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1. 发明授权

US5252767A Process for the preparation of organosiloxanes 失效
标题翻译：制备有机硅氧烷的方法
公开(公告)号：US5252767A
公开(公告)日：1993-10-12
申请号：US915160
申请日：1992-07-16
申请人： Gunther Maass , Manfred Schulze
发明人： Gunther Maass , Manfred Schulze
IPC分类号： C01B7/01 , C07F7/08 , C07F7/21 , C08G77/04 , C08G77/06
CPC分类号： C07F7/21 , C01B7/01 , C07F7/0874 , C08G77/045
摘要： This invention relates to a process for the preparation of organosiloxanes, in particular those containing a high proportion of low molecular weight cyclic and chain structured organosiloxanes, preferably cyclic dimethylsiloxanes, by hydrolysis of the corresponding organochlorosilanes, in which a high proportion of gaseous hydrogen chloride is formed at the same time.
摘要翻译：本发明涉及一种制备有机硅氧烷的方法，特别是含有高比例低分子量环状和链状结构有机硅氧烷，优选环状二甲基硅氧烷的有机硅氧烷的方法，通过水解相应的有机氯硅烷，其中高比例的气态氯化氢是同时形成。

2. 发明授权

US4439592A Preparation of polydiorganosiloxanes having terminal triorganosilyl groups 失效
标题翻译：具有末端三有机甲硅烷基的聚二有机硅氧烷的制备
公开(公告)号：US4439592A
公开(公告)日：1984-03-27
申请号：US417720
申请日：1982-09-13
申请人： Gunther Maass , Hans J. Lucking , Karl Brandle , Hans-Heinrich Moretto
发明人： Gunther Maass , Hans J. Lucking , Karl Brandle , Hans-Heinrich Moretto
IPC分类号： C08G77/00 , C08G77/06 , C08G77/26
CPC分类号： C08G77/06
摘要： The present invention relates to a process for the preparation of trioganosilyl-terminated polydiorganosiloxanes by basic polymerization of cyclic diorganopolysiloxanes and triorganosilyl-terminated siloxanes, wherein, before the polymerization, a part of the cyclic diorganosiloxane is distilled off in the presence of the polymerization catalyst at a temperature which is at least 10.degree. C. below the polymerization temperature.
摘要翻译：本发明涉及通过环状二有机聚硅氧烷和三有机甲硅烷基封端的硅氧烷的碱性聚合制备三聚氰酰甲硅烷基封端的聚二有机硅氧烷的方法，其中在聚合前，在聚合催化剂存在下蒸馏掉一部分环状二有机硅氧烷在聚合温度以下至少10℃的温度。

3. 发明授权

US4102940A Working up polysiloxane/polycarbonate copolymers 失效
标题翻译：加工聚硅氧烷/聚碳酸酯共聚物
公开(公告)号：US4102940A
公开(公告)日：1978-07-25
申请号：US747264
申请日：1976-12-03
申请人： Karl-Friedrich Thom , Gunther Maass , Manfred Beck
发明人： Karl-Friedrich Thom , Gunther Maass , Manfred Beck
IPC分类号： C08G77/00 , C08G64/18 , C08G64/40 , C08G77/42 , C08G77/448 , C08G81/00 , C08L43/04
CPC分类号： C08G81/00 , C08G64/186 , C08G64/403 , C08G77/448
摘要： In the preparation and working up of a SiOC-linked polysiloxane/polycarbonate copolymer comprising reacting an .alpha.,.omega.-dihalogenopolysiloxane with an .alpha.,.omega.-dihydroxy-oligocarbonate in the presence of a tertiary amine and a solvent, and subsequently separating off the resulting copolymer from the reaction mixture additionally containing the amine, amine hydrochloride and organic solvent, the improvement which comprises subjecting the reaction mixture to steam distillation whereby the copolymer remains behind. Advantageously, the copolymer reaction solution is added to an aqueous solution having a pH of 7 to 8 whereby the amine and hydrogen chloride also distill over. If a surface active agent is present in the aqueous solution the product will be of very fine particle size.
摘要翻译：在制备和加工含SiOC的聚硅氧烷/聚碳酸酯共聚物时，包括使α，ω-二卤基聚硅氧烷与α，ω-二羟基 - 低聚碳酸酯在叔胺和溶剂的存在下反应，随后将所得的共聚物从另外含有胺，盐酸盐和有机溶剂的反应混合物中，改进包括使反应混合物进行蒸汽蒸馏，由此共聚物保留在后面。有利地，将共聚物反应溶液加入到pH为7至8的水溶液中，由此胺和氯化氢也蒸馏出来。如果表面活性剂存在于水溶液中，则产品将具有非常细的粒度。

