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1. 发明授权

US4416808A Bis-betaine-amine oxides, process for their preparation, and cleaning agents containing them 失效
标题翻译：双甜菜碱 - 胺氧化物，其制备方法和含有它们的清洁剂
公开(公告)号：US4416808A
公开(公告)日：1983-11-22
申请号：US439732
申请日：1982-11-08
申请人： Gunter Blaschke , Alwin Reng , Jochen M. Quack
发明人： Gunter Blaschke , Alwin Reng , Jochen M. Quack
IPC分类号： A61K8/00 , A61K8/40 , A61K8/41 , A61K8/44 , A61Q5/02 , A61Q19/10 , C07C291/04 , C11D1/75 , C11D1/90 , C07C79/16 , C11D7/32
CPC分类号： C11D1/90 , A61K8/40 , A61K8/44 , A61Q19/10 , A61Q5/02
摘要： Bis-betaine-amine oxides of the formula ##STR1## in which R is a saturated or an olefinically unsaturated hydrocarbon radical having 1 to 3 double bonds and 8 to 22 carbon atoms,n.sup.1 and n.sup.2 each is an integer of from 2 to 3, n.sup.1 and n.sup.2 optionally being identical or different,m.sup.1 and m.sup.2 each is an integer of from 1 to 4, m.sup.1 and m.sup.2 optionally being identical or different, anda, b, c and d, being identical or different, each is a number of from 1 to 5, with the proviso that the sum (a+b+c+d) is at most 10.The compounds are prepared from primary amines of the formula RNH.sub.2, by dicyanoalkylation, hydrogenation, ethoxylation, reaction with alkali metal salts of .omega.-halocarboxylic acids, and subsequent oxidation with hydrogen peroxide. They are surfactants of mild action and suitable for formulating cosmetic and industrial cleaning agents.
摘要翻译：式（I）的双甜菜碱 - 胺氧化物其中R是具有1至3个双键和8至22个碳原子的饱和或不饱和烃基，n1和n2各自为2的整数至3，n1和n2任选相同或不同，m1和m2各自为1至4的整数，m1和m2任选相同或不同，a，b，c和d相同或不同，分别为数量为1至5，条件是（a + b + c + d）之和至多为10.该化合物由式RNH2的伯胺通过二氰基烷基化，氢化，乙氧基化，与碱反应制备 ω-卤代羧酸的金属盐，随后用过氧化氢氧化。它们是温和作用的表面活性剂，适用于配制化妆品和工业清洁剂。

2. 发明授权

US4415488A Triamine-trioxides, a process for their preparation, and cleaning agents containing these compounds 失效
标题翻译：三胺三氧化物，其制备方法和含有这些化合物的清洁剂
公开(公告)号：US4415488A
公开(公告)日：1983-11-15
申请号：US439731
申请日：1982-11-08
申请人： Gunter Blaschke , Alwin Reng , Jochen M. Quack
发明人： Gunter Blaschke , Alwin Reng , Jochen M. Quack
IPC分类号： A61K8/00 , A61K8/40 , A61K8/41 , A61K8/45 , A61Q5/00 , A61Q5/02 , A61Q5/04 , A61Q5/10 , A61Q11/00 , A61Q19/10 , C07C291/04 , C11D1/75 , C07C79/16 , C11D7/32
CPC分类号： C11D1/75 , A61K8/40 , A61K8/45 , A61Q19/10 , A61Q5/02 , C07C291/04
摘要： Triamine-trioxides of the formula ##STR1## in which R denotes a saturated or an olefinically unsaturated hydrocarbon radical which has 1 to 3 double bonds and 8 to 22 carbon atoms, n.sup.1 and n.sup.2 represent an integer from 2 to 3, and n.sup.1 and n.sup.2 can be identical or different, and a, b, c and d, which are identical or different, each is a number from 1 to 5, with the proviso that the sum (a+b+c+d) should be at most 10.The compounds are prepared from primary amines of the formula RNH.sub.2 by dicyanoalkylation, hydrogenation, ethoxylation and oxidation with hydrogen peroxide. They are suitable for formulating industrial and also cosmetic cleaning agents.
摘要翻译：其中R表示饱和或具有1至3个双键和8至22个碳原子的烯属不饱和烃基，其中n1和n2表示2至3的整数，n1和n2的三元胺三氧化物可以相同或不同，a，b，c和d相同或不同，各自为1至5的数，条件是（a + b + c + d）之和应至多为10 该化合物由式RNH2的伯胺通过二氰基烷基化，氢化，乙氧基化和用过氧化氢氧化制备。它们适用于制备工业和化妆品清洁剂。

