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1. 发明授权

US5849975A Process for isomerization of normal olefin 失效
标题翻译：正烯烃异构化方法
公开(公告)号：US5849975A
公开(公告)日：1998-12-15
申请号：US782015
申请日：1997-01-07
申请人： Harris E. Kluksdahl , Lawrence W. Jossens , Thomas V. Harris , Stacey I. Zones
发明人： Harris E. Kluksdahl , Lawrence W. Jossens , Thomas V. Harris , Stacey I. Zones
IPC分类号： C07C5/27 , C07C41/06
CPC分类号： C07C41/06 , C07C5/2775 , C07C2529/06
摘要： A process for skeletal isomerization of light normal C.sub.4-6 olefins to iso-olefins by contacting a hydrocarbon stream containing C.sub.4-6 normal olefins under isomerization conditions with a SSZ-32 zeolite catalyst.
摘要翻译：通过在异构化条件下使含有C4-6正烯烃的烃流与SSZ-32沸石催化剂接触，将轻质正辛烯C 4-6烯烃骨架异构化成异烯烃的方法。

2. 发明授权

US5215648A Hydrocarbon conversion processes using SSZ-31 失效
标题翻译：使用SSZ-31的烃转化方法
公开(公告)号：US5215648A
公开(公告)日：1993-06-01
申请号：US817260
申请日：1992-01-03
申请人： Stacey I. Zones , Thomas V. Harris , Andrew Rainis , Donald S. Santilli
发明人： Stacey I. Zones , Thomas V. Harris , Andrew Rainis , Donald S. Santilli
IPC分类号： B01J29/035 , B01J29/04 , B01J29/08 , B01J29/70 , B01J29/74 , B01J29/80 , B01J29/86 , C01B37/02 , C01B39/48 , C07C1/20 , C07C2/00 , C07C2/12 , C07C2/66 , C07C4/06 , C07C5/27 , C07C6/12 , C07C211/38 , C07C211/62 , C07D211/58 , C10G11/05 , C10G35/095 , C10G45/64 , C10G47/16
CPC分类号： C10G47/16 , B01J29/035 , B01J29/04 , B01J29/70 , B01J29/74 , B01J29/80 , B01J29/86 , C01B33/185 , C01B35/1009 , C01B39/48 , C07C1/20 , C07C2/00 , C07C2/12 , C07C2/66 , C07C211/38 , C07C211/62 , C07C4/06 , C07C5/2724 , C07C6/126 , C07D211/58 , C10G11/05 , C10G35/095 , C10G45/64 , B01J2229/26 , B01J2229/36 , B01J2229/42 , B01J29/084 , C01P2002/72 , C01P2002/74 , C01P2006/12 , C01P2006/14 , C01P2006/34 , C07C2103/66 , C07C2529/70 , C07C2529/74
摘要： Hydrocarbon conversion processes using a crystalline zeolite SSZ-31.
摘要翻译：使用结晶沸石SSZ-31的烃转化方法。

