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1. 发明授权

US4721608A Spheroidal alkali metal polyphosphates of low apparent density, and process for making them 失效
标题翻译：低密度的球状碱金属多磷酸盐及其制备方法
公开(公告)号：US4721608A
公开(公告)日：1988-01-26
申请号：US847485
申请日：1986-04-03
申请人： Werner Kowalski , Hans Haas , Theo Dahmen , Markus Erpenbach
发明人： Werner Kowalski , Hans Haas , Theo Dahmen , Markus Erpenbach
IPC分类号： B01D1/18 , C01B25/41 , C01B15/16 , C01B25/26
CPC分类号： B01D1/18 , C01B25/412
摘要： Alkali metal polyphosphates consisting substantially of hollow spheroidal particles with an apparent density of less than 350 g/l are made. To this end, an alkali metal orthophosphate solution is forced under a pressure of 6-40 bars into a fluidization zone; the orthophosphate solution is fluidized in the fluidization zone by injecting a finely dispersed permanent gas maintained under a pressure higher than the orthophosphate solution; and the fluidized orthophosphate solution is sprayed with the aid of a plurality of single medium nozzles arranged downstream of the fluidization zone through a flame zone peoduced inside the spray tower. Apparatus for carrying out the process.
摘要翻译：制成基本上由表观密度小于350g / l的中空球状颗粒组成的碱金属多磷酸盐。为此，在6-40巴的压力下将碱金属正磷酸盐溶液压入流化区; 通过注入保持在高于正磷酸盐溶液的压力下的细分散的永久气体，在流化区中流化正磷酸盐溶液; 并且借助于布置在流化区下游的多个单一介质喷嘴通过喷雾塔内部的火焰区喷射流化的正磷酸盐溶液。用于执行该过程的装置。

2. 发明授权

US4454054A Sodium tripolyphosphate, process for making it, and its use 失效
标题翻译：三聚磷酸钠，其制备方法及其用途
公开(公告)号：US4454054A
公开(公告)日：1984-06-12
申请号：US399756
申请日：1982-07-19
申请人： Herbert Landgraber , Werner Kowalski , Johan Scheffer , Hans Haas
发明人： Herbert Landgraber , Werner Kowalski , Johan Scheffer , Hans Haas
IPC分类号： C01B25/41 , C11D3/06 , C11D11/02 , C01B25/30 , C01B25/40
CPC分类号： C11D11/02 , C01B25/412 , C01B25/418 , C11D3/062
摘要： The disclosure relates to sodium tripolyphosphate containing up to 95 weight % phase-I, 0.1 to 22 weight % water of crystallization and 0.01 to 2.0 weight %, calculated as metal, of a compound of the metals selected from calcium, magnesium, zinc or strontium, the compound yielding ions in an aqueous medium. The disclosure also relates to a process for making the tripolyphosphate, and to its uses.
摘要翻译：本公开内容涉及含有多达95重量％的相I，0.1至22重量％的结晶水和0.01至2.0重量％的以金属计算的选自钙，镁，锌或锶的金属化合物的三聚磷酸钠，在水性介质中产生离子的化合物。本公开还涉及制备三聚磷酸盐的方法及其用途。

3. 发明授权

US4391783A Process for making abrasion-resistant sodium tripolyphosphate 失效
标题翻译：制造耐磨三聚磷酸钠的方法
公开(公告)号：US4391783A
公开(公告)日：1983-07-05
申请号：US356023
申请日：1982-03-08
申请人： Hans Haas , Werner Kowalski
发明人： Hans Haas , Werner Kowalski
IPC分类号： C01B25/41 , C01B15/16 , C01B25/26
CPC分类号： C01B25/412
摘要： The disclosure relates to a process for making granular sodium tripolyphosphate of high abrasion resistance. To this end, the disclosure provides for sodium orthophosphate to be subjected to a one-stage spray-drying operation inside a heated spray tower by means of a nozzle with condensation of the orthophosphate. More particularly the orthophosphate is sprayed jointly with a solution of a high molecular weight phosphate of sodium, potassium or ammonium.
摘要翻译：本公开涉及一种制备高耐磨性的三聚磷酸钠的方法。为此，本公开提供了正磷酸钠在加热喷雾塔内通过正磷酸盐缩合的喷嘴进行一级喷雾干燥操作。更具体地，正磷酸盐与钠，钾或铵的高分子量磷酸盐溶液一起喷雾。

