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1. 发明授权

US07579289B2 Water repellant curable aqueous compositions 有权
标题翻译：防水固化水性组合物
公开(公告)号：US07579289B2
公开(公告)日：2009-08-25
申请号：US11496193
申请日：2006-07-31
申请人： Guy Clamen , Nolwenn Colmou , William C. Finch , Barry Weinstein
发明人： Guy Clamen , Nolwenn Colmou , William C. Finch , Barry Weinstein
IPC分类号： B32B3/00 , D03D15/00 , C08G63/00 , B05D1/36 , B05D7/00
CPC分类号： C08J7/08 , C08J7/04 , Y10T442/20 , Y10T442/2311 , Y10T442/2402 , Y10T442/30
摘要： According to the present invention, water repellant curable compositions comprise: (i) one or more polyacid; (ii) one or more polyol comprising at least two hydroxyl groups; (iii) one or more reactive waterproofing agent chosen from a C5 to C30 alk(en)yl monocarboxylate of a (poly)ethoxylated trihydric polyol, C5 to C30 alk(en)ylamine (poly)alkoxylate, C5 to C30 alk(en)yl diamine (poly)alkoxylate, C5 to C30 alk(en)ylamine (poly)alkoxylate containing an ether or thiother group in the alk(en)ylamine group, and mixtures thereof. The compositions are dilutable with water to make thermosetting aqueous binder compositions. The present invention also provides methods of treating or contacting substrates chosen from a non-woven, woven and a composite, such as glass fiber substrates, with the thermosetting aqueous binder compositions, and drying and curing, and the water resistant products produced thereby.
摘要翻译：根据本发明，防水可固化组合物包含：（i）一种或多种多酸; （ii）一种或多种包含至少两个羟基的多元醇; （iii）一种或多种反应性防水剂，其选自（多）乙氧基化三羟基多元醇的C5至C30烷基（en）基单羧酸酯，C5至C30烷基（烯）基胺（多）烷氧基化物，C5至C30烷基（en）（多）烷氧基化物，在烯（en）基胺基中含有醚或硫代基团的C 5 -C 30烷（烯）基胺（多）烷氧基化物，及其混合物。组合物可用水稀释以制备热固性水性粘合剂组合物。本发明还提供了使用热固性水性粘合剂组合物处理或接触选自无纺布，织造和复合材料如玻璃纤维基材的基材，以及干燥和固化以及由此生产的防水产品的方法。

2. 发明申请

US20080009209A1 Water repellant curable aqueous compositions 有权
标题翻译：防水固化水性组合物
公开(公告)号：US20080009209A1
公开(公告)日：2008-01-10
申请号：US11496193
申请日：2006-07-31
申请人： Guy Clamen , Nolwenn Colmou , William C. Finch , Barry Weinstein
发明人： Guy Clamen , Nolwenn Colmou , William C. Finch , Barry Weinstein
IPC分类号： B32B5/02
CPC分类号： C08J7/08 , C08J7/04 , Y10T442/20 , Y10T442/2311 , Y10T442/2402 , Y10T442/30
摘要： According to the present invention, water repellant curable compositions comprise: (i) one or more polyacid; (ii) one or more polyol comprising at least two hydroxyl groups; (iii) one or more reactive waterproofing agent chosen from a C5 to C30 alk(en)yl monocarboxylate of a (poly)ethoxylated trihydric polyol, C5 to C30 alk(en)ylamine (poly)alkoxylate, C5 to C30 alk(en)yl diamine (poly)alkoxylate, C5 to C30 alk(en)ylamine (poly)alkoxylate containing an ether or thiother group in the alk(en)ylamine group, and mixtures thereof. The compositions are dilutable with water to make thermosetting aqueous binder compositions. The present invention also provides methods of treating or contacting substrates chosen from a non-woven, woven and a composite, such as glass fiber substrates, with the thermosetting aqueous binder compositions, and drying and curing, and the water resistant products produced thereby.
摘要翻译：根据本发明，防水可固化组合物包含：（i）一种或多种多酸; （ii）一种或多种包含至少两个羟基的多元醇; （iii）一种或多种反应性防水剂，其选自（多）乙氧基化三元多羟基化合物的C 5 -C 30酸（en）基单羧酸酯，C C 5 -C 30烷基（烯）烷基化物，C 5至C 30烷基（烯）基二胺（烯）烷基化物，C 5 -C 30烷基（C 3）烷基（烯）烷（alk）（alk）（alk）（alk）其中。组合物可用水稀释以制备热固性水性粘合剂组合物。本发明还提供了使用热固性水性粘合剂组合物处理或接触选自无纺布，织造和复合材料如玻璃纤维基材的基材，以及干燥和固化以及由此生产的防水产品的方法。

