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1. 发明授权

US06740773B2 Process for preparing cyclohexanedicarboxylic esters 失效
标题翻译：环己烷二羧酸酯的制备方法
公开(公告)号：US06740773B2
公开(公告)日：2004-05-25
申请号：US10160780
申请日：2002-06-03
申请人： Hans Bohnen , Thomas Klein , Klaus Bergrath
发明人： Hans Bohnen , Thomas Klein , Klaus Bergrath
IPC分类号： C07C6974
CPC分类号： C07C67/303 , C07C2601/14 , C07C69/75
摘要： The invention relates to a process for preparing cyclohexanedicarboxylic esters (hexahydrophthalic diesters) by esterifying the corresponding benzenedicarboxylic acids and immediately hydrogenating the esterification mixture in the presence of nickel catalysts.
摘要翻译：本发明涉及通过酯化相应的苯二甲酸并在镍催化剂存在下立即使酯化混合物加氢来制备环己烷二羧酸酯（六氢邻苯二甲酸二酯）的方法。

2. 发明授权

US06864387B2 Process for preparing sulfonated arylphosphines 有权
标题翻译：制备磺化芳基膦的方法
公开(公告)号：US06864387B2
公开(公告)日：2005-03-08
申请号：US10413014
申请日：2003-04-14
申请人： Michael Riedel , Ernst Wiebus , Carl D Frohning , Wilfried Fenske , Florian Rampf , Jurgen Herwig , Helmut Bahrmann , Klaus Bergrath , Wolfgang Zgorzel-Ski , Robert Eckl , Hans Bohnen , Richard Fischer , Kurt Schalapski , Wolfgang Greb
发明人： Michael Riedel , Ernst Wiebus , Carl D Frohning , Wilfried Fenske , Florian Rampf , Jurgen Herwig , Helmut Bahrmann , Klaus Bergrath , Wolfgang Zgorzel-Ski , Robert Eckl , Hans Bohnen , Richard Fischer , Kurt Schalapski , Wolfgang Greb
IPC分类号： B01J31/24 , B01J31/28 , C07C45/50 , C07F9/50 , C07C304/00
CPC分类号： B01J31/2404 , B01J31/2409 , B01J31/28 , B01J2231/321 , B01J2531/822 , B01J2531/96 , C07C45/50 , C07F9/5022 , C07F9/5054 , C07F9/5095 , C07C47/02
摘要： A process for preparing solutions of sulfonated arylphosphines comprising reacting arylphosphines with oleum, diluting the sulfonation mixture with water, extracting the diluted sulfonation mixture with a solution of a water-insoluble organic solvent, reacting the organic phase with a solution of an inorganic base in water, adjusting the resulting aqueous solutin of sulfonated arylphosphines to a pH of up to 3 by addition of an acid, and passing an inert gas stream through the aqueous solution comprising sulfonated arylphosphines until sulfur is no longer liberated from the aqueous solution of sulfonated arylphosphines.
摘要翻译：一种制备磺化芳基膦溶液的方法，包括使芳基膦与发烟硫酸反应，用水稀释磺化混合物，用水不溶性有机溶剂的溶液萃取稀释的磺化混合物，将有机相与无机碱溶于水通过加入酸将所得的磺化芳基膦的水溶液调节至最高达3的pH，并使惰性气体流通过包含磺化芳基膦的水溶液，直到硫从磺化芳基膦的水溶液中不再释放出来。

