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    • 2. 发明申请
    • Heat-stable diketopyrrolopyrrole pigment mixtures
    • 热稳定二酮吡咯并吡咯颜料混合物
    • US20070028807A1
    • 2007-02-08
    • US10576703
    • 2004-10-04
    • Olof WallquistRoman LenzLeonhard FeilerMathias DuggeliTaher YousafGerardus De Keyzer
    • Olof WallquistRoman LenzLeonhard FeilerMathias DuggeliTaher YousafGerardus De Keyzer
    • C07D487/02C08K5/00
    • C09B67/0033C09B57/004
    • The present invention relates to a process for the preparation of a mixture comprising at least two structurally different diketopyrrolopyrrole pigments of formula (1) wherein A1 and A2 are each independently of the other an aromatic or heteroaromatic radical, by reacting a succinic acid ester with at least one unsubstituted or substituted aromatic or heteroaromatic nitrile, which process comprises carrying out the reaction in the presence of at least one compound of formula (2) wherein A is an aromatic or heteroaromatic radical, R3 is hydrogen, halogen, methyl, methoxy, —CF3 or —CN, R4 is a linear or, from C3 upwards, optionally branched C1-C30alkyl, C6-C10aryl or C6-C24aralkyl radical, X is —S—, -0-, —CR5R5′—, —COO—, —CONR5—, —SO—, SO2—, —SO2NR5— or —NR5— and R5 and R5′ are each independently of the other hydrogen or a linear or, from C3 upwards, optionally branched C1-C30alkyl, C6-C10aryl or C6-C24aralkyl radical, to the use of such a mixture in the colouring of organic material and in cosmetics, and also to novel diketopyrrolopyrrole pigment mixtures.
    • 本发明涉及一种制备包含至少两种结构不同的式(1)二酮吡咯并吡咯颜料的混合物的方法,其中A 1和A 2各自独立地为 另一个是芳族或杂芳族基团,通过使琥珀酸酯与至少一种未取代或取代的芳族或杂芳族腈反应,该方法包括在至少一种式(2)的化合物存在下进行反应,其中A是 芳族或杂芳族基团,R 3是氢,卤素,甲基,甲氧基,-CF 3或-CN,R 4是直链或 ,C 3 - 从上至上,任选支链C 1 -C 3亚烷基,C 6 -C 10个芳基或C 6 -C 12亚芳基,X是-S-,-O-,-CR 5 R -COO - , - CONR 5 - , - SO - ,SO 2 - , - SO 2 - , - NR 5 - 或-NR 5 - 和R 5 - 和R 5 - 和R 5 - 各个独立于另一个氢或一个直链或者从3个以上的任选支链的C 1 -C 30 C 1 -C 6烷基,C 6 -C 10芳基或C 6 -C 24芳烷基,至 在有机材料和化妆品的着色中使用这种混合物,以及新型二酮吡咯并吡咯颜料混合物。
    • 4. 发明申请
    • Heat-stable diketopyrrolopyrrole pigment mixtures
    • 热稳定二酮吡咯并吡咯颜料混合物
    • US20080287689A1
    • 2008-11-20
    • US12218904
    • 2008-07-17
    • Olof WallquistRoman LenzLeonhard FeilerMathias DuggeliTaher YousafGerardus De Keyzer
    • Olof WallquistRoman LenzLeonhard FeilerMathias DuggeliTaher YousafGerardus De Keyzer
    • C07D487/04
    • C09B67/0033C09B57/004
    • The present invention relates to a process for the preparation of a mixture comprising at least two structurally different diketopyrrolopyrrole pigments of formula wherein A1 and A2 are each independently of the other an aromatic or heteroaromatic radical, by reacting a succinic acid ester with at least one unsubstituted or substituted aromatic or heteroaromatic nitrile, which process comprises carrying out the reaction in the presence of at least one compound of formula wherein A is an aromatic or heteroaromatic radical, R3 is hydrogen, halogen, methyl, methoxy, —CF3 or —CN, R4 is a linear or, from C3 upwards, optionally branched C1-C30alkyl, C6-C10aryl or C6-C24aralkyl radical, X is —S—, —O—, —CR5R5′—, —COO—, —CONR5—, —SO—, SO2—, —SO2NR5— or —NR5— and R5 and R5′ are each independently of the other hydrogen or a linear or, from C3 upwards, optionally branched C1-C30alkyl, C6-C10aryl or C6-C24aralkyl radical, to the use of such a mixture in the colouring of organic material and in cosmetics, and also to novel diketopyrrolopyrrole pigment mixtures.
