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1. 发明授权

US5352380A Ferroelectric liquid-crystalline polymers, a process for their preparation and their use in electrooptical components 失效
标题翻译：铁电液晶聚合物，其制备方法及其在电光元件中的应用
公开(公告)号：US5352380A
公开(公告)日：1994-10-04
申请号：US170669
申请日：1993-12-17
申请人： Gunter Scherowsky , Andreas Schliwa , Wolfgang Trapp
发明人： Gunter Scherowsky , Andreas Schliwa , Wolfgang Trapp
IPC分类号： C08F20/30 , C08F20/36 , C09K19/02 , C09K19/38 , C09K19/52 , C08F122/10 , G02F1/13
CPC分类号： C08F20/30 , C08F20/36 , C09K19/0225 , C09K19/3857
摘要： A ferroelectric, liquid-crystalline polymer is composed of repeating units of the formula I ##STR1## in which Y=H or CH.sub.3a=an integer from 6 to 12M=a group selected from the formulae which follow: ##STR2## in which --R.sup.2 =--CH.sub.3 or --Cl and b=an integer from 1 to 10. The abovementioned polymer has remarkably short response times. The polymer forms, alone or mixed with other LC components, an orthogonal smectic phase. It is possible to use this phase in the electroclinic mode.
摘要翻译：铁电液晶聚合物由式I（I）的重复单元组成，其中Y = H或CH 3 a = 6至12 M的整数=选自以下公式的基团：其中-R2 = -CH3或-Cl，b = 1〜10的整数。上述聚合物具有非常短的响应时间。聚合物单独或与其它LC组分混合形成正交近晶相。可以在电梯模式下使用该相。

2. 发明授权

US5288425A Ferroelectric, liquid-crystalline polymers, a process for their preparation and their use in electrooptical components 失效
标题翻译：铁电，液晶聚合物，其制备方法及其在电光学部件中的应用
公开(公告)号：US5288425A
公开(公告)日：1994-02-22
申请号：US635180
申请日：1991-01-03
申请人： Gunter Scherowsky , Andreas Schliwa , Wolfgang Trapp
发明人： Gunter Scherowsky , Andreas Schliwa , Wolfgang Trapp
IPC分类号： G02F1/13 , C07C69/773 , C08F20/26 , C08F20/30 , C08F20/32 , C08F20/34 , C08F20/36 , C08F20/38 , C08F120/30 , C08F220/30 , C08F220/32 , C08F220/36 , C08F290/00 , C08F299/02 , C09K19/02 , C09K19/38 , C09K19/52 , C08G63/00 , C09K19/12 , C09K19/34
CPC分类号： C09K19/0225 , C08F20/30 , C08F20/36 , C09K19/3857
摘要： A ferroelectric, liquid-crystalline polymer is composed of repeating units of the formula (I) ##STR1## in which Y.sup.1 =H, CH.sub.3 or FY.sup.2 =H or FR.sup.1 = ##STR2## or an achiral alkyl having 2 to 16 carbon atoms, and R.sup.3 =H or CH.sub.3R.sup.2 =CH.sub.3, Cl or CNg and h=an integer from 0 to 10a=2 to 20, preferably 6 to 12b,c,d,e and f=0 or 1, where d+e+f=2 or 3A.sup.1,A.sup.2 and A.sup.3 =for example, 1,4-phenylene in which one or two hydrogen atoms may be substituted by F, Cl and/or CN, 1,4-cyclohexylene andM.sup.1,M.sup.2 and M.sup.3 =for example, CO--O or O--CO.These liquid-crystalline polymers have short response times and high resistance to mechanical stresses. They can be prepared by free-radical polymerization.
摘要翻译： PCT No.PCT / EP89 / 00745 Sec。 371日期1991年1月3日 102（e）日期1991年1月3日PCT Filed 1989年6月29日PCT公布。出版物WO90 / 00584 日本1990年1月25日。铁电液晶聚合物由式（I）的重复单元（*化学结构*）组成，其中Y 1 = H，CH 3或F Y 2 = H或F R 1 =（* CHEMICAL 结构*）或具有2至16个碳原子的非手性烷基，并且R 3 = H或CH 3 R 2 = CH 3，Cl或CN g，h = 0至10的整数a = 2至20，优选6至12b，c ，d，e和f = 0或1，其中d + e + f = 2或3，A1，A2和A3 =例如，其中一个或两个氢原子可以被F，Cl和/ 或CN，1,4-亚环己基和M1，M2和M3 =例如CO-O或O-CO。这些液晶聚合物具有较短的响应时间和高的机械应力抵抗力。它们可以通过自由基聚合制备。

