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1. 发明授权

US4477498A Process for the production of perfluoroalkyl residue containing condensation products, the condensation products prepared accordingly, and their use 失效
标题翻译：生产含有缩合产物的全氟烷基残基的方法，相应制备的缩合产物及其用途
公开(公告)号：US4477498A
公开(公告)日：1984-10-16
申请号：US408084
申请日：1982-08-13
申请人： Hans Deiner , Franz Mosch , Bernhard Sandner , Willy Bernheim
发明人： Hans Deiner , Franz Mosch , Bernhard Sandner , Willy Bernheim
IPC分类号： C07D251/70 , D06M13/02 , D06M13/248 , D06M13/252 , D06M13/322 , D06M13/35 , D06M13/355 , D06M13/358 , B05D3/02
CPC分类号： C07D251/70
摘要： The present invention relates to new condensation products of(A) 1 mole of a highly etherified hexamethylol melamine and(B) 3 to 6 moles of a thiol of the formulaR.sub.f --X--SH, (1) Rf standing for perfluorinated alkyl with 4 to 14 C-atoms and X for divalent ethylene or isopropylene radicals, wherein the components (A) and (B) are reacted under increasing temperature up to at least 145.degree. C. within a period of at least 40 minutes.In form of their aqueous dispersions, the condensation products are suitable for oil- and water-repellent finishing of fibrous, preferably textile materials.
摘要翻译：本发明涉及（A）1摩尔高度醚化的六羟甲基三聚氰胺和（B）3至6摩尔式Rf-X-SH的硫醇的新的缩合产物，（1）Rf代表全氟烷基与4 至14个碳原子，X为二价乙烯或异丙烯基，其中组分（A）和（B）在至少40分钟的时间内在升高的温度下反应至多至145℃。以其水分散体的形式，缩合产物适用于纤维，优选纺织材料的防油和防水整理。

2. 发明授权

US4834764A Process for obtaining wash-and cleaning resistant textile finishes with reactive perfluoroalkyl-containing (co) polymers and/or precondensates and a blocked isocyanate compound 失效
标题翻译：具有反应性全氟烷基（共）聚合物和/或预缩合物和封端异氰酸酯化合物的洗涤和清洁抗纺织品整理剂的方法
公开(公告)号：US4834764A
公开(公告)日：1989-05-30
申请号：US124339
申请日：1987-11-20
申请人： Hans Deiner , Bernhard Sandner , Franz Mosch , Willy Bernheim
发明人： Hans Deiner , Bernhard Sandner , Franz Mosch , Willy Bernheim
IPC分类号： C08G18/62 , D06M15/295 , D06M15/576
CPC分类号： D06M15/295
摘要： The present invention relates to a process for obtaining wash- and cleaning-resistant textile finishes by impregnating with customary reactive perfluoroalkyl-containing (co)polymers and/or precondensates in aqueous dispersion and concluding heating, wherein the dispersions have NCO-containing compounds which have a molecular weight of at least 450 and/or contain a diphenylmethane-based polyisocyanate mixture in blocked form.The process according to the invention has made it possible to equip textiles with water-repellant and oil-repellant finishes which are very highly wash- and cleaning-resistant.
摘要翻译：本发明涉及一种通过在含水分散体和结束加热中用常规含反应性全氟烷基（共）聚合物和/或预缩合物浸渍来获得耐洗涤和抗清洁的纺织品整理剂的方法，其中分散体具有含有NCO的化合物，其具有至少450的分子量和/或含有封闭形式的二苯基甲烷基多异氰酸酯混合物。根据本发明的方法使得纺织品具有非常高的耐洗涤和耐清洗性的防水和防油涂层成为可能。

3. 发明授权

US3949136A Fluorine-containing organopolysiloxanes, process for their use 失效
标题翻译：含氟有机聚硅氧烷，其使用方法
公开(公告)号：US3949136A
公开(公告)日：1976-04-06
申请号：US561511
申请日：1975-03-24
申请人： Hans Deiner , Franz Mosch , Bernhard Sandner , Willy Bernheim
发明人： Hans Deiner , Franz Mosch , Bernhard Sandner , Willy Bernheim
IPC分类号： C08G77/392 , D06M15/657 , D06M13/08 , D06M15/66
CPC分类号： D06M15/657 , C08G77/392 , Y10T428/31544 , Y10T428/31663 , Y10T442/2172
摘要： New fluorine-containing organopolysiloxanes are provided which are obtained by reaction in known manner of organopolysiloxanes which contain hydrogen atoms bonded to silicon, a perfluoroalkyl compound for the formulaR.sub.f -- SO.sub.2 -- NH -- CH.sub.2 -- CH = CH.sub.2wherein R.sub.f represents perfluoroalkyl with 6 to 14 carbon atoms, and optionally a fluorine-free vinyl monomer. These new addition products are useful as oil- and water repellents for fibrous textile materials.
摘要翻译：提供新的含氟有机聚硅氧烷，其通过以已知方式与含有与硅键合的氢原子的有机聚硅氧烷反应获得，式Rf-SO 2 -NH-CH 2 -CH = CH 2的全氟烷基化合物，其中Rf表示具有6至14个全氟烷基碳原子和任选的无氟乙烯基单体。这些新添加的产品可用作纤维纺织材料的防油和防水剂。

