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1. 发明授权

US5066365A Process for the isolation of vinyl acetate by distillation 失效
标题翻译：通过蒸馏分离乙酸乙烯酯的方法
公开(公告)号：US5066365A
公开(公告)日：1991-11-19
申请号：US597572
申请日：1990-10-15
申请人： Gunter Roscher , Karl-Heinz Schmidt , Klaus Eichler , Peter Horstermann , Reinhard Gradl , Horst Langner
发明人： Gunter Roscher , Karl-Heinz Schmidt , Klaus Eichler , Peter Horstermann , Reinhard Gradl , Horst Langner
IPC分类号： B01J31/04 , B01D3/00 , B01D3/14 , C07B61/00 , C07C67/05 , C07C67/055 , C07C67/54 , C07C67/58 , C07C69/14 , C07C69/15
CPC分类号： C07C67/52 , C07C67/055 , C07C67/54 , Y10S203/10 , Y10S203/20
摘要： The invention relates to a process for the isolation of vinyl acetate which involves not combining the bottom product of the recylced gas washings with the water-saturated vinyl acetate but rather introducing it to further multiple distillation columns from the gas mixture formed in the reaction of ethylene with acetic acid and oxygen over catalysts containing palladium or palladium compounds in the gas phase.
摘要翻译：本发明涉及一种用于分离乙酸乙烯酯的方法，该方法不包括将再生气体洗涤液的底部产物与水饱和的乙酸乙烯酯混合，而是将其从乙烯反应中形成的气体混合物引入另外的多个蒸馏塔在含有钯或钯化合物的气相中的催化剂上用乙酸和氧气。

2. 发明授权

US4353783A Process for separating water from mixtures thereof with vinyl acetate and acetic acid 失效
标题翻译：从乙酸乙烯酯和乙酸与其混合物中分离水的方法
公开(公告)号：US4353783A
公开(公告)日：1982-10-12
申请号：US201752
申请日：1980-10-29
申请人： Gunter Roscher , Karl-Heinz Schmidt , Horst Langner , Hermann Neu , Aladar Lienerth , Dominik Dempf , Klaus Kaiser
发明人： Gunter Roscher , Karl-Heinz Schmidt , Horst Langner , Hermann Neu , Aladar Lienerth , Dominik Dempf , Klaus Kaiser
IPC分类号： C07C67/055 , C07C67/54 , C07C69/15 , B01D3/36
CPC分类号： C07C67/055 , C07C67/54 , B01J2219/1942
摘要： Process for separating water from a gas mixture, obtained in the manufacture of vinyl acetate by reacting ethylene with acetic acid and oxygen in contact with catalysts containing palladium or palladium compounds in the gaseous phase said gas mixture consisting essentially of acetic acid, vinyl acetate, water, carbon dioxide and ethylene, wherein(a) the gas mixture leaving the reaction zone is condensed to give a condensate containing the major portion of acetic acid, vinyl acetate and water and(b) an acetic acid solution containing the residual amount of vinyl acetate and water being prepared by absorption of the non-condensed gas in acetic acid, is characterized in that(c) the condensate obtained in step (a) and the solution obtained in step (b) are introduced separately from each other into the same distillation column, the feeding point of the condensate being above the feeding point of the solution, the water is distilled off at the head of said column as azeotrope together with the vinyl acetate and(d) the water phase is removed from the distillate separating into a water phase and a vinyl acetate phase.
摘要翻译：从气相混合物中分离水的方法，所述气体混合物是通过使乙烯与乙酸和氧气在气相中与含有钯或钯化合物的催化剂接触而在乙酸乙烯酯的制备中获得的，所述气体混合物主要由乙酸，乙酸乙烯酯，水，二氧化碳和乙烯，其中（a）离开反应区的气体混合物被冷凝，得到含有主要部分的乙酸，乙酸乙烯酯和水的冷凝物和（b）含有残留量的乙酸乙烯酯的乙酸溶液和通过在乙酸中吸收非冷凝气体制备的水，其特征在于（c）将步骤（a）中获得的冷凝物和步骤（b）中获得的溶液彼此分开引入相同的蒸馏柱，冷凝水的进料点高于溶液的进料点，水在所述塔的头部被蒸馏出来，作为共沸物一起 h乙酸乙烯酯和（d）从分离成水相和乙酸乙烯酯相的馏出物中除去水相。