3. 发明授权

US4415487A Bis-betaines, a process for their preparation, and cleaning agents containing these compounds 失效
标题翻译：双甜菜碱，其制备方法和含有这些化合物的清洁剂
公开(公告)号：US4415487A
公开(公告)日：1983-11-15
申请号：US439729
申请日：1982-11-08
申请人： Gunter Blaschke , Alwin Reng , Jochen M. Quack
发明人： Gunter Blaschke , Alwin Reng , Jochen M. Quack
IPC分类号： A61K8/00 , A61K8/41 , A61Q5/02 , A61Q19/10 , C07C67/00 , C07C227/00 , C07C227/06 , C07C229/16 , C11D1/90 , C07C79/16 , C11D7/32
CPC分类号： A61K8/44 , A61K8/45 , A61Q19/10 , A61Q5/02 , C07C255/00 , C11D1/90
摘要： Bis-betaines of the formula ##STR1## in which R denotes a saturated or an olefinically unsaturated hydrocarbon radical which has 1 to 3 double bonds and 8 to 22 carbon atoms,n.sup.1 and n.sup.2 represent an integer from 2 to 3, and n.sup.1 and n.sup.2 can be identical or different,m.sup.1 and m.sup.2 represent an integer from 1 to 4, and m.sup.1 and m.sup.2 can be identical or different, anda, b, c and d, which are identical or different, each is a number from 1 to 5, but the sum (a+b+c+d) should be at most 10.The compounds are prepared from primary amines of the formula RNH.sub.2, by dicyanoalkylation, hydrogenation, ethoxylation and reaction with alkali metal salts of .omega.-halogenocarboxylic acids. They are suitable for formluating cosmetic and industrial cleaning agents.
摘要翻译：其中R表示饱和或具有1至3个双键和8至22个碳原子的烯属不饱和烃基，其中n1和n2表示2至3的整数，n1和n2的双可以相同或不同，m1和m2表示1〜4的整数，m1和m2可以相同或不同，a，b，c和d相同或不同，分别为1〜5的数，但总和（a + b + c + d）应至多为10.化合物由式RNH2的伯胺通过二氰基烷基化，氢化，乙氧基化和与ω-卤代羧酸的碱金属盐反应制备。它们适用于化妆品和工业清洁剂的成膜。

4. 发明授权

US4588522A Betaine-amine oxides, a process for their preparation and their use as surfactants 失效
标题翻译：甜菜碱 - 氧化胺，其制备方法及其作为表面活性剂的用途
公开(公告)号：US4588522A
公开(公告)日：1986-05-13
申请号：US484528
申请日：1983-04-13
申请人： Gunter Blaschke , Alwin Reng , Jochen M. Quack
发明人： Gunter Blaschke , Alwin Reng , Jochen M. Quack
IPC分类号： B01F17/18 , C07C291/04 , C11D1/75 , C11D1/90 , C11D1/42 , C07C101/24 , C07C135/02 , C11D1/18
CPC分类号： C11D1/90 , C07C291/04 , C11D1/75
摘要： Betaine-amine oxides of the formula ##STR1## in which R denotes alkyl, alkenyl or hydroxyalkyl, each of which has 8-22 carbon atoms, R.sup.1 denotes hydrogen or methyl, R.sup.2 denotes ethylene, propylene or 2-hydroxypropylene, R.sup.3, R.sup.4 and R.sup.5 can be identical or different and denote C.sub.1 -C.sub.3 -alkyl or a group of the formula ##STR2## or R.sup.3 denotes a group of the formula --R.sup.2 --BR.sup.4 R.sup.5, X denotes a direct bond or a group of the formula--CO--,A and B denote a group of the formulae ##STR3## it being necessary for at least one amine oxide group and at least one betaine group to be present, a denotes 0 or 1, b denotes 1, 2 or 3, n denotes a number from 0 to 10 and m denotes 1, 2 or 3. These compounds are obtained by partially quaternizing the parent polyamines with the alkali metal salt of an .omega.-halogenocarboxylic acid and then oxidizing the non-quaternized nitrogen atoms. These betaine-amine oxides are suitable for use as surfactants in cleansing agents.
摘要翻译：其中R表示烷基，烯基或羟烷基，其中每一个具有8-22个碳原子，R1表示氢或甲基，R2表示乙烯，丙烯或2-羟基亚丙基，R3，R4和 R 5可以相同或不同，表示C 1 -C 3 - 烷基或式“基团”或R 3表示式-R 2 -BR 4 R 5的基团，X表示直接键或式-CO-的基团， A和B表示至少一个氧化胺基团和至少一个甜菜碱基团所需的一组式（IMAGE），a表示0或1，b表示1,2或3，n表示数 0至10，m表示1,2或3.这些化合物通过将母体多胺与ω-卤代羧酸的碱金属盐部分季铵化，然后氧化未季铵化的氮原子而获得。这些甜菜碱 - 胺氧化物适合用作清洁剂中的表面活性剂。