4. 发明授权

US4113947A Addition products of an N-allylamino-s-triazine and an organopolysiloxane 失效
标题翻译： N-亚甲基-3-三嗪和有机硅氧烷的添加产物
公开(公告)号：US4113947A
公开(公告)日：1978-09-12
申请号：US554819
申请日：1975-03-03
申请人： Hans Deiner , Franz Mosch , Willy Bernheim
发明人： Hans Deiner , Franz Mosch , Willy Bernheim
IPC分类号： C08G77/00 , C08G77/06 , C08G77/22 , C08G77/28 , C08G77/38 , C08G77/388 , D06M15/643 , C07D251/48 , C07D251/70
CPC分类号： C08G77/388 , D06M15/6436 , Y10T442/218 , Y10T442/223
摘要： The invention provides a process for the manufacture of addition products from nitrogen containing compounds which contain at least one ethylenically unsaturated radical and organopolysiloxanes which contain hydrogen atoms bonded to silicon, and a process for treating fibrous materials with the resultant addition product composition. The process comprises adding to the organopolysiloxanes allylmelamines, allylguanamines, monoallyl- or diallylureas, monoallyl- or diallylthioureas or cyclic urea derivatives which contain at least one ethylenically unsaturated radical. The addition is carried out in the presence of methylolated aminoplast formers which can also be etherified with lower alcohols, or in the presence of the cited unsaturated compounds in their methylolated form. The unsaturated compounds can also be used direct in methylolated and etherified form. The resultant addition products are used in an aqueous emulsion or an organic solvent for the treatment of fibrous materials. The treated materials are provided with a good wash-resistent water repellent finish.

5. 发明授权

US4153640A Modified polysiloxanes and process of preparing them 失效
标题翻译：改性聚硅氧烷及其制备方法
公开(公告)号：US4153640A
公开(公告)日：1979-05-08
申请号：US774161
申请日：1977-03-03
申请人： Hans Deiner , Bernhard Sandner , Willy Bernheim
发明人： Hans Deiner , Bernhard Sandner , Willy Bernheim
IPC分类号： C09K3/18 , C08F2/00 , C08F2/44 , C08F283/12 , D06M13/02 , D06M13/322 , D06M13/325 , D06M13/345 , D06M13/51 , D06M13/513 , D06M15/263 , D06M15/643 , C08G77/12 , C08G77/20 , C08L43/04 , C08L83/04
CPC分类号： D06M15/643 , C08F283/12 , D06M15/263 , Y10T428/2933 , Y10T428/2962
摘要： A process for the production of modified polymers, preferable in organic solvents, by radical-initiated polymerization of(Ia) 70 to 99.9 parts by weight of esters of the formulaCH.sub.2 .dbd.C(R)--COOR' (Ia) in which R is --H or --CH.sub.3 and R' are 1 to 18 C-alkyl radicals, at least 50% by weight of the esters of (Ia) being those in which R' are 1 to 4 C-alkyl radicals,(Ib) 0, 1 to 20 parts by weight of .omega.-hydroxyalkyl esters of acrylic, methacrylic, maleic and/or fumaric esters, the said dicarboxylic acids are possibly etherified on the second carboxylic group with 1 to 12 C-atoms containing alcohols and(Ic) 0 to 10 parts by weight of other unsaturated monomers, the sum of (Ia), (Ib) and (Ic) amounting to 100 parts by weight, in the presence of(II) 5 to 40 parts by weight of terminal blocked alkyl-hydrogen polysiloxanes, the alkyl radicals containing 1 to 4 carbon atoms, with a viscosity of 20 to 1000 cP at 20.degree. C., the ratio of alkyl radicals to hydrogen atoms thereof being from 13 : 1 to 1 : 1, in which ratios the terminal groups are not included. Organic solvents containing the obtained modified polymers and usual curing agents for alkyl-hydrogen polysiloxanes are useful for treating fibrous material to give water-tight and water-repellent effects.
摘要翻译：通过（Ia）70至99.9重量份式CH 2 = C（R）-COOR'（Ia）的酯的自由基引发聚合制备改性聚合物的方法，优选在有机溶剂中，其中R为 -H或-CH 3和R'是1至18个C-烷基，至少50重量％的（Ia）的酯是其中R'是1至4个C-烷基，（Ib）0， 1至20重量份的丙烯酸，甲基丙烯酸，马来酸和/或富马酸的ω-羟烷基酯，所述二羧酸可能在含有1至12个碳原子的醇的第二羧基上醚化，并且（Ic）0至 10重量份的其它不饱和单体，在（II）5-40重量份末端封端的烷基 - 氢聚硅氧烷的存在下，（Ia），（Ib）和（Ic）的总和为100重量份，含有1至4个碳原子的烷基，在20℃下的粘度为20至1000cP，烷基与氢原子的比例为13:1至 1：1，其中不包括端基。含有所得改性聚合物的有机溶剂和烷基氢聚硅氧烷的常用固化剂可用于处理纤维材料以提供防水和防水效果。

