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1. 发明授权

US5200306A Color photographic recording material containing a coupler which releases a photographically active compound 失效
标题翻译：含有释放摄影活性化合物的成色剂的彩色照相记录材料
公开(公告)号：US5200306A
公开(公告)日：1993-04-06
申请号：US674419
申请日：1991-03-22
申请人： Heinrich Odenwalder , Hans Vetter , Peter Bergthaller , Dirk Hubner
发明人： Heinrich Odenwalder , Hans Vetter , Peter Bergthaller , Dirk Hubner
IPC分类号： C07D249/04 , G03C7/305
CPC分类号： C07D249/04 , G03C7/30558 , Y10S430/156 , Y10S430/158
摘要： Couplers corresponding to formula I below used in multilayer color photographic recording materials are suitable for the release of photographically active compounds. ##STR1## In formula I above, A represents the residue of a coupler which, as a consequence of a reaction with the oxidation product of a silver halide developer under the photographic development conditions, releases a radical corresponding to the following formula ##STR2## Time represents a bond which, on reaction of the coupler with the oxidation product of a silver halide developer, is released together with the triazole ring attached thereto and, in turn, releases the triazole ring with delay under the development conditions;n=0, 1 or 2;R.sup.1 and R.sup.2 represent any substituents, provided the compound of formula II ##STR3## as a whole is a photographically active compound after release.
摘要翻译：在多层彩色照相记录材料中使用的对应于下式I的成色剂适于释放摄影活性化合物。在上述式I中，A表示成色剂的残留物，其作为与照相显影条件下的卤化银显影剂的氧化产物反应的结果，其释放相应于下式的图像。时间表示在偶合剂与卤化银显影剂的氧化产物的反应下与连接在其上的三唑环一起释放并随后在显影条件下延迟释放三唑环的键。 n = 0,1或2; R1和R2表示任何取代基，条件是式II化合物（II）作为整体是释放后的照相活性化合物。

2. 发明授权

US5021331A Color photographic recording material containing a DIR coupler 失效
标题翻译：含有DIR耦合器的彩色照相记录材料
公开(公告)号：US5021331A
公开(公告)日：1991-06-04
申请号：US528043
申请日：1990-05-23
申请人： Hans Vetter , Heinrich Odenwalder , Peter Bergthaller , Thomas Kruger
发明人： Hans Vetter , Heinrich Odenwalder , Peter Bergthaller , Thomas Kruger
IPC分类号： G03C7/305 , G03C7/32
CPC分类号： G03C7/305 , Y10S430/158
摘要： Highly active silver halide development inhibitors are released from DIR couplers corresponding to formula I during color development. Where DIR couplers are used in color photographic silver halide materials, high edge effects and high inter-image effects are obtained.A--(TIME).sub.n --Z IIn formula I,A is the residue of a coupler which couples with the oxidation product of a silver halide developing agent under the conditions of photographic development and, in doing so, releases a group corresponding to the following formula--(TIME).sub.n --ZTIME is a binding link which together with the group Z (a triazole ring) attached thereto is releases on reaction of the coupler with the oxidation product of a silver halide developing agent and which, in turn, releases the group Z with delay under the development conditions;n is 0 or 1;Z is a triazole ring corresponding to one of the following formulae ##STR1## R.sup.1 is alkylthio; R.sup.2 is H, alkyl, alkythio, aryl or a heterocyclic group; at least one of the substituents R.sup.1 and R.sup.2 contains at a distance of 2 to 4 atoms from the triazole ring a group --CO--OR.sup.3, --O--CO--OR.sup.3 or --O--CO--R.sup.3 hydrolyzable in aqueous alkali;R.sup.3 is alkyl, cycloalkyl or aryl.
摘要翻译：在显影期间，高活性卤化银显影抑制剂从对应于式I的DIR成色剂中释放出来。在彩色照相卤化银材料中使用DIR成色剂时，可获得高边缘效果和高图像效果。 A-（TIME）n-Z在式I中，A是在照相显影的条件下与卤化银显影剂的氧化产物偶联的成色剂的残基，并且在这样做时，释放相应于下列物质的基团式 - （TIME）nZ TIME是与连接到其上的组Z（三唑环）一起的结合链接，其与成色剂与卤化银显影剂的氧化产物反应释放，并且反过来释放基团 Z在发展条件下有延误; n为0或1; Z是对应于下式之一的三唑环：R 1是烷硫基; R2是H，烷基，链烯基，芳基或杂环基; 取代基R 1和R 2中的至少一个与三唑环在含水碱中可水解的基团-CO-OR3，-O-CO-OR3或-O-CO-R3的距离为2至4个原子; R3是烷基，环烷基或芳基。