5. 发明授权

US4620976A Pearlescent dispersion with good flow properties and a low surfactant content 失效
标题翻译：具有良好流动性和低表面活性剂含量的珠光分散体
公开(公告)号：US4620976A
公开(公告)日：1986-11-04
申请号：US741606
申请日：1985-06-05
申请人： Jochen M. Quack , Alwin Reng , Werner Skrypzak , Walter Kunz
发明人： Jochen M. Quack , Alwin Reng , Werner Skrypzak , Walter Kunz
IPC分类号： C11D3/40 , A61K8/00 , A61K8/20 , A61K8/23 , A61K8/37 , A61K8/39 , A61K8/40 , A61K8/41 , A61K8/42 , A61K8/46 , A61Q5/02 , A61Q19/10 , B01F17/10 , B01F17/38 , B01F17/42 , B01J13/00 , C09B67/46 , C09K3/00 , C11D1/28 , C11D1/52 , C11D1/66 , C11D1/75 , C11D1/86 , C11D3/33 , C11D17/00 , A61K7/06 , A61K7/08
CPC分类号： C11D17/00 , A61K8/39 , A61K8/40 , A61K8/42 , A61K8/466 , A61Q19/10 , A61Q5/02 , C11D1/523 , C11D1/86 , C11D3/0089 , A61K2800/596 , C11D1/28 , C11D1/667 , C11D1/75
摘要： Pearlescent dispersions consisting of a fatty acid glycol ester, a fatty acid alkanolamide, one or more surfactants of the formulae ##STR1## in which the individual symbols of these formulae have the meanings given in the description, salts and water in the amount to make up to 100%. Pearlescent dispersions based on these surfactants have the advantage that they already have good flow properties at temperatures below 20.degree. C.
摘要翻译：由脂肪酸乙二醇酯，脂肪酸链烷醇酰胺，一种或多种下式的表面活性剂组成的珠光分散体，其中这些式的各符号具有说明书中给出的含义，盐和水的含量可达100％。基于这些表面活性剂的珠光分散体具有的优点是它们在低于20℃的温度下已具有良好的流动性能。

6. 发明授权

US4853430A Method of increasing viscosity with fatty acid-modified polyesters and highly viscous compositions obtained thereby 失效
标题翻译：用脂肪酸改性的聚酯和由此获得的高粘性组合物增加粘度的方法
公开(公告)号：US4853430A
公开(公告)日：1989-08-01
申请号：US140914
申请日：1987-12-30
申请人： Herbert Stuhler , Alwin Reng , Werner Skrypzak , Jochen M. Quack
发明人： Herbert Stuhler , Alwin Reng , Werner Skrypzak , Jochen M. Quack
IPC分类号： A61K8/00 , A61K8/02 , A61K8/37 , A61K8/39 , A61K8/85 , A61K9/00 , A61K47/14 , A61K47/34 , A61Q5/02 , A61Q5/06 , A61Q19/10 , C08G63/48 , C08G63/66 , C08G65/32 , C11D3/37
CPC分类号： C08G63/48 , A61K47/14 , A61K8/85 , A61K9/0014 , A61Q19/10 , A61Q5/02 , A61Q5/06 , C08G63/66 , C11D3/3715 , Y10S514/844
摘要： Fatty acid-modified polysters composed of polyalkylene oxide and dimerized fatty acids, of the formula ##STR1## in which R is C.sub.8 -C.sub.22 -alkyl or C.sub.8 -C.sub.22 -alkenyl, preferably C.sub.12 -C.sub.18 -alkyl, R.sup.1 is the alkyl skeleton of a dimerized fatty acid having 22 to 42, preferably 34 carbon atoms, A is --C.sub.2 H.sub.4 -- or --C.sub.3 H.sub.6 --, n is a number from 1 to 5, preferably 1 to 3, and x is a number from 20 to 150, preferably 23 to 140. These are prepared by simultaneous reaction of the underlying dimerized fatty acid, polyalkylene oxide and fatty acid. The polyesters obtained are used as agents for increasing the viscosity of surfactant-containing cosmetic, pharmaceutical and industrial products.
摘要翻译：由式为“IMAGE”的聚环氧烷和二聚脂肪酸组成的脂肪酸改性聚酯，其中R是C 8 -C 22烷基或C 8 -C 22烯基，优选C 12 -C 18烷基，R 1是烷基骨架具有22至42个，优选34个碳原子的二聚脂肪酸，A为-C 2 H 4 - 或-C 3 H 6 - ，n为1至5，优选1至3的数，x为20至150，优选23至这些通过下列二聚脂肪酸，聚环氧烷和脂肪酸的同时反应来制备。获得的聚酯用作增加含表面活性剂的化妆品，药物和工业产品的粘度的试剂。