4. 发明授权

US4777025A Process for making phosphorus pentoxide of diminished reactivity 失效
标题翻译：五氧化二磷的反应性降低的方法
公开(公告)号：US4777025A
公开(公告)日：1988-10-11
申请号：US37985
申请日：1987-04-13
申请人： Werner Kowalski , Theo Dahmen , Hans Haas , Gunther Schimmel
发明人： Werner Kowalski , Theo Dahmen , Hans Haas , Gunther Schimmel
IPC分类号： C01B25/12
CPC分类号： C01B25/12
摘要： Hexagonal phosphorus pentoxide of diminished reactivity is made by burning liquid yellow phosphorus with a mixture of dry air and pure oxygen inside a combustion zone with the resulting formation of a gas stream containing phosphorus pentoxide; next, the gas stream coming from the combustion zone is passed initially through an intermediary zone indirectly cooled by means of fluidized matter and then through a condensing zone fitted with an immersion tube indirectly cooled by means of fluidized matter; the gas stream is passed through the immersion tube at a mean temperature of 450.degree. to 600.degree. C. and allowed to remain in the immersion tube over a period of 2 to 5 seconds.
摘要翻译：通过在燃烧区内用干燥空气和纯氧的混合物燃烧液体黄磷，形成含有五氧化二磷的气流，从而产生反应性降低的六
价五氧化二磷。接下来，来自燃烧区的气流首先通过间接通过流化物质冷却的中间区，然后通过装配有通过流化物质间接冷却的浸入管的冷凝区; 气流在450〜600℃的平均温度下通过浸入管，并在2〜5秒的时间内保持在浸入管内。

5. 发明授权

US4968490A Spheroidal alkali metal polyphosphates of low apparent density, and apparatus for making them 失效
标题翻译：低密度的球状碱金属多磷酸盐及其制造方法
公开(公告)号：US4968490A
公开(公告)日：1990-11-06
申请号：US74096
申请日：1987-07-16
申请人： Werner Kowalski , Hans Haas , Theo Dahmen , Markus Erpenbach
发明人： Werner Kowalski , Hans Haas , Theo Dahmen , Markus Erpenbach
IPC分类号： B01D1/18 , C01B25/41
CPC分类号： B01D1/18 , C01B25/412
摘要： Alkali metal polyphosphates consisting substantially of hollow spheroidal particles with an apparent density of less than 350 g/l are made. To this end, an alkali metal orthophosphate solution is forced under a pressure of 6-40 bars into a fluidization zone; the orthophosphate solution is fluidized in the fluidization zone by injecting a finely dispersed permanent gas maintained under a pressure higher than the orthophosphate solution; and the fluidized orthophosphate solution is sprayed with the aid of a plurality of single medium nozzles arranged downstream of the fluidization zone through a flame zone produced inside the spray tower. Apparatus for carrying out the process.

6. 发明授权

US4800055A Process for making a granular product containing sodium triphosphate 失效
标题翻译：制备含三磷酸钠的颗粒产品的方法
公开(公告)号：US4800055A
公开(公告)日：1989-01-24
申请号：US835894
申请日：1986-03-04
申请人： Helmut Klee , Hans Haas , Werner Kowalski , Theo Dahmen
发明人： Helmut Klee , Hans Haas , Werner Kowalski , Theo Dahmen
IPC分类号： B01J2/22 , C01B25/41 , C11D3/06 , C11D11/00 , C01B25/30
CPC分类号： C11D3/062 , C01B25/418
摘要： A granular hydrated product consisting completely or partially of sodium triphosphate for use in detergent and cleaning compositions is made. To this end, pulverulent sodium triphosphate containing less than 22 wgt % water is compacted by initially mixing it with a quantity of water sufficient for hydrating at most 100% of the sodium triphosphate to the hexahydrate and then continuously admitting the resulting mixture to a zone inside which it is made into solid matter under pressure.
摘要翻译：制备用于洗涤剂和清洁组合物的完全或部分由三磷酸钠组成的颗粒状水合产品。为此，含有少于22重量％水的粉状三水磷酸钠通过最初将其与足以使至多100％的三磷酸钠水合至六水合物的量的水进行压实，然后将所得混合物连续进入内部区域它在压力下被制成固体物质。