3. 发明授权

US07766975B2 Water repellant curable aqueous compositions 有权
标题翻译：防水固化水性组合物
公开(公告)号：US07766975B2
公开(公告)日：2010-08-03
申请号：US11481144
申请日：2006-07-05
申请人： Guy Clamen , William C. Finch , Barry Weinstein
发明人： Guy Clamen , William C. Finch , Barry Weinstein
IPC分类号： C11D3/00 , C08L31/00 , C03C25/10
CPC分类号： D04H1/645 , C03C25/47 , C08F8/14 , D04H1/4209 , D04H1/4218 , D04H1/4234 , D04H1/4242 , D04H1/4258 , D04H1/4282 , D04H1/4334 , D04H1/435 , D04H1/587 , D04H1/64 , D21H13/40 , D21H17/38 , F16D69/02 , Y10T428/24994 , Y10T442/20 , C08F20/06
摘要： The present invention provides water repellant curable compositions comprising (i) one or more polyacid comprising at least two carboxylic acid groups, anhydride groups, or salts thereof, (ii) one or more polyol comprising at least two hydroxyl groups, (iii) one or more reactive waterproofing agent chosen from a C5 to C30 alk(en)yl 2-hydroxyethyl (alk(en))amide, C5 to C30 alk(en)yl bis(2-hydroxyethyl)amide, C11 to C30 alk(en)yl 2-hydroxyethyl (alk(en))amine, C11 to C30 alk(en)yl bis(2-hydroxy-ethyl)amine, C11 to C30 alk(en)yl tris(2-hydroxyethyl)amine, C5 to C30 alk(en)yl monoglyceride, C5 to C30 alk(en)yl monocarboxylate of a trihydric polyol, and mixtures thereof, and, (iv), optionally, one or more phosphorous-containing accelerator, wherein the ratio of the number of equivalents of said carboxylic acid groups, anhydride groups, or salts thereof to the total number of equivalents of said hydroxyl groups is from 1/0.01 to 1/3. The compositions provide concentrates dilutable with water to make thermosetting aqueous binder compositions for use in methods to treat or contact substrates chosen from a non-woven, woven and a composite, e.g. glass fiber substrates, followed by drying and curing.
摘要翻译：本发明提供防水可固化组合物，其包含（i）一种或多种包含至少两个羧酸基团，酸酐基团或其盐的多元酸，（ii）一种或多种包含至少两个羟基的多元醇，（iii）一种或多种选自C5至C30烷基（烯）基2-羟基乙基（alk（en））酰胺，C 5至C 30烯（烯）基双（2-羟乙基）酰胺，C 11至C 30烯（烯）基 2-羟乙基（alk（en））胺，C 11至C 30烷基（烯）基双（2-羟基 - 乙基）胺，C 11至C 30烯（烯）基三（2-羟乙基）胺，C 5至C 30烷基 en）单酸甘油酯，三元多元醇的C 5 -C 30烯（en）基单羧酸酯及其混合物，和（iv）任选的一种或多种含磷促进剂，其中所述羧酸的当量数酸基团，酸酐基团或其盐与所述羟基的当量的总数为1 / 0.01至1/3。组合物提供可与水稀释的浓缩物以制备用于处理或接触选自无纺布，编织物和复合材料的基材的热固性水性粘合剂组合物，例如。玻璃纤维基材，然后干燥和固化。