7. 发明授权

US4606916A Quaternary oxalkylated polyesters, a process for their preparation and their use 失效
标题翻译：第四纪烷基化聚酯，其制备方法及其用途
公开(公告)号：US4606916A
公开(公告)日：1986-08-19
申请号：US680982
申请日：1984-12-12
申请人： Manfred Hofinger , Alwin Reng , Jochen M. Quack
发明人： Manfred Hofinger , Alwin Reng , Jochen M. Quack
IPC分类号： C07C219/04 , A61K8/85 , A61Q5/00 , A61Q5/02 , A61Q5/06 , A61Q5/12 , C08G63/685 , C08G63/91 , A61K7/06 , A61K7/08 , C07C67/08 , C07C69/34
CPC分类号： A61Q5/12 , A61K8/85 , C08G63/6854 , C08G63/914 , A61K2800/5426 , A61Q5/00 , A61Q5/02 , A61Q5/06
摘要： Novel quaternary oxalkylated polyesters prepared from oxalkylated fatty amines by polycondensation with a dicarboxylic acid and subsequent reaction with an alkylene oxide and a carboxylic acid or a mineral acid or with a quaternizing agent such as methyl chloride, are described. The compounds are suitable for use as cosmetic active compounds, in particular for cosmetic care of the hair.
摘要翻译：通过与二羧酸缩聚并随后与环氧烷和羧酸或无机酸或季铵化剂如氯甲烷反应，由烷氧基烷基化脂肪胺制备的新型四烷基烷基化聚酯被描述。该化合物适合用作美容活性化合物，特别是用于头发的美容护理。

8. 发明授权

US4134970A Quaternary ammonium compounds and their use in hair care compositions 失效
标题翻译：季铵化合物及其在护发组合物中的应用
公开(公告)号：US4134970A
公开(公告)日：1979-01-16
申请号：US807403
申请日：1977-06-17
申请人： Hans L. Panke , Willi Steckelberg , Jochen M. Quack , Alwin Reng
发明人： Hans L. Panke , Willi Steckelberg , Jochen M. Quack , Alwin Reng
IPC分类号： A61K8/45 , A61Q5/02 , C08G65/334 , C11D1/62 , C11D3/00 , D06M13/46 , A61K7/06 , A61K7/08 , C07C87/30 , C07C141/02
CPC分类号： D06M13/46 , A61K8/45 , A61Q5/02 , C08G65/3344 , C11D1/62 , C11D3/001
摘要： Quaternary ammonium compounds of the formula I ##STR1## wherein R.sub.1 is C.sub.8 -C.sub.24 alkyl, cyclohexyl or aryl, X and Y are hydrogen or methyl, only one X or Y being methyl at the same time, n is an integer of from 1 to 20, R.sup.2 and R.sup.3 are lower alkyl or benzyl and A is an anion. These compounds are made by common alkylation reaction of the corresponding non-quaternized compounds. They are used as surfactants, especially in hair care compositions.
摘要翻译：式I的季铵化合物其中R1是C8-C24烷基，环己基或芳基，X和Y是氢或甲基，同时只有一个X或Y是甲基，n是1〜 20，R2和R3是低级烷基或苄基，A是阴离子。这些化合物通过相应的非季铵化合物的共同烷基化反应制备。它们用作表面活性剂，特别是在护发组合物中。

