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1. 发明申请

US20070129574A1 Process for preparing symmetrical and unsymmetrical N,N-dihydrocarbylhydroxylamines 失效
标题翻译：制备对称和不对称的N，N-二烃基羟胺的方法
公开(公告)号：US20070129574A1
公开(公告)日：2007-06-07
申请号：US11607626
申请日：2006-12-01
申请人： Gunter Scherhag , Lars Wittenbecher
发明人： Gunter Scherhag , Lars Wittenbecher
IPC分类号： C07C239/08
CPC分类号： C07C239/10 , C07C2601/14
摘要： A process for preparing N,N-dihydrocarbylhydroxylamines of the general formula (I) where R1, R2, R3 and R4 are selected independently from among hydrogen, aliphatic, cycloaliphatic, heteroaromatic and aromatic radicals, or R1 and R2 and/or R3 and R4 are joined to form a ring, and not more than one radical among R1, R2, R3 and R4 is hydrogen, which comprises the steps a) reaction of hydroxylamine H2NOH or a salt of hydroxylamine with a compound of the general formula (II) or (III) where R1, R2, R3 and R4 are as defined in formula (I), b) hydrogenation of the compound formed in step a) in the presence of a catalyst, c) further reaction of the compound formed in step b) with a compound of the general formula (II) or (III) and hydrogenation of the reaction mixture in the presence of a catalyst and d), if appropriate, reaction of the salt of the dihydrocarbylhydroxylamine formed in step c) with a base.
摘要翻译：一种制备通式（I）的N，N-二烃基羟胺的方法，其中R 1，R 2，R 3和R 2 > 4个独立地选自氢，脂族，脂环族，杂芳族和芳族基团，或R 1和R 2和/或R 3 R 4和R 4连接形成环，R 1，R 2，R 2，R 4， SUP> 3和R 4是氢，其包括步骤a）羟胺H 2 NOH或羟胺的盐与一般化合物的反应式（II）或（III）其中R 1，R 2，R 3和R 4均为在式（I）中定义，b）在催化剂存在下氢化步骤a）中形成的化合物，c）步骤b）中形成的化合物与通式（II）或（III ）和催化剂存在下氢化反应混合物，和d）如果a 将步骤c）中形成的二烃基羟胺的盐与碱反应合适。

2. 发明授权

US07396959B2 Process for preparing symmetrical and unsymmetrical N,N-dihydrocarbylhydroxylamines 失效
标题翻译：制备对称和不对称的N，N-二烃基羟胺的方法
公开(公告)号：US07396959B2
公开(公告)日：2008-07-08
申请号：US11607626
申请日：2006-12-01
申请人： Gunter Scherhag , Lars Wittenbecher
发明人： Gunter Scherhag , Lars Wittenbecher
IPC分类号： C07C239/12 , C07C291/00
CPC分类号： C07C239/10 , C07C2601/14
摘要： A process for preparing N,N-dihydrocarbylhydroxylamines of the general formula (I) where R1, R2, R3 and R4 are selected independently from among hydrogen, aliphatic, cycloaliphatic, heteroaromatic and aromatic radicals, or R1 and R2 and/or R3 and R4 are joined to form a ring, and not more than one radical among R1, R2, R3 and R4 is hydrogen, which comprises the steps a) reaction of hydroxylamine H2NOH or a salt of hydroxylamine with a compound of the general formula (II) or (III) where R1, R2, R3 and R4 are as defined in formula (I), b) hydrogenation of the compound formed in step a) in the presence of a catalyst, c) further reaction of the compound formed in step b) with a compound of the general formula (II) or (III) and hydrogenation of the reaction mixture in the presence of a catalyst and d), if appropriate, reaction of the salt of the dihydrocarbylhydroxylamine formed in step c) with a base.
摘要翻译：制备通式（I）的N，N-二烃基羟胺的方法，其中R 1，R 2，R 3和R 2 > 4个独立地选自氢，脂族，脂环族，杂芳族和芳族基团，或R 1和R 2和/或R 3 R 4和R 4连接形成环，R 1，R 2，R 2，R 4， SUP> 3和R 4是氢，其包括步骤a）羟胺H 2 NOH或羟胺的盐与一般化合物的反应式（II）或（III）其中R 1，R 2，R 3和R 4均为在式（I）中定义，b）在催化剂存在下氢化步骤a）中形成的化合物，c）步骤b）中形成的化合物与通式（II）或（III ）和催化剂存在下氢化反应混合物，和d）如果a 将步骤c）中形成的二烃基羟胺的盐与碱反应合适。

3. 发明申请

US20060099458A1 1, 4-Hydroquinone functionalized phosphinates and phosphonates 审中-公开
标题翻译： 1,4-对苯二酚官能化的次膦酸酯和膦酸酯
公开(公告)号：US20060099458A1
公开(公告)日：2006-05-11
申请号：US11232390
申请日：2005-09-21
申请人： Mark Hanson , Larry Timberlake , Klemens Massone , Oliver Huttenloch , Gunter Scherhag , Matthis Maase
发明人： Mark Hanson , Larry Timberlake , Klemens Massone , Oliver Huttenloch , Gunter Scherhag , Matthis Maase
IPC分类号： B32B9/04 , C08G65/28
CPC分类号： B32B5/28 , B32B15/06 , B32B15/092 , B32B15/14 , B32B15/20 , B32B25/02 , B32B27/18 , B32B27/38 , B32B27/42 , B32B2262/0269 , B32B2262/101 , B32B2262/105 , B32B2262/106 , B32B2307/3065 , B32B2457/08 , C08G59/304 , C08G59/4071 , C08G59/621 , C08J5/24 , C08J2363/00 , C08K5/53 , H05K1/0373
摘要： There is presented novel 1,4-hydroquinone derivatized phosphinates and phosphonates. The novel compositions here presented are useful as polymer curing agents and as flame retardants.
摘要翻译：提出了新的1,4-氢醌衍生的次膦酸盐和膦酸盐。本文提出的新型组合物可用作聚合物固化剂和阻燃剂。

