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1. 发明授权

US06531538B1 Fast-drying rendering and coating composition 失效
标题翻译：快干渲染和涂料组合物
公开(公告)号：US06531538B1
公开(公告)日：2003-03-11
申请号：US09518894
申请日：2000-03-06
申请人： Hans-Peter Weitzel , Harald Zeh , Peter Ball , Klaus Marquardt
发明人： Hans-Peter Weitzel , Harald Zeh , Peter Ball , Klaus Marquardt
IPC分类号： C08K300
CPC分类号： C09D157/00 , C04B41/4857 , C09D5/024 , C04B20/10 , C04B2103/008 , C04B41/4869 , C04B41/488 , C04B41/46 , C04B41/5007 , C04B41/5035 , C08L2666/14 , C08L2666/36
摘要： The invention relates to a fast-drying rendering and coating composition comprising a binder in the form of an aqueous polymer dispersion or of a water-redispersible polymer powder, and also an organic precipitant, if desired in combination with an inorganic precipitant.
摘要翻译：本发明涉及一种快干成型和涂料组合物，其包含水性聚合物分散体或水分散性聚合物粉末形式的粘合剂，如果需要，与无机沉淀剂组合，还包括有机沉淀剂。

2. 发明授权

US06740692B2 Solvent free coating compositions for soiling-resist ant facades 有权
标题翻译：无溶剂涂料组合物，用于防腐外墙
公开(公告)号：US06740692B2
公开(公告)日：2004-05-25
申请号：US10146853
申请日：2002-05-16
申请人： Hans-Peter Weitzel , Harald Zeh
发明人： Hans-Peter Weitzel , Harald Zeh
IPC分类号： C08L302
CPC分类号： C08B37/0015 , C08L5/16 , C09D133/06 , C08L2666/26 , C08L2666/28 , C08L2666/54
摘要： Solventlessly preparable coating compositions for producing soiling-resistant coatings, comprise: a) at least one film-forming polymer of one or more vinyl ester, (meth)acrylate, vinylaromatic, olefin, 1,3-diene, or vinyl halide monomers, and, if desired, further monomers copolymerizable therewith, in the form of an aqueous dispersion or water-redispersible powder, b) one or more photoinitiators and/or fungicides, c) at least one pigment, d) one or more fillers, and, if desired, e) further additives, wherein the photoinitiators and fungicides b) are in the form of complexes with cyclodextrin or its derivatives.
摘要翻译：用于生产耐污染涂料的无溶剂制备涂料组合物包括：a）至少一种成膜聚合物，其一种或多种乙烯基酯，（甲基）丙烯酸酯，乙烯基芳族化合物，烯烃，1,3-二烯烃或卤乙烯单体，和如果需要，可以以水分散体或水可再分散粉末的形式与其共聚的其它单体，b）一种或多种光引发剂和/或杀真菌剂，c）至少一种颜料，d）一种或多种填料，以及如果所需的e）其它添加剂，其中光引发剂和杀真菌剂b）与环糊精或其衍生物形成复合物。

3. 发明申请

US20050250899A1 Use of copolymers stabilized with a protective colloid in cement-free or low-cement coating materials 审中-公开
标题翻译：在无水泥或低水泥涂层材料中使用用保护胶体稳定的共聚物
公开(公告)号：US20050250899A1
公开(公告)日：2005-11-10
申请号：US11112778
申请日：2005-04-22
申请人： Andreas Bacher , Hans-Peter Weitzel , Franz Jodlbauer , Harald Zeh
发明人： Andreas Bacher , Hans-Peter Weitzel , Franz Jodlbauer , Harald Zeh
IPC分类号： C04B24/26 , C04B28/14 , C08F218/10 , C08L31/04 , C09D5/03 , C09D7/12 , C09D123/08 , C09D131/02 , C09D131/04 , C08L31/02
CPC分类号： C09D131/02 , C08L31/04 , C08L2666/04
摘要： The present invention relates to the use of copolymers stabilized with a protective colloid, in the form of their polymer powders redispersible in water or in the form of their aqueous polymer dispersions, in cement-free or low-cement coating materials, wherein the copolymer is obtainable by free radical polymerization, in water, of a) from 35 to 65% by weight of vinyl acetate, b) from 5 to 20% by weight of ethylene, c) from 40 to 70% by weight of vinyl esters of alpha-branched, tertiary monocarboxylic acids having 5 to 15 carbon atoms, and optionally d) from 0.1 to 10% by weight of further copolymerizable, ethylenically unsaturated comonomers, the data in % by weight totaling 100% by weight.
摘要翻译：本发明涉及在水泥或低水泥涂层材料中以保护胶体稳定的共聚物的形式，其聚合物粉末可再分散于水或其水性聚合物分散体形式，其中共聚物为可通过自由基聚合在水中获得a）35至65重量％的乙酸乙烯酯，b）5至20重量％的乙烯，c）40至70重量％的α-烯烃的乙烯基酯，具有5至15个碳原子的支链叔碳酸单羧酸，以及任选的d）0.1至10重量％的另外可共聚的烯键式不饱和共聚单体，其重量百分比为100重量％。

