金属或金属氮化物基于Nb，NbN，W，WN，Ta，TaN或它们的任何合金或固体溶液。

7. 发明申请

US20100020381A1 FUNCTIONALIZED GLAZING 有权
标题翻译：功能化玻璃
公开(公告)号：US20100020381A1
公开(公告)日：2010-01-28
申请号：US12519182
申请日：2007-12-06
申请人： Vincent Legois , Pierre Chaussade , Jean-Christophe Giron , Pierre-Alain Gillet
发明人： Vincent Legois , Pierre Chaussade , Jean-Christophe Giron , Pierre-Alain Gillet
IPC分类号： G02F1/153 , B32B17/06 , G02F1/01 , G02F1/1333
CPC分类号： B32B17/10045 , B32B17/10174 , B32B17/10293 , B32B17/10302 , B32B17/10495 , B32B17/1077 , B32B2605/18 , B64C1/1492 , H05B3/86 , H05B2203/013
摘要： Glazing comprising, in succession: a first rigid substrate (S1); a second rigid substrate (S2); a third rigid substrate (S3); at least one “active” system (A) that includes at least one layer and is placed between the substrates (S1 and S2), the first substrate (S1) optionally being set back in relation to the other two substrates (S2, S3); and at least one polymer film having the function of retaining glazing fragments should the glazing break, said film being placed between the substrate (S1) and the substrate (S2) and between the substrate (S2) and the substrate (S3).
摘要翻译：连续地包括：第一刚性基板（S1）; 第二刚性基板（S2）; 第三刚性基板（S3）; 至少一个“主动”系统（A），其包括至少一个层并且被放置在基板（S1和S2）之间，第一基板（S1）可选地相对于其它两个基板（S2，S3）回退， ; 并且具有保留玻璃碎片功能的至少一种聚合物膜应该是玻璃破裂，所述膜被放置在基底（S1）和基底（S2）之间以及基底（S2）和基底（S3）之间。

8. 发明授权

US09102565B2 Material and glazing comprising said material 有权
标题翻译：包括所述材料的材料和玻璃
公开(公告)号：US09102565B2
公开(公告)日：2015-08-11
申请号：US13394249
申请日：2010-09-07
申请人： Anne Durandeau , Andriy Kharchenko , Bruno Mauvernay , Emilie Thollas , Etienne Sandre-Chardonnal , Pierre-Alain Gillet , Ulrich Billert
发明人： Anne Durandeau , Andriy Kharchenko , Bruno Mauvernay , Emilie Thollas , Etienne Sandre-Chardonnal , Pierre-Alain Gillet , Ulrich Billert
IPC分类号： B32B15/04 , B32B17/06 , C03C17/34 , C03C17/36
CPC分类号： C03C17/3435 , C03C17/36 , C03C17/3618 , C03C17/3626 , C03C17/3649 , C03C17/3652 , C03C17/366 , C03C17/3681 , C03C2217/71 , Y10T428/265
摘要： The subject of the invention is a material comprising a glass substrate coated on at least one of its faces with a thin-film multilayer comprising, starting from said substrate, at least one lower dielectric layer, at least one functional layer made of a metal or metal nitride, at least one upper dielectric layer and at least one layer of titanium oxide at least partially crystallized in the anatase form, said metal or metal nitride being based on Nb, NbN, W, WN, Ta, TaN or any of their alloys or solid solutions.
摘要翻译：本发明的主题是一种材料，其包括涂覆在其至少一个表面上的玻璃基板，薄膜多层包括从所述基板开始的至少一个下介电层，至少一个由金属制成的功能层或金属氮化物，至少一个上介电层和至少一层氧化钛，其以锐钛矿形式至少部分结晶，所述金属或金属氮化物基于Nb，NbN，W，WN，Ta，TaN或它们的任何合金或固体溶液。

9. 发明授权

US07929194B2 Functionalized glazing 有权
标题翻译：功能化玻璃
公开(公告)号：US07929194B2
公开(公告)日：2011-04-19
申请号：US12519182
申请日：2007-12-06
申请人： Vincent Legois , Pierre Chaussade , Jean-Christophe Giron , Pierre-Alain Gillet
发明人： Vincent Legois , Pierre Chaussade , Jean-Christophe Giron , Pierre-Alain Gillet
IPC分类号： G02F1/153 , G02F1/03
CPC分类号： B32B17/10045 , B32B17/10174 , B32B17/10293 , B32B17/10302 , B32B17/10495 , B32B17/1077 , B32B2605/18 , B64C1/1492 , H05B3/86 , H05B2203/013
摘要： Glazing comprising, in succession: a first rigid substrate (S1); a second rigid substrate (S2); a third rigid substrate (S3); at least one “active” system (A) that includes at least one layer and is placed between the substrates (S1 and S2), the first substrate (S1) optionally being set back in relation to the other two substrates (S2, S3); and at least one polymer film having the function of retaining glazing fragments should the glazing break, said film being placed between the substrate (S1) and the substrate (S2) and between the substrate (S2) and the substrate (S3).
摘要翻译：连续地包括：第一刚性基板（S1）; 第二刚性基板（S2）; 第三刚性基板（S3）; 至少一个“主动”系统（A），其包括至少一个层并且被放置在基板（S1和S2）之间，第一基板（S1）可选地相对于其它两个基板（S2，S3）回退， ; 并且具有保留玻璃碎片功能的至少一种聚合物膜应该是玻璃破裂，所述膜被放置在基板（S1）和基板（S2）之间以及基板（S2）和基板（S3）之间。

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