3. 发明授权

US4409396A Process for the manufacture of unsaturated carboxylic acid esters 失效
标题翻译：制备不饱和羧酸酯的方法
公开(公告)号：US4409396A
公开(公告)日：1983-10-11
申请号：US299019
申请日：1981-09-03
申请人： Dominik Dempf , Ludwig Schmidhammer , Gerhard Dummer , Gunter Roscher , Karl-Heinz Schmidt , Ernst Selbertinger , Rudolf Strasser
发明人： Dominik Dempf , Ludwig Schmidhammer , Gerhard Dummer , Gunter Roscher , Karl-Heinz Schmidt , Ernst Selbertinger , Rudolf Strasser
IPC分类号： C07C69/025 , B01J31/00 , C07B61/00 , C07C67/055 , C07C69/145 , C07C69/15 , C07C69/155
CPC分类号： C07C67/055
摘要： The invention relates to a process for the manufacture of unsaturated carboxylic acid esters by the reaction of olefins or cyclo-olefins with oxygen and carboxylic acids in the gaseous phase, in the presence of a catalyst which contains elements of the subsidiary group VIII of the periodic system and/or compounds thereof, and an alkali metal acetate, at temperatures of from 100.degree. to 250.degree. C. and pressures of from 0.5 to 21 bar absolute, wherein from 1 to 8000 parts per million (by weight), calculated on the carboxylic acid used, of organic chlorine compounds are added to the reaction mixture.
摘要翻译：本发明涉及一种通过烯烃或环烯烃与气相中的氧和羧酸反应制备不饱和羧酸酯的方法，该催化剂含有周期性的第VIII族的元素的催化剂系统和/或其化合物和碱金属乙酸盐，其温度为100-250℃，压力为0.5-21巴绝对值，其中按重量百分数计算为1至8000份（按重量计）使用羧酸的有机氯化合物加入到反应混合物中。

4. 发明申请

US20110250270A1 Compositions containing a capillary-active system with application-relevant diffferentiability and their use 审中-公开
标题翻译：包含具有应用相关差异性的毛细管活性系统及其用途的组合物
公开(公告)号：US20110250270A1
公开(公告)日：2011-10-13
申请号：US13134769
申请日：2011-06-16
申请人： Rolf D. Beutler , Karl-Heinz Schmidt , Bettina Funke , Kirstin Becker
发明人： Rolf D. Beutler , Karl-Heinz Schmidt , Bettina Funke , Kirstin Becker
IPC分类号： A61K9/28 , A61P3/02 , A61K31/51 , A61P17/18 , A61K36/87 , A61K36/55
CPC分类号： A61Q5/00 , A23L33/10 , A23L33/115 , A23L33/15 , A23L33/175 , A23V2002/00 , A61K8/02 , A61K31/20 , A61K36/16 , A61K36/896 , A61K45/06 , A61K2300/00 , A23V2250/0606 , A23V2250/704 , A23V2250/314 , A23V2250/1882
摘要： A composition that has a capillary-active system C optionally containing a capillary activator system CA consisting of drugs that increase blood flow, stabilize the vascular wall, and/or dilate the blood vessels; and/or a capillary-protective system CP comprising drugs for endothelial stabilization, lipoprotein protection, and for stabilization of leukocytes/platelets; and/or a capillary energy supply system CE comprising redox systems and cofactors in energy provision and energy carriers. This system C is combined with a selective action system S. The compositions are useful, systemically or enterally, especially for the selective control, for example, of structural changes, functional disturbances of the target organs in question (hair, skin, cerebrum, skeleton, muscles, gastrointestinal tract, eyes) as supplements (food supplements, supplementary balanced diet, dietary components), or pharmaceutical agents.
摘要翻译：一种组合物，其具有任选地含有毛细管活化剂系统CA的毛细管活性系统C C，其由增加血流量，稳定血管壁和/或扩张血管的药物组成; 和/或包含用于内皮稳定，脂蛋白保护和用于白细胞/血小板稳定的药物的毛细管保护系统CP; 和/或包含能量提供和能量载体中的氧化还原体系和辅因子的毛细管能量供应系统CE。该系统C与选择性作用系统S组合。组合物有用，系统地或肠内，特别是用于选择性控制，例如结构变化，所涉及的目标器官的功能紊乱（毛发，皮肤，大脑，骨骼，肌肉，胃肠道，眼睛）作为补充剂（食品补充剂，补充均衡饮食，膳食成分）或药剂。