4. 发明授权

US06187861B1 Process for preparing crosslinkable binders 失效
标题翻译：制备可交联粘合剂的方法
公开(公告)号：US06187861B1
公开(公告)日：2001-02-13
申请号：US09285622
申请日：1999-04-03
申请人： Hans-Peter Weitzel , Harald Zeh
发明人： Hans-Peter Weitzel , Harald Zeh
IPC分类号： C08L2904
CPC分类号： C08L51/003 , C08F265/04 , C08F265/06 , C08L23/08 , C08L23/0853 , C08L33/04 , C08L2312/00 , C08L2666/04
摘要： A process is provided for preparing crosslinkable binders in the form of the aqueous dispersions by polymerizing vinyl ester-olefin copolymers in the presence of protective colloid, which comprises polymerizing vinyl ester-olefin copolymers having a Tg of less than −10° C. by emulsion polymerization in the presence of a protective colloid based on (meth)acrylate polymers comprising from 80 to 95% by weight, based on the overall weight of the polymer, of acrylates or methacrylates of aliphatic alcohols of 1 to 12 carbon atoms and from 5 to 20% by weight, based on the overall weight of the copolymer, of ethylenically unsaturated monocarboxylic or dicarboxylic acids, the latter copolymer having a glass transition temperature Tg of from 60 to 120° C., and, after the end of polymerization, introducing the crosslinkable groups by reacting the carboxyl groups of the (meth)acrylate polymers with ethylenically unsaturated compounds comprising functions suitable for esterifying the carboxyl group.
摘要翻译：提供一种通过在保护胶体存在下聚合乙烯基酯 - 烯烃共聚物来制备水性分散体形式的可交联粘合剂的方法，其包括通过乳液聚合Tg低于-10℃的乙烯基酯 - 烯烃共聚物在基于（甲基）丙烯酸酯聚合物的保护胶体存在下进行聚合，所述聚合物包含80至95重量％，基于聚合物的总重量，具有1至12个碳原子的脂族醇的丙烯酸酯或甲基丙烯酸酯和5至 20重量％，基于共聚物的总重量，烯键式不饱和一元羧酸或二羧酸，后一共聚物的玻璃化转变温度Tg为60至120℃，并且在聚合结束后，引入通过使（甲基）丙烯酸酯聚合物的羧基与烯键式不饱和化合物反应，包含适于酯化羧基的功能的交联基团 oup。

5. 发明授权

US06242512B1 Re-dispersible polymer powder and aqueous polymer dispersions obtainable therefrom 失效
标题翻译：可再分散聚合物粉末和可由其获得的聚合物水分散体
公开(公告)号：US06242512B1
公开(公告)日：2001-06-05
申请号：US09101661
申请日：1998-07-14
申请人： Reiner Figge , Harald Zeh , Rudolf Weissgerber
发明人： Reiner Figge , Harald Zeh , Rudolf Weissgerber
IPC分类号： C08J312
CPC分类号： C09D5/34 , C04B40/0042 , C04B2103/0057 , C08L33/02 , C08L35/00 , Y10S524/904 , Y10S525/934 , C04B22/062 , C04B24/26 , C04B24/2641 , C04B2103/0094 , C04B24/2664 , C08L2666/04
摘要： The invention provides a redispersible polymer powder based on a mixture of water-insoluble polymer and a water-soluble atomized protective colloid which can be de-activated through a pH change. In addition, the invention concerns aqueous dispersions that can be prepared with the polymer powder and the use of the polymer powder or its aqueous dispersions as a bonding agent in adhesives, plasters or paints.
摘要翻译：本发明提供基于水不溶性聚合物和水溶性雾化保护胶体的混合物的可再分散的聚合物粉末，其可以通过pH变化而被去活化。此外，本发明涉及可以用聚合物粉末制备的水性分散体以及聚合物粉末或其水分散体作为粘合剂，灰泥或油漆中的粘合剂的用途。

