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1. 发明授权

US4501905A Cyclic carbonic acid derivatives 失效
标题翻译：环状碳酸衍生物
公开(公告)号：US4501905A
公开(公告)日：1985-02-26
申请号：US555754
申请日：1983-11-28
申请人： Heinrich Krimm , Hans-Josef Buysch
发明人： Heinrich Krimm , Hans-Josef Buysch
IPC分类号： C07D319/06 , C07D493/10 , C08G64/02 , C08G64/30
CPC分类号： C07D493/10 , C07D319/06 , C08G64/0216 , C08G64/305
摘要： New cyclic carbonic acid derivatives of the formula ##STR1## in which R denotes either --CH.sub.2 OH, R.sup.1 then representing an alkyl radical having 1 to 4 C atoms, or ##STR2## R.sup.1 and R.sup.2 then independently of one another representing methyl or ethyl, or ##STR3## R.sup.1 and R.sup.3 then each representing an alkyl radical having 1 to 4 C atoms,or in whichR and R.sup.1 together denote ##STR4## wherein A represents the group ##STR5## or oxygen, a process for their preparation, and their use as copolymerization components in the preparation of polycarbonates.
摘要翻译：式（IMAGE）的新的环状碳酸衍生物，其中R表示-CH 2 OH，R 1表示具有1至4个C原子的烷基，或者R 1和R 2彼此独立地代表甲基或乙基，或 R1和R3分别代表具有1至4个C原子的烷基，或其中R和R 1一起表示“IMAGE”，其中A表示基团或氧，其制备方法及其用途作为制备聚碳酸酯的共聚组分。

2. 发明授权

US4335051A Process for the preparation of dimethyl carbonate 失效
标题翻译：碳酸二甲酯的制备方法
公开(公告)号：US4335051A
公开(公告)日：1982-06-15
申请号：US155036
申请日：1980-05-30
申请人： Hans-Josef Buysch , Heinrich Krimm , Siegfried Bohm
发明人： Hans-Josef Buysch , Heinrich Krimm , Siegfried Bohm
IPC分类号： C07C69/96 , C07C68/00 , C07C68/02
CPC分类号： C07C68/02
摘要： In a process for the preparation of dimethyl carbonate by reacting methanol with phosgene and/or methyl chloroformate, the improvement wherein the reaction is carried out in the presence of an aqueous alkali metal hydroxide solution and in the presence of an inert, water-immiscible organic solvent, at a temperature in the range from -20.degree. C. to +40.degree. C.
摘要翻译：在通过甲醇与光气和/或氯甲酸甲酯反应制备碳酸二甲酯的方法中，其反应在碱金属氢氧化物水溶液的存在下和在惰性的与水不混溶的有机物的存在下进行溶剂，温度范围为-20℃至+ 40℃。

3. 发明授权

US4307032A Process for the preparation of dialkyl carbonates 失效
标题翻译：制备碳酸二烷基酯的方法
公开(公告)号：US4307032A
公开(公告)日：1981-12-22
申请号：US149388
申请日：1980-05-13
申请人： Heinrich Krimm , Hans-Josef Buysch , Hans Rudolph
发明人： Heinrich Krimm , Hans-Josef Buysch , Hans Rudolph
IPC分类号： C07C69/96 , B01J23/00 , B01J23/08 , B01J27/00 , B01J31/00 , C07B61/00 , C07C29/128 , C07C68/06
CPC分类号： C07C29/128 , B01J23/08 , C07C68/065 , Y02P20/52
摘要： A process for preparing a dialkyl carbonate by contacting a glycol carbonate with an alcohol at an elevated temperature in the presence of a thallium compound.
摘要翻译：在铊化合物的存在下，通过使高碳酸酯与醇在高温下接触来制备碳酸二烷基酯的方法。

4. 发明授权

US4181676A Process for the preparation of dialkyl carbonates 失效
标题翻译：制备碳酸二烷基酯的方法
公开(公告)号：US4181676A
公开(公告)日：1980-01-01
申请号：US938725
申请日：1978-08-31
申请人： Hans-Josef Buysch , Heinrich Krimm , Hans Rudolph
发明人： Hans-Josef Buysch , Heinrich Krimm , Hans Rudolph
IPC分类号： C07C69/96 , B01J23/00 , B01J27/00 , B01J31/00 , C07B61/00 , C07C29/128 , C07C68/06
CPC分类号： C07C29/128 , C07C68/065 , Y02P20/52
摘要： An improved process for the preparation of a dialkyl carbonate by contacting a glycol carbonate with alcohol at an elevated temperature in the presence of an alkali metal or alkali metal compound, the improvement residing in employing less than 0.01 percent by weight of alkali metal and/or alkali metal compound, based upon the weight the reaction mixture.
摘要翻译：通过在碱金属或碱金属化合物的存在下，在升高的温度下使乙二醇碳酸酯与醇接触来制备碳酸二烷基酯的改进方法，其改进在于使用少于0.01重量％的碱金属和/或碱金属化合物，基于反应混合物的重量。