4. 发明申请

US20050048212A1 Curable aqueous composition and use as heat-resistant nonwoven binder 有权
标题翻译：可固化的水性组合物并用作耐热非织造粘合剂
公开(公告)号：US20050048212A1
公开(公告)日：2005-03-03
申请号：US10806580
申请日：2004-03-23
申请人： Guy Clamen , Richard Dobrowolski , Hal Morris , Barry Weinstein
发明人： Guy Clamen , Richard Dobrowolski , Hal Morris , Barry Weinstein
IPC分类号： C08L33/00 , C08F8/14 , C08K3/32 , C08K5/053 , C08K5/09 , C08K5/49 , D04H1/4209 , D04H1/4218 , D04H1/4234 , D04H1/4242 , D04H1/4258 , D04H1/4342 , D04H1/435 , D04H1/587 , D06M13/148 , D06M13/192 , D06M15/263 , D06M15/327 , B05D3/02
CPC分类号： D04H1/4218 , C08F8/14 , D04H1/4209 , D04H1/4234 , D04H1/4242 , D04H1/4258 , D04H1/4342 , D04H1/435 , D04H1/587 , D06M13/148 , D06M13/192 , D06M15/263 , D06M15/327 , C08F20/00
摘要： A curable aqueous composition including (a) a polyacid including at least two carboxylic acid groups, anhydride groups, or salts thereof; (b) a polyol including at least two hydroxyl groups; and (c) an emulsion polymer including, as copolymerized units, greater than 30% by weight, based on the weight of the emulsion polymer solids, ethylenically unsaturated acrylic monomer including a C5 or greater alkyl group; wherein the ratio of the number of equivalents of the carboxylic acid groups, anhydride groups, or salts thereof to the number of equivalents of the hydroxyl groups is from 1/0.01 to 1/3, and wherein the carboxylic acid groups, anhydride groups, or salts thereof are neutralized to an extent of less than 35% with a fixed base is provided. Also provided is a method for treating heat-resistant fibers or a heat-resistant nonwoven formed therefrom with the curable aqueous composition and the article prepared thereby.
摘要翻译：一种可固化水性组合物，其包含（a）包含至少两个羧酸基团的多酸，酸酐基团或其盐; （b）包含至少两个羟基的多元醇; 和（c）乳液聚合物，其包含基于乳液聚合物固体重量的大于30重量％的共聚单元，包含C5或更高烷基的烯属不饱和丙烯酸单体; 其中羧酸基团，酸酐基团或其盐的当量数与羟基的当量数的比率为1 / 0.01至1/3，并且其中羧酸基团，酸酐基团或其盐被中和至小于35％的程度，提供固定碱。还提供了由可固化水性组合物和由其制备的制品来处理耐热纤维或由其形成的耐热非织造物的方法。

5. 发明授权

US07199179B2 Curable aqueous composition and use as heat-resistant nonwoven binder 有权
标题翻译：可固化的水性组合物并用作耐热非织造粘合剂
公开(公告)号：US07199179B2
公开(公告)日：2007-04-03
申请号：US10806580
申请日：2004-03-23
申请人： Guy Clamen , Richard Dobrowolski , Hal Conley Morris , Barry Weinstein
发明人： Guy Clamen , Richard Dobrowolski , Hal Conley Morris , Barry Weinstein
IPC分类号： C08F220/10
CPC分类号： D04H1/4218 , C08F8/14 , D04H1/4209 , D04H1/4234 , D04H1/4242 , D04H1/4258 , D04H1/4342 , D04H1/435 , D04H1/587 , D06M13/148 , D06M13/192 , D06M15/263 , D06M15/327 , C08F20/00
摘要： A curable aqueous composition including (a) a polyacid including at least two carboxylic acid groups, anhydride groups, or salts thereof; (b) a polyol including at least two hydroxyl groups; and (c) an emulsion polymer including, as copolymerized units, greater than 30% by weight, based on the weight of the emulsion polymer solids, ethylenically unsaturated acrylic monomer including a C5 or greater alkyl group; wherein the ratio of the number of equivalents of the carboxylic acid groups, anhydride groups, or salts thereof to the number of equivalents of the hydroxyl groups is from 1/0.01 to 1/3, and wherein the carboxylic acid groups, anhydride groups, or salts thereof are neutralized to an extent of less than 35% with a fixed base is provided. Also provided is a method for treating heat-resistant fibers or a heat-resistant nonwoven formed therefrom with the curable aqueous composition and the article prepared thereby.
摘要翻译：一种可固化水性组合物，其包含（a）包含至少两个羧酸基团的多酸，酸酐基团或其盐; （b）包含至少两个羟基的多元醇; 和（c）乳液聚合物，其包含基于乳液聚合物固体重量的大于30重量％的共聚单元，包含C 5或更高烷基的烯属不饱和丙烯酸单体; 其中羧酸基团，酸酐基团或其盐的当量数与羟基的当量数的比率为1 / 0.01至1/3，并且其中羧酸基团，酸酐基团或其盐被中和至小于35％的程度，提供固定碱。还提供了由可固化水性组合物和由其制备的制品来处理耐热纤维或由其形成的耐热非织造物的方法。