3. 发明授权

US07102034B2 Process for preparing sulfonated arylphosphines 失效
标题翻译：制备磺化芳基膦的方法
公开(公告)号：US07102034B2
公开(公告)日：2006-09-05
申请号：US11007399
申请日：2004-12-08
申请人： Michael Riedel , Ernst Wiebus , Carl D Frohning , Wilfried Fenske , Florian Rampf , Jurgen Herwig , Helmut Bahrmann , Klaus Bergrath , Wolfgang Zgorzel-Ski , Robert Eckl , Hans Bohnen , Richard Fischer , Kurt Schalapski , Wolfgang Greb
发明人： Michael Riedel , Ernst Wiebus , Carl D Frohning , Wilfried Fenske , Florian Rampf , Jurgen Herwig , Helmut Bahrmann , Klaus Bergrath , Wolfgang Zgorzel-Ski , Robert Eckl , Hans Bohnen , Richard Fischer , Kurt Schalapski , Wolfgang Greb
IPC分类号： C07C45/00
CPC分类号： B01J31/2404 , B01J31/2409 , B01J31/28 , B01J2231/321 , B01J2531/822 , B01J2531/96 , C07C45/50 , C07F9/5022 , C07F9/5054 , C07F9/5095 , C07C47/02
摘要： A process for preparing sulfonated arylphosphines by reaction of arylphosphines with oleum, wherein, after reaction of the arylphosphines with oleum, the sulfonation mixture is firstly diluted with water, an inert gas stream is then passed through the diluted sulfonation mixture until SO2 is no longer liberated from the diluted sulfonation mixture and the latter is then worked up further in a customary manner and its use.
摘要翻译：通过芳基膦与发烟硫酸的反应制备磺化芳基膦的方法，其中在芳基膦与发烟硫酸反应之后，首先用水稀释磺化混合物，然后使惰性气体流通过稀释的磺化混合物直到SO 2 不再从稀释磺化混合物中释放出来，而后者则以常规方式进一步处理及其用途。

4. 发明申请

US20060276669A1 Process for preparing sulfonated arylphosphines 审中-公开
标题翻译：制备磺化芳基膦的方法
公开(公告)号：US20060276669A1
公开(公告)日：2006-12-07
申请号：US11480178
申请日：2006-06-30
申请人： Michael Riedel , Ernst Wiebus , Carl Frohning , Wilfried Fenske , Florian Rampf , Jurgen Herwig , Helmut Bahrmann , Klaus Bergrath , Wolfgang Zgorzel-Ski , Robert Eckl , Hans Bohnen , Richard Fischer , Kurt Schalapski , Wolfgang Greb
发明人： Michael Riedel , Ernst Wiebus , Carl Frohning , Wilfried Fenske , Florian Rampf , Jurgen Herwig , Helmut Bahrmann , Klaus Bergrath , Wolfgang Zgorzel-Ski , Robert Eckl , Hans Bohnen , Richard Fischer , Kurt Schalapski , Wolfgang Greb
IPC分类号： C07F9/02 , C07C45/90
CPC分类号： B01J31/2404 , B01J31/2409 , B01J31/28 , B01J2231/321 , B01J2531/822 , B01J2531/96 , C07C45/50 , C07F9/5022 , C07F9/5054 , C07F9/5095 , C07C47/02
摘要： An aqueous catalyst solution comprising rhodium and an aqueous solution comprising sulfonated arylphosphines by reacting arylphosphines with oleum to form a sulfonation mixture, diluting the sulfonation mixture with water, extracting the diluted sulfonation mixture with a solution of a water-insoluble amine in a water-insoluble organic solvent, reacting the resulting water-immiscible organic phase with a solution of an inorganic base in water, adjusting the resulting aqueous solution of sulfonated arylphosphines of pH of up to 3 by addition of an acid, and passing an inert gas stream through the aqueous solution comprising sulfonated arylphosphines until sulfur dioxide is no longer liberated from the aqueous solution of sulfonated arylphosphines.
摘要翻译：包含铑的水溶液和包含磺化芳基膦的水溶液，通过使芳基膦与发烟硫酸反应形成磺化混合物，用水稀释磺化混合物，用水不溶性胺在水不溶性的溶液中萃取稀释的磺化混合物有机溶剂，使得到的与水不混溶的有机相与无机碱在水中的溶液反应，通过加入酸调节得到的pH为3的磺化芳基膦水溶液，并将惰性气流通过水溶液包含磺化芳基膦的溶液，直到二氧化硫不再从磺化芳基膦的水溶液中释放出来。