5. 发明授权

US4105641A Process for the preparation of aliphatic polycarbonates and polyurethanes therefrom 失效
标题翻译：制备聚氨酯和其中的聚氨酯的方法
公开(公告)号：US4105641A
公开(公告)日：1978-08-08
申请号：US778659
申请日：1977-03-17
申请人： Hans-Josef Buysch , Heinrich Krimm , Hans Rudolph
发明人： Hans-Josef Buysch , Heinrich Krimm , Hans Rudolph
IPC分类号： C08G18/44 , C08G64/02 , C08G64/16 , C08G64/30 , C08G18/08
CPC分类号： C08G64/0208 , C08G18/44 , C08G64/1608 , C08G64/305
摘要： The present invention relates to a process for the preparation of polycarbonates which contain aliphatically bound hydroxyl groups by transesterification of aliphatic dihydroxy compounds with glycol carbonate, optionally in the presence of transesterification catalysts, with simultaneous separation of the glycol by fractional distillation, which process is characterized in that ethylene glycol is removed from the reaction mixture as an azeotropic mixture by means of inert solvents with which ethylene glycol is substantially immiscible. The present invention further relates to the preparation of polyurethanes from these polycarbonates.

6. 发明授权

US4440937A Cyclic carbonic acid derivatives 失效
标题翻译：环状碳酸衍生物
公开(公告)号：US4440937A
公开(公告)日：1984-04-03
申请号：US340943
申请日：1982-01-20
申请人： Heinrich Krimm , Hans-Josef Buysch
发明人： Heinrich Krimm , Hans-Josef Buysch
IPC分类号： C07D319/06 , C07D493/10 , C08G64/02 , C08G64/30
CPC分类号： C07D493/10 , C07D319/06 , C08G64/0216 , C08G64/305
摘要： New cyclic carbonic acid derivatives of the formula ##STR1## in which R denotes either --CH.sub.2 OH, R.sup.1 then representing an alkyl radical having 1 to 4 C atoms, or ##STR2## R.sup.1 and R.sup.2 then independently of one another representing methyl or ethyl, or ##STR3## R.sup.1 and R.sup.5 then each representing an alkyl radical having 1 to 4 C atoms, or in whichR and R.sup.1 together denote ##STR4## wherein A represents the group ##STR5## or oxygen, a process for their preparation, and their use as copolymerization components in the preparation of polycarbonates.
摘要翻译：式（IMAGE）的新的环状碳酸衍生物，其中R表示-CH 2 OH，R 1表示具有1至4个C原子的烷基，或者R 1和R 2彼此独立地代表甲基或乙基，或 R1和R5分别代表具有1-4个C原子的烷基，或其中R和R 1一起表示，其中A代表基团或氧，其制备方法及其用途作为制备聚碳酸酯的共聚组分。

7. 发明授权

US4377670A Copolymers based on aliphatic polycarbonates and lactams 失效
标题翻译：基于脂肪族聚碳酸酯和内酰胺的共聚物
公开(公告)号：US4377670A
公开(公告)日：1983-03-22
申请号：US314242
申请日：1981-10-23
申请人： Heinrich Krimm , Hans-Josef Buysch , Artur Botta
发明人： Heinrich Krimm , Hans-Josef Buysch , Artur Botta
IPC分类号： C08G69/00 , C08G63/00 , C08G64/00 , C08G64/42 , C08G69/18 , C08G69/44 , C08G71/00 , C08G71/04 , C08G63/62 , C08G69/16
CPC分类号： C08G69/44 , C08G71/04
摘要： Anionic copolymers of lactams and aliphatic polycarbonates having urethane and carboxylic acid ester groups, preferably having recurring structural units of the formula:--NH--CO--O--Y--O--CO--(CR.sub.2).sub.n --whereinR represents hydrogen or C.sub.1 -C.sub.4 -alkyl;n represents an integer of from 2 to 13;Y represents the residue of an alcohol of the following formula:HO--X--OH,whereinX represents an open-chain, cyclic or mixed open-chain-cyclic alkylene radical having from 2 to 12 carbon atoms which is optionally substituted by C.sub.1 -C.sub.4 -alkyl and optionally interrupted by from 1 to 3 oxygen atoms, or a polyethylene glycol having a molecular weight up to 10,000 or an alkoxylation product of bifunctional phenols.
摘要翻译：具有氨基甲酸酯和羧酸酯基的内酰胺和脂族聚碳酸酯的阴离子共聚物，优选具有下式的重复结构单元：-NH-CO-O-Y-O-CO-（CR2）n-，其中R表示氢或C1-C4-烷基; n表示2〜13的整数， Y表示下式的醇的残基：HO-X-OH，其中X表示具有2至12个碳原子的开链，环状或混合的开链 - 环状亚烷基，其任选被C1- C4烷基，任选地被1至3个氧原子间隔，或分子量高达10,000的聚乙二醇或双功能酚的烷氧基化产物。