4. 发明授权

US08519035B2 Cyclic phosphines as flame retardants 失效
标题翻译：环状膦作为阻燃剂
公开(公告)号：US08519035B2
公开(公告)日：2013-08-27
申请号：US12676495
申请日：2008-09-03
申请人： Alexander Tishkov , Gunter Scherhag , Klemens Massonne , Matthias Maase , Calvin Emanuel , Larry D. Timberlake , Mark V. Hanson
发明人： Alexander Tishkov , Gunter Scherhag , Klemens Massonne , Matthias Maase , Calvin Emanuel , Larry D. Timberlake , Mark V. Hanson
IPC分类号： C08K5/49
CPC分类号： C08K5/50 , C08G79/06 , C08K5/0066 , C08L67/02 , C08L69/00 , C08L85/02 , C08L101/00 , C08L2666/22 , C08L85/00 , C08L2666/02 , C08L2666/18
摘要： The present invention is related to the use of specific cyclic and/or polymeric aryl-phosphines as flame retardants and to a method for reducing the flammability of organic material by incorporating into the material these specific cyclic and/or polymeric phosphines. Moreover, the invention is related to a polymeric composition containing a polymeric material and at least one of the specific cyclic and/or polymeric phosphines in an amount of from 1 to 15% by weight, based on the weight of the polymeric material. The invention also relates to a composition comprising at least one of the specific cyclic and/or polymeric phosphines and at least one polymerizable monomer.
摘要翻译：本发明涉及特定的环状和/或聚合芳基膦作为阻燃剂的用途，以及通过将这些特定的环状和/或聚合膦掺入到材料中来降低有机材料的可燃性的方法。此外，本发明涉及聚合物组合物，该聚合物组合物含有基于聚合物材料重量的1至15重量％的聚合物材料和至少一种特定环和/或聚合膦。本发明还涉及包含至少一种特定的环和/或聚合膦和至少一种可聚合单体的组合物。

5. 发明申请

US20110263764A1 CYCLIC PHOSPHINES AS FLAME RETARDANTS 失效
标题翻译：循环磷酸盐作为阻燃剂
公开(公告)号：US20110263764A1
公开(公告)日：2011-10-27
申请号：US12676495
申请日：2008-09-03
申请人： Alexander Tishkov , Gunter Scherhag , Klemens Massonne , Matthias Maase , Calvin Emanuel , Larry D. Timberlake , Mark V. Hanson
发明人： Alexander Tishkov , Gunter Scherhag , Klemens Massonne , Matthias Maase , Calvin Emanuel , Larry D. Timberlake , Mark V. Hanson
IPC分类号： C08K5/49 , C07F9/50
CPC分类号： C08K5/50 , C08G79/06 , C08K5/0066 , C08L67/02 , C08L69/00 , C08L85/02 , C08L101/00 , C08L2666/22 , C08L85/00 , C08L2666/02 , C08L2666/18
摘要： The present invention is related to the use of specific cyclic and/or polymeric aryl-phosphines as flame retardants and to a method for reducing the flammability of organic material by incorporating into the material these specific cyclic and/or polymeric phosphines. Moreover, the invention is related to a polymeric composition containing a polymeric material and at least one of the specific cyclic and/or polymeric phosphines in an amount of from 1 to 15% by weight, based on the weight of the polymeric material. The invention also relates to a composition comprising at least one of the specific cyclic and/or polymeric phosphines and at least one polymerizable monomer.
摘要翻译：本发明涉及特定的环状和/或聚合芳基膦作为阻燃剂的用途，以及通过将这些特定的环状和/或聚合膦掺入到材料中来降低有机材料的可燃性的方法。此外，本发明涉及聚合物组合物，该聚合物组合物含有基于聚合物材料重量的1至15重量％的聚合物材料和至少一种特定环和/或聚合膦。本发明还涉及包含至少一种特定的环和/或聚合膦和至少一种可聚合单体的组合物。

6. 发明授权

US06822110B2 CaO-catalyzed preparation of isophoronenitrile 失效
标题翻译： CaO催化制备异佛尔酮腈
公开(公告)号：US06822110B2
公开(公告)日：2004-11-23
申请号：US10701513
申请日：2003-11-06
申请人： Dagmar Pascale Kunsmann-Keitel , Gerold Braun , Ingo Münster , Klaus Mundinger , Gunter Scherhag , Wolfgang Siegel
发明人： Dagmar Pascale Kunsmann-Keitel , Gerold Braun , Ingo Münster , Klaus Mundinger , Gunter Scherhag , Wolfgang Siegel
IPC分类号： C07C25300
CPC分类号： C07C253/10 , C07C255/46
摘要： The present invention describes a process for preparing isophoronenitrile by adding HCN to isophorone. The catalyst used is CaO which has a BET surface area of >1.5 m2/g. The use of such a catalyst achieves high yields and selectivities.
摘要翻译：本发明描述了通过向异佛尔酮中加入HCN制备异佛尔酮腈的方法。所使用的催化剂是BET表面积> 1.5m 2 / g的CaO。这种催化剂的使用实现了高产率和选择性。

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