3. 发明授权

US5021332A Color photographic recording material containing a DIR coupler 失效
标题翻译：含有DIR耦合器的彩色照相记录材料
公开(公告)号：US5021332A
公开(公告)日：1991-06-04
申请号：US528045
申请日：1990-05-23
申请人： Peter Bergthaller , Thomas Kruger , Hans Vetter , Heinrich Odenwalder
发明人： Peter Bergthaller , Thomas Kruger , Hans Vetter , Heinrich Odenwalder
IPC分类号： G03C7/26 , C07D403/06 , G03C7/305 , G03C7/32 , G03C7/392
CPC分类号： C07D403/06 , G03C7/30535 , Y10S430/158
摘要： Good edge effects and inter-image effects are obtained where DIR couplers corresponding to formula I are used in color photogrpahic silver halide materials. ##STR1## in which R.sup.1 is H, Cl, --CF.sub.3, alkoxy, sulfamoyl;R.sup.2 is H, Cl, alkyl, cycloalkyl, alkoxy, alkoxycarbonyl, carbamoyl;n is 0, 1 or 2;X is O or S;Y is a group with a silver halide development inhibiting function releasable during color development;Z is benzoyl, pivaloyl, carbamoyl or a quinazolin-4-on-2-yl group.
摘要翻译：获得良好的边缘效果和图像间效果，其中对应于式I的DIR成色剂用于彩色光致卤化银材料。（I）其中R1是H，Cl，-CF3，烷氧基，氨磺酰基; R2是H，Cl，烷基，环烷基，烷氧基，烷氧基羰基，氨基甲酰基; n为0,1或2; X是O或S; Y是具有在显色期间可释放的卤化银显影抑制功能的组; Z是苯甲酰基，新戊酰基，氨基甲酰基或喹唑啉-4-基-2-基。

4. 发明授权

US4897341A Color photographic recording material containing a dir-coupler 失效
标题翻译：含有双向耦合器的彩色照相记录材料
公开(公告)号：US4897341A
公开(公告)日：1990-01-30
申请号：US109762
申请日：1987-10-19
申请人： Heinrich Odenwalder , Hans Ohlschlager , Friedrich-Wilhelm Kunitz , Dirk Hubner
发明人： Heinrich Odenwalder , Hans Ohlschlager , Friedrich-Wilhelm Kunitz , Dirk Hubner
IPC分类号： G03C7/36 , G03C7/305
CPC分类号： G03C7/30535
摘要： Remarkably high inter-image and edge effects are obtained when DIR-Couplers corresponding to Formula I are added to multilayered color photographic recording materials, in particular to green sensitive or red sensitive layers. The sharpness and color reproduction may thereby be improved. ##STR1## R.sup.1 and R.sup.2 denote alkyl or an aromatic group, R.sup.3 denotes H, alkyl or acylamino,R.sup.4 denotes H or alkylR.sup.5 denotes alkyl, alkinyl, aryl, acyloxy, carbamoyl or a cyclic imido group andn has the value 0 or 1and the total number of carbon atoms in R.sup.3, R.sup.4 and R.sup.5 is greater than 3 but not greater than 11.
摘要翻译：当将对应于式I的DIR耦合器添加到多层彩色照相记录材料，特别是绿色敏感层或红色敏感层时，可获得非常高的图像间和边缘效应。从而可以提高清晰度和色彩再现。 R1和R2表示烷基或芳基，R3表示H，烷基或酰氨基，R4表示H或烷基R5表示烷基，炔基，芳基，酰氧基，氨基甲酰基或环状酰亚胺基，n的数值为0或 1，R3，R4和R5中的碳原子总数大于3但不大于11。