3. 发明授权

US5637254A Ferroelectric liquid-crystalline polymers, a process for their preparation and their use in electrooptical components 失效
标题翻译：铁电液晶聚合物，其制备方法及其在电光元件中的应用
公开(公告)号：US5637254A
公开(公告)日：1997-06-10
申请号：US412617
申请日：1995-03-29
申请人： Gunter Scherowsky , Andreas Schliwa , Wolfgang Trapp
发明人： Gunter Scherowsky , Andreas Schliwa , Wolfgang Trapp
IPC分类号： C08F20/30 , C09K19/02 , C09K19/38 , C09K19/52 , C09K19/00 , C09K19/30 , C09K19/34
CPC分类号： C09K19/3857 , C08F20/30 , C09K19/0225
摘要： A ferroelectric, liquid-crystalline polymer is composed of repeating units of the formula (I) ##STR1## in which Y=H, CH.sub.3 or F,R.sup.1 =a radical having at least two chiral centers such as for example ##STR2## a=2 to 20, preferably 6 to 12, b,c,d,e and f=0 or 1 with the proviso that d+e+f=2 or 3,A.sup.1,A.sup.2 and A.sup.3 =for example, 1,4-phenylene, cyclohexylene or 2,5-pyrimidinediyl,M.sup.2 and M.sup.3 =CO--O, O--CO, CO--S, S--CO, CH.sub.2 --O, O--CH.sub.2, and ##STR3## These liquid-crystalline polymers have short response times and resistance to mechanical stresses.They can be prepared by free-radical polymerization.
摘要翻译：铁电液晶聚合物由式（I）的重复单元组成，其中Y = H，CH 3或F，R 1 =具有至少两个手性中心的基团，例如 a = 2至20，优选6至12，b，c，d，e和f = 0或1，条件是d + e + f = 2或3，A1，A2和A3 =例如，1,4-亚苯基，亚环己基或2,5-嘧啶二基，M2和M3 = CO-O，O-CO，CO-S，S-CO，CH2-O，O-CH2和这些液晶聚合物具有较短的响应时间和耐机械应力。它们可以通过自由基聚合制备。

4. 发明授权

US5310499A Oxazolidinone derivatives, and the use thereof as dopes in liquid-crystal mixtures 失效
标题翻译：恶唑烷酮衍生物及其作为液晶混合物中的掺杂物的用途
公开(公告)号：US5310499A
公开(公告)日：1994-05-10
申请号：US732626
申请日：1991-07-19
申请人： Gunter Scherowsky , Michael Sefkow , Gerd Illian , Rainer Wingen
发明人： Gunter Scherowsky , Michael Sefkow , Gerd Illian , Rainer Wingen
IPC分类号： C07D263/20 , C07D263/22 , C07D263/24 , C07D263/26 , C07D413/06 , C07D413/08 , C07D413/10 , C07D413/12 , C07D413/14 , C07D417/06 , C07D417/08 , C07D417/10 , C07D417/12 , C07D417/14 , C09K19/34 , C09K19/58 , G02F1/13 , C07D239/02 , C07P263/04
CPC分类号： C07D263/20 , C07D263/24 , C07D413/10 , C07D417/12 , C09K19/3483 , C09K19/3491 , C09K19/3497
摘要： Chiral oxazolidinones of the formula (I) or (II) ##STR1## in which R.sup.1 is, for example, a straight-chain or branched alkyl radical having 1 to 16 carbon atoms orR.sup.2 and R.sup.3 are, for example, --H, --CH.sub.3 or phenyl,j, 1 and n are zero, 1 or 2,k and m are zero or 1,A.sup.1, A.sup.2 and A.sup.3 are, for example, phenyl or cyclohexyl,M.sup.1 and M.sup.2 are, for example, COO or CH.sub.2 O, andX is, for example, CH.sub.2 or COO,are suitable as dopes in liquid-crystal mixtures. They result in liquid-crystalline ferroelectric phases having short response times. A further advantage is that the oxazolidinones induce a helix of very low pitch, so that they are also suitable for helix compensation in LC mixtures.
摘要翻译：式（I）或（II）的手性恶唑烷酮，其中R 1是例如具有1至16个碳原子的直链或支链烷基或R 2和R 3 是例如-H，-CH 3或苯基，j，1和n分别为0,1或2，k和m为0或1，A 1，A 2和A A为例如苯基或环己基，M 1和M 2 例如是COO或CH 2 O，X是例如CH 2或COO，适合作为液晶混合物中的掺杂物。它们产生具有较短响应时间的液晶铁电相。另一个优点是恶唑烷酮诱导非常低沥青的螺旋，使得它们也适用于LC混合物中的螺旋补偿。

