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    • 1. 发明授权
    • Low-pill, low-flammability polyesters, production thereof and structures
formed therefrom
    • 低丸,低可燃性聚酯,其生产和由其形成的结构
    • US5494993A
    • 1996-02-27
    • US296105
    • 1994-08-25
    • Volker FreudenbergerPeter KleinHans-Jerg Kleiner
    • Volker FreudenbergerPeter KleinHans-Jerg Kleiner
    • C08G63/68C08G63/692C08G63/695D01F6/84C08G79/02
    • D01F6/84C08G63/6922C08G63/6926C08G63/6952C08G63/6956Y10T442/696
    • Described are low-pill, low-flammability linear fiber-forming polyesters formed from dicarboxylic acid and diol components, which polyesters contain in their polymer chain modifying units formed by esterification or transesterification from compounds of the formulae I and/or II and/or III ##STR1## where R.sup.1 and R.sup.2 are identical or different and each is a univalent aliphatic, araliphatic or aromatic hydrocarbon radical having 1 to 12 carbon atoms, orR.sup.1 and R.sup.2 are together a bivalent aliphatic, araliphatic or aromatic radical,R.sup.3 is an (n+1)-valent organic radical,A is a group capable of ester formation, n is an integer from 1 to 3,R.sup.4 and R.sup.5 are identical or different and each is hydrogen or a univalent aliphatic, araliphatic or aromatic hydrocarbon radical having 1 to 12 carbon atoms,y is an integer from 1 to 10,R.sup.6 is hydrogen or a univalent aliphatic, araliphatic or aromatic hydrocarbon radical having 1 to 12 carbon atoms, and the index z is 0 or an integer from 1 to 2*i and the index i is a sufficiently small integer. Also described are processes for producing these polyesters and their use.
    • 描述了由二羧酸和二醇组分形成的低丸,低可燃性线性纤维形成聚酯,该聚酯在其通过式I和/或II和/或III的化合物的酯化或酯交换形成的聚合物链修饰单元中含有 R 2是相同或不同的,并且各自是具有1至12个碳原子的单价脂肪族,芳脂族或芳族烃基,或者R 1和R 2一起是二价脂族,芳脂族或芳族基团,R 3是(n + 1) )价有机基团,A是能够形成酯的基团,n是1至3的整数,R4和R5相同或不同,各自是氢或具有1至12个碳原子的一价脂族,芳脂族或芳族烃基 原子,y为1至10的整数,R6为氢或具有1至12个碳原子的单价脂族,芳脂族或芳族烃基,并且指数z为0或1至2 * i的整数,并且指数i 是一样 足够小的整数。 还描述了生产这些聚酯的方法及其用途。
    • 2. 发明授权
    • Process for preparing phosphorus-containing dicarboxylic acids alkyl
esters thereof
    • 制备含磷二羧酸烷基酯的方法
    • US5693842A
    • 1997-12-02
    • US711736
    • 1996-09-05
    • Hans-Jerg KleinerVolker FreudenbergerPeter Klein
    • Hans-Jerg KleinerVolker FreudenbergerPeter Klein
    • C07F9/32C07F9/53C07F9/6571C07F9/6574C07F9/02
    • C07F9/657172C07F9/3211C07F9/5304
    • The invention relates to a process for preparing phosphorus-containing compounds of the formula I ##STR1## in which R.sup.1 and R.sup.2 are an alkyl radical having 1 to 8 carbon atoms, a cyclohexyl radical, a cyclopentyl radical, an aryl radical or a halogen-, alkyl- or alkoxy-substituted aryl radical, where R.sup.1 and R.sup.2 together with the phosphorus atom can also form a ring, n and m=0 or 1 and R.sup.3 and R.sup.4 are alkyl radicals having 1 to 4 carbon atoms or n=0, m=0 or 1 and R.sup.3 and R.sup.4 are H, by adding compounds of the formula II ##STR2## into dialkyl esters of fumaric acid or of maleic acid of the formula (III) or dialkyl esters of itaconic acid of the formula (IV) ##STR3## in which R.sup.3 and R.sup.4 have the meaning given above, and, optionally reacting an alkyl ester of a phosphorus-containing dicarboxylic acid of the formula (I), where n=0, with water in the presence of catalytic amounts of an acid to give the phosphorus-containing dicarboxylic acid.
    • 本发明涉及制备具有1至8个碳原子的式I的含磷化合物的方法,环己基,环戊基,芳基或卤素,烷基或烷氧基取代的芳基,其中 R 1和R 2与磷原子一起也可以形成环,n和m = 0或1,并且R 3和R 4是具有1至4个碳原子的烷基或n = 0,m = 0或1,并且R 3和R 4是H 通过将式II的化合物(II)加入到富马酸的二烷基酯或式(III)的马来酸或式(IV)的衣康酸的二烷基酯中。 >,并且在催化量的酸存在下,任选使式(I)的含磷二羧酸的烷基酯(其中n = 0)与水反应,得到含磷二羧酸。