5. 发明申请

US20050171377A1 Process for preparing sulfonated arylphosphines 失效
标题翻译：制备磺化芳基膦的方法
公开(公告)号：US20050171377A1
公开(公告)日：2005-08-04
申请号：US11007399
申请日：2004-12-08
申请人： Michael Riedel , Ernst Wiebus , Carl Frohning , Wilfried Fenske , Florian Rampf , Jurgen Herwig , Helmut Bahrmann , Klaus Bergrath , Wolfgang Zgorzel-Ski , Robert Eckl , Hans Bohnen , Richard Fischer , Kurt Schalapski , Wolfgang Greb
发明人： Michael Riedel , Ernst Wiebus , Carl Frohning , Wilfried Fenske , Florian Rampf , Jurgen Herwig , Helmut Bahrmann , Klaus Bergrath , Wolfgang Zgorzel-Ski , Robert Eckl , Hans Bohnen , Richard Fischer , Kurt Schalapski , Wolfgang Greb
IPC分类号： B01J31/24 , B01J31/28 , C07C45/50 , C07F9/50 , C07F9/02
CPC分类号： B01J31/2404 , B01J31/2409 , B01J31/28 , B01J2231/321 , B01J2531/822 , B01J2531/96 , C07C45/50 , C07F9/5022 , C07F9/5054 , C07F9/5095 , C07C47/02
摘要： A process for preparing sulfonated arylphosphines by reaction of arylphosphines with oleum, wherein, after reaction of the arylphosphines with oleum, the sulfonation mixture is firstly diluted with water, an inert gas stream is then passed through the diluted sulfonation mixture until SO2 is no longer liberated from the diluted sulfonation mixture and the latter is then worked up further in a customary manner and its use.
摘要翻译：通过芳基膦与发烟硫酸的反应制备磺化芳基膦的方法，其中在芳基膦与发烟硫酸反应之后，首先用水稀释磺化混合物，然后使惰性气体流通过稀释的磺化混合物直到SO 2 不再从稀释磺化混合物中释放出来，而后者则以常规方式进一步处理及其用途。

6. 发明授权

US06500908B1 Catalyst system 有权
标题翻译：催化剂体系
公开(公告)号：US06500908B1
公开(公告)日：2002-12-31
申请号：US09509787
申请日：2000-06-09
申请人： Hans Bohnen , Cornelia Fritze
发明人： Hans Bohnen , Cornelia Fritze
IPC分类号： C08F452
CPC分类号： C08F10/00 , C08F4/65916 , C08F4/65927 , C08F4/65912
摘要： A catalyst system comprises a) a cocatalytically active chemical compound A, b) at least one metallocene B and c) an aluminum compound C.
摘要翻译：催化剂体系包括a）助催化活性化合物A，b）至少一种茂金属B和c）铝化合物C.

7. 发明授权

US06329313B1 Covalently supported chemical compound which can be neutral or ionic in the claims 失效
公开(公告)号：US06329313B1
公开(公告)日：2001-12-11
申请号：US08907938
申请日：1997-08-12
申请人： Cornelia Fritze , Frank Küber , Hans Bohnen
发明人： Cornelia Fritze , Frank Küber , Hans Bohnen
IPC分类号： B01J2102
CPC分类号： C08F10/00 , C08F4/65908 , C08F4/65912 , C08F4/65916 , C08F4/65922 , C08F110/06
摘要： The present invention relates to a supported chemical compound of the formula (I) in which Ac+ is a cation, c is an integer from 1 to 10, b is an integer ≧0, T is a support, y is an integer ≧1, a is an integer from 0 to 10, where a·y=c·b, and N is a unit of the formula (II) in which R independently at each occurrence is an identical or different substituent of M1 such as a halogen atom or a C1-C40 carbon-containing group, such as a C1-C40-alkyl, C1-C40-haloalkyl, C6-C40-aryl, C6-C40-haloaryl, C7-C40-arylalkyl or C7-C40-halo-arylalkyl group, X independently at each occurrence is identical or different and is a C1-C40 carbon-containing group, for example a divalent, carbon-containing group such as a C1-C40-alkylene, C1-C40-haloalkylene, C6-C4-arylene, C6-C40-haloarylene, C7-C40-arylalkylene or C7-C40-halo-arylalkylene, C2-C40-alkynylene, C2-C40-haloalkynylene, C2-C40-alkenylene or C2-C40haloalkenylene group, or a trivalent, carbon-containing group, such as a C1-C40-alkanetriyl, C1-C40-haloalkanetriyl, C6-C40-arenetriyl, C6-C40-haloarenetriyl, C7-C40-arenealkanetriyl, C7-C40-haloarenealkanetriyl, C2-C40-alkynetriyl, C2-C40haloalkynetriyl, C2-C40-alkenetriyl or C2-C40-haloalkenetriyl group, M independently at each occurrence is identical or different and is an element of group IIa, IIIa, IVa or Va of the Periodic Table of the Elements, d is 0 or 1, e is 0 or 1, f is 0 or 1, g is an integer from 0 to 10, h is an integer from 0 to 10, k is an integer from 0 to 10, r is an integer from 0 to 10, i is an integer from 0 to 1000, j is an integer from 1 to 6, S at each occurrence is identical or different and is a spacer which links M covalently with T, w is identical or different at each occurrence and is 0, 1 or 2, and z is 0, 1 or 2. The compound of the formula (I) is suitable as a catalyst component for olefin polymerization.

