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1. 发明授权

US4539391A Continuous hydrolytic preparation of polylactams 失效
标题翻译：多聚内酰胺的连续水解制备
公开(公告)号：US4539391A
公开(公告)日：1985-09-03
申请号：US581711
申请日：1984-02-21
申请人： Gunter Pipper , Rainer Theysohn , Franz Zahradnik
发明人： Gunter Pipper , Rainer Theysohn , Franz Zahradnik
IPC分类号： C08G69/00 , C08G69/16
CPC分类号： C08G69/16
摘要： Polylactams are prepared continuously by a process in which a lactam containing from 1 to 25% by weight of water is heated in a prepolymerization zone under a pressure of from 1 to 10 bar at from 220.degree. to 280.degree. C. for 1 to 10 minutes, water being vaporized at the same time, with the proviso that the degree of conversion on emergence from the prepolymerization zone is not less than 85%, the prepolymer and the vapor are separated continuously, and the prepolymer is passed into a polymerization zone and is polymerized further under superatmospheric pressure at from 240.degree. to 290.degree. C.
摘要翻译：连续制备聚内酰胺，其中将含有1至25重量％的水的内酰胺在预聚合区中在220-280℃的1至10巴的压力下加热1至10分钟，同时蒸发水，条件是预聚合区出现的转化度不低于85％，预聚物和蒸气连续分离，预聚物进入聚合区，并且是在240〜290℃的超大气压下进一步聚合。

2. 发明授权

US4092284A Flameproof nylon molding compositions 失效
标题翻译：防火尼龙成型组合物
公开(公告)号：US4092284A
公开(公告)日：1978-05-30
申请号：US731126
申请日：1976-10-12
申请人： Rainer Theysohn , Rolf Wurmb , Wolfgang Seydl , Franz Zahradnik
发明人： Rainer Theysohn , Rolf Wurmb , Wolfgang Seydl , Franz Zahradnik
IPC分类号： C08K3/32 , C08K3/02 , C08K3/34 , C08L77/00 , C08L91/00
CPC分类号： C08K3/02 , C08K3/34
摘要： Filled nylon molding compositions of increased rigidity containing red phosphorus as a flameproofing agent and talc or mica as a filler. They may be converted to moldings which are used, above all, in the electrical industry.
摘要翻译：含有红磷作为阻燃剂的刚性增加的填充尼龙成型组合物和滑石或云母作为填料。它们可以转化为首先在电气工业中使用的模制品。

3. 发明授权

US4537949A Continuous preparation of nylon with diamine recycling 失效
标题翻译：连续制备尼龙与二胺回收
公开(公告)号：US4537949A
公开(公告)日：1985-08-27
申请号：US620563
申请日：1984-06-14
申请人： Franz Schmidt , Gunter Pipper , Josef G. Floss , Franz Zahradnik
发明人： Franz Schmidt , Gunter Pipper , Josef G. Floss , Franz Zahradnik
IPC分类号： C08G69/26 , C08G69/00 , C08G69/28 , C08L77/00
CPC分类号： C08G69/28
摘要： Nylons are prepared by a continuous process in which, in an evaporator zone, an aqueous solution of a salt of a dicarboxylic acid of 6 to 18 carbon atoms and a diamine of 6 to 18 carbon atoms is heated to 250.degree.-300.degree. C. under superatmospheric pressure, with simultaneous vaporization of water and formation of a prepolymer, the prepolymer and the vapors are separated continuously, the vapors are rectified and the entrained diamines are recycled, and the prepolymer is fed to a polycondensation zone and subjected to polycondensation under superatmospheric pressure of from 1 to 10 bar and at from 250.degree. to 300.degree. C., wherein the aqueous salt solution is heated under superatmospheric pressure of from 1 to 10 bar during a residence time of less than 60 seconds, with the proviso that, on leaving the evaporator zone, the degree of conversion is not less than 93% and the water content of the prepolymer is not more than 7% by weight.
摘要翻译：尼龙通过连续方法制备，其中在蒸发器区中将6至18个碳原子的二羧酸盐和6至18个碳原子的二胺的水溶液加热至250-300℃。在超大气压下，随着水的蒸发和预聚物的形成，预聚物和蒸气被连续分离，蒸气被精馏，夹带的二胺被再循环，并将预聚物进料到缩聚区，并在超大气压下进行缩聚压力为1至10巴，在250至300℃，其中在低于60秒的停留时间内，盐水溶液在1至10巴的超大气压下加热，条件是在离开蒸发区，转化度不低于93％，预聚物的含水量不超过7重量％。