4. 发明授权

US4001168A Transparent storage-stable polysiloxanes which cross-link under atmospheric conditions 失效
标题翻译：在大气条件下交联的透明储存稳定的聚硅氧烷
公开(公告)号：US4001168A
公开(公告)日：1977-01-04
申请号：US559473
申请日：1975-03-18
申请人： Gunther Maass , Hans Joachim Lucking , Hans Sattlegger , Karl-Heinz Rudolph
发明人： Gunther Maass , Hans Joachim Lucking , Hans Sattlegger , Karl-Heinz Rudolph
IPC分类号： C08L83/00 , C08K3/36 , C08K5/544 , C08L83/04
CPC分类号： C08K5/54 , C08K3/36 , C08G77/16 , C08G77/70
摘要： A polysiloxane composition which can be cross-linked under atmospheric conditions and which consists essentially of:A. 100 parts by weight of an .alpha.,.omega.-dihydroxymethylphenylpolysiloxane with about 7-15 mole % of diphenylsiloxy units or about 14-28 mole % of methylphenylsiloxy units, and having a viscosity of between about 1,000 and 500,000 cSt (at 20.degree. C),b. about 1 to 40 parts by weight of an uncoated reinforcing filler consisting essentially of SiO.sub.2 having a specific surface area of about 40 to 500 m.sup.2 /g by the BET method, andC. about 1 to 10 parts by weight of a cross-linking agent of the formulaRSiX.sub.3whereinR is an alkyl, halogenoalkyl, aryl, or arylalkyl radical, andX is an alkoxy, acyloxy, oximato or alkylamino radical.A curing catalyst may also be present. The composition is clear as are the silicone rubbers produced upon curing.
摘要翻译：可在大气条件下交联的聚硅氧烷组合物，其基本上由以下组成：

5. 发明授权

US4426509A Storable crosslinkable organopolysiloxane molding compositions 失效
标题翻译：可存储的可交联有机聚硅氧烷模塑组合物
公开(公告)号：US4426509A
公开(公告)日：1984-01-17
申请号：US411750
申请日：1982-08-26
申请人： Gunther Maass , Hans Sattlegger , Hans J. Lucking
发明人： Gunther Maass , Hans Sattlegger , Hans J. Lucking
IPC分类号： C08L83/00 , C08K5/5419 , C08K5/5425 , C08K5/5435 , C08L83/04 , C08G77/04
CPC分类号： C08K5/5425 , C08K5/54 , C08K5/5435 , C08G77/16 , Y10S528/901
摘要： In a plastic organosiloxane molding composition which in the absence of water is capable of being stored and in the presence of moisture is cross-linked to a rubber, the composition comprising a hydroxypolydiorganosiloxane, a nitrogen base and heavy metal compound as cross-linking catalyst, and a cross-linking agent, the improvement which comprises employing as the cross-linking agent a compound of the formula ##STR1## or a partial hydrolysis product thereof, wherein R is an optionally substituted alkyl, alkenyl or aryl group,R.sub.1 is hydrogen or R,R.sub.2 is an acyl, carbalkoxy or carbaroxy group or R.sub.1,a is 1-3, andn is 0, 1 or 2 and a+n.ltoreq.3.Upon curing no unpleasant odors are given off upon decomposition of the cross-linking agent.
摘要翻译：在不存在水的塑料有机硅氧烷模塑组合物中，在存在水分的情况下，与橡胶交联，该组合物包含作为交联催化剂的羟基聚二有机硅氧烷，氮碱和重金属化合物，和交联剂，其改进包括使用式（I）的化合物或其部分水解产物作为交联剂，其中R是任选取代的烷基，烯基或芳基，R 1是氢或 R 2，R 2为酰基，烷氧基或碳酰氧基或R 1，a为1-3，n为0,1或2，a + n为3。