8. 发明授权

US06177376B1 Process for preparing a metallocene catalyst system 失效
标题翻译：金属茂催化剂体系的制备方法
公开(公告)号：US06177376B1
公开(公告)日：2001-01-23
申请号：US09015130
申请日：1998-01-29
申请人： Cornelia Fritze , Hans Bohnen , Frank K{umlaut over (u)}ber
发明人： Cornelia Fritze , Hans Bohnen , Frank K{umlaut over (u)}ber
IPC分类号： B01J3100
CPC分类号： C08F10/00 , C08F4/6192 , C08F110/06 , C08F4/61916 , C08F4/61908 , C08F4/61912
摘要： The present invention relates to a process for preparing a metallocene catalyst system, which comprises reacting a metallocene starting compound in a solvent with a compound capable of transferring hydrocarbon radicals and converting the resulting metallocene compound which is &sgr;-substituted by one or more hydrocarbon radicals in solution without isolation into a polymerization-active catalyst system by means of an activator.
摘要翻译：本发明涉及一种制备茂金属催化剂体系的方法，该方法包括使茂金属起始化合物在溶剂中与能够转移烃基的化合物反应，并将所得的茂金属化合物转化成一个或多个烃基的西格玛化合物溶液，而不通过活化剂分离成聚合活性催化剂体系。

9. 发明授权

US06583238B1 Catalyst system, method for the production thereof, and the utilization thereof for the polymerization of olefins 失效
标题翻译：催化剂体系，其制备方法及其在烯烃聚合中的应用
公开(公告)号：US06583238B1
公开(公告)日：2003-06-24
申请号：US09646177
申请日：2000-09-14
申请人： Markus Göres , Hans Bohnen
发明人： Markus Göres , Hans Bohnen
IPC分类号： C08F444
CPC分类号： C08F10/00 , C08F4/65912 , Y10S526/943 , C08F4/65927
摘要： A catalyst system with at least one specifically substituted metallocene which contains a cationic group as a substituent, a process for preparing such a catalyst system and its use in the polymerization of olefins. In particular, said catalyst system has (a) at least one support, (b) at least one cocatalyst and (c) at least one metallocene of the formula where M1, R1, R2, R3, m, m′, A, k and X are defined herein.
摘要翻译：具有至少一种含有阳离子基团作为取代基的具体取代的金属茂的催化剂体系，制备这种催化剂体系的方法及其在烯烃聚合中的应用。特别地，所述催化剂体系具有（a）至少一种载体，（b）至少一种助催化剂和（c）至少一种茂金属，所述茂金属在M1，R1，R2，R3，m，m'，A， X在本文中定义。

10. 发明授权

US06482902B1 Catalyst system 失效
标题翻译：催化剂体系
公开(公告)号：US06482902B1
公开(公告)日：2002-11-19
申请号：US09600313
申请日：2000-07-13
申请人： Hans Bohnen , Cornelia Fritze
发明人： Hans Bohnen , Cornelia Fritze
IPC分类号： C08F4622
CPC分类号： C08F10/00 , C08F4/65927 , C08F110/06 , C08F4/65916 , C08F4/65912 , C08F4/65908
摘要： The present invention relates to a catalyst system comprising metallocene, cocatalyst, support material and, if desired, further organometallic compounds. The catalyst system can advantageously be used for the polymerization of olefins, where the use of aluminoxanes such as methylaluminoxane (MAO), which usually has to be used in a large excess, as cocatalyst can be dispensed with and a high catalyst activity and good polymer morphology are nevertheless achieved.
摘要翻译：本发明涉及包含茂金属，助催化剂，载体材料和如果需要的其它有机金属化合物的催化剂体系。催化剂体系可以有利地用于烯烃的聚合，其中可以省去使用通常必须以大量过量使用的铝氧烷如甲基铝氧烷（MAO）作为助催化剂并具有高催化剂活性和良好的聚合物形态学仍然实现。

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