5. 发明授权

US5381102A Device with a current divider for controlling adjustment of signals from sensors 失效
标题翻译：具有用于控制传感器信号调节的电流分配器的装置
公开(公告)号：US5381102A
公开(公告)日：1995-01-10
申请号：US243423
申请日：1994-05-16
申请人： Karl-Heinz Schmidt
发明人： Karl-Heinz Schmidt
IPC分类号： G01D3/00 , F02B3/06 , G01D3/028 , G01D18/00 , G01N27/04 , G01N27/417 , G01R27/26
CPC分类号： G01D18/00 , G01N27/4175 , F02B3/06
摘要： A device for adjusting sensor signals, and, in particular, signals supplied to a sensor for detecting an operating parameter of a motor vehicle having an internal combustion engine. The device has adjustment elements and a current divider, which includes at least one adjustable resistor and a second resistor, coupled in series with the sensor.
摘要翻译：一种用于调节传感器信号的装置，特别是提供给用于检测具有内燃机的机动车辆的操作参数的传感器的信号。该装置具有调节元件和分流器，其包括与传感器串联耦合的至少一个可调电阻器和第二电阻器。

6. 发明授权

US4059028A Multiple speed hub with coaster brake 失效
标题翻译：多速轮毂带过山车刹车
公开(公告)号：US4059028A
公开(公告)日：1977-11-22
申请号：US670521
申请日：1976-03-25
申请人： Horst Schulz , Josef Flosser , Reinhard Kessler , Karl-Heinz Schmidt , Ewald Eisend , Erich Hild , Karl-Heinz Loffler , Werner Steuer
发明人： Horst Schulz , Josef Flosser , Reinhard Kessler , Karl-Heinz Schmidt , Ewald Eisend , Erich Hild , Karl-Heinz Loffler , Werner Steuer
IPC分类号： B62M11/16 , F16H3/44
CPC分类号： B62M11/16
摘要： In a multiple speed hub with coaster brake for a bicycle, unintentional jamming of the brake is prevented by the provision of novel pawl clutches interposed between a planetary transmission and the hub shell. The recesses of pawl carriers pivotally receiving the clutch pawls are circumferentially oversized to permit limited circumferential movement of each pawl between a driving position and an idling position.
摘要翻译：在用于自行车的具有过山车制动器的多速轮毂中，通过设置插入在行星传动装置和轮毂壳之间的新型棘爪离合器来防止制动器的意外卡住。枢转地接收离合器棘爪的棘爪托架的凹部周向地大尺寸，以允许每个棘爪在驱动位置和怠速位置之间的周向运动受限。

7. 发明授权

US4043938A Methods for reactivating zeolites 失效
标题翻译：沸石再生方法
公开(公告)号：US4043938A
公开(公告)日：1977-08-23
申请号：US546244
申请日：1975-02-03
申请人： Hans-Heinrich Reif , Klaus Wehner , Jurgen Welker , Karl-Heinz Schmidt , Waltraud Schnick , Lutz Widmann , Otto Schicker , Gunter Seidel , Karsten Kalb , Wolfhard Dollase , Helmut Furtig , Werner Hose , Wolfgang Roscher , Udo Hadicke , Herbert Knoll , Rudiger Seidel , Gunter Nemitz , Edith Sturmer , Manfred Kaiser
发明人： Hans-Heinrich Reif , Klaus Wehner , Jurgen Welker , Karl-Heinz Schmidt , Waltraud Schnick , Lutz Widmann , Otto Schicker , Gunter Seidel , Karsten Kalb , Wolfhard Dollase , Helmut Furtig , Werner Hose , Wolfgang Roscher , Udo Hadicke , Herbert Knoll , Rudiger Seidel , Gunter Nemitz , Edith Sturmer , Manfred Kaiser
IPC分类号： B01J20/34 , C10G25/12 , B01J29/38 , C07C7/12
CPC分类号： B01J20/3408 , C10G25/12
摘要： A zeolite of type 5A, which has been used to separate normal paraffins from a hydrocarbon mixture containing normal paraffins by bringing the hydrocarbon mixture into contact with the zeolite whereby the zeolite absorbs the normal paraffins and then desorbing the normal paraffins from the zeolite by contacting the zeolite with water-containing ammonia vapour, is reactivated by first contacting the zeolite with at least one of water, aqueous solutions and water-containing gases at a temperature below 350.degree. C and then heating the zeolite to a temperature above 350.degree. C.
摘要翻译： 5A型沸石，其已经用于通过使烃混合物与沸石接触而使含有正构链烷烃的烃混合物分离出正构烷烃，由此沸石吸收正构烷烃，然后通过使沸石接触来解吸正常链烷烃具有含水氨蒸气的沸石通过首先在低于350℃的温度下将沸石与水，水溶液和含水气体中的至少一种接触，然后将沸石加热至高于350℃的温度来再活化。