6. 发明授权

US4079070A Preparation of cyclic diphenylsiloxanes 失效
标题翻译：环状二苯基硅氧烷的制备
公开(公告)号：US4079070A
公开(公告)日：1978-03-14
申请号：US709993
申请日：1976-07-30
申请人： Gunther Maass , Hans-Joachim Lucking , Joachim Maas , Klaus Seyfried
发明人： Gunther Maass , Hans-Joachim Lucking , Joachim Maas , Klaus Seyfried
IPC分类号： C07F7/21 , C07F7/08
CPC分类号： C07F7/21
摘要： In the preparation of a cyclic diphenylsiloxane of the formula ##STR1## WHEREIN N IS 3 OR 4, BY HYDROLYSIS OF A DIPHENYLDIHALOGENOSILANE, THE IMPROVEMENT WHICH COMPRISES ADDING THE DIPHENYLDIHALOGENOSILANE, IN THE PRESENCE OF AN ORGANIC, APROTIC SOLVENT TO AN AQUEOUS BASIC SOLUTION, THE BASE BEING EMPLOYED IN AN AMOUNT WHICH IS AT LEAST STOICHIOMETRICALLY EQUIVALENT TO THE HALOGEN CONTENT, WHEREBY THE CYCLIC DIPHENYLSILOXANE IS OBTAINED IN HIGH YIELD AND PURITY. The base is preferably lithium hydroxide, potassium hydroxide or sodium hydroxide and is used in the form of an at least 5 molar solution, about 2.1 to 2.5 equivalents being used per mole of diphenyldihalogenosilane.
摘要翻译：在制备通过二氢苯并恶唑烷酮的水解制备下式的“式”的环状二苯基硅氧烷的情况下，其中包含加入二苯基二氢恶唑烷酮的改进，在有机溶剂的存在下，将其溶解于水性碱性溶液中基本上以最低限度地等效于卤素含量的量进行操作，因为循环二苯基硅烷以高的产量和纯度获得。碱优选为氢氧化锂，氢氧化钾或氢氧化钠，并以至少5摩尔溶液的形式使用，每摩尔二苯基二卤代硅烷使用约2.1至2.5当量。

7. 发明授权

US4060537A Preparation of organosiloxanes 失效
标题翻译：有机硅氧烷的制备
公开(公告)号：US4060537A
公开(公告)日：1977-11-29
申请号：US747262
申请日：1976-12-03
申请人： Gunther Maass , Hans Joachim Lucking , Werner Buchner , Bruno Degen
发明人： Gunther Maass , Hans Joachim Lucking , Werner Buchner , Bruno Degen
IPC分类号： C08G77/00 , C07F7/08 , C07F7/18 , C07F7/21 , C08G77/06
CPC分类号： C07F7/21 , C07F7/0874
摘要： In the preparation of cyclic and linear organosiloxanes by reacting an organohalogenosilane with a compound of the formulaROR'in whichR is an alkyl radical with 1-4 C atoms, andR' is hydrogen or an alkyl radical with 1-4 C atoms,The improvement which comprises effecting the reaction in an aqueous solution of a Lewis acid. Preferably the organohalogenosilane is a di- or tri-organo-chloro or -bromo-silane wherein the organo radical is selected from the group consisting of alkyl or alkenyl of up to 4 C atoms or aryl, especially dimethyldichlorosilane, and the Lewis acid is a 40-90% solution of ZnCl.sub.2, FeCl.sub.3, CdCl.sub.2 or H.sub.2 SO.sub.4. Advantageously ROR' is methanol, ethanol, propanol, dimethyl ether or diethyl ether.
摘要翻译：在通过有机卤代硅烷与式ROR'的化合物（其中R是具有1-4个C原子的烷基，R'是氢或具有1-4个C原子的烷基）反应制备环状和线性有机硅氧烷的过程中，其包含在路易斯酸的水溶液中影响反应的改进。优选地，有机卤代硅烷是二 - 或三 - 有机氯或溴 - 硅烷，其中有机基团选自由高达4个C原子的烷基或烯基或芳基，特别是二甲基二氯硅烷组成的组，路易斯酸是 40-90％的ZnCl2，FeCl3，CdCl2或H2SO4溶液。有利的是ROR是甲醇，乙醇，丙醇，二甲醚或乙醚。

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