3. 发明授权

US5282958A Use of modified 5-7 a pore molecular sieves for isomerization of hydrocarbons 失效
标题翻译：使用改性的5-7孔分子筛进行烃的异构化
公开(公告)号：US5282958A
公开(公告)日：1994-02-01
申请号：US556560
申请日：1990-07-20
申请人： Donald S. Santilli , Mohammad M. Habib , Thomas V. Harris , Stacey I. Zones
发明人： Donald S. Santilli , Mohammad M. Habib , Thomas V. Harris , Stacey I. Zones
IPC分类号： C07B61/00 , B01J29/00 , B01J29/83 , B01J29/85 , C10G45/64 , C10G65/04 , C10G73/44 , C10M101/02 , C10N30/02 , C10N60/00 , C10N60/02 , C10N70/00 , C07C5/13 , C10G11/02
CPC分类号： C10G45/64 , C10G2300/70 , C10G2400/10
摘要： A process is disclosed for dewaxing a hydrocarbon feed to produce a dewaxed lube oil. The feed includes straight chain and slightly branched chain paraffins having 10 or more carbon atoms. In the process the feed is contacted under isomerization conditions with an intermediate pore size molecular sieve having a crystallite size of no more than about 0.5.mu. and pores with a minimum diameter of at least 4.8.ANG. and with a maximum diameter of 7.1.ANG. or less. The catalyst has sufficient acidity so that 0.5 g thereof when positioned in a tube reactor converts at least 50% of hexadecane at 370.degree. C., a pressure of 1200 psig, a hydrogen flow of 160 ml/min, and a feed rate of 1 ml/hr. It also exhibits 40 or greater isomerization selectivity when used under conditions leading to 96% conversion of hexadecane to other chemicals. The catalyst includes at least one Group VIII metal. The contacting is carried out at a pressure from about 15 psig to about 3000 psig.
摘要翻译：公开了一种用于使烃进料脱蜡以生产脱蜡润滑油的方法。进料包括具有10个或更多个碳原子的直链和轻链支链烷烃。在该过程中，进料在异构化条件下与具有不超过约0.5（my）的微晶尺寸的中孔分子筛和最小直径至少为4.8（Aangstroem）的孔和最大直径为7.1 （Aangstroem）或更少。该催化剂具有足够的酸度，使得当其位于管式反应器中时，其0.5g在370℃下转化至少50％的十六烷，压力为1200psig，氢气流量为160ml / min，进料速率为1 ml / hr。当在导致十六烷转化为其他化学品的96％的条件下使用时，它还具有40或更高的异构化选择性。该催化剂包括至少一种第VIII族金属。接触在约15psig至约3000psig的压力下进行。

4. 发明授权

US07115198B2 Hydrocarbon conversion using molecular sieve SSZ-51 有权
标题翻译：使用分子筛SSZ-51进行烃转化
公开(公告)号：US07115198B2
公开(公告)日：2006-10-03
申请号：US10691896
申请日：2003-10-22
申请人： Stacey I. Zones , Thomas V. Harris
发明人： Stacey I. Zones , Thomas V. Harris
IPC分类号： C10G11/00 , C10G47/16 , B01J27/18
CPC分类号： C10G65/12 , C07C1/20 , C07C2/12 , C07C2/66 , C07C2/76 , C07C5/2518 , C07C5/2708 , C07C5/2775 , C07C6/126 , C07C2529/85 , C10G3/49 , C10G11/05 , C10G29/205 , C10G45/64 , C10G47/20 , C10G2300/1088 , C10G2300/1092 , C10G2300/1096 , C10G2300/301 , C10G2400/02 , C10G2400/10 , C10G2400/30 , Y02P30/20
摘要： A novel crystalline aluminophosphate and metalloaluminophosphate of the molecular sieve type, denominated SSZ-51, is prepared by hydrothermal synthesis from reactive sources of aluminum and phosphorus, fluorine and an organic templating agent, 4-dimethylaminopyridine. SSZ-51 is useful in catalysts for, e.g., hydrocarbon conversion reactions.
摘要翻译：通过从铝和磷，氟和有机模板剂4-二甲基氨基吡啶的反应源水热合成制备了分子筛型新型SSZ-51的新型结晶铝磷酸盐和金属铝磷酸盐。 SSZ-51可用于例如烃转化反应的催化剂。

5. 发明授权

US07153483B2 Crystalline molecular sieve SSZ-51 composition of matter and synthesis thereof 有权
标题翻译：结晶分子筛SSZ-51组成物质及其合成
公开(公告)号：US07153483B2
公开(公告)日：2006-12-26
申请号：US10691857
申请日：2003-10-22
申请人： Stacey I. Zones , Allen W. Burton , Thomas V. Harris , Lucy M. Bull
发明人： Stacey I. Zones , Allen W. Burton , Thomas V. Harris , Lucy M. Bull
IPC分类号： C01B37/04 , C01B37/06 , C01B37/08
CPC分类号： B01J29/85 , B01J29/84 , C01B39/54 , Y10S423/30
摘要： A novel crystalline aluminophosphate and metalloaluminophosphate of the molecular sieve type, denominated SSZ-51, is prepared by hydrothermal synthesis from reactive sources of aluminum and phosphorus, fluorine and an organic templating agent, 4-dimethylaminopyridine.
摘要翻译：通过从铝和磷，氟和有机模板剂4-二甲基氨基吡啶的反应源水热合成制备分子筛型新型结晶磷酸铝和金属铝磷酸盐，称为SSZ-51。