4. 发明授权

US4837264A Polyamide compositions containing alkyl orthotitanate or dialkyltin dilaurate 失效
标题翻译：含有原钛酸烷基酯或二月桂酸二烷基锡的聚酰胺组合物
公开(公告)号：US4837264A
公开(公告)日：1989-06-06
申请号：US140794
申请日：1988-01-05
申请人： Franz Zahradnik , Karlheinz Ulmerich , Graham E. McKee , Horst Reimann , Richard Pflueger , Rainer Theysohn
发明人： Franz Zahradnik , Karlheinz Ulmerich , Graham E. McKee , Horst Reimann , Richard Pflueger , Rainer Theysohn
IPC分类号： C08K3/22 , C08K5/057 , C08K5/09 , C08K5/098 , C08K5/56 , C08K5/57 , C08L33/04 , C08L51/04 , C08L51/06 , C08L77/00
CPC分类号： C08L51/04 , C08K3/22 , C08K5/057 , C08K5/098 , C08K5/57 , C08L77/00
摘要： High-impact polyamide molding compositions contain as essential components(X) from 40 to 98% by weight, based on (X)+(Y), of a thermoplastic polyamide,(Y) from 2 to 60% by weight, based on (X)+(Y), of a rubberlike polymer which contains, as copolymerized units, an acrylic or methacrylic ester or an unsaturated carboxylic acid,(Z) from 0.001 to 2% by weight, based on (X)+(Y), of a metal compound selected from the group consisting of(Z.sub.1) salts of divalent, trivalent or tetravalent metals with C.sub.2 -C.sub.4 -carboxylic acids,(Z.sub.2) oxides of germanium or antimony and(Z.sub.3) alkyl orthotitanates and dialkyltin dilaurates.
摘要翻译：高抗冲聚酰胺成型组合物含有基于（X）+（Y）为40〜98重量％的热塑性聚酰胺的基本成分（X），（Y）为2〜60重量％作为共聚单元含有基于（X）+（Y）的0.001至2重量％的丙烯酸或甲基丙烯酸酯或不饱和羧酸（Z）的橡胶状聚合物，X）+（Y）的选自（Z1）二价，三价或四价金属的二价，三价或四价金属的金属化合物与C 2 -C 4羧酸，（Z 2）锗或锑的氧化物和（Z 3）烷基钛酸钛和二烷基锡二月桂酸酯的金属化合物。

5. 发明授权

US4574131A Preparation of high-impact nylon molding materials 失效
标题翻译：高冲击尼龙成型材料的制备
公开(公告)号：US4574131A
公开(公告)日：1986-03-04
申请号：US645813
申请日：1984-08-30
申请人： Rainer Theysohn , Hans G. Dorst , Graham E. McKee , Rolf Steinberger , Walter Ziegler , Franz Zahradnik
发明人： Rainer Theysohn , Hans G. Dorst , Graham E. McKee , Rolf Steinberger , Walter Ziegler , Franz Zahradnik
IPC分类号： C08K9/06 , C08J3/20 , C08L23/00 , C08L33/00 , C08L33/02 , C08L51/00 , C08L51/02 , C08L51/06 , C08L75/00 , C08L75/04 , C08L77/00 , C08L101/00 , C08K3/34
CPC分类号： C08L77/00
摘要： A process for the preparation of high-impact nylon molding materials, containing 30-88% by weight of a thermoplastic nylon, 10-50% by weight of an organosilane-coated silicate reinforcing filler, 0.1-5% by weight of a polyurethane ionomer, 2-30% by weight of a carboxyl-containing thermoplastic elastomer and, where appropriate, effective amounts of conventional additives, by mixing the silicate filler, coated with an organosilane and a polyurethane ionomer, with the thermoplastic elastomer and the nylon at above the melting point of the nylon, wherein, in a first stage, the silicate filler coated with an organosilane and a polyurethane ionomer is mixed with the nylon at above the melting point of the latter, and in a second stage the thermoplastic elastomer is finely dispersed in the filler-containing nylon at above the melting point of the latter.
摘要翻译：一种用于制备高冲击尼龙成型材料的方法，其包含30-88重量％的热塑性尼龙，10-50重量％的有机硅烷涂覆的硅酸盐增强填料，0.1-5重量％的聚氨酯离聚物，2-30重量％的含羧基的热塑性弹性体，并且在合适的情况下，通过将涂覆有机硅烷和聚氨酯离子交联聚合物的硅酸盐填料与热塑性弹性体和尼龙混合，在适当的情况下，尼龙的熔点，其中，在第一阶段中，涂覆有有机硅烷和聚氨酯离子交联聚合物的硅酸盐填料在尼龙的熔点之上与尼龙混合，第二阶段将热塑性弹性体细分散在含有填料的尼龙在其熔点以上。