    • 本发明涉及制备包含至少两种结构不同的下式的二酮吡咯并吡咯颜料的混合物的方法,其中A 1和A 2各自独立地为另一个 芳族或杂芳族基团,通过琥珀酸酯与至少一种未取代或取代的芳族或杂芳族腈反应,该方法包括在至少一种下式的化合物存在下进行反应其中A是芳族或杂芳族基,R 3是氢,卤素,甲基,甲氧基,-CF 3或-CN,R 4是线性的,或者是C 1 -C 3 - 3个以上,任选支链C 1 -C 30烷基,C 6 -C 10芳基 或C 6 -C 24芳烷基,X是-S-,-O-,-CR 5 R 5, -COO - , - CONR 5 - , - SO - ,SO 2 - , - SO 2 NR 2 - 5 - 或-NR 5 - 和R 5和R 5 - 各自独立地为另一个氢或直链或者从C 3向上,任选支链C 1 -C 30烷基, C 6 -C 12芳基或C 6 -C 24 - 芳烷基,使用这种混合物 在有机材料和化妆品的着色中,以及新型二酮吡咯并吡咯颜料混合物。
    • 5. 发明授权
    • Heat-stable diketopyrrolopyrrole pigment mixtures
    • 热稳定二酮吡咯并吡咯颜料混合物
    • US07417154B2
    • 2008-08-26
    • US10576703
    • 2004-10-04
    • Olof WallquistRoman LenzLeonhard FeilerMathias DüggeliTaher YousafGerardus De Keyzer
    • Olof WallquistRoman LenzLeonhard FeilerMathias DüggeliTaher YousafGerardus De Keyzer
    • C07D487/04C09B67/22
    • C09B67/0033C09B57/004
    • The present invention relates to a process for the preparation of a mixture comprising at least two structurally different diketopyrrolopyrrole pigments of formula (1) wherein A1 and A2 are each independently of the other an aromatic or heteroaromatic radical, by reacting a succinic acid ester with at least one unsubstituted or substituted aromatic or heteroaromatic nitrile, which process comprises carrying out the reaction in the presence of at least one compound of formula (2) wherein A is an aromatic or heteroaromatic radical, R3 is hydrogen, halogen, methyl, methoxy, —CF3 or —CN, R4 is a linear or, from C3 upwards, optionally branched C1-C30alkyl, C6-C10aryl or C6-C24aralkyl radical, X is —S—, —O—, —CR5R5′—, —COO—, —CONR5—, —SO—, SO2—, —SO2NR5— or —NR5— and R5 and R5′ are each independently of the other hydrogen or a linear or, from C3 upwards, optionally branched C1-C30alkyl, C6-C10aryl or C6-C24aralkyl radical, to the use of such a mixture in the coloring of organic material and in cosmetics, and also to novel diketopyrrolopyrrole pigment mixtures
    • 本发明涉及一种制备包含至少两种结构不同的式(1)二酮吡咯并吡咯颜料的混合物的方法,其中A 1和A 2各自独立地为 另一个是芳族或杂芳族基团,通过使琥珀酸酯与至少一种未取代或取代的芳族或杂芳族腈反应,该方法包括在至少一种式(2)的化合物存在下进行反应,其中A是 芳族或杂芳族基团,R 3是氢,卤素,甲基,甲氧基,-CF 3或-CN,R 4是直链或 ,C 3 - 从上至上,任选支链C 1 -C 3亚烷基,C 6 -C 10个芳基或C 6 -C 2 4芳烷基,X是-S-,-O-,-CR 5 R -COO - , - CONR 5 - , - SO - ,SO 2 - , - SO 2 - , - NR 5 - 或-NR 5 - 和R 5 - 和R 5 - 和R 5 - 各个独立于另一个氢或一个直链或者从3个以上的任选支链的C 1 -C 30 C 1 -C 6烷基,C 6 -C 10芳基或C 6 -C 24芳烷基,至 在有机材料和化妆品的着色中使用这样的混合物,以及新型二酮吡咯并吡咯颜料混合物