9. 发明授权

US4781918A Cosmetic agents for hair and skin treatment 失效
标题翻译：用于头发和皮肤处理的化妆品
公开(公告)号：US4781918A
公开(公告)日：1988-11-01
申请号：US106058
申请日：1987-10-07
申请人： Manfred Hofinger , Alwin Reng , Jochen M. Quack
发明人： Manfred Hofinger , Alwin Reng , Jochen M. Quack
IPC分类号： A61K8/30 , A61K8/00 , A61K8/40 , A61K8/45 , A61Q5/00 , A61Q5/12 , A61Q19/00 , A61K7/06 , A61K7/09
CPC分类号： A61K8/45 , A61Q19/00 , A61Q5/00 , A61Q5/12
摘要： An agent for treatment of hair and skin, containing a quarternary ammonium compound of the formula ##STR1## in which R.sub.1 and R.sub.2 may be identical or different and denote C.sub.8 -C.sub.22 -alkyl or C.sub.8 -C.sub.22 -alkenyl, R.sub.3 denotes C.sub.1 -C.sub.3 -alkyl, x denotes a number from 1 to 3, and A.sup..crclbar. denotes the anion of C.sub.2 -C.sub.6 -carboxylic acid, which may contain 1 to 3 hydroxyl groups, or the hydrogen phosphate anion.
摘要翻译：用于治疗毛发和皮肤的试剂，其含有式（Ia）的季铵化合物，其中R 1和R 2可以相同或不同，表示C 8 -C 22 - 烷基或C 8 -C 22 - 链烯基，R 3表示C 1 -C 3 - 烷基，x表示1〜3的数，A（ - ）表示可含有1〜3个羟基的C 2 -C 6羧酸的阴离子或磷酸氢根阴离子。

10. 发明授权

US4654163A Nonionic fluent pearl luster dispersions 失效
标题翻译：非离子流利珍珠光泽分散体
公开(公告)号：US4654163A
公开(公告)日：1987-03-31
申请号：US716047
申请日：1985-03-26
申请人： Jochen M. Quack , Alwin Reng , Werner Skrypzak , Walter Kunz
发明人： Jochen M. Quack , Alwin Reng , Werner Skrypzak , Walter Kunz
IPC分类号： C11D1/722 , A61K8/00 , A61K8/37 , A61K8/39 , A61K8/42 , A61Q5/02 , A61Q19/10 , B01J13/00 , C11D1/52 , C11D1/66 , C11D1/72 , C11D1/74 , C11D1/825 , C11D1/835 , C11D3/40 , C11D17/00 , A61K7/06
CPC分类号： A61K8/375 , A61K8/39 , A61K8/42 , A61Q5/02 , C11D1/523 , C11D1/835 , C11D1/8355 , C11D17/00 , C11D3/0089 , C11D1/667 , C11D1/721 , C11D1/722 , C11D1/74
摘要： Pearl luster dispersions comprising a fatty acid glycol ester, a fatty acid alkanolamide, a nonionic surfactant of the formulaR.sub.5 --O--(A--O).sub.m --(B--O).sub.n --R.sub.6where R.sub.5 denotes C.sub.8 -C.sub.30 -alkyl or alkenyl, R.sub.6 denotes hydrogen or a group of the formula --CH.sub.2 O--R.sub.7, R.sub.7 denotes C.sub.1 -C.sub.10 -alkyl or alkenyl, A and B, independently of each other, denote a group of the formula --C.sub.2 H.sub.4 -- or --C.sub.3 H.sub.6 --, and m and n each denote a number from 1 to 30, and water to 100%.Pearl luster dispersions based on this nonionic surfactant have the advantage that they are fluent even at temperatures below 20.degree. C.
摘要翻译：包含脂肪酸二醇酯，脂肪酸链烷醇酰胺，式R 5 -O-（AO）m - （BO）n -R 6的非离子表面活性剂，其中R 5表示C 8 -C 30 - 烷基或链烯基的珍珠光泽分散体，R6表示氢或式-CH 2 O-R 7的基团，R 7表示C 1 -C 10烷基或烯基，A和B彼此独立地表示式-C 2 H 4 - 或-C 3 H 6 - 的基团，m和n各自表示数字从1到30，水到100％。基于该非离子表面活性剂的珍珠光泽分散体的优点是即使在低于20℃的温度下它们也是流利的。

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