6. 发明授权

US5106801A Zeolite SSZ-31 失效
标题翻译：沸石SSZ-31
公开(公告)号：US5106801A
公开(公告)日：1992-04-21
申请号：US471158
申请日：1990-01-26
申请人： Stacey I. Zones , Thomas V. Harris , Andrew Rainis , Donald S. Santilli
发明人： Stacey I. Zones , Thomas V. Harris , Andrew Rainis , Donald S. Santilli
IPC分类号： B01J29/035 , B01J29/04 , B01J29/08 , B01J29/70 , B01J29/74 , B01J29/80 , B01J29/86 , B01J29/87 , B01J29/88 , B01J29/89 , C01B33/40 , C01B33/42 , C01B37/02 , C01B39/00 , C01B39/04 , C01B39/06 , C01B39/48 , C07C1/20 , C07C2/00 , C07C2/12 , C07C2/66 , C07C4/06 , C07C5/22 , C07C5/27 , C07C6/00 , C07C6/12 , C07C211/38 , C07C211/62 , C07D211/58 , C10G11/05 , C10G35/095 , C10G45/64 , C10G47/16
CPC分类号： C10G47/16 , B01J29/035 , B01J29/04 , B01J29/70 , B01J29/74 , B01J29/80 , B01J29/86 , C01B33/185 , C01B35/1009 , C01B39/48 , C07C1/20 , C07C2/00 , C07C2/12 , C07C2/66 , C07C211/38 , C07C211/62 , C07C4/06 , C07C5/2724 , C07C6/126 , C07D211/58 , C10G11/05 , C10G35/095 , C10G45/64 , B01J2229/26 , B01J2229/36 , B01J2229/42 , B01J29/084 , C01P2002/72 , C01P2002/74 , C01P2006/12 , C01P2006/14 , C01P2006/34 , C07C2103/66 , C07C2529/70 , C07C2529/74
摘要： A crystalline zeolite SSZ-31 is prepared by various methods using quaternary ammonium ion templates.
摘要翻译：通过使用季铵离子模板的各种方法制备结晶沸石SSZ-31。

7. 发明授权

US08524965B2 Method of making an alkylated aromatic using acidic ionic liquid catalyst 有权
标题翻译：使用酸性离子液体催化剂制备烷基化芳族化合物的方法
公开(公告)号：US08524965B2
公开(公告)日：2013-09-03
申请号：US11315960
申请日：2005-12-21
申请人： Curt B. Campbell , Thomas V. Harris , Gilles Sinquin
发明人： Curt B. Campbell , Thomas V. Harris , Gilles Sinquin
IPC分类号： C07C2/68 , C07C2/70
CPC分类号： C10G29/205 , C07C2/68 , C07C2527/125 , C07C2531/02 , C10G2300/1022 , C10G2300/1088 , C10G2300/1096 , C10G2400/30 , C07C15/107 , C07C15/113
摘要： A process for alkylating an aromatic compound comprising reacting at least one aromatic compound with a mixture of olefins selected from olefins having from about 8 to about 100 carbon atoms, in the presence of an acidic ionic liquid catalyst, wherein the resulting product comprises at least about 50 weight percent of a 1, 2, 4 tri-substituted aromatic compound or a 1, 2, 3 tri-substituted aromatic compound or mixtures thereof.
摘要翻译：一种用于烷基化芳族化合物的方法，包括使至少一种芳族化合物与选自具有约8至约100个碳原子的烯烃的烯烃的混合物在酸性离子液体催化剂存在下反应，其中所得产物包含至少约 50重量％的1,2,4取代的芳族化合物或1,2,3取代的芳族化合物或其混合物。

