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    • 9. 发明申请
    • Thermoplastic elastomer blend, method of manufacture and use thereof
    • 热塑性弹性体共混物,其制造方法和用途
    • US20060247378A1
    • 2006-11-02
    • US11215407
    • 2005-08-30
    • Hari Sunkara
    • Hari Sunkara
    • C08L77/00
    • C08L77/12C08L33/04C08L2666/06
    • A curable thermoplastic elastomeric composition comprising: (a) polyalkylene ether ester amide elastomer; (b) crosslinkable poly(meth)acrylate rubber; and (c) a crosslinking system to crosslink the rubber. A melt processible thermoplastic elastomeric composition comprising: (a) a continuous phase comprising polyalkylene ether ester amide elastomer; and (b) crosslinked poly(meth)acrylate rubber disperse phase. A process for manufacturing a melt processible thermoplastic elastomeric composition comprising the steps: (a) providing a cross-linkable poly(meth)acrylate rubber; (b) providing crosslinking system in an amount effective to crosslink the poly(meth)acrylate rubber; (c) providing polyalkylene ether ester amide elastomer; (d) forming a mixture of the cross-linkable poly(meth)acrylate rubber, the polyalkylene ether ester amide elastomer and the crosslinking system; (e) cross-linking the cross-linkable poly(meth)acrylate rubber in the mixture using the crosslinking system; and (f) recovering a melt processible thermoplastic elastomeric composition comprising the polyether ester elastomer as a continuous phase and the crosslinked poly(meth)acrylate rubber as a disperse phase. A shaped article (e.g., an extruded or molded article) made from a melt processible thermoplastic elastomeric composition comprising: (a) a continuous phase comprising polyalkylene ether ester amide elastomer, and (b) a disperse phase comprising cross-linked poly(meth)acrylate rubber. Preferably the shaped article is selected from the group consisting of hoses, gaskets, films, belts, cable jackets, seals, gears and bearings.
    • 一种可固化热塑性弹性体组合物,其包含:(a)聚亚烷基醚酯酰胺弹性体; (b)可交联聚(甲基)丙烯酸酯橡胶; 和(c)使橡胶交联的交联体系。 一种可熔融加工的热塑性弹性体组合物,其包含:(a)包含聚亚烷基醚酯酰胺弹性体的连续相; 和(b)交联聚(甲基)丙烯酸酯橡胶分散相。 一种制造可熔融加工的热塑性弹性体组合物的方法,包括以下步骤:(a)提供可交联的聚(甲基)丙烯酸酯橡胶; (b)提供有效交联聚(甲基)丙烯酸酯橡胶的量的交联体系; (c)提供聚亚烷基醚酯酰胺弹性体; (d)形成可交联聚(甲基)丙烯酸酯橡胶,聚亚烷基醚酯酰胺弹性体和交联体系的混合物; (e)使用交联体系交联该混合物中的可交联聚(甲基)丙烯酸酯橡胶; 和(f)回收作为连续相的包含聚醚酯弹性体的可熔融加工的热塑性弹性体组合物和作为分散相的交联的聚(甲基)丙烯酸酯橡胶。 由可熔融加工的热塑性弹性体组合物制成的成型制品(例如,挤出或模塑制品),其包含:(a)包含聚亚烷基醚酯酰胺弹性体的连续相,和(b)包含交联的聚(甲基) 丙烯酸酯橡胶。 优选地,成形制品选自由软管,垫圈,薄膜,皮带,电缆套,密封件,齿轮和轴承组成的组。