8. 发明授权

US5396609A Method of protecting programs and data in a computer against unauthorized access and modification by monitoring address regions 失效
标题翻译：通过监控地址区域来保护计算机中的程序和数据免遭未经授权的访问和修改的方法
公开(公告)号：US5396609A
公开(公告)日：1995-03-07
申请号：US466960
申请日：1990-01-18
申请人： Karl-Heinz Schmidt , Georg Menache , Wilhelm Waidelich
发明人： Karl-Heinz Schmidt , Georg Menache , Wilhelm Waidelich
IPC分类号： G06F12/14 , G11C7/00 , H04L9/32
CPC分类号： G06F12/1491
摘要： A method of protecting programs and data in computers against unauthorized access and modifications employs a programmable hardware circuit to monitor memory regions of a computer. The memory regions are divided into different access levels, and the circuit is programmed to permit access only to predetermined regions. If an unauthorized access is attempted by a program, an address corresponding to the program location initiating the unauthorized access is detected and the program is stopped. This ensures that the procedures for protecting the operating system cannot be circumvented to gain unauthorized access to data of any type. After programming of the circuit is completed, the programming cannot be changed except by actuation of a hardware switch or by re-starting the computer. Removal of the circuit will cause short circuits, thus making it impossible to shut the circuit off without being detected.
摘要翻译：一种在计算机中保护程序和数据以防止未经授权的访问和修改的方法使用可编程硬件电路来监视计算机的存储器区域。存储区域被分成不同的访问级别，并且该电路被编程为仅允许访问预定区域。如果程序尝试未经授权的访问，则检测到与启动未授权访问的程序位置相对应的地址，并停止程序。这确保了不能避免操作系统的保护程序，以获得对任何类型的数据的未经授权的访问。在电路编程完成后，除了硬件开关的驱动或重新启动计算机外，无法改变编程。电路的去除会导致短路，从而使得不能在不检测到电路的情况下关闭电路。

9. 发明授权

US5240149A Closure cap 失效
标题翻译：封闭帽
公开(公告)号：US5240149A
公开(公告)日：1993-08-31
申请号：US698838
申请日：1991-05-10
申请人： Karl-Heinz Schmidt
发明人： Karl-Heinz Schmidt
IPC分类号： B05B11/04 , B65D47/20
CPC分类号： B05B11/043 , B65D47/2081 , Y10T137/2544 , Y10T137/7843
摘要： The invention relates to a closure cap (5) having a dispensing opening (6) for containers with flexible walls, which can be pressed together by hand for the dispensing of spray product which is in connection with the dispensing opening (6) by means of a dip tube (7). Upstream of the dispensing opening (6) is an outlet valve (8), which is open when there is positive pressure in the container, whereas an air-admitting opening (9) is assigned an air-admitting valve (10), which is open when there is negative pressure in the container. By virtue of the outlet valve (8) upstream of the dispensing opening (6), the readmission of air to the container and consequently the risk of sucking in through the dispensing opening (6) substances contaminating the container content is prevented. Maintaining the quality of the spray product in the container is ensured by virtue of the air-admitting opening (9), separate from the dispensing opening (6), and the air-admitting valve (10), which opens only when there is negative pressure in the container.
摘要翻译：本发明涉及一种具有用于具有柔性壁的容器的分配开口（6）的封闭盖（5），所述分配开口（6）可用手压在一起，以通过借助于分配开口（6）与分配开口汲取管（7）。分配开口（6）的上游是当容器中存在正压时打开的出口阀（8），而空气进入开口（9）被分配有空气进口阀（10）容器内有负压时打开。通过在分配开口（6）上游的出口阀（8），防止空气再次进入容器，并且因此通过分配开口（6）吸入的风险被阻止污染容器内容物质。通过与分配开口（6）分开的空气进入开口（9）和仅在存在负离子的情况下打开的进气阀（10）来确保在容器中保持喷射产品的质量容器压力

10. 发明授权

US4928176A Electronic camera-processing circuit for automatically tracking particles which move across an optical image 失效
标题翻译：用于自动跟踪移动穿过光学图像的颗粒的电子照相机处理电路
公开(公告)号：US4928176A
公开(公告)日：1990-05-22
申请号：US178645
申请日：1988-04-07
申请人： Karl-Heinz Schmidt , Wilhelm Waidelich
发明人： Karl-Heinz Schmidt , Wilhelm Waidelich
IPC分类号： G01P3/36
CPC分类号： G01P3/36
摘要： An electronic camera combined with processing circuitry for observing the movement of particles in a sedimentation cell or the like, tracking movement of selected particles, and determining their velocity and/or velocity distribution. The electronic circuit includes an electronic masking circuit for enabling the selection and tracking of individual particles in the image received by the camera.
摘要翻译：一种与用于观察沉降池等中的颗粒运动的处理电路结合的电子照相机，跟踪选定颗粒的运动，并确定其速度和/或速度分布。电子电路包括用于使得能够选择和跟踪由相机接收的图像中的各个颗粒的电子屏蔽电路。

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