6. 发明授权

US4791027A Nylon granules having an outer shell 失效
标题翻译：具有外壳的尼龙颗粒
公开(公告)号：US4791027A
公开(公告)日：1988-12-13
申请号：US155521
申请日：1988-02-12
申请人： Horst Reimann , Franz Zahradnik , Hans-Peter Weiss
发明人： Horst Reimann , Franz Zahradnik , Hans-Peter Weiss
IPC分类号： C08J3/12 , C08J3/20 , C08K5/00 , C08K5/09 , C08K5/098 , C08K5/10 , C08K5/101 , C08K7/02 , C08L77/00 , B32B27/34
CPC分类号： C08K5/098 , C08J3/203 , C08K5/101 , C08J2377/00 , Y10T428/2998
摘要： Nylon granules are based on(A) from 20 to 99.99% by weight of a nylon,(B) from 0 to 60% by weight of fibrous or particulate fillers or a mixture thereof and(C) from 0 to 40% by weight of an impact modifying rubber and contain(D) from 0.01 to 1% by weight of an outer shell consisting of a mixture of(d.sub.1) zinc stearate or aluminum stearate or a mixture thereof,(d.sub.2) calcium stearate and(d.sub.3) an ester of an aliphatic carboxylic acid of 6 to 24 carbon atoms with an aliphatic saturated alcohol of 2 to 24 carbon atoms.
摘要翻译：尼龙颗粒基于（A）20至99.99重量％的尼龙，（B）0至60重量％的纤维或颗粒填料或其混合物，和（C）0至40重量％抗冲击改性橡胶，含有（d）0.01重量％至1重量％的由（d1）硬脂酸锌或硬脂酸铝或其混合物的混合物组成的外壳，（d2）硬脂酸钙和（d3） 6至24个碳原子的脂族羧酸与2至24个碳原子的脂族饱和醇。

7. 发明授权

US4053457A Manufacture of polyamides 失效
标题翻译：聚氨酯的制造
公开(公告)号：US4053457A
公开(公告)日：1977-10-11
申请号：US644960
申请日：1975-12-29
申请人： Claus Cordes , Franz Zahradnik
发明人： Claus Cordes , Franz Zahradnik
IPC分类号： C08G69/00 , C08G69/16 , C08G69/46
CPC分类号： C08G69/16 , C08G69/46
摘要： A process for the manufacture of polyamides from .epsilon.-caprolactam and/or other polyamide-forming starting compounds by polymerization and subsequent extraction of the polymer. The extract containing solvent, monomer and oligomers is concentrated in the absence of atmospheric oxygen, the surfaces which come into contact with the extract being made of materials which are inert under the conditions of the concentration process, and the concentrate, without further purification or separation, is polymerized by itself or together with other polyamide-forming starting compounds.

8. 发明授权

US5052123A Drying and heating of polyamide granules 失效
标题翻译：干燥和加热聚酰胺颗粒
公开(公告)号：US5052123A
公开(公告)日：1991-10-01
申请号：US547304
申请日：1990-07-03
申请人： Klaus J. Tischendorf , Manfred Liebscher , Farid Rizk , Franz Zahradnik
发明人： Klaus J. Tischendorf , Manfred Liebscher , Farid Rizk , Franz Zahradnik
IPC分类号： C08G69/46 , B29B13/06 , B29K77/00 , C08G69/00
CPC分类号： B29B13/065
摘要： Polyamide granules are dried and heated by feeding a suspension of granules in water into a sieve (1), where the bulk of the water is removed, and then into a tower dryer (10), where they are deposited in bed form and then freed of the remaining water while moving in plug flow under the force of gravity with a counter-current inert gas stream at from 70.degree. to 200.degree. C. The tower dryer possesses an inlet at the top (11) and outlet at the bottom (34) for the granules and also feed lines (20, 22, 31) for the inert gas. To achieve a uniform degree of drying of the granules, the inert gas is divided on entry into the tower dryer at a point between the drying zone and the heating zone into a stream which flows radially inward into the bed of granules on the one hand and a stream which flows radially inward and outward on the other. In this way the inert gas is distributed particularly uniformly and the granules are dryable in a very short drying zone down to a water content of 0.0001 kg of water/kg of polymer. The lower, conically tapered area of the tower dryer--bin 30--ensures a uniform rate of descent of the granules and hence a uniform solid-phase condensation with a favorable molecular weight distribution. The tower dryer (10) is followed by a fluidized bed cooler (41) in which the granules are cooled with air to
摘要翻译：将聚酰胺颗粒干燥并通过将颗粒在水中的悬浮液加入到筛子（1）中，其中大部分水被除去，然后进入塔式干燥器（10），在塔式干燥器（10）中以床形式沉积然后释放的剩余水，同时在重力作用下用70度到200度的逆流惰性气流在活塞流中移动。塔式干燥器具有顶部（11）和底部出口（34）的入口）和用于惰性气体的进料管线（20,22,31）。为了实现颗粒的均匀干燥程度，惰性气体在干燥区域和加热区域之间的一段入口处分成塔式干燥器，一方面径向向内流入颗粒床，另一端径向向外流动的气流。以这种方式，惰性气体分布特别均匀，并且颗粒在非常短的干燥区域中可干燥至0.0001kg水/ kg聚合物的含水量。塔式干燥器箱30的下锥形锥形区域确保了颗粒均匀的下降速率，因此具有均匀的固相冷凝并具有良好的分子量分布。塔式干燥器（10）之后是流化床冷却器（41），其中颗粒用空气冷却至<50℃。

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