8. 发明授权

US08524623B2 Electrochemical removal of conjunct polymers from chloroaluminate ionic liquids 有权
标题翻译：从氯铝酸盐离子液体电化学去除结合聚合物
公开(公告)号：US08524623B2
公开(公告)日：2013-09-03
申请号：US12437508
申请日：2009-05-07
申请人： Hye-Kyung Timken , Saleh Elomari , Thomas V. Harris , James N. Ziemer
发明人： Hye-Kyung Timken , Saleh Elomari , Thomas V. Harris , James N. Ziemer
IPC分类号： C07C2/58
CPC分类号： B01J38/48 , B01J31/0284 , B01J31/40 , C07C2/58 , C10G29/205 , Y02P20/584 , C07C9/16
摘要： A process for regenerating a spent ionic liquid catalyst including (a) applying a voltage across one or more pairs of electrodes immersed in a spent ionic liquid catalyst comprising conjunct polymer-metal halide complexes to provide freed conjunct polymers and a regenerated ionic liquid catalyst; and (b) separating the freed conjunct polymers from the regenerated ionic liquid catalyst is described. An alkylation process incorporating the regeneration process is also described.
摘要翻译：一种用于再生废离子液体催化剂的方法，包括（a）在浸入包含结合的聚合物 - 金属卤化物络合物的废离子液体催化剂中的一对或多个电极上施加电压以提供释放的结合聚合物和再生的离子液体催化剂; 和（b）从再生离子液体催化剂中分离释放的结合聚合物。还描述了结合再生方法的烷基化方法。

9. 发明授权

US08187993B2 Methods and compositions for stabilizing catalytic processes 有权
标题翻译：用于稳定催化过程的方法和组合物
公开(公告)号：US08187993B2
公开(公告)日：2012-05-29
申请号：US12611695
申请日：2009-11-03
申请人： Thomas V. Harris
发明人： Thomas V. Harris
IPC分类号： B01J31/06
CPC分类号： B01J31/0278 , B01J31/0284 , B01J31/26 , B01J31/40
摘要： Methods and compositions for stabilizing the activity of catalytic compositions during catalytic processes, such as alkylation. A catalytic composition comprising a partially deactivated ionic liquid catalyst may be regenerated by reaction with a metal to form reactivated catalyst and an inorganic catalyst precursor; and the catalytic composition may be amended in-process by addition of an organic catalyst precursor for reaction with the inorganic catalyst precursor to form fresh ionic liquid catalyst. The organic catalyst precursor may be protected from water, e.g., during handling, by hydrophobic material(s).
摘要翻译：用于在催化过程如烷基化过程中稳定催化组合物的活性的方法和组合物。包含部分失活的离子液体催化剂的催化组合物可以通过与金属反应而再生以形成再活化的催化剂和无机催化剂前体; 并且可以通过加入与无机催化剂前体反应的有机催化剂前体在工艺中修饰催化组合物以形成新鲜的离子液体催化剂。有机催化剂前体可以例如在处理期间被疏水材料保护而不被水保护。

10. 发明授权

US07732363B2 Regeneration of acidic catalysts 有权
标题翻译：酸性催化剂的再生
公开(公告)号：US07732363B2
公开(公告)日：2010-06-08
申请号：US11315749
申请日：2005-12-20
申请人： Saleh Elomari , Thomas V. Harris
发明人： Saleh Elomari , Thomas V. Harris
IPC分类号： B01J20/34
CPC分类号： B01J31/4092 , B01J27/30 , B01J27/32 , B01J31/0284 , B01J31/0288 , B01J31/0298 , B01J35/12 , B01J38/50 , B01J38/54 , B01J2231/12 , B01J2231/20 , B01J2231/4205 , B01J2231/44 , B01J2531/31 , C01B17/905 , C07D213/20 , Y02P20/584
摘要： A process for regenerating a used acidic catalyst which has been deactivated by conjunct polymers by removing the conjunct polymers so as to increase the activity of the catalyst is disclosed. Methods for removing the conjunct polymers include hydrogenation, addition of a basic reagent and alkylation. The methods are applicable to all acidic catalysts and are described with reference to certain ionic liquid catalysts.
摘要翻译：公开了一种通过除去结合聚合物以使催化剂的活性提高而使被结合的聚合物失活的酸性催化剂再生的方法。去除结合聚合物的方法包括氢化，加入碱性试剂和烷基化。该方法适用于所有酸性催化剂，并参照某些离子液体催化剂进行了描述。

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