5. 发明授权

US5334328A Chiral azetidinone derivatives, and their use as dopes in liquid-crystal mixtures 失效
标题翻译：手性氮杂环丁酮衍生物，以及它们作为液晶混合物中的掺杂物的用途
公开(公告)号：US5334328A
公开(公告)日：1994-08-02
申请号：US900167
申请日：1992-06-17
申请人： Gunter Scherowsky , Claas Junghans , Anke Kaltbeitzel , Rainer Wingen , Britta Michalski
发明人： Gunter Scherowsky , Claas Junghans , Anke Kaltbeitzel , Rainer Wingen , Britta Michalski
IPC分类号： C07D205/08 , C07D205/085 , C07D401/10 , C07D403/10 , C07D403/12 , C07D405/10 , C07D409/10 , C07D417/10 , C09K19/58 , G02F1/13 , G09F9/35 , C09K19/34
CPC分类号： C07D403/12 , C07D205/08 , C09K19/588
摘要： Azetidinones of the formula I ##STR1## in which, for example, R.sup.1 is an alkyl or alkenyl radical, R.sup.2 and R.sup.3 are hydrogen or an alkyl or alkenyl radical, Z is hydrogen or (pseudo)halogen, A.sup.1, A.sup.2 and A.sup.3 are a ring system, and M is a spacer group, can be added to liquid-crystal mixtures. Even when admixed in small amounts, they cause considerable twist in the cholesteric and smectic C* phase, which can compensate the pitch of another dope or produce a short S.sub.C * pitch.
摘要翻译：式I（I）的氮杂环丁酮其中例如R1是烷基或烯基，R2和R3是氢或烷基或烯基，Z是氢或（假）卤素，A1，A2和 A3是环系，M是间隔基，可以添加到液晶混合物中。即使少量混合，它们在胆甾醇和近晶C *相中引起相当大的扭曲，这可以补偿另一种涂料的间距或产生短的SC *间距。

6. 发明授权

US5227090A Ferroelectric, liquid-crystalline polymers, a process for their preparation and their use in electrooptical components 失效
标题翻译：电解液晶聚合物，其制备方法及其在电子部件中的应用
公开(公告)号：US5227090A
公开(公告)日：1993-07-13
申请号：US635134
申请日：1990-12-27
申请人： Gunter Scherowsky , Uwe Muller
发明人： Gunter Scherowsky , Uwe Muller
IPC分类号： G02F1/13 , C08F20/26 , C08F20/30 , C08F20/34 , C08F20/36 , C08F120/30 , C08F120/36 , C09K19/38
CPC分类号： C08F20/36 , C09K19/3857
摘要： Ferroelectric, liquid-crystaline polymers contain repeating units of the formula (I) ##STR1## in which the symbols have the following meanings: B=a group having at least one chiral center, of the formula ##STR2## in which R.sup.6, R.sup.7 and R.sup.8 are identical or different and are H, CH.sub.3, OCH.sub.3, F, Cl or Br, and at least one of the groups R.sup.6, R.sup.7 and R.sup.8 must be H and X=H, F, Cl or Br and R.sup.9 =H or C.sub.1 -C.sub.10 -alkyl,Y=H, CH.sub.3 or F,R.sup.1 =for example a straight-chain or branched alkyl having 1 to 16 carbon atomsa=2 to 20, preferably 6 to 12b, c, d, e and f=0 or 1 with the proviso that d+e+f=2 or 3A.sup.1, A.sup.2, A.sup.3 =for example, 1,4-phenylene or 2,5-pyridinediyl,M.sup.1, M.sup.2 and M.sup.3 =for example CO--O, or O--CO, andG=for example, a straight-chain or branched alkylene having 1 to 16 carbon atoms.
摘要翻译：铁电液晶聚合物含有式（I）＆lt; IMAGE＆gt;的重复单元，其中符号具有以下含义：B =具有至少一个手性中心的基团，具有式其中R 6，R 7和R 8相同或不同，为H，CH 3，OCH 3，F，Cl或Br，且R 6，R 7和R 8中的至少一个必须为H且X = H，F， Cl或Br，R 9 = H或C 1 -C 10烷基，Y = H，CH 3或F，R 1 =例如具有1至16个碳原子的直链或支链烷基a = 2至20，优选6至12b ，c，d，e和f = 0或1，条件是d + e + f = 2或3 A1，A2，A3 =例如1,4-亚苯基或2,5-吡啶二基，M1，M2和 M3 =例如CO-O或O-CO，G =例如具有1至16个碳原子的直链或支链亚烷基。