6. 发明申请

US20100303549A1 AQUEOUS PREPARATIONS OF POLYMER-MODIFIED SETTING ACCELERATORS, AND USE THEREOF IN THE CONSTRUCTION INDUSTRY 有权
标题翻译：聚合物改性加速器的水性制备及其在建筑行业的应用
公开(公告)号：US20100303549A1
公开(公告)日：2010-12-02
申请号：US12599982
申请日：2008-05-15
申请人： Klaus Bonin , Harald Zeh
发明人： Klaus Bonin , Harald Zeh
IPC分类号： E02B3/12 , C04B24/26 , B32B13/04
CPC分类号： C04B40/0039 , C04B2103/12 , C04B2111/00663 , C04B2111/00732 , C04B12/04 , C04B14/303 , C04B22/062 , C04B22/10 , C04B24/2652 , C04B2103/404
摘要： The invention relates to aqueous preparations of polymer-modified setting accelerators, said preparations being characterised in that at least one setting accelerator and at least one cationically stabilised polymer are contained therein.
摘要翻译：本发明涉及聚合物改性凝固促进剂的水性制剂，所述制剂的特征在于其中含有至少一种凝固促进剂和至少一种阳离子稳定的聚合物。

7. 发明授权

US06863985B2 Hydrophobicized copolymers 有权
标题翻译：疏水共聚物
公开(公告)号：US06863985B2
公开(公告)日：2005-03-08
申请号：US10271881
申请日：2002-10-16
申请人： Kurt Stark , Harald Zeh , Klaus Bueppelmann
发明人： Kurt Stark , Harald Zeh , Klaus Bueppelmann
IPC分类号： C08F220/12 , B32B9/04 , C08F30/08
CPC分类号： C08F220/12 , Y10T428/31663
摘要： Functionalized copolymers hydrophobicized with silicones, in the form of aqueous dispersions or water-redispersible powders are prepared by copolymerizing a) from 60 to 99.89% by weight of one or more monomers selected from the group consisting of vinyl esters of optionally branched C1-15 alkylcarboxylic acids, methacrylates and acrylates of C1-15 alcohols, vinylaromatics, olefins, dienes, and vinyl halides, b) from 0.01 to 30% by weight of one or more silicones with from 10 to 1,000 SiO(CnH2n+1)2 repeat units where n is from 1 to 6, and where from 90 to 100% by weight of the silicones b) contain at least one but not more than two polymerizable groups, c) from 0.05 to 5.0% by weight of one or more hydrolyzable silane monomers selected from the group consisting of ethylenically unsaturated hydrolyzable silicon compounds, and hydrolyzable epoxysilanes, aminosilanes and mercaptosilanes, and d) from 0.05 to 5.0% by weight of one or more monomers selected from the group consisting of ethylenically unsaturated epoxy compounds. The copolymers may be used as binders for paints and coatings with high wet abrasion resistance.
摘要翻译：用水分散体或水可再分散粉末形式的硅氧烷疏水化的官能化共聚物通过以下方法制备：a）将60至99.89重量％的一种或多种选自任选支化的C 1-15烷基羧酸的乙烯基酯的单体，C1-15醇，乙烯基芳烃，烯烃，二烯和卤乙烯的甲基丙烯酸酯和丙烯酸酯，b）0.01至30重量％的一种或多种具有10至1,000个SiO（C n H 2n + 1）2重复单元的硅氧烷，其中n 为1至6，其中90至100重量％的硅氧烷b）含有至少1个但不多于2个可聚合基团，c）0.05至5.0重量％的一种或多种可水解硅烷单体，其选自由烯键式不饱和可水解硅化合物组成的组和可水解的环氧硅烷，氨基硅烷和巯基硅烷，和d）0.05-5.0重量％的一种或多种选自乙烯基 lly不饱和环氧化合物。共聚物可用作具有高耐湿磨性的油漆和涂料的粘合剂。