    • 6. 发明授权
    • Heat-stable diketopyrrolopyrrole pigment mixtures
    • 热稳定二酮吡咯并吡咯颜料混合物
    • US07786313B2
    • 2010-08-31
    • US12218904
    • 2008-07-17
    • Olof WallquistRoman LenzLeonhard FeilerMathias DüggeliTaher YousafGerardus De Keyzer
    • Olof WallquistRoman LenzLeonhard FeilerMathias DüggeliTaher YousafGerardus De Keyzer
    • C07D487/04C09B67/22
    • C09B67/0033C09B57/004
    • The present invention relates to a process for the preparation of a mixture comprising at least two structurally different diketopyrrolopyrrole pigments of formula wherein A1 and A2 are each independently of the other an aromatic or heteroaromatic radical, by reacting a succinic acid ester with at least one unsubstituted or substituted aromatic or heteroaromatic nitrile, which process comprises carrying out the reaction in the presence of at least one compound of formula wherein A is an aromatic or heteroaromatic radical, R3 is hydrogen, halogen, methyl, methoxy, —CF3 or —CN, R4 is a linear or, from C3 upwards, optionally branched C1-C30alkyl, C6-C10aryl or C6-C24aralkyl radical, X is —S—, —O—, —CR5R5′—, —COO—, —CONR5—, —SO—, SO2—, —SO2NR5— or —NR5— and R5 and R5′ are each independently of the other hydrogen or a linear or, from C3 upwards, optionally branched C1-C30alkyl, C6-C10aryl or C6-C24aralkyl radical, to the use of such a mixture in the coloring of organic material and in cosmetics, and also to novel diketopyrrolopyrrole pigment mixtures.
    • 本发明涉及制备包含至少两种结构不同的下式的二酮吡咯并吡咯颜料的混合物的方法,其中A1和A2各自独立地为芳族或杂芳族基团,琥珀酸酯与至少一种未取代的 或取代的芳族或杂芳族腈,该方法包括在至少一种下式化合物存在下进行反应其中A是芳族或杂芳族基,R 3是氢,卤素,甲基,甲氧基,-CF 3或-CN,R 4 C 1 -C 10烷基,C 6 -C 10芳基或C 6 -C 24芳烷基,X是-S-,-O-,-CR 5 R 5'-,-COO-,-CONR 5 - ,-SO- ,SO 2 - ,-SO 2 NR 5 - 或-NR 5 - 以及R 5和R 5'各自独立地为氢或直链或从C3向上任选支链的C 1 -C 30烷基,C 6 -C 10芳基或C 6 -C 24芳烷基, 这样的混合物在 有机材料和化妆品着色,以及新型二酮吡咯并吡咯颜料混合物。
    • 9. 发明申请
    • POLYSILOXANE ANTIMICROBIALS
    • 多晶硅抗微生物
    • US20110110998A1
    • 2011-05-12
    • US12309091
    • 2007-07-04
    • Sophie Marquais-BienewaldOlof WallquistAndrea PreussStewart Todd Elder
    • Sophie Marquais-BienewaldOlof WallquistAndrea PreussStewart Todd Elder
    • A01N55/10A01N25/34C07F7/18A01P1/00C09D5/14
    • C08G77/388A01N55/00