5. 发明授权

US4840880A Color photographic recording material containing a yellow DIR coupler 失效
标题翻译：含有黄色DIR耦合器的彩色照相材料
公开(公告)号：US4840880A
公开(公告)日：1989-06-20
申请号：US75574
申请日：1987-07-20
申请人： Hans Ohlschlager , Gunter Renner , Friedrich-Wilhelm Kunitz , Heinrich Odenwalder , Dirk Hubner
发明人： Hans Ohlschlager , Gunter Renner , Friedrich-Wilhelm Kunitz , Heinrich Odenwalder , Dirk Hubner
IPC分类号： G03C7/26 , C07D249/12 , G03C7/305 , G03C7/36
CPC分类号： G03C7/30535 , C07D249/12
摘要： High interimage effects and edge effects can be obtained in multilayer color photographic recording materials if yellow DIR couplers of formula I are used therein, particularly if used in green sensitized or red sensitized layers. Sharpness and color reproduction are substantially improved. ##STR1## wherein R.sup.1 denotes a straight chained or branched alkyl group with up to 18 carbon atoms;R.sup.2, R.sup.3 denote identical or different alkyl groups with up to 18 carbon atoms;R.sup.4 denotes H, halogen, alkyl with up to 6 carbon atoms or alkoxy with up to 6 carbon atoms;R.sup.5 denotes H or alkyl with up to 9 carbon atoms; andR.sup.6 denotes a saturated or unsaturated aliphatic group with up to 10 carbon atoms,the total number of carbon atoms in R.sup.5 and R.sup.6 being not less than 5 and not greater than 10.
摘要翻译：如果在其中使用式I的黄色DIR成色剂，特别是如果用于绿色敏化或红色敏化层，则可以在多层彩色照相记录材料中获得高的图像效果和边缘效果。显着提高了清晰度和色彩再现性。（I）其中R 1表示具有至多18个碳原子的直链或支链烷基; R2，R3表示具有至多18个碳原子的相同或不同的烷基; R 4表示H，卤素，具有至多6个碳原子的烷基或具有至多6个碳原子的烷氧基; R5表示H或最多9个碳原子的烷基; R6表示具有至多10个碳原子的饱和或不饱和脂族基团，R5和R6中碳原子总数不小于5且不大于10。

6. 发明授权

US4833070A Color photographic recording material containing a yellow DIR coupler 失效
标题翻译：含有黄色DIR耦合器的彩色照相材料
公开(公告)号：US4833070A
公开(公告)日：1989-05-23
申请号：US90457
申请日：1987-08-28
申请人： Friedrich-Wilhelm Kunitz , Hans hlschlager , Heinrich Odenwalder , Dirk Hubner
发明人： Friedrich-Wilhelm Kunitz , Hans hlschlager , Heinrich Odenwalder , Dirk Hubner
IPC分类号： G03C7/36 , C07D249/12 , G03C7/305
CPC分类号： G03C7/30535
摘要： Remarkably high interimage and Eberhard effects are obtained when yellow DIR couplers corresponding to formuls I are added to multilayered color photographic recording materials, in particular to the green-sensitive or red-sensitive layers. These couplers can improve the sharpness and color reproduction. ##STR1## R.sup.1 denoted alkyl or aryl, R.sup.2 denotes alkyl with up to 18 carbon atoms,R.sup.3 denotes halogen, SO.sub.2 --R.sup.6, SO.sub.2 --NR.sup.7 --R.sup.8 or NH--SO.sub.2 --R.sup.6,R.sup.4 denoted H, alkyl or aryl.R.sup.5 denotes alkyl, cycloalkyl, alkinyl, aralkyl or aryl,R.sup.6 denotes alkyl or aryl,R.sup.7 denotes H or alkyl andR.sup.8 denoted H, alkyl, aryl, CO--R.sup.6 or ##STR2## and the total number of carbon atoms in R.sup.4 and R.sup.5 is not greater than 11.
摘要翻译：当将对应于形态1的黄色DIR成色剂添加到多层彩色照相记录材料中，特别是绿色敏感层或红色敏感层时，可以获得极高的图像和Eberhard效果。这些耦合器可以提高清晰度和色彩再现性。 R1表示烷基或芳基，R2表示具有至多18个碳原子的烷基，R3表示卤素，SO2-R6，SO2-NR7-R8或NH-SO2-R6，R4表示H，烷基或芳基。 R5表示烷基，环烷基，炔基，芳烷基或芳基，R6表示烷基或芳基，R7表示H或烷基，R8表示H，烷基，芳基，CO-R6或，R4和R5中的碳原子总数不大于11。

