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    • 5. 发明授权
    • Benzoxanthene and benzothioxanthene dyestuffs
    • 苯并噻唑和苯并噻唑衍生物
    • US3853884A
    • 1974-12-10
    • US38478573
    • 1973-08-02
    • HOECHST AG
    • TROSTER H
    • C09B57/14D06P1/16C07D35/32
    • C09B57/14
    • wherein X is oxygen or sulfur, R1 is hydrogen, alkyl having 1 to 20 carbon atoms, methoxycarbonylmethyl, ethoxycarbonylmethyl, lower alkoxycarbonyl or phenyl, R2 is alkoxycarbonyl having 1 to 20 carbon atoms, lower acyl or benzoyl, cyano, carbonamido or phenylcarbonamido, R3 and R4 represent simultaneously hydrogen or lower alkoxy or R3 is lower alkoxy and R4 is hydrogen, R5 and R6 are hydrogen or halogen atoms, lower alkyl, alkoxy or alkoxycarbonyl. These dyestuffs yield brilliant yellow to red dyeings in synthetic polymers especially in polyethylene terephthalate with an intense yellow green to orange fluorescence. Due to their high fluorescence they can also be used for preparing daylight fluorescent pigments.

      Dyestuffs consisting of the mixture of isomers of the formula I
    • 由式I的异构体的混合物组成的染料,其中X是氧或硫,R1是氢,具有1-20个碳原子的烷基,甲氧基羰基甲基,乙氧基羰基甲基,低级烷氧基羰基或苯基,R2是具有1-20个碳原子的烷氧基羰基,低级 酰基或苯甲酰基,氰基,碳酰氨基或苯基碳酰氨基,R3和R4同时代表氢或低级烷氧基或R3是低级烷氧基,R4是氢,R5和R6是氢或卤原子,低级烷基,烷氧基或烷氧基羰基。 这些染料在合成聚合物中产生明亮的黄色至红色染料,特别是在具有强黄绿色至橙色荧光的聚对苯二甲酸乙二醇酯中。 由于其高荧光,它们也可用于制备日光荧光颜料。