    • Disclosed are oligo- or polysiloxanes, which are characterized by containing at least 3, for example 4-3000, Si atoms in the main chain, and wherein at least one thereof is contained in a moiety of the formula (I) whose open bond of the O atom is linked to another Si atom of the oligo- or polysiloxane main chain, and whose open bond of the Si atom is linked either to another O atom of the oligo- or polysiloxane main chain or to R′1, where R1 and R′1 independently are C1-C10alkyl, R2 and R3 independently are C1-C18alkylene, X is a divalent spacer group selected from O, NR4, N(COR′5), CONR′4, OCONR′4;. Y is selected from OCOR5, NHCOR5, NHR4, COOR5, CONHR4, NR′4R4; R4 is selected from C6-C18 organic residues containing at least one aryl moiety; R′4 is as defined for R4; or is selected from H, C1-C20alkyl, C7-C20phenylalkyl, C4-C12cycloalkyl; R5 is R7—Z; R′5 is as defined for R5; or is selected from H, C1-C20alkyl, C7-C20phenylalkyl, C4-C12cycloalkyl; R7 is C1-C20alkylene, which may be interrupted by phenylene, C4-C12cycloalkylene, O, NR′4; or is unsubstituted or substituted phenylene or C4-C12cycloalkylene; Z is halogen or N+R8R8R10; R8, R9 and R10 independently are selected from C1-C20alkyl, C7-C20phenylalkyl, C4-C12cycloalkyl, unsubstituted or substituted aryl; or 2 of R8, R9 and R10 are linked together to form a quaternized aliphatic, substituted or unsubstituted N-heterocyclic ring of 4-6 carbon atoms such as a piperidine ring; or all of R8, R9 and R10 are linked together to form, together with the nitrogen atom they are bonding to, a substituted or unsubstituted N-heterocyclic ring system of 4-7 carbon atoms. The novel compounds are effective as antimicrobials.
    • 公开了低聚或聚硅氧烷,其特征在于在主链中含有至少3个,例如4-3000个Si原子,并且其中至少一个包含在式(I)的部分中,其开环键 O原子与低聚或聚硅氧烷主链的另一个Si原子连接,并且其Si原子的开环键连接到寡聚或聚硅氧烷主链的另一个O原子或R'1,其中R 1和 R 1独立地是C 1 -C 10烷基,R 2和R 3独立地是C 1 -C 18亚烷基,X是选自O,NR 4,N(COR'5),CONR 4,OCONR 4的二价间隔基。 Y选自OCOR5,NHCOR5,NHR4,COOR5,CONHR4,NR'4R4; R4选自含有至少一个芳基部分的C6-C18有机残基; R'4如R4所定义; 或选自H,C 1 -C 20烷基,C 7 -C 20苯基烷基,C 4 -C 12环烷基; R5为R7-Z; R'5如R5所定义; 或选自H,C 1 -C 20烷基,C 7 -C 20苯基烷基,C 4 -C 12环烷基; R 7是C 1 -C 20亚烷基,其可被亚苯基,C 4 -C 12亚环烷基,O,NR'4中间; 或未取代或取代的亚苯基或C 4 -C 12亚环烷基; Z为卤素或N + R8R8R10; R 8,R 9和R 10独立地选自C 1 -C 20烷基,C 7 -C 20苯基烷基,C 4 -C 12环烷基,未取代或取代的芳基; 或2的R 8,R 9和R 10连接在一起形成4-6个碳原子的季铵化的脂族,取代或未取代的N-杂环,例如哌啶环; 或全部R 8,R 9和R 10连接在一起,与它们所键合的氮原子一起形成取代或未取代的4-7个碳原子的N-杂环体系。 新型化合物作为抗微生物剂是有效的。