8. 发明授权

US4330665A Process for the preparation of aromatic polycarbonates 失效
标题翻译：制备芳族聚碳酸酯的方法
公开(公告)号：US4330665A
公开(公告)日：1982-05-18
申请号：US256227
申请日：1981-04-21
申请人： Heinrich Krimm , Hans-Josef Buysch , Hans Rudolph
发明人： Heinrich Krimm , Hans-Josef Buysch , Hans Rudolph
IPC分类号： C08G63/00 , C08G64/20 , C08G64/30 , C08G63/62
CPC分类号： C08G64/307
摘要： The invention is directed to a process for the preparation of polycarbonates of Mw 20,000 to 180,000 by transesterification of diphenols and carbonic acid dialkyl esters in the presence of organo-tin-IV compounds and a monophenol.
摘要翻译：本发明涉及通过在有机锡 - Ⅳ-IV化合物和单酚存在下二元酚和碳酸二烷基酯的酯交换制备Mw为20,000至180,000的聚碳酸酯的方法。

9. 发明授权

US4054597A Thiodiglycol polycarbonates 失效
标题翻译：硫二甘醇聚碳酸酯
公开(公告)号：US4054597A
公开(公告)日：1977-10-18
申请号：US687437
申请日：1976-05-17
申请人： Heinrich Krimm , Hans-Josef Buysch , Hermann Schnell
发明人： Heinrich Krimm , Hans-Josef Buysch , Hermann Schnell
IPC分类号： C08G18/46 , C08G64/02 , C07C149/14 , C08G63/62
CPC分类号： C08G64/025 , C08G18/4676
摘要： The present invention relates to an interfacial process for the production of polycarbonates having terminal, aliphatically bonded hydroxyl groups by reacting predominantly dihydric alcohols with phosgene or chlorocarbonic acid esters of predominantly dihydric alcohols and/or phenols using alkali liquors as HCl-binding agents and in the presence of inert solvents, the process according to the invention being distinguished by the fact that concentrated, aqueous alkali liquors are used as the HCl-binding agents and thiodiglycol, optionally mixed with additional monohydric and polyhydric alcohols, is used as the dihydric alcohol. The present invention further relates to the new polycarbonates produced according to the novel process and to the use of these new polycarbonates for the production of polyurethane plastics.
摘要翻译：本发明涉及通过使用碱金属作为HCl结合剂，主要使二元醇与主要为二元醇和/或酚的光气或氯代碳酸酯主要反应的具有末端脂族键合羟基的聚碳酸酯的界面方法，惰性溶剂的存在，根据本发明的方法的区别在于使用浓缩的碱水溶液作为HCl结合剂，并且任选与另外的一元醇和多元醇混合的硫二甘醇用作二元醇。本发明还涉及根据新方法生产的新的聚碳酸酯以及这些新的聚碳酸酯用于生产聚氨酯塑料的用途。

10. 发明授权

US3979462A Condensation resins of phenols and .alpha.,.alpha.'-dihydroxy-diisopropyl benzenes 失效
标题翻译：苯酚的缩合树脂和{60，{60 {40-二羟基 - 二异丙基苯
公开(公告)号：US3979462A
公开(公告)日：1976-09-07
申请号：US636921
申请日：1975-12-02
申请人： Heinrich Krimm , Hans-Josef Buysch , Dieter Freitag
发明人： Heinrich Krimm , Hans-Josef Buysch , Dieter Freitag
IPC分类号： C07C37/16 , C08G8/12 , C08G61/02 , C07C39/12
CPC分类号： C08G61/02 , C07C37/16 , C08G8/12
摘要： A process for the production of light colored condensation resins, wherein phenols are reacted with .alpha.,.alpha.'-dihydroxy-diisopropyl benzenes in the presence of acids of phosphorus at temperatures of between 70.degree. and 270.degree.C.
摘要翻译：一种生产浅色缩合树脂的方法，其中在70℃至270℃的温度下，在磷酸存在下，苯酚与α，α'-二羟基 - 二异丙基苯反应。

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