6. 发明申请

US20070006390A1 Water repellant curable aqueous compositions 有权
标题翻译：防水固化水性组合物
公开(公告)号：US20070006390A1
公开(公告)日：2007-01-11
申请号：US11481144
申请日：2006-07-05
申请人： Guy Clamen , William Finch , Barry Weinstein
发明人： Guy Clamen , William Finch , Barry Weinstein
IPC分类号： C11D3/00
CPC分类号： D04H1/645 , C03C25/47 , C08F8/14 , D04H1/4209 , D04H1/4218 , D04H1/4234 , D04H1/4242 , D04H1/4258 , D04H1/4282 , D04H1/4334 , D04H1/435 , D04H1/587 , D04H1/64 , D21H13/40 , D21H17/38 , F16D69/02 , Y10T428/24994 , Y10T442/20 , C08F20/06
摘要： According to the present invention, water repellant curable compositions comprise: (i) one or more polyacid comprising at least two carboxylic acid groups, anhydride groups, or salts thereof; (ii) one or more polyol comprising at least two hydroxyl groups; (iii) one or more reactive waterproofing agent chosen from a C5 to C30 alk(en)yl 2-hydroxyethyl (alk(en))amide, C5 to C30 alk(en)yl bis(2-hydroxyethyl)amide, C1 to C30 alk(en)yl 2-hydroxyethyl (alk(en))amine, C11 to C30 alk(en)yl bis(2-hydroxy-ethyl) amine, C11 to C30 alk(en)yl tris(2-hydroxyethyl)amine, C5 to C30 alk(en)yl monoglyceride, C5 to C30 alk(en)yl monocarboxylate of a trihydric polyol, and mixtures thereof; and, (iv), optionally, one or more phosphorous-containing accelerator, wherein the ratio of the number of equivalents of said carboxylic acid groups, anhydride groups, or salts thereof to the total number of equivalents of said hydroxyl groups is from 1/0.01 to 1/3. The compositions provide concentrates dilutable with water to make thermosetting aqueous binder compositions. Further, the present invention provides methods of treating or contacting substrates chosen from a non-woven, woven and a composite, such as glass fiber substrates, with the thermosetting aqueous binder compositions, and drying and curing, as well as water resistant products produced thereby.
摘要翻译：根据本发明，防水可固化组合物包含：（i）一种或多种包含至少两个羧酸基团，酸酐基团或其盐的多酸; （ii）一种或多种包含至少两个羟基的多元醇; （iii）一种或多种反应性防水剂，其选自C 5至C 30烷基（烯）基2-羟乙基（alk（en））酰胺，C

7. 发明申请

US20090137746A1 Method for making polymers 有权
标题翻译：聚合物的制备方法
公开(公告)号：US20090137746A1
公开(公告)日：2009-05-28
申请号：US12313809
申请日：2008-11-25
申请人： Barry Weinstein , Kenneth Bruce Laughlin , William C. Finch
发明人： Barry Weinstein , Kenneth Bruce Laughlin , William C. Finch
IPC分类号： C08F8/32 , C08F8/00
CPC分类号： C08F8/32 , C08F220/06
摘要： A method for preparing acid-containing polymers by reacting them in the presence of end-capped polyols or amines in the presence of phosphorous-containing compounds.
摘要翻译：在含磷化合物存在下，在封端的多元醇或胺存在下使它们反应制备含酸聚合物的方法。