7. 发明授权

US5336436A Optically active oxirane derivatives, and their use as dopes in liquid-crystal mixtures 失效
标题翻译：光学活性环氧乙烷衍生物及其作为液晶混合物中的掺杂物的用途
公开(公告)号：US5336436A
公开(公告)日：1994-08-09
申请号：US902990
申请日：1992-06-22
申请人： Gunter Scherowsky , Kirsten Gruneberg
发明人： Gunter Scherowsky , Kirsten Gruneberg
IPC分类号： C07D303/23 , C07D303/24 , C07D405/12 , C09K19/58 , C09K19/34 , C07D239/02 , C07D303/12
CPC分类号： C07D405/12 , C07D303/24 , C09K19/588
摘要： Optically active oxirane derivatives containing a mesogenic molecular unit are suitable as dopes in liquid-crystal mixtures. They give liquid-crystalline ferroelectric phases having short response times and electroclinic phases having large electroclinic coefficients. A further advantage is that they induce a helix of very small pitch, so that they are also suitable for helix compensation in LC mixtures.
摘要翻译：含有介晶分子单元的光学活性环氧乙烷衍生物适合作为液晶混合物中的掺杂物。它们产生具有较短响应时间的液晶铁电相和具有大电位系数的电极相。另一个优点是它们诱导非常小间距的螺旋，使得它们也适用于LC混合物中的螺旋补偿。

8. 发明授权

US4532069A Anthraquinone dyestuffs for liquid crystal dielectrics 失效
标题翻译：蒽醌染料用于液晶电介质
公开(公告)号：US4532069A
公开(公告)日：1985-07-30
申请号：US564865
申请日：1983-12-23
申请人： Gunter Scherowsky , Michael Butow
发明人： Gunter Scherowsky , Michael Butow
IPC分类号： C09B1/10 , C09B1/06 , C09B1/503 , C09K3/34 , C09B1/02 , C09B1/04 , C09B1/50 , G02F1/13 , G09F9/35
CPC分类号： C09B1/06 , C09B1/503
摘要： New anthraquinone dyestuffs of the general formula I ##STR1## wherein Hal is a halogen atom and the two radicals R are each H or NH.sub.2 and the alkyl group has 1-8 C atoms, exhibit a high order parameter and are suitable for use as components of liquid-crystal dielectrics.
摘要翻译：新型蒽醌染料，其通式为Ⅰ，其中Hal为卤素原子，两个基团R为H或NH2，烷基为1-8个C原子，表现出高阶参数，适用于液晶电介质的成分。