7. 发明授权

US4546073A Photographic recording material containing a precursor of a photographically-active compound 失效
标题翻译：含有摄影活性化合物前体的摄影记录材料
公开(公告)号：US4546073A
公开(公告)日：1985-10-08
申请号：US610786
申请日：1984-05-16
申请人： Peter Bergthaller , Heinrich Odenwalder , Reinhard Matejec
发明人： Peter Bergthaller , Heinrich Odenwalder , Reinhard Matejec
IPC分类号： G03C7/00 , C07D249/18 , C07D257/04 , G03C7/305 , G03C7/32 , G03C7/26
CPC分类号： C07D257/04 , C07D249/18 , G03C7/30576 , Y10S430/156 , Y10S430/158
摘要： Precursor compounds from which photographically-active compounds are released with a time delay correspond to the following general formula ##STR1## wherein A represents the residue of a compound which undergoes oxidative coupling;X represents --O--, --S-- or --NR.sup.1 --;Y represents a releasable group which may consist of or contain the residue of a photographically-active compound; andR represents a group for controlling the kinetics of release.Advantageous pictorial properties (inter-image effect, edge effect, modulation transfer function) are obtained with compounds according to the present invention if the photographically-active residue is the residue of a development inhibitor.
摘要翻译：照相活性化合物以时间延迟释放的前体化合物对应于下列通式：其中A表示经历氧化偶联的化合物的残基; X表示-O - ， - S-或-NR1-; Y表示可以由摄影活性化合物的残基组成或含有的可释放基团; R表示用于控制释放动力学的基团。如果照相活性残基是显影抑制剂的残留物，则可以用根据本发明的化合物获得有利的图案性质（图像间效应，边缘效应，调制转移功能）。

8. 发明授权

US5215875A Color photographic recording material 失效
标题翻译：彩色摄影记录材料
公开(公告)号：US5215875A
公开(公告)日：1993-06-01
申请号：US712258
申请日：1991-06-07
申请人： Reinhart Matejec , Hans Vetter , Heinrich Odenwalder
发明人： Reinhart Matejec , Hans Vetter , Heinrich Odenwalder
IPC分类号： G03C5/42 , G03C1/74 , G03C7/00 , G03C7/30 , G03C7/392 , G03C7/407
CPC分类号： G03C7/39224 , G03C7/302 , G03C7/3022 , Y10S430/144
摘要： A color photographic recording material comprising at least one blue-sensitive silver halide emulsion layer containing at least one yellow coupler, at least one green-sensitive silver halide emulsion layer containing at least one magenta coupler and at least one red-sensitive silver halide emulsion layer containing at least one cyan coupler and typical intermediate and protective layers, in which the silver halide coating of all the photosensitive layers, expressed as AgNO.sub.3, amounts to no more than 0.3 g/m.sup.2 and the color-coupler-containing layers contain at least one p-phenylenediamine compound containing at least one primary amino group and at least one ballast group dissolved in hydrophobic oil droplets, can be developed in an environment-friendly manner using an intensifying bath.
摘要翻译：一种彩色照相记录材料，其包含至少一种含有至少一种黄色成色剂的感蓝卤化银乳剂层，至少一种含有至少一种品红成色剂的至少一种感绿卤化银乳剂层和至少一种感红卤化银乳剂层含有至少一个青色成色剂和典型的中间和保护层，其中以AgNO 3表示的所有感光层的卤化银涂层不超过0.3g / m 2，并且含色调剂的层含有至少一种可以使用强化浴以环保的方式显影含有至少一个伯氨基和至少一个溶解在疏水性油滴中的压载物的对苯二胺化合物。