8. 发明授权

US08957137B2 Acid-resistant, hydraulically setting masses 有权
标题翻译：耐酸，液压设置质量
公开(公告)号：US08957137B2
公开(公告)日：2015-02-17
申请号：US13141289
申请日：2009-12-15
申请人： Harald Zeh , Jörgen Bezler , Stefan Bonimeier , Armin Hoffman , Hermann Lutz
发明人： Harald Zeh , Jörgen Bezler , Stefan Bonimeier , Armin Hoffman , Hermann Lutz
IPC分类号： C04B24/26 , C08K3/00 , C04B28/08 , C04B14/14 , C04B24/42 , C04B24/08 , C04B103/00 , C04B111/23
CPC分类号： C04B28/08 , C04B14/14 , C04B24/08 , C04B24/26 , C04B24/42 , C04B2103/0052 , C04B2111/23
摘要： The invention relates to acid-resistant, hydraulically setting masses based on a) slag sand, b) one or more pozzolanas, c) one or more fillers, d) one or more polymers based on ethylenically unsaturated monomers, and water.
摘要翻译：本发明涉及基于a）渣砂，b）一种或多种火山灰，c）一种或多种填料，d）一种或多种基于烯属不饱和单体的聚合物和水的耐酸，水硬性固化物质。

9. 发明授权

US06573326B2 Thickeners based on vinyl alcohol copolymers 失效
公开(公告)号：US06573326B2
公开(公告)日：2003-06-03
申请号：US09925912
申请日：2001-08-09
申请人： Theo Mayer , Werner Bauer , Harald Zeh , Bernd Kayser , Andreas Bacher , Ulf Dietrich
发明人： Theo Mayer , Werner Bauer , Harald Zeh , Bernd Kayser , Andreas Bacher , Ulf Dietrich
IPC分类号： C08K300
CPC分类号： C08F8/12 , C08F218/08 , C08F218/12 , C08F218/10 , C08F220/14 , C08F2220/1858
摘要： The invention relates to thickeners based on fully or partially hydrolyzed vinyl alcohol copolymers with a molecular weight Mw greater than 100,000, obtainable by hydrolyzing vinyl acetate copolymers which, besides vinyl acetate units, also contain comonomer units which derive from one or more comonomers selected from the group consisting of 1-(C1-5)-alkylvinyl esters of C1-5 carboxylic acids, allyl esters, vinyl esters of alpha-branched C5-12 carboxylic acids, and C1-18-alkyl (meth)acrylates, in the form of their aqueous solution or in powder form.

10. 发明授权

US09242904B2 Aqueous preparations of polymer-modified setting accelerators, and use thereof in the construction industry 有权
标题翻译：聚合物改性固化促进剂的水性制剂及其在建筑行业中的应用
公开(公告)号：US09242904B2
公开(公告)日：2016-01-26
申请号：US12599982
申请日：2008-05-15
申请人： Klaus Bonin , Harald Zeh
发明人： Klaus Bonin , Harald Zeh
IPC分类号： C04B24/26 , C04B40/00 , C04B103/12 , C04B111/00
CPC分类号： C04B40/0039 , C04B2103/12 , C04B2111/00663 , C04B2111/00732 , C04B12/04 , C04B14/303 , C04B22/062 , C04B22/10 , C04B24/2652 , C04B2103/404
摘要： The invention relates to aqueous preparations of polymer-modified setting accelerators, said preparations being characterized in that at least one setting accelerator and at least one cationically stabilized polymer are contained therein.
摘要翻译：本发明涉及聚合物改性凝固促进剂的水性制剂，所述制剂的特征在于其中含有至少一种凝固促进剂和至少一种阳离子稳定的聚合物。

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