7. 发明授权

US4717557A Spheroidal alkali metal polyphosphates of low apparent density, and process for making them 失效
标题翻译：低密度的球状碱金属多磷酸盐及其制备方法
公开(公告)号：US4717557A
公开(公告)日：1988-01-05
申请号：US847492
申请日：1986-04-03
申请人： Werner Kowalski , Hans Haas , Theo Dahmen , Markus Erpenbach
发明人： Werner Kowalski , Hans Haas , Theo Dahmen , Markus Erpenbach
IPC分类号： B01D1/18 , C01B25/41 , C01B15/16 , C01B25/26
CPC分类号： C01B25/412 , B01D1/18
摘要： Alkali metal polyphosphates consisting substantially of hollow spheroidal particles with an apparent density of less than 320 g/l are made. To this end, an aqueous alkali metal orthophosphate solution and an aqueous solution of an inflating agent are simultaneously forced under a pressure of 6-40 bars into a fluidization zone; the two solutions are fluidized in the fluidization zone by injecting a finely dispersed permanent gas maintained under a pressure higher than the two solutions and the fluidized solutions are sprayed with the aid of a plurality of single medium nozzles arranged downstream of the fluidization zone through a flame zone produced inside the spray tower. Apparatus for carrying out the process.
摘要翻译：制成基本上具有小于320g / l的表观密度的中空球状颗粒的碱金属多磷酸盐。为此，在6-40巴的压力下同时迫使碱金属正磷酸盐水溶液和充气剂的水溶液进入流化区; 通过注入保持在高于两种溶液的压力下的细分散的永久气体，借助于布置在流化区下游的多个单一介质喷嘴通过火焰喷射流化溶液，两种溶液在流化区中流化在喷雾塔内产生的区域。用于执行该过程的装置。

8. 发明授权

US4534946A Process for making alkali metal polyphosphates 失效
标题翻译：制备碱金属多磷酸盐的方法
公开(公告)号：US4534946A
公开(公告)日：1985-08-13
申请号：US558777
申请日：1983-12-06
申请人： Ben Damman , Hans Scheffer , Paul de Witte , Johannes Krause , Hans Haas , Werner Kowalski
发明人： Ben Damman , Hans Scheffer , Paul de Witte , Johannes Krause , Hans Haas , Werner Kowalski
IPC分类号： B01J19/24 , B01J19/26 , C01B25/41 , C01B25/30
CPC分类号： C01B25/414 , B01J19/2465 , B01J19/26 , B01J2208/00 , B01J2219/00105 , B01J2219/00121 , B01J2219/00157
摘要： The disclosure relates to a process for making alkali metal polyphosphates, especially alkali metal triphosphates. To this end, the disclosure provides for an alkali metal phosphate solution or suspension to be forced through at least one nozzle and for them to be sprayed inside a spray tower through a flame zone produced by a one or more burners arranged in annular fashion. More particularly, the disclosure provides for fine particulate alkali metal polyphosphates, especially alkali metal triphosphates, to be additionally introduced into the spray tower from above and for them to be regularly distributed across the spray region(s) of the nozzle(s) with formation of agglomerated products.The disclosure also relates to an apparatus for carrying out the process. The apparatus is comprised of a cylindrical spray tower (1) having a tapered lower end (3) and being closed by means of a cover (2); a spray means (6) being passed centrally through the cover (2); a plurality of burners (11) and a solid matter feed means being passed through the cover concentrically with respect to the spray means (6) and so as to be spaced therefrom; and a bevelled issuing gas outlet (4) opening upwardly from the tapered end of the spray tower (1).
摘要翻译：本公开涉及制备碱金属多磷酸盐，特别是碱金属三磷酸盐的方法。为此，本公开内容提供了要强制通过至少一个喷嘴的碱金属磷酸盐溶液或悬浮液，并且它们通过由环形方式布置的一个或多个燃烧器产生的火焰区喷射在喷雾塔内。更具体地，本公开内容提供细颗粒碱金属多磷酸盐，特别是碱金属三磷酸盐，从上方另外引入喷雾塔，并且它们被规则地分布在喷嘴的喷射区域之间，形成的附聚产品。本公开还涉及一种用于执行该过程的装置。该装置由具有锥形下端（3）并通过盖（2）封闭的圆柱形喷射塔（1）组成; 喷雾装置（6）通过所述盖（2）中心地通过; 多个燃烧器（11）和固体物质进料装置相对于喷射装置（6）同心地穿过盖子并与其间隔开; 以及从喷雾塔（1）的锥形端部向上开口的倾斜的发出气体出口（4）。