8. 发明授权

US08592518B2 Rapid cure thermosets from 5- and 6- membered cyclic enamine compounds made from dialdehydes 有权
标题翻译：快速固化由二醛制成的5-和6-元环状烯胺化合物的热固性材料
公开(公告)号：US08592518B2
公开(公告)日：2013-11-26
申请号：US13152502
申请日：2011-06-03
申请人： Brad Bailey , William C. Finch , Hyun K. Jeon , Charles James Rand , Robert L. Sammler , Francis J. Timmers , Barry Weinstein
发明人： Brad Bailey , William C. Finch , Hyun K. Jeon , Charles James Rand , Robert L. Sammler , Francis J. Timmers , Barry Weinstein
IPC分类号： C08L61/20 , C08L61/22 , C08L61/32
CPC分类号： C08L79/02 , C08G12/34 , C09J161/26 , C09J161/32
摘要： The present invention provides thermosetting aqueous binder compositions of one or more cyclic enamine, including bis-enamines and di- or higher functional enamines, optionally containing a water soluble or dispersible or dispersible primary amine compound. The binders are at least substantially formaldehyde free, need no polycarboxylic or polycarboxylate component, and yet provide excellent hot wet tensile strength when cured for as little time as a minute or less in use.
摘要翻译：本发明提供一种或多种环状烯胺的热固性水性粘合剂组合物，包括双 - 烯胺和二 - 或更高官能的烯胺，任选地含有水溶性或可分散或可分散的伯胺化合物。粘合剂至少基本上不含甲醛，不需要多元羧酸或多羧酸酯成分，并且在使用中固化少至几分钟或更短时间时提供优异的热湿拉伸强度。

9. 发明申请

US20110306726A1 RAPID CURE THERMOSETS FROM 5- AND 6- MEMBERED CYCLIC ENAMINE COMPOUNDS MADE FROM DIALDEHYDES 有权
标题翻译：来自二氯乙烯的5-和6-成员的循环电化学化合物的快速固化热稳定剂
公开(公告)号：US20110306726A1
公开(公告)日：2011-12-15
申请号：US13152502
申请日：2011-06-03
申请人： Brad C. BAILEY , Robert L. Sammler , Francis J. Timmers , Hyun K. Jeon , William C. Finch , Charles J. Rand , Barry Weinstein
发明人： Brad C. BAILEY , Robert L. Sammler , Francis J. Timmers , Hyun K. Jeon , William C. Finch , Charles J. Rand , Barry Weinstein
IPC分类号： C08L61/22
CPC分类号： C08L79/02 , C08G12/34 , C09J161/26 , C09J161/32
摘要： The present invention provides thermosetting aqueous binder compositions of one or more cyclic enamine, including bis-enamines and di- or higher functional enamines, optionally containing a water soluble or dispersible or dispersible primary amine compound. The binders are at least substantially formaldehyde free, need no polycarboxylic or polycarboxylate component, and yet provide excellent hot wet tensile strength when cured for as little time as a minute or less in use.
摘要翻译：本发明提供一种或多种环状烯胺的热固性水性粘合剂组合物，包括双 - 烯胺和二 - 或更高官能的烯胺，任选地含有水溶性或可分散或可分散的伯胺化合物。粘合剂至少基本上不含甲醛，不需要多元羧酸或多羧酸酯成分，并且在使用中固化少至几分钟或更短时间时提供优异的热湿拉伸强度。

10. 发明授权

US07906591B2 Method for making polymers 有权
标题翻译：聚合物的制备方法
公开(公告)号：US07906591B2
公开(公告)日：2011-03-15
申请号：US12313809
申请日：2008-11-25
申请人： Barry Weinstein , Kenneth Bruce Laughlin , William C. Finch
发明人： Barry Weinstein , Kenneth Bruce Laughlin , William C. Finch
IPC分类号： C08F8/14 , C08F8/00 , C08F8/40 , C08F19/00 , C08F220/06 , C08L79/06
CPC分类号： C08F8/32 , C08F220/06
摘要： A method for preparing acid-containing polymers by reacting them in the presence of end-capped polyols or amines in the presence of phosphorous-containing compounds.
摘要翻译：在含磷化合物存在下，在封端的多元醇或胺存在下使它们反应制备含酸聚合物的方法。

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