9. 发明授权

US5006457A Photographic recording material 失效
标题翻译：摄影记录材料
公开(公告)号：US5006457A
公开(公告)日：1991-04-09
申请号：US434927
申请日：1989-11-09
申请人： Hans Vetter , Hans hlschlager , Heinrich Odenwalder , Bernhard Morcher , Friedhelm Sommer , Lothar Rosenhahn
发明人： Hans Vetter , Hans hlschlager , Heinrich Odenwalder , Bernhard Morcher , Friedhelm Sommer , Lothar Rosenhahn
IPC分类号： G03C1/34
CPC分类号： G03C1/34 , G03C1/346
摘要： The invention relates to a photographic recording material comprising a layer support and, arranged thereon, at least one photosensitive silver halide emulsion layer which contains an antifogging agent corresponding to formula (I) ##STR1## in which A, R.sub.1 and R.sub.2 are as defined in the specification. The antifogging agents according to the invention reduce fogging without significantly affecting gradation and improve the staility of the photographic material in storage.
摘要翻译：本发明涉及一种照相记录材料，其包括层载体，并且在其上布置有至少一种感光卤化银乳剂层，其含有对应于式（I）的防雾剂，其中A，R1和R2为如说明书中所定义。根据本发明的防雾剂可减少雾化，而不会显着影响灰度，并提高储存过程中照相材料的稳定性。

10. 发明授权

US4360581A Color photographic recording material containing non-diffusing electron donor compounds 失效
标题翻译：含有非扩散电子给体化合物的彩色照相记录材料
公开(公告)号：US4360581A
公开(公告)日：1982-11-23
申请号：US208187
申请日：1980-11-19
申请人： Heinrich Odenwalder , Hans Vetter , Wilhelmus Janssens , Jan Jaeken
发明人： Heinrich Odenwalder , Hans Vetter , Wilhelmus Janssens , Jan Jaeken
IPC分类号： C09B55/00 , C07D209/08 , C07D209/40 , G03C8/00 , G03C8/08 , G03C8/10 , G03C5/54 , G03C1/40
CPC分类号： G03C8/00 , C07D209/08 , C07D209/40 , G03C8/08
摘要： Electron donor compounds of the formula I are effective to reduce non-diffusing reducible color providing compounds which when reduced release under the photographic development conditions a diffusible dye.R.sup.1 (--L.sup.1 .dbd.L.sup.2).sub.n --NH--SO.sub.2 --X (I)in whichL.sup.1, L.sup.2 represent methine groups which may be part of a carbocyclic or heterocyclic ringR.sup.1 represents --OR.sup.2, --SR.sup.2 or --NHR.sup.3R.sup.2 represents H or a hydrolysable groupR.sup.3 represents H, alkyl, aryl, acyl including a group that together with L.sup.1 completes a ringn=1 or 2X represents a non-colored organic group.
摘要翻译：式I的电子给体化合物有效地减少不扩散可还原的提供颜色的化合物，当在照相显影条件下减少释放可扩散的染料时。其中L1，L2表示可以是碳环或杂环的一部分的次甲基的R1（-L1 = L2）n-NH-SO2-X（I）表示-OR2，-SR2或-NHR3R2表示H或可水解基团R 3表示H，烷基，芳基，酰基，包括与L1一起完成环的基团n = 1或2 X表示无色有机基团。

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