9. 发明申请

US20050105954A1 Gelled composition applicator 有权
标题翻译：凝胶组合物涂布器
公开(公告)号：US20050105954A1
公开(公告)日：2005-05-19
申请号：US10966260
申请日：2004-10-15
申请人： Hans Haas , Marcia Snyder , Thomas Polatas , Robert Harmacek
发明人： Hans Haas , Marcia Snyder , Thomas Polatas , Robert Harmacek
IPC分类号： A46B11/00 , A46B17/02 , A61J20060101 , B05C17/005 , B43K23/12 , B67D7/06
CPC分类号： B05C17/00503 , B43M11/08
摘要： An adhesive composition applicator includes a housing having sidewalls and a neck that tapers to an opening. The housing encloses a gelled adhesive composition. The housing has a cross-sectional area and the opening has a cross-sectional area less than that of the housing cross-sectional area. A cap is provided that engages the housing. A mechanism is provided for urging the gelled composition material from the housing through the opening. The neck optionally also includes a shield to prevent gelled adhesive composition from running down the neck and provides a barrier against gelled adhesive smear reaching the point of intersection between the cap and the housing. To facilitate application of gelled composition to a point of application, a spatula is provided adjacent to the opening.
摘要翻译：粘合剂组合物施用器包括具有侧壁和颈部的壳体，该颈部朝向开口逐渐变细。外壳包封凝胶粘合剂组合物。壳体具有横截面积，并且开口的横截面面积小于壳体横截面积的横截面面积。提供与壳体接合的盖。提供了一种机构，用于通过开口将凝胶化的组合物材料从壳体推动。颈部任选地还包括屏蔽件，以防止凝胶化的粘合剂组合物沿着颈部向下运动，并提供阻挡胶粘剂涂抹物的屏障，到达帽和壳体之间的交点。为了便于将凝胶化的组合物施用于施用点，在开口附近提供刮刀。

10. 发明授权

US07204570B2 Refrigerator for bottles 有权
公开(公告)号：US07204570B2
公开(公告)日：2007-04-17
申请号：US10801965
申请日：2004-03-15
申请人： Roland Benitsch , Rainer Brachert , Hans Haas , Christian Mayershofer
发明人： Roland Benitsch , Rainer Brachert , Hans Haas , Christian Mayershofer
IPC分类号： A47B96/02
CPC分类号： F25D31/007 , F25D25/024 , F25D2325/023 , F25D2331/803 , F25D2400/08
摘要： A refrigerator includes a housing having a cooled interior space. At least one drawer is disposed in the interior space for storing bottles in an inclined or horizontal position. The drawer has a frame with two opposite sides. The drawer also has a plurality of rods to be releasably mounted parallel to and spaced apart from one another between the two opposite sides of the frame at selectable distances from one another.

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