9. 发明授权

US4996330A Chiral substituted tartarimides 失效
标题翻译：手性取代的酒石酰胺
公开(公告)号：US4996330A
公开(公告)日：1991-02-26
申请号：US373179
申请日：1989-06-28
申请人： Gunter Scherowsky , Peter Schreiber
发明人： Gunter Scherowsky , Peter Schreiber
IPC分类号： C07D207/40 , C07D207/416 , C09K19/54 , C09K19/58 , G02F1/137 , G02F1/139
CPC分类号： C07D207/416 , C09K19/588
摘要： Chiral substituted tartarimides, a process for their preparation and their use as doping agents in liquid-crystal mixtures.The new chiral N-substituted tartarimides which are esterified on both of the OH groups (pyrrolidinediones) are characterized by the general formula (I) ##STR1## in which the symbols have the following meaning: R.sup.2 denotes linear or branched (C.sub.1 -C.sub.16)-alkyl, it being possible for one or two non-adjacent CH.sub.2 groups to be replaced by O or S, or, if n1=1, also denotes F, Cl, Br or CN,A.sup.1 and A.sup.2 independently of one another denote 1,4-phenylene, diazine-2,5-diyl, diazine-3,6-diyl, 1,4-cyclohexylene, 1,3-dioxane-2,5-diyl, 1,3-dithiane-2,5-diyl or 1,4-bicyclo(2,2,2)octylene, it being also possible for these groups to be at least monosubstituted by F, Cl, Br, CN and/or (C.sub.1 -C.sub.12)-alkyl (if appropriate one or two non-adjacent CH.sub.2 groups are replaced by O atoms),denotes CO--O, O--CO, CH.sub.2 --CH.sub.2, OCH.sub.2, CH.sub.2 O, CH.dbd.N, N.dbd.CH or N.dbd.N,n1 and n3 independently of one another denote zero, 1 or 2, n1 and n3 not being zero at the same time,n2 denotes zero or 1, n1+n2+n3 being not more than 4, andR.sup.1 denotes linear or branched (C.sub.1 -C.sub.16)-alkyl or R.sup.3 --(A.sup.1 --).sub.n1 (B--).sub.n2 (A.sup.2 --).sub.n3, in which R.sup.3 is H or R.sup.2.These compounds are preferably used as doping agents in twistable liquid-crystal mixtures, in which they effect temperature compensation and twisting.
摘要翻译：手性取代的酒石酰胺，它们的制备方法及其作为液晶混合物中的掺杂剂的用途。在两个OH基上被酯化的新的手性N-取代的酒石酰胺（吡咯烷二酮）的特征在于通式（I）其中符号具有以下含义：R 2表示直链或支链（C1 -C 16） - 烷基，一个或两个不相邻的CH2基团可以被O或S替代，或者如果n1 = 1，也可以彼此独立地表示F，Cl，Br或CN，A1和A2 表示1,4-亚苯基，二嗪-2,5-二基，二嗪-3,6-二基，1,4-亚环己基，1,3-二恶烷-2,5-二基，1,3-二噻烷-2,5 - 二基或1,4-二环（2,2,2）亚辛基，这些基团也可以至少被F，Cl，Br，CN和/或（C 1 -C 12） - 烷基单独取代（如果合适一个或两个不相邻的CH2基团被O原子取代），表示CO-O，O-CO，CH2-CH2，OCH2，CH2O，CH = N，N = CH或N = N，n1和n3独立地为一个另一个表示零，1或2，n1和n3同时不为零，n2表示零或1，n1 + n2 + n3不大于4，R1表示线芳基或支链（C1-C16） - 烷基或R3-（A1-）n1（B-）n2（A2-）n3，其中R3是H或R2。这些化合物优选用作可扭曲液晶混合物中的掺杂剂，其中它们实现温度补偿和扭曲。

10. 发明授权

US4988459A Use of optically active oxirane-2-carboxylic acid esters as dopants in liquid-crystal mixtures, liquid-crystal mixtures containing same and novel optically active oxirane-2-carboxylic acid esters 失效
标题翻译：使用光学活性环氧乙烷-2-羧酸酯作为液晶混合物中的掺杂剂，含有它们的液晶混合物和新的光学活性环氧乙烷-2-羧酸酯
公开(公告)号：US4988459A
公开(公告)日：1991-01-29
申请号：US199101
申请日：1988-05-26
申请人： Gunter Scherowsky , Jurgen Gay , Hans-Rolf Dubal , Claus Escher , Wolfgang Hemmerling , Ingrid Muller , Dieter Ohlendorf , Rainer Wingen
发明人： Gunter Scherowsky , Jurgen Gay , Hans-Rolf Dubal , Claus Escher , Wolfgang Hemmerling , Ingrid Muller , Dieter Ohlendorf , Rainer Wingen
IPC分类号： C07D301/30 , C07D303/48 , C07D405/06 , C07D405/12 , C07D407/12 , C07D409/12 , C09K19/58 , G02F1/139 , G02F1/361 , G02F1/37
CPC分类号： C07D405/12 , C07D303/48 , C09K19/58 , C09K19/588 , G02F1/1418 , G02F1/3615 , G02F1/37
摘要： Optically active oxirane-2-carboxylic acid esters with a mesogenic molecular component suitable as dopants in liquid-crystal mixtures. They result in liquid-crystalline ferroelectric phases with short switching times and in electroclinic phases with large electroclinic coefficients. A further advantage lies in the fact that they induce a helix with a very small pitch so that they are also suitable for helix compensation in LC mixtures.
摘要翻译：具有适合作为液晶混合物中掺杂剂的介晶分子成分的光学活性环氧乙烷-2-羧酸酯。它们产生具有短切换时间的液晶铁电相和具有大电位系数的电极相。另一个优点在于它们诱导具有非常小间距的螺旋，使得它们也适用于LC混合物中的螺旋补偿。

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