6. 发明授权

US4004059A Method to make fibrous material oil and water repellent at the same time 失效
标题翻译：同时使纤维材料防油和防水的方法
公开(公告)号：US4004059A
公开(公告)日：1977-01-18
申请号：US547078
申请日：1975-02-04
申请人： Hans Deiner , Bernhard Sandner , Willy Bernheim
发明人： Hans Deiner , Bernhard Sandner , Willy Bernheim
IPC分类号： C09K3/00 , C09K3/18 , D06M15/277 , D06M15/643 , D06M13/18
CPC分类号： D06M15/643 , D06M15/277 , Y10T428/2962 , Y10T428/31544 , Y10T442/2172
摘要： While good oil-repellency can be imparted to fibre materials by treating them with polymers containing perfluoralkyl groups, it is difficult to impart water-repellency to the fibre materials at the same time and also give the treated materials a good handle. This is achieved by treating the fibre materials with, besides the perfluoralkyl group-containing polymers, an addition product of a) an unsaturated compound which is an olefin, a vinyl or allyl ester of an aliphatic straight or branched chain acid, a vinyl ether whose alkyl radical has at least 4 carbon atoms, an allyl ether whose alkyl radical has at least 4 carbon atoms and/or a vinyl halide with b) an organopolysiloxane which contains hydrogen atoms bonded to silicon atoms, the addition product containing on average more than 7 carbon atoms in the alkyl radical and at least 0.20 mole of the unsaturated component a) per gram atom of hydrogen in the siloxane component b).
摘要翻译：通过用含有全氟烷基的聚合物处理纤维材料，可以赋予纤维材料良好的拒油性，难以同时赋予纤维材料防水性，并且也使处理过的材料具有良好的手感。这是通过除含全氟烷基的聚合物以外处理纤维材料来实现的，该加成产物是a）不饱和化合物，其是烯烃，脂族直链或支链酸的乙烯基或烯丙酯，乙烯基醚，烷基具有至少4个碳原子，其烷基具有至少4个碳原子的烯丙基醚和/或乙烯基卤化物，以及b）含有与硅原子键合的氢原子的有机聚硅氧烷，该加成产物平均含有7个以上烷基中的碳原子和至少0.20摩尔不饱和组分a）在硅氧烷组分b）中每克原子的氢。

7. 发明授权

US4390650A Process for making fibrous material water repellent 失效
标题翻译：使纤维材料防水的方法
公开(公告)号：US4390650A
公开(公告)日：1983-06-28
申请号：US301569
申请日：1981-09-14
申请人： Hans Deiner , Willy Bernheim
发明人： Hans Deiner , Willy Bernheim
IPC分类号： D06M13/507 , D06M15/643 , C08L83/06
CPC分类号： D06M13/507 , D06M15/643
摘要： Process for making fibrous material water repellent by treating it with an aqueous bath containing(A) an emulsified organo polysiloxane with at least 2 hydroxyl groups optionally modified in a manner able to cross-link,(B) a non-ionic emulsion of poly silicic acid ester,(C) a reaction product which has been obtained by reaction of an organic compound containing at least one halohydrin and/or epoxy group with an organic compound containing hydrogen atoms bound to nitrogen, which in form of its salt is water-soluble or at least water-dispersible.The treated material is dried and optionally cured.
摘要翻译：通过用含有（A）具有至少2个可以交联的方式修饰的羟基的乳化有机聚硅氧烷处理含水浴来制造纤维材料防水剂的方法，（B）聚硅氧烷的非离子乳液酸酯，（C）通过使含有至少一个卤代醇和/或环氧基的有机化合物与含有与氮结合的氢原子的有机化合物反应而获得的反应产物，其形式为其盐是水溶性的或至少水分散性。将经处理的材料干燥并任选地固化。

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